The lcast numbcr of molccules arc contained in

1, Gram Atonmic Mass and Gram Molar Mass 11.

(a) 2 g hylrogen (b) %g oxygen
I. What is the mass per cent of carbon in carbon dioxide?
(a) 0034°, (b) 27.27" (c) 4 g nitrogcn (dy l6 gCO2
(d) 28.7" 12. Which is not a molecular formula?
(c) 3.4°o
2. In a compound 4,B, : (a)CoH20, (b)Ca(NO; )2
(c) CzH402 (d) Nz0
(a) Mole of 4=inole of B=mole of A,B, 13, Vapour density of a
(b) cquivalent of 4=cquivalent ofB =cquivalent of A,B,
volatile substance is 4 (CH4 = 1 h
molar mass would be:
(c) Amole of 4 = YxXmole of B=(X + Y)Xmole (a) 8 (b) 2
of 4, B, (c) 64 (d) 128
(d) Y xX mole of4= Y x X mole of B
(e) None of the above
3. Dulong Petit's law is valid for:
14. If 0.22 g of a substance when
(a) metals (b) non-metals vaporized displaced as
cm of air measured over water at 293 K and 755
(c) clectrolytes (d) all of these
4. The empirical formula and molecular mass of a pressure and if vapour pressure of H,0= 17.4 mm ih
the molar mass of the substance will be:
compound are CIl0 and 180 g respectively. What will
be the
molecular formula of the compound? (a) 222.2 (b) 332.3
(a) CoHRO (b) CH,0 (c) 121.1 (d) 127.5
(c) CaHiO, (d) C;H402 15. 11.2 litre of NH3 at STP has electrons:
5. The number of atoms in n moles of gas can be (a) 3.01 xl021 (b) 3.01 >x1022
given by:
(a) n xAv. no. x atomicity (b XAv. no. (c) 3.01 >x\025 (d) 3.01 x1024
atomicity 16. Two elements X (atomic mass =
Av.no. x atomicity 75) and Y (atomic
(c) (d) none of these mass = I6) combine to give a
n compound having 75.8
ofX. The formula of the compound
6. One mole of PA molecules contain: is:
(a) XY
(a) Imolecule (b) X,Y
(b) 4 molecules (c) X;Y, (d) X2Y3
(c)x 6.022 x 10 atoms (d) 24.088 ×10 atoms 17. The pair of species having
4 same
(a) CH;COOH and CoHi206 percentage of carbon is:
7. The total number of (b) CH;COOH and
protons, clectrons and ncutrons in 12 C)H5OH
gorCis: (c) HCOOCH} and
(a) 1.084 x10 (d) C&Hi2O, and Ci2H2n01|
(c) 6.022 × 10*
(b) 6.022 x 10² 18. 510 mg of a liquidCi2H2201|
on
8. The numerical value of
N/n
(d) 18
apparatus displaces 67.2
vaporization
cm of
in Victor Meyer
molecules in n moles of gas) is: (where is number of air
N at
mass of the liquid is: (STP). The mola
(a) 8.314 (a) 130
(b) 6.02 x1023 (c) 170 (b) 17
(c) I.602 x10-24 19. If a (d) 1700
atomscompound
(d) L.66 x10-!9
9. Onc litre N. 7 contains two oxygen atoms, four
and number
litre O and I litre CO are taken in a
atoms, the vapour ofhydrogen atoms
density of it is: is double of
carbo
carbo
mixture under identical conditions of P and T. The (a) 88
amounl of gases present in mixture is given by: (c) 132 (b) 44
20 The (d) 72
(a) N, = W), > WCO
(C)WN.
(b) wN, = W(O > WO:
(d) wco > WN, > Wo haemoglobin trom the red blood
ammals
e molarcontains
10. Which has the maximum numbcr of atoms? mass of approximately corpuscles
0.33% of iron by
of m
(a) 6 g( (b) lg H,
of iron atoms
cach
mass of iron = S6): haemoglobin
molecule of
as
67,200. The
ima
nunb
(c)2g Mg (d) 30 g Ca (a) 2
(c) 4 (b) 3
(d) s
haemoglobin
is
(aton
21. The vapour density of as is threc 12. The
timcs that ol gas B 1
the molar mass ofA is . the
molar nass of Bis: Rravincte compositon of water as H: OIs:
(a) l:|
(a) 3 / (C)T: (b) |:2
33. (d) |:16
(d) MW3
22. The vapour density of a volatile Calculate g-alomof clcment in40 kg. if rnass of onc atorn
ol an
chloride of a metal is 95
and the specific heat of the metal is 0.13 clement is 6.644 10
23
B
cal/g. Thc (a) lo' Balom
cquiv alent mass of the metal will be (b) 10 g-atom
(a) 6 (b) 12
approximatcly: (c) 10 g-atom (d) None of thesc
(c) 18 34. Number of g-atom of S present in
(d) 24 49g H2S04 are.
23. A gas is found to have the fomula (a) 0.5 (b) |
(CO),. Its VD is 70. (c) 0.2
The value of x must be: (d) 0.3
(a) 7 35. The CI andCa ions in
(b) 4 222gCaCl, are respectively:
(c) 5 (d) 6 (a) 4N, 2N (b) 2 N, 4 N
24. The volume occupied by one molecule of water (density (c) 1 N, 2N (d) 2 N. I N
lg cm)is: 36. The number of moles of water in 488 g BaCl,2H-O are:
(a) 18 cm (a) 2
(b) 22400 cm (b) 3
(c) 6.023 x10-2 cm3 (c) 4 (d) 5
(d) 3.0 x10- cm 37. An oxide of a metal (M) contains 40% by mass of
25. Vapour density of a metal
chloride 66. Its oxide Oxygen. Metal (M) has atomic mass of 24. The empirical
contains 53% metal. The atomic mass of the metal is:
formula of the oxide is:
(a) 21 (b) 54
(c) 27.06
(a) M0 (b) MO
(d) 2.706 (c) M03
26. 224 mL of atriatomic gas weighs lgat 273K and I atm.
(d) M}04
The mass of one atom of this gas is: 38. Number of mole of I m' gas at NTP are:
(a) 44.6 (b) 40.6
(a) 8.30 x 10-2 g (b) 2.08 x 10-g (c) 42.6 (d) 48.6
(c) 5.53 x 10-g (d) 6.24 x 10g 39. The highest mass corresponds to which of the following?
27. The pair of compounds which cannot exist in solution is: (a) I molecule ofO) (b) | x 10-23 gmole of 0
(a) NaHCO; and NaOH (b) NaC0;and NaHCO; (c) An 0* ion (d) 1mole ofO
(c) NaCO; and NaOH (d) NaHCO and NaCl
40. The largest number of molecules are in:
28. The per cent of Nin 66% pure (NH4);S04 sample is: (a) 36 g H0 (b) 28 g Co
(a)32 (b) 28 (c) 46 gCzHsOH (d) S4 g N05
(c) 14 (d) Nonc of these
41. Which contains grcatest number of oxygen atoms?
29. Total number of atoms present in L0 cm of solid (a) l g of O
glucose (density 0.8 gcm') at 25°C are: (b) l gof O;
(b) 6.42 xl0** (c) l g ofO,
(a) 2 68 xl0! (d) Al have the same number of atoms
(c) 2.68 xl0" (d) 2.68 x1023
is in 42. The percentage of nitrogen in urea is about:
30. Mass of oxvgen in one mole cach of Fe 0; and FeO (a) 38.4 (b) 46.6
the simple ratio of: (c) 59.1 (d) 61.3
(a)3:2 (b)I:2 43. Number of electrons in I.8 mL of H0 is:
(d) 3:1 6.02 x J03 (b) 3.01 |x 1023
(c)2:I a mole of
(a)
are present in (d) 60.22 x 10²!
31. How many atons
CHCOOC, H6?
(c) 0.6022 x 102 amu is:
44. The mass of an atom of atomic mass 260
atom/mol (b) 4.32 x10-2g
(a) 14 x 6.02 10- (a) 4.32 xI0-2g
(b) 10 6.02 10 atom mol (c) 4.32 xlg (d) 4.32 x1og
ic)7 th 02 10 atom mol
dy Nonc of the ahove
 18

45. Whch has the

highest mass
(a) lg-atom of (
(b) 12 ole ofCH4
(c) 10 ml of water
(d) 3.011 0 atoms of ovvgen
46. Pand ( are two clements wheh forms P(0, and /0,
015 molc of P weghs Isog and 0 IS mole of /:
wCighs 93 . the atennic masses of and () arc
55.
respectivcl
(a) 6. IN (b) IN, 6
(c) 6, 72 (d) 36, 52
47. Number of years required to spend Avogadro's numbet
of rupce at the rate of I million rupee per second :
(a)l9 xI0 (b) 1.9 x I0 y
56.
(d)|.9x\o"
48. Acylinder made up of an alloy containing Fe. Co and Mo
cqual to 71°%. 12% and |7% respectively. The density of (2
alloy is 8.20 g'mL. How many Co aloms are there in a (C
cylinder of radius 2.50 cm and a length of 10.0 cm. 57. Th
Atomic mass of Co = 60 g mnol -1. 75
(a)1.9x1025 (b) 1.9 x1024 S

(c)1.9x 106 (d)1.9x1023 (a)

(c)
2. Stoichiometry 58. On
 \
21. (c) Vapour density of A= 3x<Vapour
I. (b) Molar mass of (0, = 44
density of B
Molar mass of =3x Molar mass of b
00 = 2727°, 9 (hi Molar mass of metal chloride 95 * 2 = J90
6.4
L. (b) Equal cquIvalents of reactant react to gve sane cquivalent o alomic mass of metal : 0.13 = 49.23
product.
3. (a) The law is valid for metals only Let the metal chloride be MCI.
4. (c) Empirical fomula mass of CH0= 0 Then 49.23 + n 35.5 190
Molar mass = 180 n=3.9 4;
Molar mass = cmpirical fomula mass Xn
.. Equivalent mass of metal = -121
.n=6
. Molecular fomula = (CH:O, = CH,0% 70 x 2 = |40:
23. (c) Molar mass =
5. (a) No. of molecules in n mole n Av, no; AIso no, of atom in l (CO),.:. (12+ 16). x= 140
molecule atomic1ty. molecules
6, (d) mole Pa =N molecules of P = 4 V atoms of P. 24. (d) :: 18g water has N
:.lgor I mL water has molecules
7. (a) C contains 6N protons, 6 N clectrons and 6 N neutrons.
Xn =N.
8. (b) or molecules occupy volume =
9. (c) wN, = IxPx ;wco
28 =wo, -x ..l molecule occupies volume
RT
-Bl8 33x102 cm!
10. (d) Mole of Ca =0
40 (the largest value) N 6.023x
11. (c) Mole of Nis (the lowest value) 25. (c) Molar mass of chloride = 66 x 2= 132
Equivalent of metal = Equivalent of O
12. (b) lonic compounds are usually referred in tems of their formula.
The exact molar mass of ionic compounds is not
determined
experimentally. Simply their formula mass is reported. E=9
13. (c) VD of substance = 4 (when VD of CH4 ) Let metal chloride be MCI,
:. VD of substance =8 x 4 (when VD of CH4 8) 9xn+35.5n =132
.. Molar mass of substance = 32 x 2 = 64 n=3
wRT
14. (c) m=py 0.22 x 0.082 1x 293 . Atomic mass of metal 27
O55 -17.7)/ 760]x(45/1000)
26. tc) PVRT
15. (d) I mole NH, 10 N electron

mole NH, 10xN x3.01x 10 electron Ix224xo.0821

1000m x273
.. Molar mass of gas 100
16. (d) g-atom ofx=-1.01
75 Now 3 N atoms (triatomic gas) weighs l00 g
.:. Iatom of gas mass 00 100
g-atom of y= = 1.5 3N Sx6.023x023
K:::2:3 = 5.53 x10g
17. (a) Both have same empirical fomula CH,0. 27, (a) NaHCO being an acid
salt will react with Na)
18. (c) Victor Meyer's mcthod is used for volatile substances.
NaOH + NaHCO NaCO +H;0
28. (c) .:. 132 g (NH ) SO4 has N= 28 g
m wRT_ S10x10 x00821 x273120 28x 66
Ix67.2/1000 .66 g (NH4 SO4 has N
132-14g
19. (b) The compound is CaHO: 29. (b) Mass =0.8xl = 0.8g
Molar mass = 88 180 g CoH206 has 24 N atom
88 0.8 gCaH:06 has 24x0.8xN
Vapour density ==4 180 =6,42 x 102 .

30. (d) Mass of Oin Fe;O and FeO is 48: 16

20. (c) I00 gsample z 0.33g iron
1. (a One molecule of CHCoOC2Hs
67200 g= 221.8g iron contains l4 o
32. (c) Mass of H:0 in HO is 2: 16
Number of iron atoms per molecule of haemoglobin
33. (c) Mass of N atom = 6.644 x I0 -23 x6,023x
221.8
$6
4 or 40 g g-atom:
x10 40 g
 L. b) Molar mass of (0, = 44 21.(c) Vapour density ofA = 3x Vapour
I00 2727°.
Molar mass of A =3XMolar mass of of e density
22. (b) Molar mass of metal chloride 95 x 2= l
2. (b) Equal eyuivalents of rcactant eact to gise sane cquivalent ol atomic mass of metal 6.4
product. 0.R49.23
3. (a) The law is
vald for metals only
4. (c) Empiical fomula mass of (H0- Let the metal chloride be MCI,,
0
Molar mass 180 Then 49.23 +n35.5 190
n=3.9 4;
Molar mass empirncal fomula mass XH
.. Equivalent mass of metal=2-123
Molecular formula = (CH:0O, = CaH:O%
$. (a) No. of mnolecules in # 23. (c) Molar mass =70 x 2= 140:
mole n Av. no, Also no. of atom in I
(CO),.:. (12 + 16).x = 140
molecule atomicity.
6. (d) mole P =N molecules of P, = 4N atoms of P. 24. (d) : 18g water has N molecules
7. (a) C contains 6 N protons, 6N clectrons and 6 N ncutrons. .lgor I mL water has molecules
8. (b) = X=N4,
9. (c)
n
or molecules occupy volume =lcmd =)
.Imolecule occupies volume
10. (d) Mole of Ca = 30 18
1o23 cm!
40 (the largest value) 6.023 x1233x
11. (c) Mole of Ng is
=(the lowest valuc) 25. (c) Molar mass of chloride = 66 x 2 = 132
12. (b) lonic compounds are usually
referred in terms of their fomula. Equivalent of metal = Equivalen of O
The exact molar mass of ionic $3_47
compounds is not determined
cxperimentally. Simply their formula mass is reported.
13. (c) VD of substance = 4 E=9
(when VD of CH4 = 1) Let metal chloride be MCI,
..VD of substance = 8 x4 (when VD of CH48) 9xn+ 35.Sn = 132
.:. Molar mass of substance =32 x2 =64
n=3
14. (c) m=pywRT 0.22 x 0.0821 x 293 .. Atomic mass of metal 27
15. (d) I mole NH
OS5-17.7)/ 760]x(45/1000] 26. (c) PV "RT
10N electron m

1.2 mole NH3 = 10xN

22.4 >x=3.01x 10 electron lx24l,
1000*0.0821 x273
:. Molar mass of gas 100
16. (d) g-atom of x=B = L.01 Now 3 N atoms (triatomic gas)
g-atom of y= .2s .:.
weighs 100 g
I atom of gas mass = 00 100
16 3N 3x6.023 x 023 8
:::2:3 =
17. (a) Both have same empirical 27. (a) 5.53 x10 2g
formula CH:0. NaHCOg being an acid salt will
react with NaO1
18. (c) Victor Meyer's method is used for volatile substances.
NaOH + NaHCO NaC0, + H,0
28. (c) .:. 132 g (NH4)2 SO4 has N 28g
m= MRI. $10x 10x0.0821 x 273 = 170
PI Ix67.2 1000 . 66 g (NH4- SO4 has N28 x 66
19. (b) The compound is C4H,0:
3214 g
29. (b) Mass = 0.8xl 0.8 g
Molar mass = 88 180 g CoH:0, has 24 N alom
Vapour density = 83 = 44 0.8 g CaH:06 has 24
20. (c) I00 g sample = 0.33 g iron 30. (d) Mass of Oin Fe:03 and FeO is 48: 16 x0.8XN642
180 x 102

67200 g= 221.8g iron 31. (a) One molecule of CH;CO0C,Hs contains 14

.: Number of iron atoms per molecule of haemoglobin
32. (c) Mass of H:0in H-0 is 2: 16 atomns.
221.84 33, (c) Mass of Natom = 6.644 x10= x6.023 x =
or 40g = g-atom: 40 :
14. () ON g nle rato On te0, and F e ) = .16
35. (a)
|:S0, conans So Iole of S
1.35

|lgabntany
36. c) 44 g
lBaCl
N ons
ofCa and 2N ons ol O
S1. (d) Per cent loss of H;0) in one mole of

37. 2H0contains
(b)g-atom metal
of
2 moles
ofwalet Na,S04 nll,) 142+ In)
55

n- 10
8-aln of oVen
2.5 52. (d) zH, 30)2C0, 211,0
sImole ralio of 2% gC;H reacts with 96 g oxyyen.

38. (a)
M:0::2.5:2.S
:1:1
53. (a) C+0)
224 litre I nole: 12 gCnccds 22.4 Iitre O or 5 22.4 litre air.
54. (b) Mass is always conserved in a chemical reaction.
lm' =l0 litre
=22.4 =44.6
39. (d) Imole of 0, 55. (a) H;+0’H,0
has 32 e: the highest
40. (a) 2
mole of H,0= 36 g value in all the given data. Mole before rcaction,
H;0= 2N
41. (d) l6gO
contains atoms ofO molecules.
N Now mole ratio for H2:0,:H,0::1i:V2:1;
Also, O, is limiting reagent thus, mole ratio afler reaction,
32 g O contains 2N
atoms of O
48 g O; contains 3N 2
42. (b) 60 g atoms ofO
NH;CONH, has 28 g N i. mass of H,0formed =x18 =112.5 g
:. 100 g urca has N =0X10 46.69 56. (d) Silica Water Clay Mineral
60
43. (a) 18 mL H0 or 18 g 45 43 Initial %
H50 has 10N electrons. 8
44. (a) Iatom = 260 amu = (92- a) % after heating
260 x L66 The % ratio of silica and clay remains constant on heating
45. (a) Calculate mass of x\02g=4.32 x10g 45
each. i.e..
46. (a) Let atomic masses of P 2-4
and O be a and b
0.15(2u + 36) = 15.9 respcctively -H20
a= 47%
57. (a) CGH:0H
0.15(a+ 2h) = 9.3 molar mas l02
CGH)2
molar mass 84
u =26
" 102 gcyclohexanol gives 84 gCoH12
b= 18
47. (d) Rupce spent sec = 10" :. 100 g cyclohexanol will give 84 x\00 g CaHy2
102
Total rupee =6.023 x |0 Also % yield is 75%
:. 10 x 60 x 60x 24 x 365 rupee :: 100 gcyclohexanol will give =54 X100xgCAH,
spent in onc year 102^100
.:. 6.023 x10 rupee spent in yr = 6.023 x 10 -61.769 gCoHi
10 x 60 x 60× 24 x 365
S8. (d) g-atom of l; -2:
=1.9x 100y 80
48. (b) Mass of alloy Volume of cylinder x density g-alom of oxygen= 5
=Ir`hxd . Compound is I;0s
x(2.5x 10x 8.02 =1610.7 g 59. (c) Let a g of Cu be oxidised to give CuO, i. e., (63.6+ 16)
63.6
Thus, final mass
Mass of Co in cylinder I610.7 x12. =193.3 g
100 =(3.18-a)+ 63.6+ l6j10
63.6
.:. No. of atom of Co = 6023 xl060 x193.3-10v10A a= 2.94 g
Thus, % of Cu left unoxidised
49. (d) Imole C'a Imole CaCO; = 100g (3.18-2.94),
3.18
100 =155%
Rating mg of Ca0; needed per g chelating agent (molar
mass 380) 60. (c) 3li, 2NH
l00x 10 0.5
= 263 mg
380
(os
50. (a sg Fe:0i=le Fe0:=Xmole o :. NH; would have formed
le F)!moie O
 Now
6. ( Rutane md iobutane hanc same moleclar formula
Thus n2
a2rt -2(29 29
Therefore.
ZNgCHo requres : "NaHSO, H:0
78. (ay NaOH H;SO.
To0g CHo requres 0 Fquvalent mass ofH;SO, - Molar mass I
ZNaoH H,SO, +NaHSO, H;0.
mass
62. ic) 4nhg ('a': will gve 28 n kg polvethylene Equivalent mass of H,SO,- Molar
raass valence factor
-.20 kg CaC% wll eane nx 20 = N.75 kg 79. (a) Molar mass = cquivalent and give same
64 n in same number of equiv alentAlso eguivalkt
80. lc) Elements react cquivalents
63. (a) Limiting reagent is one which is completely consumed in number of of products
neaction mass
equivalent mass
64. (c) C0:+ C ’ 2C0
es == -49;
2 81. (b) Equivalent mass =olar
basicity
1-t2r = |4 findx.
Basicity =2:Only two H are replaced
65. (c) 2KCIO; 2KC] + 30,‘: Also H;O is monovalent. thus
245 g KCIO; on heating shows a mass loss =96 g (of O:) 82. (a) 0.5 mole of H}0 20 g:
Molar mass = Equivalent mass
.. 100 g KCIO; on heating shows a mass losSs
I mole ofHj0*=40g
96x 100 8 39.18%,
245
83. (d) Valence of M=3.
66. (c) 3H, + Ny’2NH;:
Initial volume or mole = 4
Thus, formula of chloride is MCl3.
Final volume or mole = 2 84. (a) Let atomic mass of metal bex
l6 bg oxygen combines with xag metal
67. (a) Ag:CO,2Ag+ CO; + (V2)0, -q-8 a-x
.. 8g oxygen combines with==E
68. (d) CGHA +a+lo,c0, +(b/2)H;0 26-E
a
Excess
Also molar mass of metal oxide = ax + 16hg mol
10g = 40 85. (d) meq. of oxide = meq, of hydroxide:
0.995 1.S20 :. E= 9
Sh= 50
69. (c) Stoichiometry represents mole ratio or volume ratio o!
Thus. F8E+17
reactants and products. 86. (c) Molar mass of MCI, = 2x32.7+ 7| = 136.4
70. (b) See mole ratio A:B:C::1:2:1 87. (b) Equivalent of metal oxide = Equivalent of oxygen
71. (a) Mass and no, of atoms are conserved in a balanced chemical 100_ 20 :.E40
equation. This is law of conservation of mass.
72. (b) The reaction is not balanced. 88. (c) Equivalent of metal Equivalent of C1
73. (b) Follow law of multiple proportion. 74.4 -35.5_35.5
74. (c) Equivalent of metal Equivalent ofoxygen,
E= 38.9
Thus,
1.053.15-1.05
89. (a) meq. of metal = neq. of oxygen
E-4 6040
E
75. (d) meq. of oxide - mey. of H.
E=12
01596 6x 10 E=18.6 Now, meq. of metal = meq. of bromide
E+8
.. atomic mass I8,6 3= $5.8 100-a_ a
(:: valence - 3) 12
76. (b) quivalent of metal Equivalent of oxide
a87o
1.6 2
90. (d) Valence = 26.89 -3
77. (a) Molar mass of metal 8.9
chlonde = S0 2- 100, :.
Let metal chlonde be MCI, then M= Exact atomic mass =89 3=26.7
29% and Cl 71% 91. (d)
Equivalent of metal Equtvalent of chloride, or = Equivalent of metal Equivalent of chionne
355 :. E=2=11,75
355