Conforms to 91/155/EEC - 2001/58/EC - United Kingdom (UK)

SAFETY DATA SHEET

MAXIGARD
1. Identification of the substance/preparation and of the company/undertaking
Product name : MAXIGARD
Material Uses : Industrial applications: Corrosion inhibitor for recirculating cooling water
treatment.

Manufacturer / Supplier :
Drew Marine Drew Marine
Ashland Specialty Chemical Company Ashland Specialty Chemical Company
Malledijk 20 One Drew Plaza
3208 LA Spijkenisse Boonton, NJ 07005
Netherlands United States
Tel. No.: Tel. No.:
+31 181 457 070 +1 (973) 263 7600
Fax: Fax:
+31 181 625 792 +1 (973) 263 4491
Emergency telephone number
(Germany) : +49 621 60-43333
Fax:
(Germany) : +49 621 60-92664

2. Composition/information on ingredients
Substance/Preparation : Preparation

Chemical name* CAS No. % EC Number Classification

Sodium nitrate 7631-99-4 5-10 231-554-3 Xn; R22
Xi; R36/38
Disodium tetraborate, decahydrate 1303-96-4 5-10
Sodium nitrite 7632-00-0 1-5 231-555-9 O; R8
T; R25
N; R50
Sodium metasilicate 6834-92-0 1-5 229-912-9 C; R34
Xi; R37
Sodium hydroxide 1310-73-2 1-5 215-185-5 C; R35
4(5)-Methyl-benzotriazole (Sodium salt) 64665-57-2 0.5-1 265-004-9 Xn; R22
C; R34
See Section 16 for the full text of the R Phrases declared above

* Occupational Exposure Limit(s), if available, are listed in Section 8

3. Hazards identification
The preparation is classified as dangerous according to Directive 1999/45/EC and its amendments.
Classification : Toxic
R25- Toxic if swallowed.
R34- Causes burns.
Effects and symptoms
Inhalation : Slightly hazardous in case of inhalation. Inhalation of the spray mist may
produce severe irritation of respiratory tract, characterized by coughing,
choking or shortness of breath. Overexposure by inhalation may cause
respiratory irritation.
Ingestion : May be fatal if swallowed. May cause burns to mouth, throat and stomach.

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Skin contact : Corrosive to skin on contact. Skin contact may produce burns.
Eye Contact : Corrosive to eyes.
Target Organs : Contains material which causes damage to the following organs: blood, lungs,
upper respiratory tract, skin, eye, lens or cornea.

4. First-aid measures
First-Aid measures
Inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Obtain medical attention immediately.
Ingestion : If swallowed, do not induce vomiting unless directed to do so by medical
personnel. Never give anything by mouth to an unconscious person. Loosen
tight clothing such as a collar, tie, belt or waistband. Obtain medical attention
immediately.
Skin contact : In case of contact, immediately flush skin copiously with water for at least 15
minutes while removing contaminated clothing and shoes. Cold water may be
used. Wash clothing before reuse. Clean shoes thoroughly before reuse.
Obtain medical attention immediately.
Eye Contact : Check for and remove any contact lenses. In case of contact, immediately
flush eyes with a copious amount of water for at least 15 minutes. Cold water
may be used. Obtain medical attention immediately.

5. Fire-fighting measures
Extinguishing Media
Suitable : SMALL FIRE: Use dry chemical powder or CO2.
LARGE FIRE: Use water spray, fog or foam. Do not use water jet.
Hazardous thermal (de)composition : These products are carbon oxides (CO, CO2) and water, nitrogen oxides (NO,
products NO2...). Some metallic oxides.
Protection of fire-fighters : Fire fighters should wear self-contained positive pressure breathing apparatus
(SCBA) and full turnout gear.

6. Accidental release measures

Personal Precautions : Splash goggles. Full suit. Boots. Gloves.
Environmental precautions and : Stop leak if without risk. Absorb with dry earth, sand or other noncombustible
cleanup methods material. Use water spray curtain to divert vapour drift. Use water spray to
reduce vapours. Prevent entry into sewers, basements or confined areas; dike
if needed. Call for assistance on disposal.Neutralize the residue with a
dilute solution of acetic acid. Finish cleaning by spreading water on the
contaminated surface and allow to evacuate through the sanitary system.
Note: See section 8 for personal protective equipment and section 13 for waste disposal.

7. Handling and storage

Handling : Keep locked up. Keep container dry. Do not breathe
gas/fumes/vapour/spray. Wear suitable protective clothing. If ingested, seek
medical advice immediately and show the container or the label. Keep away
from incompatibles such as reducing agents, combustible materials, organic
materials, acids.
Storage : Keep container tightly closed. Keep container in a cool, well-ventilated area.
Packaging materials
Recommended use : Use original container.

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8. Exposure controls/personal protection

Engineering measures
Hygiene measures
Occupational Exposure Limits
: Provide exhaust ventilation or other engineering controls to keep the airborne
concentrations of vapours below their respective occupational exposure limits.
: Wash hands, forearms, and face thoroughly after handling compounds and
before eating, smoking, using lavatory, and at the end of day.

Ingredient Name Occupational Exposure Limits

Disodium tetraborate, decahydrate EH40-OES (United Kingdom (UK), 2000).
TWA: 5 mg/m3
Sodium hydroxide EH40-OES (United Kingdom (UK), 2001). Notes: OES
STEL: 2 mg/m3

Respiratory system : Wear appropriate respirator when ventilation is inadequate.

Skin and body : Full suit.

Hands : Impervious gloves.
Eyes : Face shield.

9. Physical and chemical properties

Physical state : Liquid.
Colour : Reddish. pink
Odour : Odourless.
Boiling point : 100°C (212°F)
Melting point : -23°C (-9°F)
Density : 1.26 g/cm3
Vapour pressure : The highest known value is 2.33 kPa (17.5 mmHg) (at 20°C) (Water).
Evaporation Rate : 0.36 (Water) compared to n-Butyl acetate

Solubility : Easily soluble in cold water.

pH : 11.5 to 12.5 [Basic.]
Flash point : Not applicable.

10. Stability and reactivity

Stability : The product is stable.
Materials to avoid : Reactive with reducing agents, combustible materials, organic materials,
acids.
Do not use amines together with this product. Suspected cancer-causing
N-nitrosamines could be formed. Incompatible with heat, amines, ammonium
salts, cellulose, oxidizable metals ( copper, zinc, aluminium) and acids.
Incompatible with alcohols. (e.g. Isopropanol, Glycol. )
Hazardous decomposition products : These products are carbon oxides (CO, CO2) and water, nitrogen oxides (NO,
NO2...). Some metallic oxides.

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11. Toxicological information

Acute toxicity
Ingredient Name Test Result Route Species
Sodium nitrate LD50 1267 mg/kg Oral Rat
LD50 2680 mg/kg Oral Rabbit
Disodium tetraborate, decahydrate LD50 2660 mg/kg Oral Rat
LD50 5330 mg/kg Oral Guinea pig
Sodium nitrite LD50 180 mg/kg Oral Rat
LD50 186 mg/kg Oral Rabbit
LD50 175 mg/kg Oral Mouse
LDLo 22 mg/kg Oral child
LDLo 71 mg/kg Oral Human
LDLo 321 mg/kg Oral man
Sodium metasilicate LD50 1153 mg/kg Oral Rat
LD50 770 mg/kg Oral Mouse
LDLo 250 mg/kg Oral Dog
LDLo 250 mg/kg Oral pig
Sodium hydroxide LDLo 500 mg/kg Oral Rabbit

Chronic toxicity : Repeated or prolonged contact with spray mist may produce chronic eye
irritation and severe skin irritation. Repeated or prolonged exposure to spray
mist may produce respiratory tract irritation, leading to frequent attacks of
bronchial infection. Repeated exposure to an highly toxic material may
produce general deterioration of health by an accumulation in one or many
human organs.
Skin irritation : Hazardous in case of skin contact (corrosive).
Eye irritation : Hazardous in case of eye contact (corrosive).
Carcinogenic effects : Not available.

Mutagenic Effects : Not available.

Reproduction toxicity : Not available.

12. Ecological information

Ecotoxicity Data
Ingredient Name Species Period Result
MAXIGARD Fish (LC50) 96 hours 1095 mg/l
Disodium tetraborate, decahydrate Daphnia (EC50) 48 hours 141 mg/l
Persistence/degradability : The BOD is 1100 mg/l [5 day(s)] (MAXIGARD). The COD is 46000 mg/l [28
day(s)] (MAXIGARD).

13. Disposal considerations

Methods of disposal ; Waste of : Waste must be disposed of in accordance with federal, state and local
residues ; Contaminated packaging environmental control regulations.

European Waste Catalogue (EWC) : 06 03 08

Hazardous Waste : The classification of the product may meet the criteria for a hazardous waste.
Additional Information : 06 03 08 saline solutions containing nitrates and related compounds

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14. Transport information

International transport regulations
Land - Road/Railway
UN number : Not regulated.
Proper shipping name : -
ADR/RID Class : -
Other information : Remarks
Not controlled under ADR (Europe).
Sea
UN number : Not regulated.
Proper shipping name : -
IMDG Class : -
Other information : Remarks
Not controlled under IMDG.

15. Regulatory information

EU Regulations
Hazard symbol(s) :

Toxic
Risk Phrases : R25- Toxic if swallowed.
R34- Causes burns.
Safety Phrases : S26- In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.
S36/37/39- Wear suitable protective clothing, gloves and eye/face protection.
S45- In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
Contains : Sodium nitrite 231-555-9
Sodium hydroxide 215-185-5
Product Use : Classification and labelling have been performed according to EU directives
67/548/EEC, 88/379/EEC, including amendments and the intended use.
- Industrial applications.

16. Other information

Full text of R-Phrases with no.
appearing in Section 2 - United
Kingdom (UK)
Text of classifications appearing in
Section 2 - United Kingdom (UK)
HISTORY
Date of printing
: R8- Contact with combustible material may cause fire.
R22- Harmful if swallowed.
R25- Toxic if swallowed.
R34- Causes burns.
R35- Causes severe burns.
R36/38- Irritating to eyes and skin.
R37- Irritating to respiratory system.
R50- Very toxic to aquatic organisms.
: O - Oxidizing
T - Toxic
C - Corrosive
Xn - Harmful
Xi - Irritant
N - Dangerous for the environment.
: 10/17/2002.

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Date of issue : 10/16/2002.

Version : 3
MAXIGARD® is a registered trademark of Ashland Inc.
Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor
any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained
herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown
hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these
are the only hazards that exist.
Date of issue Version
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