P Block Group 18 Revision Notes Jee Mains L Neet L Kota Short Notes L Inorganic Chemistry L

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Chemistry HandBook

GROUP 18 ELEMENTS NOBLE GAS


1. Relative Abundance: In Dewar's method, the separation of noble gases is
Ar> Ne> Kr> He > Xe > Rn summerized below
2. Melting and Boiling point: Mixture of noble gases (He, Ne, Ar, Kr, Xe)
Rn> Xe>Kr> Ar> Ne> He in contact with coconut charcoal at 173K

He has the lowest boiling point among all element


Noble gases are monoatomic, colourless, odourless, Unadsorbed adsorbedXKe)
spraingly soluble in water and diffusing through (He, Ne) (Ar, Kr.
most in contact with charcoal at 93 K in contact with another charcoal at
commonly used laboratry materials. liquid air temperature.
5. O,IPtFJ is the first noble gas compound.
6. Ar, Kr and Xe form clathrate compound Adsorbed Unadsorbed
when pass e He In the first charcoal Second charcoal
in ice with high pressure. Kr, Xe. Temp. raised Ar
TO. 183 K
A.6H,O (A = Ar/Kr/Xe)
Evolved Kr Remained adsorbed Xe

The viscosity of He is extermely low, about 1/100th of


hydrogen gas.
Prepration of Xe-Fluoride:
F673K, 1 bar
XeFz
2F 873K. 7 bar O
Ke XeF XeF, +O,
143K
3F 573K, 70 bar
> XeF
Properties:
Fluoride donor: Eg. XeF2 + MFs >[XeF;f MF,F
(M=As/Sb/P)

Fluoride acceptor: Eg. MF


Xers (M-Na/K/Rb/Cs) M'|XeF,

Fluorinating agents: Eg. XeFs/PtF,/SF, +Xe

XeF +NO 2NOF + Xe

Reaction with SiO,: Eg. 2XeF +SiO, SiF, + XeOF


Hydrolysis:
HO
Xe +2HF +0
XeF

20H Xe +2F +HO+0


6XeF, +12H,0 4Xe +2XeO, +24HF + 30,
Partial hydrolysis
XeOF, +2-HF
HO
XeF XeO, + 6HF
BHO

70H HXeO+3tHO +F*


ex.OH

(NeO+Xe +2H1,0 +0,)

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