Safety Data Sheet

Issue date 01-April-2017 (DD-MMM-YYYY)

Revision date 15-March-2021 (DD-MMM-YYYY)
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING

Product Identifier DT New GSL ( Special Color ) and New Soyatone ( Process Color )
UN number Not applicable

Recommended Use Printing ink (oil-based)

Restrictions on use No information available

Details of the supplier of the safety data sheet

Company Name Importer / Supplier

PT.SAKATA INX INDONESIA
Graha Indochem Lt. 7,Jl. Pantai Indah Kapuk Boulevard SSB / E,
Jakarta 14470, Indonesia
Emergency Telephone Number +62-21-5961878
Email address sakata_inx@cbn.net.id

2. Hazards Identification
GHS - Classification
Skin sensitization Category 1A
Reproductive Toxicity Category 2
Specific target organ toxicity (repeated exposure) Category 1
Acute aquatic toxicity Category 3
Chronic aquatic toxicity Category 3

Pictogram including precautionary statements

Label Elements
Pictogram

Signal Word DANGER

hazard statements
MAY BE HARMFUL IF SWALLOWED
Causes serious eye irritation
May cause allergy or asthma symptoms or breathing difficulties if inhaled
May cause an allergic skin reaction
Suspected of damaging fertility or the unborn child
Causes damage to organs through prolonged or repeated exposure
Harmful to aquatic life with long lasting effects

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precautionary statements
Precautionary Statements - Prevention
Obtain special instructions before use
Do not handle until all safety precautions have been read and understood
Use personal protective equipment as required
Wash face, hands and any exposed skin thoroughly after handling
In case of inadequate ventilation wear respiratory protection
Contaminated work clothing should not be allowed out of the workplace
Wear protective gloves
Do not breathe dust/fume/gas/mist/vapors/spray
Do not eat, drink or smoke when using this product
Avoid release to the environment
Precautionary Statements - Response
IF exposed or concerned: Get medical advice/attention
Specific treatment
eye
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing
If eye irritation persists: Get medical advice/attention
skin
IF ON SKIN: Wash with plenty of soap and water
If skin irritation or rash occurs: Get medical advice/attention
Wash contaminated clothing before reuse
inhalation
IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing
If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician
Precautionary Statements - Storage
Store locked up
Precautionary Statements - Disposal
Dispose of contents/container to an approved waste disposal plant

Hazards not otherwise classified (HNOC)

3. COMPOSITION/INFORMATION ON INGREDIENTS
Pure substance/mixture mixture

Impurities and/or Stabilizing Additives which Contribute to Not applicable

the Classification

Chemical Additions No information available

Ingredients contributing to the classification of the mixture, etc.

Chemical name Synonyms CAS No weight-%
Petroleum hydrocarbon (mineral oil) - - 10-15
Soybean oil - 8001-22-7 20-30
Carbon black / Organic Pigments - - 0-30
2-Naphthalenecarboxylic acid, - 5281-04-9 0-20
3-hydroxy-4-[(4-methyl-2-sulfophenyl)azo]-,
calcium salt (1:1)
Titanium dioxide - 13463-67-7 0-<5
Micro crystalline waxes (solid paraffin) 0-<5
Stoddard solvent 8052-41-3 0-<1
Rosin - - 0-<1
Hexanoic acid, 2-ethyl-, cobalt(2+) salt - 136-52-7 0-<1
2-Ethyl-1,3-hexanediol - 94-96-2 0-<1
Naphtha, petroleum, hydrodesulfurized heavy - 64742-82-1 0-<1
2,6-Di-tert-butyl-p-cresol - 128-37-0 0-<1

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4. First aid measures

FIRST AID MEASURES

General advice Do not breathe dust/fume/gas/mist/vapors/spray

Do not get in eyes, on skin, or on clothing

inhalation If breathing is irregular or stopped, administer artificial respiration

Seek immediate medical attention/advice
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing
Call a POISON CENTER or doctor/physician if you feel unwell

Skin contact Wash off immediately with soap and plenty of water while removing all contaminated
clothes and shoes
Get medical attention if irritation develops and persists

Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes

INGESTION Get medical attention

Clean mouth with water

Most important symptoms and effects, both acute and delayed

Indication of any immediate medical attention and special treatment needed

5. Fire-fighting measures
Suitable extinguishing media

Suitable extinguishing media
CO2, dry chemical, dry sand, alcohol-resistant foam, mist of alkali salts water
Move containers from fire area if you can do it without risk
Use extinguishing measures that are appropriate to local circumstances and the
surrounding environment
Remove combustible materials from their surroundings immediately

Specific extinguishing methods

Special exposure hazards in a fire

Special protective equipment for Use personal protective equipment as required

fire-fighters In the event of fire and/or explosion do not breathe fumes
Special protective equipment for fire-fighters

Flammable properties May re-ignite after fire is extinguished

Flammable/combustible material

Unsuitable extinguishing media Do not use a solid water stream as it may scatter and spread fire

Special Extinguishing Media Cool container with water spray

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6. Accidental release measures

Personal precautions

Personal precautions Stay upwind

Evacuate personnel to safe areas
ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area)
Use personal protective equipment as required
In case of fire: Stop leak if safe to do so
Do not touch damaged containers or spilled material unless wearing appropriate protective
clothing
Ensure adequate ventilation, especially in confined areas
Wash thoroughly after handling

Environmental Precautions

Environmental Precautions Dispose of contents/container to an approved waste disposal plant

Do not flush into surface water or sanitary sewer system
Avoid release to the environment
Collect spillage

Methods and material for containment and cleaning up

Methods for Containment Prevent further leakage or spillage if safe to do so

Methods for cleaning up Use personal protective equipment as required

Take up mechanically, placing in appropriate containers for disposal
Clean contaminated surface thoroughly
Soak up with inert absorbent material
Dam up

OTHER INFORMATION Ventilate the area

7. Handling and Storage

Precautions for safe handling

Advice on safe handling Use personal protection recommended in Section 8

Use only in well-ventilated areas
Avoid contact with skin, eyes or clothing
Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea
Do not breathe dust/fume/gas/mist/vapors/spray
Wash contaminated clothing before reuse
Wash hands thoroughly and gargle after handling
Burn or dispose of the wiping cloths used to clean up the product at once

Conditions for safe storage, including any incompatibilities

Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place
Keep away from heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric
motors and static electricity)
The product shall be stored in the original containers/vessels

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8. Exposure Controls/Personal Protection

Control parameters
Chemical name Indonesia ACGIH TLV OSHA PEL Japan
Carbon black TWA: 3.5 mg/m3 TWA: 3 mg/m3 inhalable TWA: 3.5 mg/m3 4 mg/m3 (Class 2 Dust,total
fraction dust)
1 mg/m3 (Class 2
Dust,respirable dust)
2,6-Di-tert-butyl-p-cresol TWA: 10 mg/m3 TWA: 2 mg/m3 inhalable - -
fraction and vapor
Micro crystalline waxes (solid TWA: 2 mg/m3 - - -
paraffin)
Titanium dioxide TWA: 10 mg/m3 TWA: 10 mg/m3 TWA: 15 mg/m3 total dust 0.3 mg/m3 (Provisional)
Stoddard solvent TWA: 100 ppm TWA: 100 ppm TWA: 500 ppm -
TWA: 525 mg/m3 TWA: 2900 mg/m3

Engineering controls Ensure adequate ventilation, especially in confined areas

Showers
Eyewash stations
Ventilation systems
Personal protective equipment (PPE)

Respiratory protection In case of mist, spray or aerosol exposure wear suitable personal respiratory protection and
protective suit

Hand protection Wear protective gloves

9. Physical and Chemical Properties

Physical state Paste
appearance No information available
color colored
ODR oily odor
odor threshold no data available
pH no data available
Melting point/freezing point no data available
Flammable nature No information available
Boiling point/boiling range no data available
Flash Point ＞90℃
Evaporation Rate no data available
Combustibility >= fire point 60 °C
explosive limits
Explosive upper limit no data available
Explosive lower limit no data available
Vapor pressure No information available
Vapor density no data available
Specific gravity 0.9-1.2(25℃)
solubility(ies)
Water solubility Immiscible in water
Organic Solvent Solubility soluble in oil
Partition coefficient no data available
Autoignition temperature no data available
decomposition temperature no data available
Kinematic viscosity no data available

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Chemical name Boiling point °C density Vapor pressure Vapor density Flash Point Autoignition
temperature
2-Naphthalenecarboxylic - 1.65 g/cm3 - - >400 °C >450 °C
acid,
3-hydroxy-4-[(4-methyl-2-s
ulfophenyl)azo]-, calcium
salt (1:1)
2,6-Di-tert-butyl-p-cresol 265 °C 1.03 g/cm3 at 0.013 hPa at 20 °C 7.6 127 °C closed cup 470 °C
20 °C
2-Ethyl-1,3-hexanediol 244.2 °C 760 - <0.01 mmHg at - 127 °C open cup 360 °C
mmHg 20 °C
Naphtha, petroleum, - 0.782 - 0.799 1.5 - 4 hPa at - >23 °C closed cup 240 °C 1013 hPa
hydrodesulfurized heavy g/cm3 at 15 °C 20 °C IP 170
Stoddard solvent 150 - 210 °C - 2 mmHg at 20 °C 5 38 - 60 °C 226 - 260 °C
Carbon black - 1.86 g/cm3 - - - -
Titanium dioxide 2500 - 3000 °C 3.9 - 4.1 g/cm3 - - - -

10. Stability and Reactivity

reactivity No information available

stability Stable under normal conditions

Will gradually oxidize and polymerize in air

Possibility of hazardous reactions None under normal processing

Conditions to Avoid Rags and dusters that were used to wipe off the material may be spontaneously
combustible

Materials to avoid

Hazardous decomposition May emit toxic fumes under fire conditions

products

11. Toxicological Information

Information on toxicological effects

skin corrosion/irritation No information available

Serious eye damage/eye irritation No information available

sensitization No information available

Germ Cell Mutagenicity No information available

Carcinogenicity
Chemical name IARC
2,6-Di-tert-butyl-p-cresol Group 3
Carbon black Group 2B
Titanium dioxide Group 2B
Hexanoic acid, 2-ethyl-, cobalt(2+) salt Group 2B
IARC Note:
Group 1:Carcinogenic to humans, Group 2A:Probably carcinogenic to humans, Group 2B:Possibly carcinogenic to humans,
Group 3:Not classifiable as to carcinogenicity in humans

Reproductive Toxicity No information available

STOT - single exposure No information available

STOT - repeated exposure No information available
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Information on likely routes of exposure

inhalation Reference to other sections; 4

INGESTION Reference to other sections; 4
Skin contact Reference to other sections; 4
Eye Contact Reference to other sections; 4

Symptoms related to the physical, chemical and toxicological characteristics

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Symptoms No information available

developmental toxicity No information available

Neurological Effects No information available

Aspiration Hazard No information available

Numerical measures of toxicity

Product Information

Unknown acute toxicity 43.4%(Sample/Magenta INK) of the mixture consists of ingredient(s) of unknown toxicity

The following values are calculated based on chapter 3.1 of the GHS document

Oral LD50 3,465 mg/kg (Sample/Magenta INK)

dermal LD50 8,662 mg/kg (Sample/Magenta INK)
inhalation
mist 18.71 mg/l (Sample/Magenta INK)
Component Information
Chemical name Oral LD50 dermal LD50 Inhalation LC50 Classification Japan GHS
according to Classification / Other
Regulation (EC) No.
1272/2008 [CLP]
ANNEX VI Table3.1 /
Other
petroleum hydrocarbon - - - Asp. Tox. 1 (H304) Asp. Tox. 1
(mineral oil)
Carbon black - - - STOT RE 1 (H372) STOT RE 1
Self-heat. 1
Self-heat. 2
Titanium dioxide > 10000 mg/kg - - Eye Irrit. 2B (H320) Eye Irrit. 2B
( Rat )
Micro crystalline waxes (solid - - - Eye Irrit. 2B (H320) Eye Irrit. 2B
paraffin) STOT SE 3 (H335) STOT SE 3
2-Naphthalenecarboxylic acid, 1000 mg/kg ( Rat ) > 2500 mg/kg ( Rat ) > 5.4 mg/L ( Rat ) 4 h Acute Tox. 4 (H302) -
3-hydroxy-4-[(4-methyl-2-sulfo Acute Tox. 5 (H313)
phenyl)azo]-, calcium salt Acute Tox. 5 (H333)
(1:1)
rosin - - - Acute Tox. 4 (H332) Acute Tox. Inh. (D/M)
Eye Irrit. 2B (H320) 4
Resp. Sens. 1 (H334) Eye Irrit. 2B
Skin Sens. 1 (H317) Resp. Sens. 1
Aquatic Acute 2 Skin Sens. 1
(H401) Aquatic Acute 2
Aquatic Chronic 2 Aquatic Chronic 2
(H411)

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Stoddard solvent - - - STOT RE 1 (H372) Aquatic Chronic 1

Asp. Tox. 1 (H304) Skin Irrit. 2
Skin Irrit. 2 (H315) Aquatic Acute 1
STOT SE 3 (H335) Asp. Tox. 1
STOT SE 3 (H336) STOT RE 2
Aquatic Acute 1 STOT SE 3
(H400) Flam. Liq. 1
Aquatic Chronic 1 Flam. Liq. 2
(H410) Flam. Liq. 3
2-Ethyl-1,3-hexanediol 1400 mg/kg ( Rat ) - - Eye Dam. 1 (H318) Repr. 2
Acute Tox. 4 (H302) Eye Irrit. 2A
Repr. 2 (H361)
Hexanoic acid, 2-ethyl-, - - - Eye Irrit. 2A (H319) Eye Irrit. 2A
cobalt(2+) salt Skin Sens. 1A (H317) Skin Sens. 1A
Repr. 2 (H361) Repr. 2
Aquatic Acute 1 Aquatic Acute 1
(H400) Aquatic Chronic 3
Aquatic Chronic 3
(H412)
2,6-Di-tert-butyl-p-cresol 890 mg/kg ( Rat ) > 2000 mg/kg ( Rat ) - Acute Tox. 4 (H302) Aquatic Chronic 1
Acute Tox. 4 (H312) Repr. 2
Eye Irrit. 2B (H320) Eye Irrit. 2B
Repr. 2 (H361) Aquatic Acute 1
STOT SE 1 (H370) STOT RE 2
STOT RE 2 (H373) STOT SE 1
Aquatic Acute 1
(H400)
Aquatic Chronic 1
(H410)
Naphtha, petroleum, > 5000 mg/kg ( Rat ) > 3160 mg/kg - STOT RE 1 (H372) Skin Irrit. 2
hydrodesulfurized heavy ( Rabbit ) Asp. Tox. 1 (H304) STOT SE 3
Acute Tox. 5 (H303) STOT RE 2
Acute Tox. 5 (H313) Asp. Tox. 1
Skin Irrit. 2 (H315) Aquatic Acute 1
STOT SE 3 (H335) Aquatic Chronic 1
STOT SE 3 (H336)
Aquatic Acute 1
(H400)
Aquatic Chronic 1
(H410)
GHS/CLP Classification Note:
Acute Tox. Der. :Acute toxicity - Dermal, Acute Tox. Inh. (D/M) :Acute toxicity - Inhalation - Dusts and Mists, Acute Tox. Inh.
(Gas) :Acute toxicity - Inhalation - Gases, Acute Tox. Inh. (Vap) :Acute toxicity - Inhalation - Vapours, Acute Tox. Oral :Acute
toxicity - Oral, Aquatic Acute :Acute Hazardous to the aquatic environment, Aquatic Chronic :Chronic Hazardous to the aquatic
environment, Asp. Tox. :Aspiration hazard, Carc. :Carcinogenicity, Expl. :Explosives, Eye Dam. :Serious eye damage, Eye
Irrit. :Eye irritation, Flam. Gas :Flammable gases (including chemically unstable gases), Flam. Liq. :Flammable liquids, Flam.
Solid :Flammable solids, Lact. :Effects on or via lactation, Met. Corr. :Corrosive to metals, Muta. :Germ cell mutagenicity,
Org. Perox. :Organic peroxides, Ox. Gas :Oxidizing gases, Ox. Liq. :Oxidizing liquids, Ox. Sol. :Oxidizing solids, Press.
Gas :Gases under pressure, Pyr. Liq. :Pyrophoric liquids, Pyr. Sol. :Pyrophoric solids, Repr. :Reproductive toxicity, Resp.
Sens. :Respiratory sensitization, Self-heat. :Self-heating substances and mixtures, Self-react. :Self-reactive substances and
mixtures, Skin Corr. :Skin corrosion, Skin Irrit. :Skin irritation, Skin Sens. :Skin sensitization, STOT RE :Specific target organ
toxicity – Repeated exposure, STOT SE :Specific target organ toxicity – Single exposure, Water-react. :Substances and
mixtures which, in contact with water emit flammable gases

12. Ecological Information

ecotoxicity

100% (Sample/Magenta INK) of the mixture consists of component(s) of unknown hazards to the aquatic environment

Chemical name Partition coefficient

2,6-Di-tert-butyl-p-cresol 4.17

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13. Disposal Considerations

Waste from Residues / Unused Should not be released into the environment
Products Disposal should be in accordance with applicable regional, national and local laws and
regulations

Contaminated packaging Improper disposal or reuse of this container may be dangerous and illegal

OTHER INFORMATION Store in a tightly sealed drum to prevent the spillage of the content

14. Transport Information

Containers/vessels must be leakage-free. Loading must be done to prevent containers from
falling, dropping down and being damaged
Take necessary steps to prevent collapse

UN number Not applicable

Packing group Not applicable
ERG Code 133
Proper shipping name Not applicable

IMDG Not regulated

UN number Not applicable
Packing group Not applicable

ICAO (air) Not regulated

UN number Not applicable
Packing group Not applicable

IATA Not regulated

UN number Not applicable
Packing group Not applicable

DOT Not regulated

UN number Not applicable
Packing group Not applicable

TDG Not regulated

UN number Not applicable
Packing group Not applicable

MEX Not regulated

UN number Not applicable
Packing group Not applicable

RID Not regulated

UN number Not applicable
Packing group Not applicable

ADR Not regulated

UN number Not applicable
Packing group Not applicable

ADN Not regulated

UN number Not applicable
Packing group Not applicable

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15. Regulatory information

Safety, health and environmental regulations/legislation specific for the substance or
mixture

Regulation on Management of Hazardous and Poisonous Not applicable

Substances

Decision on Chemical Control at work place Not applicable

Regulation on Procurement, Distribution and Control of Not applicable

Hazardous

Regulation on the Control of Production and Use of Not applicable

Hazardous Materials for Industry

16. Other information

Issue date 01-April-2017 (DD-MMM-YYYY)
Revision date 15-March-2021 (DD-MMM-YYYY)
Revision note Added soyban oil as composition / ingredient information
Annotation Soybean oil is also used in waxes and auxiliaries. Therefore, the ink composition contains
20% or more of soybean oil component.
Key literature references and LOLI Database (ChemADVISOR, Inc.)
sources for data

Disclaimer
The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief
at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing,
storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process, unless specified in the text

End of Safety Data Sheet

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