Phenol, Synthetic 1.0.1.0

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Revision date: 11/23/2021

SAFETY DATA SHEET Version: 1.0


according to 29 CFR 1910.1200 and ANSI standard Z400.1-2010 Language: en-US
Date of print: 9/22/2022

Phenol, synthetic
Page: 1 of 16

1. Product and company identification


Product identifier
Trade name: Phenol, synthetic

Relevant identified uses of the substance or mixture and uses advised against
General use: Phenol is an important raw material of the chemical industry. It is used for manufacturing
of Bisphenol A, Phenol-Formaldehyde-Resins and Caprolactam. Furthermore it is used
for manufacturing of Alkyl Phenols, Salicylic Acid and Nitrophenols.

Identified uses: 1. Manufacture, processing and distribution of substances and mixtures (*)
2. Use in laboratories
3. Uses in coatings
4. Use as binders and release agents
5. Rubber production and processing
6. Polymer manufacturing
7. Polymer processing
8. Phenolic resin processing (uses of downstream users of phenolic resins)
* Examples for processing:
use as an intermediate,
use as a monomer etc.,
use as a solvent,
use for the manufacturing of resins

Details of the supplier of the safety data sheet


Company name: INEOS Phenol
Mobile Site
Street/POB-No.: 7770 Rangeline Road
Postal Code, city: US-36582 Theodore, Alabama
WWW: www.ineos.com
Telephone: 251-443-3000
Telefax: 251-443-3001
Department responsible for information:
Telephone: 251-443-3000

Emergency phone number


Telephone:
+1 800-424-9300
Chemtrec (International):
Customer Contract number (CCN): #11278

2. Hazards identification
Emergency overview
Appearance: Form: liquid (> 40.9 °C)
solid (< 40.9 °C)
Color: colorless (liquid)
white (solid)
Odor: Pungent aromatic

printed by INEOS Mobile with Qualisys SUMDAT


Revision date: 11/23/2021
SAFETY DATA SHEET Version: 1.0
according to 29 CFR 1910.1200 and ANSI standard Z400.1-2010 Language: en-US
Date of print: 9/22/2022

Phenol, synthetic
Page: 2 of 16

Classification: Flammable Liquid - Category 4; Acute Toxicity - oral - Category 3; Acute Toxicity -
dermal - Category 3; Acute Toxicity - inhalative - Category 3; Skin Corrosion -
Category 1B; Germ cell mutagenicity -
Category 2; Specific Target Organ Toxicity (Repeated Exposure) -
Category 2; Aquatic toxicity - chronic - Category 2;
Hazard symbols:

Signal word: Danger


Hazard statements: H227 Combustible liquid.
H301 Toxic if swallowed.
H311 Toxic in contact with skin.
H314 Causes severe skin burns and eye damage.
H331 Toxic if inhaled.
H341 Suspected of causing genetic defects.
H373 May cause damage to organs through prolonged or repeated exposure.
H411 Toxic to aquatic life with long lasting effects.
Precautionary statements:
P201 Obtain special instructions before use.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking.
P260 Do not breathe dust/fume/gas/mist/vapors/spray.
P264 Wash hands and face thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P302+P352 IF ON SKIN: Wash with plenty of water/soap.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse

skin with water/or shower.


P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact

lenses, if present and easy to do. Continue rinsing.


P308+P313 IF exposed or concerned: Get medical advice/attention.
P310 Immediately call a POISON CENTER/doctor.
P321 Specific treatment (see ' First aid ' on this label).
P361+P364 Take off immediately all contaminated clothing and wash it before reuse.
P363 Wash contaminated clothing before reuse.
P370+P378 In case of fire: Use dry chemical powder, Foam, water spray jet to extinguish.
P391 Collect spillage.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P501 Dispose of contents/container to hazardous or special waste collection point.
Regulatory status
This material is considered hazardous by the U.S. OSHA Hazard Communication
Standard (29 CFR 1910.1200).

printed by INEOS Mobile with Qualisys SUMDAT


Revision date: 11/23/2021
SAFETY DATA SHEET Version: 1.0
according to 29 CFR 1910.1200 and ANSI standard Z400.1-2010 Language: en-US
Date of print: 9/22/2022

Phenol, synthetic
Page: 3 of 16

Hazards not otherwise classified


After resorption: injuries of the internal organs liver, kidneys, heart. Strong skin absorption
as main danger of phenol poisoning at the workplace with paralysis of the central nervous
system (with lethal consequences in severe cases) as well as liver and kidney damage
see section 11: Toxicological information

3. Composition / Information on ingredients


Chemical characterization: C6 H6 O = C6 H5 OH
Phenol, Hydroxybenzene
CAS-Number: 108-95-2
RTECS-Number: SJ3325000
Hazardous impurities Keep in a cool, well-ventilated place.
Storage temperature:
Liquid: 122 °F up to 140 °F
Solid: 59 °F up to 77 °F

4. First aid measures


General information: First aider: Pay attention to self-protection!
Remove the casualty into fresh air and keep them calm. Remove contaminated clothing. If
victim is at risk of losing consciousness, position and transport on their side.
In case of inhalation: Provide for adequate fresh air. If breathing becomes irregular or ceases, apply rescue
breathing or artificial respiration immediately, where required supply oxygen. Immediately
get medical attention.
Following skin contact: Take off immediately all contaminated clothing. Immediately get medical attention. Treat
by intermittent water washes and polyethylene glycol (e.g. PEG300 or PEG400). Time is
essential to prevent tissue destruction. Wash as much product from the skin as possible
with water and PEG alternating at least for 30 minutes or until further medical attention is
received. When using PEG gloves must be worn.
After eye contact: If product gets into the eye, keep eyelid open and rinse immediately with large quantities
of water, for at least 30 minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. Subsequently seek the immediate attention of an ophthalmologist.
After swallowing: Rinse mouth immediately and drink plenty of water. Do not induce vomiting. Immediately
get medical attention.
Most important symptoms/effects, acute and delayed
In case of inhalation:
Mucous membrane irritation, cough, shortage of breath, damage of respiratory tract.
After contact with skin:
Strong skin absorption as main danger of phenol poisoning at the workplace with
paralysis of the central nervous system (with lethal consequences in severe cases) as
well as liver and kidney damage
After eye contact: burns

printed by INEOS Mobile with Qualisys SUMDAT


Revision date: 11/23/2021
SAFETY DATA SHEET Version: 1.0
according to 29 CFR 1910.1200 and ANSI standard Z400.1-2010 Language: en-US
Date of print: 9/22/2022

Phenol, synthetic
Page: 4 of 16

Information to physician
Symptoms and dangers:
No specific antidote therapy for phenol poisoning is known. Therefore it is important to
remove the phenol completely from the body surface and out of the body as quickly as
possible, and in the case of inhalation prophylactic treatment to prevent pulmonal oedema
is of great importance. Phenol causes strong caustic burns of the skin and mucous
membranes due to its protein degenerating action. The skin initially discolours white, later
red. After initial pain, local anaesthesia appears. Absortive poisoning by large amounts of
phenol is possible also through small affected skin regions and quickly leads to paralysis
of the central nervous system as well as strong depression of the body temperature.
Inhaling phenol vapors can lead to damage of the bronchial system and pulmonal
oedema. Systemic damage to kidneys, liver and heart as well as neuropsychiatric
disturbances are produced.
Treatment:
Thoroughly clean the wetted skin areas, if possible with polyethylene glycol (e.g.
polyethylene glycol 300). In case of eye contact, rinse copiously with water, in case of
burns rinse continuously with water as far as possible and take to an eye specialist or
eye clinic. In case of inhalation, to prevent pulmonal oedemia, initiate inhalative cortisone
therapy as early as possible (e.g. every 10 minutes 5 strokes of a cortisone containing
aerosol dosing spray); administer codeine against dry coughing. In case of commencing
or manifested pulmonary oedemia, systemic administration of cortisone. Caution: A low
symptom or symptom-free interval is possible. If swallowed, gastric lavage after
intubation, activated charcoal, saline laxative.

5. Fire fighting measures


Flash point/flash point range:
177.8 °F
Auto-ignition temperature: No data available
Suitable extinguishing media:
Dry chemical powder, foam, water spray jet
In enclosed areas: carbon dioxide
Extinguishing media which must not be used for safety reasons:
Full water jet.
Specific hazards arising from the chemical
Combustible liquid. Vapors are heavier than air and will travel at floor level.
In case of warming: Development of explosive gas/vapor.
Hazardous vapors may form during fires.
In case of fire may be liberated: carbon monoxide and carbon dioxide.
Protective equipment and precautions for firefighters:
Wear a self-contained breathing apparatus and chemical protective clothing.
Additional information: Heating will lead to pressure increase: Danger of bursting and explosion. Move container
away or cool with water from a protected position. Collect contaminated fire extinguishing
water separately. This must not be discharged into drains. Fire residuals and
contaminated extinguishing water must be disposed of in accordance with the regulations
of the local authorities.

printed by INEOS Mobile with Qualisys SUMDAT


Revision date: 11/23/2021
SAFETY DATA SHEET Version: 1.0
according to 29 CFR 1910.1200 and ANSI standard Z400.1-2010 Language: en-US
Date of print: 9/22/2022

Phenol, synthetic
Page: 5 of 16

6. Accidental release measures


Personal precautions: Remove all sources of ignition. Keep upwind.
Do not breathe vapors. Do not breathe dust. Avoid contact with the substance.
Wear suitable protective clothing. Provide adequate ventilation.
Leaks may be repaired only with full protection (tightly closing chemical protection
clothing, respirator equipment independent of the ambient air).
Environmental precautions:
Do not allow to penetrate into soil, waterbodies or drains.
Danger to drinking water when soaking into the soil or waters. In case of entry into
waterways, soil or drains, inform the responsible authorities.
Methods for clean-up: Allow the leaked product to solidify if this is possible without endangering people. Take
up mechanically, placing in appropriate containers for disposal.
Phenol, liquid: Collect spillage. Absorb with liquid-binding material (e.g. sand,
diatomaceous earth, acid- or universal binding agents) and place in closed containers for
disposal. Final cleaning.
Collect the rinsing water when cleaning-down contaminated equipment and plant
components (to prevent phenol from escaping into deep soil layers).

7. Handling and storage


Handling
Advices on safe handling: Execute works under fume hood. Do not inhale substance.
Avoid contact with skin, eyes, and clothing.
The material is to be handled with extreme caution.
Requires good ventilation.
Welding operations are permitted only under supervision.
Precautions against fire and explosion:
Keep away from sources of ignition - No smoking.

Specific use(s) For use in industrial installations and professional treatment only.
Storage
Requirements for storerooms and containers:
Keep container tightly closed.
Storage temperature:
Liquid: 122 °F up to 140 °F
Solid: 59 °F up to 77 °F
Keep container in a well-ventilated place. Protect from light.
Material: steel or Refined steel.
Keep locked up. Only trained personnel may be allowed to enter storage area.
Hints on joint storage: Do not store together with food. Do not store together with: Solvent, aluminium,
aldehydes, halogens, hydrogen peroxide, oxidizing agents, strong acids, strong bases,
formaldehyde, nitrites, nitrates, halogenates, peroxide compounds.
Further details: Reserved for industrial and professional use.

printed by INEOS Mobile with Qualisys SUMDAT


Revision date: 11/23/2021
SAFETY DATA SHEET Version: 1.0
according to 29 CFR 1910.1200 and ANSI standard Z400.1-2010 Language: en-US
Date of print: 9/22/2022

Phenol, synthetic
Page: 6 of 16

8. Exposure controls / personal protection


Exposure guidelines
Occupational exposure limit values:

Type Limit value


USA: ACGIH: TWA 19 mg/m³; 5 ppm (may be absorbed through the skin)
USA: IDLH: TWA 250 ppm
USA: NIOSH: Ceiling 60 mg/m³; 15.6 ppm (may be absorbed through the skin)
USA: NIOSH: TWA 19 mg/m³; 5 ppm (may be absorbed through the skin)
USA: OSHA: TWA 19 mg/m³; 5 ppm (may be absorbed through the skin)

Biological limit values:

Type Limit value Parameter Material Time of sampling


USA: ACGIH-BEI 250 mg/g creatinine phenol urine end of exposure or end of shift
Additional information: All exposure relevant information (human health and environment) is summarised in
annexes to this safety data sheet.

Engineering controls
Execute works under fume hood. Do not inhale substance.
The substance should only be handled in closed apparatus or systems.
Process exhaust through separator/filter as needed.
See also information in chapter 7, section storage.

Personal protection equipment (PPE)


Eye/face protection: Goggles or face protection shield.
Skin protection: Protective work clothing, chemical resistant safety shoes.
Protective gloves according to
Glove material: Neoprene, PVC
Breakthrough time:
140 min. (Neoprene)
75 min. (PVC)
Observe glove manufacturer's instructions concerning penetrability and breakthrough time.
Nitrile rubber not recommended.
Respiratory protection: Respiratory protection must be worn whenever the TLV (WEL) levels have been exceeded.
Up to 50 ppm: air purifying respirator with organic vapor cartridge with filter types N95,
R95 or P95.
Up to 125 ppm: supplied air respirator or powered air purifying respirator with organic
vapor cartridge
Up to 250 ppm: supplied air respirator, powered air purifying respirator or full face mask
(DIN EN 136) with organic vapor cartridge
General hygiene considerations:
Take off immediately all contaminated clothing.
When using do not eat, drink or smoke.
Have eye wash bottle or eye rinse ready at work place.
Keep away from food, drink and animal feedingstuffs.
Preventive skin protection. Wash hands before breaks and immediately after handling the
product. Follow up by applying a genrous amount of protective skin cream.
Alternatives to the personal protective measures as mentioned can only be determined in agreement with a
responsible safety expert.

printed by INEOS Mobile with Qualisys SUMDAT


Revision date: 11/23/2021
SAFETY DATA SHEET Version: 1.0
according to 29 CFR 1910.1200 and ANSI standard Z400.1-2010 Language: en-US
Date of print: 9/22/2022

Phenol, synthetic
Page: 7 of 16

Environmental exposure controls


Do not allow to penetrate into soil, waterbodies or drains.
Danger to drinking water when soaking into the soil or waters. In case of entry into
waterways, soil or drains, inform the responsible authorities.
Although Phenol is biodegradable and Bioaccumulation potential is low EPA has set
regulatory limits for ptotection of human health.

9. Physical and chemical properties


Information on basic physical and chemical properties
Appearance: Form: liquid (> 40.9 °C)
solid (< 40.9 °C)
Color: colorless (liquid)
white (solid)
Odor: Pungent aromatic
Odor threshold: 0.022 - 22 mg/m³

pH: at 68 °F, 10 g/L: 4 - 5


Melting point/freezing point: 105.62 °F
Initial boiling point and boiling range: 359.42 °F (1013 hPa, DIN 510751)
Flash point/flash point range: 177.8 °F
Evaporation rate: No data available
Flammability: 1103 °F
Explosion limits: LEL (Lower Explosion Limit): 1.30 Vol-%
UEL (Upper Explosive Limit): 9.00 Vol-%
Vapor pressure: at 68 °F: 0.2 hPa
at 122 °F: 3 hPa
Vapor density: No data available
Density: at 77 °F: 1.13 g/cm³ (DIN 51 757)
Water solubility: at 68 °F: 84 g/L
at 77 °F: 87 g/L
at 154.4 °F: completely miscible
Partition coefficient: n-octanol/water: 1.47 log P(o/w) (CPC)
Based on the n-octanol/water partition coefficient significant accumulation in
organisms is not expected.
Auto-ignition temperature: No data available
Thermal decomposition: none

Viscosity, dynamic: at 122 °F: 3.437 mPa*s


Explosive properties: Product is not explosive.
Ignition temperature: 1103 °F (DIN 51 794)
Additional information: Molar mass: 94.11 g/mol
Relative vapor density at 68 °F (air=1): 3.2

10. Stability and reactivity


Reactivity: Hygroscopic

Chemical stability: Stable under recommended storage conditions.

printed by INEOS Mobile with Qualisys SUMDAT


Revision date: 11/23/2021
SAFETY DATA SHEET Version: 1.0
according to 29 CFR 1910.1200 and ANSI standard Z400.1-2010 Language: en-US
Date of print: 9/22/2022

Phenol, synthetic
Page: 8 of 16

Possibility of hazardous reactions:


No dangerous reactions are known.

Conditions to avoid: No decomposition when used properly.


It may react to form catechol, hydroquinone, as a result of radical formation. Protect from
moisture contamination.

Incompatible materials: Oxidizing agents, aldehydes, isocyanates, nitrites, nitrides, Friedel-Crafts catalysts.
Avoid ignitible vapor-air-mixtures.
Unsuitable materials: Metals, rubber, various plastics, alloys
Hazardous decomposition products:
Carbon monoxide and carbon dioxide
Thermal decomposition: none

11. Toxicological information


Toxicological tests
Acute toxicity: LD50 Rat, oral: 340 mg/kg bw (OECD 401)
LDLo Human, oral: 140 mg/kg bw
LD50 Rat, dermal: 660 mg/kg bw (OECD 402)
LC50 Rat, inhalative: > 900 mg/m³/8h
LC0 Rat, inhalative: 900 mg/m³/8h

printed by INEOS Mobile with Qualisys SUMDAT


Revision date: 11/23/2021
SAFETY DATA SHEET Version: 1.0
according to 29 CFR 1910.1200 and ANSI standard Z400.1-2010 Language: en-US
Date of print: 9/22/2022

Phenol, synthetic
Page: 9 of 16

Toxicological effects: Acute toxicity (oral): Acute Toxicity - oral -


Category 3 = Toxic if swallowed. Toxic if swallowed.
Acute toxicity (dermal): Acute Toxicity - dermal -
Category 3 = Toxic in contact with skin. Toxic in contact with skin.
Acute toxicity (inhalative): Acute Toxicity - inhalative -
Category 3 = Toxic if inhaled. Toxic if inhaled.
Skin corrosion/irritation: Skin Corrosion -
Category 1B = Causes severe skin burns and eye damage. Causes severe skin burns
and eye damage.
Serious eye damage/irritation: Lack of data.
Sensitisation to the respiratory tract: Lack of data.
Skin sensitisation: Based on available data, the classification criteria are not met. Not
known to cause sensitization.
Germ cell mutagenicity/Genotoxicity: Germ cell mutagenicity -
Category 2 = Suspected of causing genetic defects.
Bacterial mutagenicity: negative.
Chromosomal aberrations in-vitro: positive.
Micronucleus test: in-vitro: positive.
Gene-mutations mammalian cells in-vitro: positive.
Sister chromatid exchange in-vitro: positive.
Micronucleus test: in-vivo: weak positive.
Carcinogenicity: Based on available data, the classification criteria are not met.
Specific symptoms in animal studies: None carcinogenic effect.
Reproductive toxicity: Based on available data, the classification criteria are not met.
Specific symptoms in animal studies: No reproductive hazards have been observed.
Effects on or via lactation: Lack of data.
Specific target organ toxicity (single exposure): Based on available data, the classification
criteria are not met.
Specific target organ toxicity (repeated exposure): Specific Target Organ Toxicity
(Repeated Exposure) -
Category 2 = May cause damage to organs through prolonged or repeated exposure. May
cause damage to organs through prolonged or repeated exposure. Organs affected:
nervous system, skin, liver, kidneys
Aspiration hazard: Based on available data, the classification criteria are not met.
Other information: For carcinogenic effects
IARC Rating: Group 3
OSHA Carcinogen: not listed
NTP Rating: not listed

Symptoms
In case of inhalation:
Mucous membrane irritation, cough, shortage of breath, damage of respiratory tract.
After contact with skin:
Strong skin absorption as main danger of phenol poisoning at the workplace with
paralysis of the central nervous system (with lethal consequences in severe cases) as
well as liver and kidney damage
After eye contact: burns

printed by INEOS Mobile with Qualisys SUMDAT


Revision date: 11/23/2021
SAFETY DATA SHEET Version: 1.0
according to 29 CFR 1910.1200 and ANSI standard Z400.1-2010 Language: en-US
Date of print: 9/22/2022

Phenol, synthetic
Page: 10 of 16

12. Ecological information


Ecotoxicity
Aquatic toxicity: Toxic to aquatic life with long lasting effects.
Algae toxicity:
EC50 Pseudokirchneriella subcapitata (green algae), (freshwater, cell number): 61.1
mg/L/96h.
EC50 Entomoneis cf punctulata, (marine water, growth rate): 76 mg/L/72h.
Bacterial toxicity:
IC50 Nitrosomonas sp: 21 mg/L/24h.
Daphnia toxicity:
EC50 Ceriodaphnia dubia: 3.1 mg/L/48h.
Fish toxicity:
LC50 Oncorhynchus mykiss: 8.9 mg/L/96h.
Longterm fish toxicity:
60 d NOEC (Cirrhina mrigala): 0.077 mg/L.
Long-term daphnia toxicity:
16 d EC10 (Daphnia magna, growth): 0.46 mg/L.
Additional information:
EC50 Lemna minor (little duckweed): 61.82 mg/L/7d.
LC50 eisenis foetida: 401 mg/kg soil/14d.
EC50 Lactuca sativa: 79 mg/kg soil/14d.
EC10 Effects on soil microorganisms. 100 mg/kg soil/14d.

Mobility in soil
Adsorption coefficient:
Koc: 82.8 L/kg, at 20 °C (calculated as log Pow)
The soil sorption coefficient indicates a low sorption of phenol onto soil organic matter.
Evaporation rate (Volatilisation) at 20°C: H=0.022 Pa* m³/mol.
The calculated Henry's Law constant indicates a low to moderate volatility from aqueous
solution.

Persistence and degradability


Further details: Abiotic degradation:
Air (Indirect photodegradation by reaction with OH radicals.): half-life time (DT50) approx.
14h
Water: Not susceptible to hydrolysis.
Biodegradation:
Activated sludge: 62 %/100h, readily biodegradable (OECD 301C).
Activated sludge (anaerobic): 80.1 %/50d, rapidly biodegradable under anaerobic
conditions (ECETOC method).
Water: 86 - 96 % / 20d, easily bio-degradable (BOD-test APHA).
COD: 2.3 g/g
ThOD: 2.26 mg/L

Additional ecological information


Volatile organic compounds (VOC):
100 % by weight
General information: Do not allow to enter into ground-water, surface water or drains.

printed by INEOS Mobile with Qualisys SUMDAT


Revision date: 11/23/2021
SAFETY DATA SHEET Version: 1.0
according to 29 CFR 1910.1200 and ANSI standard Z400.1-2010 Language: en-US
Date of print: 9/22/2022

Phenol, synthetic
Page: 11 of 16

13. Disposal considerations


Product
Recommendation: RCRA waste code: U188 commercial chemical product or off-spec commercial chemical
product
Dispose of waste according to applicable legislation.
wastes not otherwise specified

Package
Recommendation: Dispose of waste according to applicable legislation.
Handle contaminated packages in the same way as the substance itself.
Non-contaminated packages may be recycled.

14. Transport information


UN number

liquid (> 40.9 °C) solid (< 40.9 °C)


DOT: UN2312 UN1671
IMDG, IATA-DGR: UN 2312 UN 1671

UN proper shipping name

liquid (> 40.9 °C) solid (< 40.9 °C)


DOT, IMDG, IATA-DGR: UN 2312, PHENOL, MOLTEN UN 1671, PHENOL, SOLID

Transport hazard class(es)

liquid (> 40.9 °C) solid (< 40.9 °C)


DOT: 6.1 6.1
IMDG: Class 6.1, Subrisk - Class 6.1, Subrisk -
IATA-DGR: Class 6.1 Class 6.1

Packing group

liquid (> 40.9 °C) solid (< 40.9 °C)


DOT, IMDG: II II
IATA-DGR: II

Environmental hazards

liquid (> 40.9 °C) solid (< 40.9 °C)


Marine pollutant yes yes

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Pollution category: Y
Vessel type: 2
Product name: Phenol

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Revision date: 11/23/2021
SAFETY DATA SHEET Version: 1.0
according to 29 CFR 1910.1200 and ANSI standard Z400.1-2010 Language: en-US
Date of print: 9/22/2022

Phenol, synthetic
Page: 12 of 16

USA: Department of Transportation (DOT)

liquid (> 40.9 °C) solid (< 40.9 °C)


Labels: 6.1 6.1
Symbols: +
Special Provisions: B14, T7, TP3 IB8, IP2, IP4, N78, T3, TP33
Packaging – Exceptions: None 153
Packaging – Non-bulk: 202 212
Packaging – Bulk: 243 242
Quantity limitations – Forbidden 25 kg
Passenger aircraft / rail:
Quantity limitations – Cargo only: Forbidden 100 kg
Vessel stowage – Location: B A
Vessel stowage – Other: 40

Sea transport (IMDG)

liquid (> 40.9 °C) solid (< 40.9 °C)


EmS: F-A, S-A F-A, S-A
Limited quantities: 0 500 g
EQ: E0 E4
Air transport (IATA)

liquid (> 40.9 °C) solid (< 40.9 °C)


Passenger Ltd.Qty.: Forbidden Pack.Instr. Y644 - Max. Net Qty/Pkg.
1 kg
Passenger: Forbidden Pack.Instr. 669 - Max. Net Qty/Pkg.
25 kg
Cargo: Forbidden Pack.Instr. 676 - Max. Net Qty/Pkg.
100 kg
EQ: E0 E4

printed by INEOS Mobile with Qualisys SUMDAT


Revision date: 11/23/2021
SAFETY DATA SHEET Version: 1.0
according to 29 CFR 1910.1200 and ANSI standard Z400.1-2010 Language: en-US
Date of print: 9/22/2022

Phenol, synthetic
Page: 13 of 16

15. Regulatory information


National regulations - U.S. Federal Regulations
TSCA Section 12(b) Export Notification Requirements.
Hazardous Air Pollutants: Listed Section 112 Hazardous air polluants
Clear water Act:
Section 311: Hazardous Substance: RQ 1000 lbs
Section 304 (a): Priority Pollutant
SARA: Section 311/312: Hazardous Classifications: Immediate (acute), Fire
EPA Pesticides:
Listed as active ingredients
Listed as inert ingredients
TSCA Inventory: listed
TSCA HPVC: not listed
Carcinogen Status:
IARC Rating: Group 3
OSHA Carcinogen: not listed
NTP Rating: not listed
Clean Air Act:
Hazardous Air Pollutants: yes
SOCMI Chemical: yes
Clean Water Act:
Hazardous Substances: RQ 1000 lbs.
Priority Pollutant: yes
Other Environmental Laws:
CERCLA: RQ 1000 lbs.
RCRA Hazardous Wastes: Code U188
RCRA Groundwater Monitoring: Methods 8040, 8270 / PQL 1, 10
SARA Title III Section 302, EHS: TPQ 500/10000 lbs. / RQ 1000 lbs.
SARA Title III Section 313, Toxic Release: Conc. 1.0% / Threshold Standard
NIOSH Recommendations:
Occupational Health Guideline: 0493

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Revision date: 11/23/2021
SAFETY DATA SHEET Version: 1.0
according to 29 CFR 1910.1200 and ANSI standard Z400.1-2010 Language: en-US
Date of print: 9/22/2022

Phenol, synthetic
Page: 14 of 16

National regulations - U.S. State Regulations


Louisiana Right_To_Know:
Listed of Extremely Hazardous Substances: TQ 500 lbs
California Proposition 65 code: not listed
Delaware Air Quality Management List:
DRQ: 1000 - RQ State: Federal Regulations Apply
Idaho Air Pollutant List:
Title 585: AAC: 0.95 - EL: 1.27 - OEL: 19 - Title 586: -
Maine Hazardous Air Pollutants:
Me 2005: HAP - Hap Rpt: 2000
Massachusetts Haz. Substance codes: 2,4,5,6 *E* F6 F8 F9
Minnesota Haz. Substance:
Codes: ANO - Ratings: 8.45 - Status: Air Pollutant. Title III. TRI. Water Pollutant
New Jersey RTK Hazardous Substance:
DOT: 1671 - Sub No.: 1487 - TPQ: - EHS: Yes
New York List of Hazardous Substances:
RQ-Air: 1000 - RQ-Land: 1 - Note: No Note Associated with this chemical.
Pennsylvania Haz. Substance code: E
Washington Air Contaminant:
TWA: 5 ppm - 19 mg/m³
Skin: Protective measures should be taken to prevent or reduce skin absorption.
National regulations - EC member states
EC-number: 203-632-7
EU index number: 604-001-00-2
Further regulations, limitations and legal requirements:
EINECS No.: 203-632-7
EU No.: 604-001-00-2
REACH No.: 01-2119471329-32-0002
Customs tariff number: 2907 11 00

16. Other information


Text for labeling: Contains 100 % Phenol, synthetic. Safety data sheet available on request.
Hazard rating systems: NFPA Hazard Rating:
Health: 4 (Severe)
2 Fire: 2 (Moderate)
4 0 Reactivity: 0 (Minimal)
HMIS Version III Rating: HEALTH * 4

Health: 4 (Severe) - Chronic effects FLAMMABILITY 2


Flammability: 2 (Moderate) PHYSICAL HAZARD 0
Physical Hazard: 0 (Minimal) X
Personal Protection: X = Consult your supervisor

printed by INEOS Mobile with Qualisys SUMDAT


Revision date: 11/23/2021
SAFETY DATA SHEET Version: 1.0
according to 29 CFR 1910.1200 and ANSI standard Z400.1-2010 Language: en-US
Date of print: 9/22/2022

Phenol, synthetic
Page: 15 of 16

Abbreviations and acronyms:


ADN: European Agreement concerning the International Carriage of Dangerous Goods by
Inland Waterways
ADR: European Agreement concerning the International Carriage of Dangerous Goods by
Road
AS/NZS: Australian Standards/New Zealand Standards
CAS: Chemical Abstracts Service
CFR: Code of Federal Regulations
CLP: Classification, Labelling and Packaging
CNS: Central Nervous System
COD: Chemical Oyxgen Demand
DIN: German Insitute for Standardization
DMEL: Derived minimal effect level
DNEL: Derived no-effect level
EC: European Community
EC50: Effective Concentration 50%
EINECS: European Inventory of Existing Commercial Chemical Substances
EN: European Standard
EQ: Excepted quantities
EU: European Union
IATA: International Air Transport Association
IATA-DGR: International Air Transport Association – Dangerous Goods Regulations
IBC Code: International Code for the Construction and Equipment of Ships carrying
Dangerous Chemicals in Bulk
IC50: Inhibition Concentration 50%
IMDG Code: International Maritime Dangerous Goods Code
LC0: Lethal concentration 0%
LC50: Median lethal concentration
LD50: Lethal dose 50%
LEL: Lower Explosion Limit
log P(o/w): Partition coefficient: octanol/water
MARPOL: Maritime Pollution: The International Convention for the Prevention of Pollution
from Ships
MFSU: Manufacture, formulation, supply and use
NF: French Standard
NOEC: No Observed Effect Concentration
OEL: Occupational Exposure Limit Value
OSHA: Occupational Safety and Health Administration
PBT: Persistent, bioaccumulative and toxic
PNEC: Predicted no-effect concentration
PVC: Polyvinyl chloride
RCRA: Resource Conservation Recovery Act
REACH: Registration, Evaluation, Authorisation and Restriction of Chemicals
RID: Regulations Concerning the International Carriage of Dangerous Goods by Rail
STOT RE: Specific target organ toxicity - repeated exposure
ThOD: Theoretical Oxygen Demand
TLV: Threshold Limit Value
TRGS: Technical Rules for Hazardous Substances
UN: United Nations
vPvB: Very persistent and very bioaccumulative
WEL: Workplace Exposure Limit
Literature: REACH Registration Dossier Phenol. P&D-REACH Consortium, 2010

Date of first version: 11/23/2021

printed by INEOS Mobile with Qualisys SUMDAT


Revision date: 11/23/2021
SAFETY DATA SHEET Version: 1.0
according to 29 CFR 1910.1200 and ANSI standard Z400.1-2010 Language: en-US
Date of print: 9/22/2022

Phenol, synthetic
Page: 16 of 16

Department issuing data sheet


Contact person: see section 1: Department responsible for information

INEOS Phenol provides the information contained herein in good faith but makes no representation as to its
comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary
handling of the material by a properly trained person using this product. Individuals receiving the information
must exercise their independent judgment in determining its appropriateness for a particular purpose. INEOS
Phenol makes no representations or warranties, either expressed or implied, including without limitation any
warranties of merchantability, fitness for a particular purpose with respect to the information set forth herein or
the product which the information refers. Accordingly, INEOS Phenol will not be responsible for damages
resulting from the use of or reliance upon this information.

Most recent product information is available at:


http://sumdat.net/i5fh74au

printed by INEOS Mobile with Qualisys SUMDAT

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