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Board Pattern Test-01 Lakshya JEE Fastrack (2024) 29/10/2023

CHEMSITRY

SECTION - A Passage-II
Passage type question (1-2): (4 × 2 = 8) 2. Read the passage given below and answer the
Passage-I following questions:
1. Read the passage given below and answer the Consider the reaction represented by the equation:
following questions: CH3Cl(g) + H2O(g) → CH3OH(g) + HCl(g)
The concentration of a solute is very important in These kinetic data were obtained for the given
studying chemical reactions because it determines reaction concentrations:
how often molecules collide in solution and thus Initial rate of
indirectly determine the rate of reactions and the Initial conc. (M) disappearance of
conditions at equilibrium. CH3Cl Ms–1
There are several ways to express the amount of [CH3Cl] [H2O]
solute present in a solution. The concentration of a 0.2 0.2 1
solution is a measure of the amount of solute that 0.4 0.2 2
has been dissolved in a given amount of solvent or 0.4 0.4 8
solution. Concentration can be expressed in terms The following questions are multiple choice
of molarity, molality, parts per million, mass questions. Choose the most appropriate answer:
percentage, volume percentage, etc. (i) The rate law for the reaction will be:
The following questions are multiple choice (1) r = k [CH3Cl] [H2O]
questions. Choose the most appropriate answer: (2) r = k [CH3Cl]2 [H2O]
(i) 1.24 M aqueous solution of KI has density of (3) r = k [CH3Cl] [H2O]2
1.15 g/cm3. Molality of this solution will be: (4) r = k [CH3Cl]2 [H2O]4
(Molar mass of KI = 166 g mol–1)
(1) 2.61 (ii) Order with respect to [CH3Cl] will be:
(2) 1.31 (1) 0 (2) 1
(3) 4.12 (3) 2 (4) 3
(4) 3.12
(iii) Overall order of the reaction will be:
(ii) Which of the following is temperature (1) 0 (2) 1
dependent? (3) 2 (4) 3
(1) Molarity
(2) Molality (iv) Unit of rate constant will be:
(3) Mole fraction (1) sec–1
(4) Mass percentage (2) litre2 mol–2 sec–1
(3) litre mol–1 sec–1
(iii) A solution of CaCl2 is 0.5 mol/L; then the (4) mol litre–1 sec–1
moles of chloride ion in 500 mL will be:
(1) 0.5 (2) 0.25 Multiple Choice Questions (3–16) (14 × 1 = 14)
(3) 1.0 (4) 0.75 3. At 25°C, the values of rate constant, activation
energy and Arrhenius constant of a reaction are
(iv) For preparing 0.1 M solution of H2SO4 in one 3×10–4 sec–1, 129 kJ/mol and 2×1015 sec–1
litre, we need H2SO4: respectively. The value of rate constant as T →  is:
(1) 9.8 g (1) Zero (2) 2 × 1015
(2) 4.9 g (3) 3 × 10–4 (4) 6 × 1011
(3) 49.0 g
(4) 0.98 g
 2

4. What is the activation energy for the reverse of 11. Calculate the cell potential (in V) if ΔG = –96.5
this reaction? kJ/mol and n = 1.
N2O4(g) → 2NO2(g) (1) 0.1 (2) 1
Data for the given reaction is H = + 54 kJ and (3) 10 (4) 100
Ea = + 57.2 kJ.
(1) –54 kJ (2) + 3.2 kJ 12. For a first order reaction, A → Products, initial
(3) + 60.2 kJ (4) +111.2 kJ concentration of A is 0.1 M, which becomes
0.001M after 5 minutes. Rate constant for the
reaction in min–1 is:
5. The standard Eored values of A, B and C are
(1) 0.4606 (2) 0.2303
+0.68 V, –2.54 V, –0.50 V respectively. The order
(3) 0.9212 (4) 1.3818
of their reducing power is:
(1) A > B > C (2) A > C > B
13. If liquids A and B form an ideal solution:
(3) C > B > A (4) B > C > A
(1) The free energy of mixing is zero.
(2) The free energy as well as entropy of mixing
6. How many coulombs are required for the
are zero.
oxidation of 1 mole of H2O2 to O2?
(3) The enthalpy of mixing is zero.
(1) 9.65 × 104 C (2) 93000 C
5 (4) The entropy of mixing is zero.
(3) 1.93 × 10 C (4) 19.3 × 102 C

14. y g of a non-volatile organic substance of

7. Free energy change (G) is related to the emf of
molecular mass M is dissolved in 250 g benzene.
the cell (E):
Molal elevation constant of benzene is Kb.
(1) E = nFG
Elevation in its boiling point is given by:
(2) G = – nFE
M 4K b y
RT (1) (2)
(3) G = − Flog E Kb y M
n
nF Kb y Kb y
(4) G = − log E (3) (4)
RT 4M M

8. The standard electrode potentials for the reactions, 15. A solution of sucrose (molar mass = 342 g mol–1)
Ag+(aq.) + e– → Ag(s) has been prepared by dissolving 68.5 g of sucrose
in 1000 g of water. The freezing point of the
Sn2+(aq.) + 2 e– → Sn(s)
solution obtained will be:
at 25°C are 0.80 volt and –0.14 volt respectively.
The emf of the cell, (Kf for water = 1.86 K kg mol–1)
Sn | Sn2+ (1M) || Ag+ (1M) | Ag is: (1) –0.372°C (2) –0.520°C
(1) 0.66 volt (2) 0.80 volt (3) +0.372°C (4) –0.570°C
(3) 1.08 volt (4) 0.94 volt
16. In the first order reaction the concentration of the
9. The unit of rate constant for the reaction reactants is reduced to 25% in one hour. The half
2H2 + 2NO → 2H2O + N2 life period of the reaction is:
which has rate = K[H2][NO]2, is: (1) 2 hours (2) 4 hours
(1) mol L–1 s–1 (2) s–1 (3) 1/2 hour (4) 1/4 hour
–2 2 –1
(3) mol L s (4) mol L–1
SECTION - B
10. The van't Hoff factor for 0.1M Ba(NO3)2 solution (Very Short Answer Questions) (17 – 25) (9 × 2 = 18)
is 2.74. The degree of dissociation is: 17. Calculate the overall order from the given rate
(1) 1.3 % (2) 87 % expressions.
(3) 100 % (4) 74 % 1. Rate = k[A]1/2 [B]3/2
2. Rate = k[A]3/2[B]–1

18. The half-life period of a 1st order reaction is 60
min. What percentage of the substance will be left
after 240 min?
19. What are isotonic solutions?
20. Why do gases nearly always tend to be less
soluble in liquids as the temperature is raised?
21. Electrolysis of KBr(aq) gives Br2 at anode but
does not give F2. Give a reason.
22. What is meant by abnormal molecular mass?
Illustrate it with suitable examples.
23. Time required to decompose SO2Cl2 to half its
initial amount is 60 minutes. If the decomposition
is a first order reaction, calculate the rate constant
of the reaction.
24. The molar conductivity of a 1.5 M solution of an
electrolyte is found to be 138.9 S cm2 mol–1.
Calculate the conductivity of this solution.
25. The standard electrode potential (E°) for Daniel
cell is +1.1 V. Calculate the G° for the reaction
Zn(s) + Cu2+(aq) → Zn2+(aq) + Cu(s)
(1F = 96500 C mol–1)
SECTION - C
(Short Answer Questions) (26 – 30) (5 × 3 = 15)
26. Following reactions may occur at cathode during
the electrolysis of aqueous silver nitrate solution
using silver electrodes:
Ag(+aq ) + e− ⎯⎯
→ Ag( s ) , E = 0.80 V
1
H(+aq ) + e− ⎯⎯→ H2( s ) , E = 0.00V
2
On the basis of their standard electrode potential
values, which reaction is feasible at cathode and why?
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27. 18 g of glucose, C6H12O6 (Molar mass-180 g
mol–1) is dissolved in 1 kg of water in a saucepan.
At what temperature will this solution boil? (Kb
for water = 0.52 K kg mol–1, boiling point of pure
water = 373.15 K)
28. Calculate the mass of compound (molar mass
= 256 g mol–1) to be dissolved in 75 g of benzene
to lower its freezing point by 0.48 K (Kf = 5.12 K
kg mol–1)
29. The resistance of a conductivity cell containing
0.001 M KCl solution at 298 K is R = 1500 Ω.
What is the cell constant if conductivity of
0.001 M KCl solution at 298 K is 0.146 × 10–3 S
cm–1?
30. A reaction is of second order with respect to a
reactant. How will the rate of reaction be affected
if the concentration of this reactant is
(i) Doubled
(ii) Reduced to half ?
SECTION - D
(Long Answer Questions) (31 – 33) (3 × 5 = 15)
31. What is meant by rate of a reaction? Differentiate
between average rate and instantaneous rate of a
reaction.
32. Depict the galvanic cell in which the reaction
Zn(s) + 2Ag+(aq) → Zn2+(aq) + 2Ag(s) takes
place. Further show:
(i) Which of the electrode is negatively
charged?
(ii) The carriers of the current in the cell.
(iii) Individual reaction at each electrode.
33. 100 mg of a protein is dissolved in just enough
water to make 10.0 mL of solution. If this solution
has an osmotic pressure of 13.3 mm Hg at 25°C,
what is the molar mass of the protein?
(R = 0.0821 L atm mol–1 K–1 and 760 mm Hg = 1
atm)