Conforms to 91/155/EEC - 2001/58/EC - United Kingdom (UK)

SAFETY DATA SHEET

TOTAL ALKALINITY INDICATOR GP
1. Identification of the substance/preparation and of the company/undertaking
Product name : TOTAL ALKALINITY INDICATOR GP
Material Uses : Industrial applications: Analytical reagent. Use only in accordance with Drew
Test Procedures.

Manufacturer / Supplier :
Drew Marine Drew Marine
Ashland Specialty Chemical Company Ashland Specialty Chemical Company
Malledijk 20 One Drew Plaza
3208 LA Spijkenisse Boonton, NJ 07005
Netherlands United States
Tel. No.: Tel. No.:
+31 181 457 070 +1 (973) 263 7600
Fax: Fax:
+31 181 625 792 +1 (973) 263 4491
Emergency telephone number
(Germany) : +49 621 60-43333
Fax:
(Germany) : +49 621 60-92664

2. Composition/information on ingredients
Substance/Preparation : Preparation
Chemical characterization : Aqueous solution containing: Isopropanol / Azo dye.

Chemical name* CAS No. % EC Number Classification

Propan-2-ol 67-63-0 40-50 200-661-7 F; R11
Xi; R36
R67
See Section 16 for the full text of the R Phrases declared above

* Occupational Exposure Limit(s), if available, are listed in Section 8

3. Hazards identification
The preparation is classified as dangerous according to Directive 1999/45/EC and its amendments.
Classification : Highly flammable, Irritant
R11- Highly flammable.
R36- Irritating to eyes.
R67- Vapours may cause drowsiness and dizziness.
Effects and symptoms
Inhalation : Slightly hazardous in case of inhalation.
Ingestion : Ingestion may cause gastrointestinal irritation and diarrhoea. Adverse
symptoms may include abdominal cramps/pain .
Skin contact : Slightly hazardous in case of skin contact (irritant, permeator). Skin
inflammation is characterized by itching, scaling, reddening, or, occasionally,
blistering.
Eye Contact : Hazardous in case of eye contact (irritant). Inflammation of the eye is
characterized by redness, watering and itching. Adverse symptoms may
include blurred or double vision .

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Target Organs : Contains material which causes damage to the following organs: upper
respiratory tract, skin, central nervous system (CNS), eye, lens or cornea.

4. First-aid measures
First-Aid measures
Inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Get medical attention if symptoms appear.
Ingestion : Do NOT induce vomiting unless directed to do so by medical personnel.
Never give anything by mouth to an unconscious person. Loosen tight clothing
such as a collar, tie, belt or waistband. Get medical attention if symptoms
appear.
Skin contact : Wash with soap and water. Cold water may be used. Get medical attention if
irritation develops.
Eye Contact : Check for and remove any contact lenses. In case of contact, immediately
flush eyes with a copious amount of water for at least 15 minutes. Cold water
may be used. Obtain medical attention.

5. Fire-fighting measures
Extinguishing Media
Suitable : SMALL FIRE: Use dry chemical powder or CO2.
LARGE FIRE: Use alcohol foam, water spray or fog. Cool containing vessels
with water jet in order to prevent pressure build-up, autoignition or explosio
Hazardous thermal (de)composition : These products are carbon oxides (CO, CO2) and water.
products
Protection of fire-fighters : Fire fighters should wear self-contained positive pressure breathing apparatus
(SCBA) and full turnout gear.

6. Accidental release measures

Personal Precautions : Splash goggles. Full suit. Vapour respirator. Boots. Gloves. A self-contained
breathing apparatus should be used to avoid inhalation of the product.
Environmental precautions and : Keep away from heat. Keep away from sources of ignition. Stop leak if
cleanup methods without risk. Absorb with dry earth, sand or other noncombustible materia
Prevent entry into sewers, basements or confined areas; dike if needed.
Note: See section 8 for personal protective equipment and section 13 for waste disposal.

7. Handling and storage

Handling : Keep away from heat. Keep away from sources of ignition. Do not breathe
gas/fumes/vapour/spray. If ingested, seek medical advice immediately and
show the container or the label. Keep away from incompatibles such as
oxidizing agents, acids, alkalis.
Storage : Store in a segregated and approved area. Keep container in a cool,
well-ventilated area. Keep container tightly closed and sealed until ready f
use. Avoid all possible sources of ignition (spark or flame).
Packaging materials
Recommended use : Use original container.

8. Exposure controls/personal protection

Engineering measures
Hygiene measures
: Provide exhaust ventilation or other engineering controls to keep the airborne
concentrations of vapours below their respective occupational exposure limits.
Ensure that eyewash stations and safety showers are close to the workstation
location.
: Wash hands after handling compounds and before eating, smoking, using
lavatory, and at the end of day.

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Occupational Exposure Limits

Ingredient Name Occupational Exposure Limits

Propan-2-ol EH40-OES (United Kingdom (UK), 2001). Notes: OES
STEL: 1250 mg/m3
STEL: 500 ppm
TWA: 999 mg/m3
TWA: 400 ppm

Respiratory system : Wear appropriate respirator when ventilation is inadequate. Vapour respirator.

Skin and body : Lab coat.

Hands : Impervious gloves.
Eyes : Splash goggles.

9. Physical and chemical properties

Physical state : Liquid.
Colour : Green.
Odour : Alcohol-like.
Odour threshold : The lowest known value is 90 ppm (Propan-2-ol).
Boiling point : 80°C (176°F)
Melting point : <-10°C (14°F)
Density : 0.93 g/cm3
Vapour density : >1 (Air = 1)
Vapour pressure : The highest known value is 4.4 kPa (33 mmHg) (at 20°C) (Propan-2-ol).
Evaporation Rate : <1 compared to Ether (anhydrous).

Solubility : Easily soluble in cold water.

pH : Not available.
Flash point : CLOSED CUP: 20°C (68°F).
Autoignition temperature : The lowest known value is 399.05°C (750.3°F) (Propan-2-ol).
Lower explosion limit : The greatest known range is LOWER: 2.3% UPPER: 12.7% (Propan-2-ol)

10. Stability and reactivity

Stability : The product is stable.
Materials to avoid : Reactive with oxidizing agents, acids, alkalis.
Keep away from the following materials: Aluminium , strong alkalis , strong
acids .
Hazardous decomposition products : These products are carbon oxides (CO, CO2) and water.

11. Toxicological information

Acute toxicity
Ingredient Name Test Result Route Species
Propan-2-ol LD50 5045 mg/kg Oral Rat
LD50 6410 mg/kg Oral Rabbit
LD50 3600 mg/kg Oral Mouse
LD50 12800 Dermal Rabbit
mg/kg
LDLo 1537 mg/kg Oral Dog
LDLo 3570 mg/kg Oral human

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LDLo 5272 mg/kg Oral man

LC50 16000 Inhalation Rat
mg/m3 (8
hours)

Chronic toxicity : Repeated or prolonged exposure is not known to aggravate medical condition.
Local effects
Skin irritation : Slightly hazardous in case of skin contact (irritant).
Eye irritation : Hazardous in case of eye contact (irritant).
Specific effects
Carcinogenic effects : Classified 3 (Not classifiable for humans.) by IARC [Propan-2-ol].

Mutagenic Effects : Not available.

Reproduction toxicity : Not available.

12. Ecological information

Ecotoxicity Data
Ingredient Name Species Period Result
Propan-2-ol Fish (LC50) 96 hours 100 to 1000 mg/l
Daphnia (EC50) 48 hours >1000 mg/l
Algae (IC50) 72 hours >1000 mg/l
Persistence/degradability : Not available.

13. Disposal considerations

Methods of disposal ; Waste of : Waste must be disposed of in accordance with federal, state and local
residues ; Contaminated packaging environmental control regulations.

European Waste Catalogue (EWC) : 14 02 02

Hazardous Waste : The classification of the product may meet the criteria for a hazardous waste.
Additional Information : 14 02 02 solvent mixes or organic liquids free of halogenated solvents

14. Transport information

International transport regulations
Land - Road/Railway
UN number : 1219
Proper shipping name : ISOPROPANOL mixture
ADR/RID Class : 3
Packing group : II
ADR/RID label :

Other information : Hazard identification number

33
Sea
UN number : 1219
Proper shipping name : ISOPROPANOL mixture
IMDG Class : 3
Packing group : II

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IMDG label :

Other information : Emergency Schedules (EmS)

3-06

15. Regulatory information

EU Regulations
Hazard symbol(s) :

Highly flammable, Irritant

Risk Phrases : R11- Highly flammable.
R36- Irritating to eyes.
R67- Vapours may cause drowsiness and dizziness.
Safety Phrases : S16- Keep away from sources of ignition - No smoking.
S37/39- Wear suitable gloves and eye/face protection.
S51- Use only in well-ventilated areas.
Product Use : Classification and labelling have been performed according to EU directives
67/548/EEC, 88/379/EEC, including amendments and the intended use.
- Industrial applications.

16. Other information

Full text of R-Phrases with no. : R11- Highly flammable.
appearing in Section 2 - United R36- Irritating to eyes.
Kingdom (UK) R67- Vapours may cause drowsiness and dizziness.
Text of classifications appearing in : F - Highly flammable
Section 2 - United Kingdom (UK) Xi - Irritant
HISTORY
Date of printing : 10/21/2002.
Date of issue : 7/18/2002.
Version : 2.07
Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor
any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained
herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown
hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these
are the only hazards that exist.
Date of issue Version
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