vier Kan TIEU CHUAN NHA NUGC | TCVN 138-64 ‘Aw CHO cOne HOA BY BAN KHOA HQC NHA NUGC Vigo Be ledng vA fe chute Tien ehudin nay ap dung cho axit sunfurie acquy sin xuat bling phuong phap tiép xtc. , L YEU CAU KY THUAT Chia axit ra thanh hai Jogi: 1 va Il tay theo ham hugng tap chit chira trong no. 1, Nong dé axit c& hai loai J vi Il déu phai dat trén 9244. Mau ofa axit timg loai khong duge dim hon mau cia dung dich mu quy dinh & mye 11 Ham hong (%) cde tap chit khong duo qua: rin TAP cBdt Losi T | Losi 1 2) Cin khiag bay boi (khéng kB Iugag cht tana bi ey ch Lrongete toa thing Itchy oe ee ee 0,08 0,05 b) Mangen Qin)... +2. + «| 9,00005 | 0,0001 StF. + | 9,006 0,012 Aco... ee. + | 0,0005 | 0.0005 ep Asen (As). oe + =| 9.00005 | 0,0001 8) Oxyt nit (Nada). 2 2 hh) Cée ebft khir kali pemanganat . iy Rim loa ning bj két tia bdi sunfas (khong kB chi va s8t) [thee as aah 3 onc t9 =| 0,00005 | 0,0001 theo quy dik & aye 18 4, Axit sunfuric acquy phai durgc bd phan kidm tra kf thuat cia nha may sin xndt kiém nghiém va chdp nhan. Bén nha may khi giao hing phai dim bao axit bin ra theo ding cde yéu cau cia tiéu chuin nay. Méi 10 hang phai duge kém theo gidy ching nbn xéc nban chét lugng cia axit. Kon KE Abad Mas hoe trots Bat hye Bdeh Khoa bide urbe naty t-10-1968Trang 2/16 TCVN 138-64 Axit sunfurle aequy I, PHUONG PRAP THt 5. Béa nhan hang cd quy8a cin cir vo cde quy dink ve dy mau va edo phuong phap thir cita tigu chu&a nay dé kitm tra chit Iugng ofa axit néu thay olin thiét. 6, Lay miu d8 thir trong 5% s6 chai cia Jo bing nhung khong duge it qui 5 chai déi vai 10 hang be. Dung cu Iiy mAu LA mot ong thity tinh dai dé thong dén tan @ay chai. True khi iy miu pha quay ‘that 48a oxit dung trong chai. Trutng hp cba anit trong cde toa thing lst chi tbi ly miu trong tirng toa mt, yj tri fy 14 & trén, & gitka va & day toa r3i tron chung fai. Khdi hong chung cia mau thik khoing 1kg. 7. Tron miu the ly dege dem dung vio hai chai thiy tinh sach, kho, c6 nat thy tinh nhim. Ngoai chai din nb&n, trén nbn ghi: Ten don vi sin xnit, ten va Jogi sin phim, 96 higu cia 16 hang hofe toa thing ad duge ldy mau, ngiy, thdng, nim, nguoi ly mau. Mot chai dem phan tich. Mot chai d2 lai trong 3 thang d2‘d6i chitug-khi cam phan tich trong tai. Chon phong thi nghiém phan tich trong tai do sir 1hda thujn ca ede bén hitu quan. 8."Trong trudng hop Két qua phan tich khong at sulci thi phai ly mgt hegng axit gap ddi trong mau thir dé ‘phan tich lai. Két qua lin phan tich ndy di chi mot chi tiéu khong daf tht ci 16 hang cling du bj loai ba. 8, Nhitng thuéc thir diing 48 phan tich, danh tir tinh khiét loai I tng voi logi ex.a2 ola Lién x0 hay ¢pa> cia cae mrt khie, danh tir loa HT tag véi cs. 8.a» ca Litn x6 hay ce.py'tia ede nude khéc. 10. Xée dink ndng 26 azit sun furic (H,S0,) a) Nguyén tée cha phrong phip Dang dung dich kiém manh da biét trudc nding do a chun d@ axit,Trang 318 Axit sunfurle acquy TCYN 138-64 b) Héa phim Natri hydroxyt NaOH hay koli hydroxyt KOH, tink khi¢t foai I, dung dich 0,5N. Metyl dd, dung dich requ 0,19. c) Gach tam ‘Trong mot lo cin ob nap da say kho dén khdi Ingng khong 48i va can truée chinh xic dén 0,0002g, cho vo khong 3g (2,5—3ml) axit clin thir, day nfip lai va can chinh xéc dén 0,00029. Chuy&n hét axit vita ctn duge vio binh clu dinh mire dung tich 250in! di cho sfin khodng 150ml nwéc edt, lam ngudi, them nwéc c&t dén vach vA Ide clin than, Ding pipet My 50m! dung dich vira pha dem chudia dé bang dung dich natri hydroxyt hay kali hydroxyt. Chit chi thi li metyt da. Nong d6 (9%) axit c&n thir X, tinh theo cong thire: V.N.49,04,250,100 _ 24,52. V.N aa ¢ trong dé: Ve=lugng dung dich kitm di ding a8 chun a9, tinh bing ml; N= ning do dirong lung fia dung dich ki8m 4a ding: 49,04 — dwong luong gam cita H,S0,; G — lwgng axit cin thir di cAn, tinh bing g. U1. Xée dink euong a6 miu a) Nguyén the cita phurong phép So sanh bang mit miu ofa axit cin thir voi mia cia dung dich miu, b) Hoa phom Amoni hydroxyl NHOH, tinh khidt loai IT, dang ajeh 25%. Natri sunfua NogS.9H,0, tinh khiét loai H, dung dich 2% Gelatin, loni ding trong thre phim, dung dich 1%. Chi axetat Pb (CH;COO),.3H,0, tinh khiét loi 1; dung dich mau ditu ché nhur sau: Hoa tan 0.1579 chi axetat bing nude efit rdi chuytn vao binh cau dinh mire dung tich 1 lit. ‘Them nuée eft dn vach vi lac chn thén.Trang 4jt6 oh TCYN 138-64 Axit sunfurie sequy. ¢) Céch lam Chon hai 8ng so miu e6 mu sfc va kich thude nh nhaw. ‘Trong mét ng cho vao khofng 20ml axit cn thir, Sng cdn lai cho vao 10m! miréc eft, 3m! dung dich gelatin, 2~3 giot amoni hydroxyt, 8ml dung dich natri sunfua va Um! dung djch chi axetat miu néu ding d® xA¢ djnh anit loai {, va 2m! dung dich chi axetat miu néu ding 48 xAc dinh axit loai II va ldo du. Mau eda axit cin thir khong dege dam hon miu ciia dung dich nay. 12, Xée dink ham long edn khéng bay hot Lac kf méu exit clin thir. Cho vao chén sir hay bach kim 48 lam kh6 d&n kh8i Iwgng khong dBi va cin chink xtc dén 0,0002g khoing 25ml axit clin thir. Can chén dung axit chinh xtc d€n 0,01g. Sau do cho axit bay hoi dén khd trén bép cét hay bép dign. Nung ofn kh6 & 600 —700°C tir 5—7 phat. Lam ngudi trong binh hit &m rdi can chinh xAc dén 0,00029. Ham Iugng (#4) ein khong bay hoi Xy tinh theo cong thite : = 82.100, ~~ G trong dé: Gy — lugng on khong bay hoi, tinh bang gi G —lwgng axit cn thir 4a cf, tink bing g. 13, Xée dink ham long mangan (Mn) a) Nguyén téc cita phuong phap Oxy hoa tap ch&t mangan thanh axit pemanganic cd miu tim hng, So sanh bing mat maa cha dung dich nay voi mau cia dung dich mu. b) Héa phim Asit sunturic H,SO,. tinh Kehi¢t loai I, ty trong 1.84. Bac nitrat AgNO,, tinh khit loai If, dung dich 0,1 N. Axit photphoric H,PO,, tinh khiét logi Il, t trong 1,65. Amoni pesunfat (NH,)2 Sa0¢, tinh khidt loai It. Kali pemanganat KMnO,, tinh khiét logi I, dung dich mau ia ché nhwr sau:Trang 516 Axit sunfurie acquy TCYN 138-64 Dung dich A: Hoa tan 2,877g kali pemanganat bing nuxéc ‘ot néng rdi chuyén yao binh cdu dinh mic dung tich 1 lit, lam ngudi, thém nuae c&t dén vaeh va lic clin than; Dung dich B: 10m! dung dich A pha long bang nwée eft trong binh cu djnh mite dén th? tich 100ml. Amd dung dich B tuong tng voi 0,1mg mangan. ¢) Caich lam Cho 10 — 16ml nurdc c&t, 2m! axit sunfuric tinh khiét loai I va Iml axit photphoric vao chén dung cin khong bay hoi (muc 12), Bun s6i, loc dung dich vo ede 100ml va riza tiép cn tren gidy loc 2—3 Van. Thém vao dung dich loc 1m! bac nitrat, 1= 2 amoni pesunfat, dua nhe cho déa kbi phan hiy hét amoni pesunfal ya xudt hign miu tim hing. Lac dung dich da agudi dd vao ng so miu. Liy mot Sng so miu khde cd miu slic va kich thirée giéng nhw Ong kia, cho vao mot lgng née eft gin bing thé tich dung dich vita thu duge & Sng truoe, Dang microburet nhé tir tir dung dich B vao Sng nwréc cit, lac du cho dén Khi mau cia hai dung dich giéng nhau, Ham Ing (96) mangan Xq tinh theo cong thie: X= V.0,0001.100 _ 0,01 * ¢ 6 trong 46: Y= lwong dung dich B di ding, tinh bling ml; G — lugng axit edn thir da cin 5 moc 12, tink bang g. 14, Xée dink ham long sit (Fe) ‘A. Phuong phip ding may do mau quang didn a) Nguyén tde ctia phurong phép Ding may do mau quang dign d@ so mau cia phire chat da Auge tgo thinh giita ion Fe [II véi ion sunfosalixilat trong méi truong exit. b) Héa phéim Phen st Fe (SO,), (NH,).12H,0, tinh khiét loai 1. Axit sunfosalixilic CgF,(OH) (SOgH) COOH, tinh kbidt loai |.Trung 6704 Axit nitric HNOs, tinh khiét loi I, t trong 1,40. Tropeolin 00, tinh khiét logi II. Axit clohydric HCI, tink khiét loai Il, (9 trong 1,19 va dung djch 2N. Axit sunfuric H,SO,, tinh Ebivt loai I, t} trong 1,84. a dinitrophenol, tinh khiét loai Il. Amoni hydroxyt NH,OH, tinh khiét loai IT, dung dich 25%, 10%, 5%. Nuoc oft. Dung dich I: Cho 50g axit santurie tinh khiét loai § vao cde dung tich 850 — 400m dii co sin khoang 120m! nuée edt, them Sil axit nitrie, dun soi trong 5 — 7 phat. Sau khi ngudi cho thém Sml dung dich J/, tung hda bing amoni bydroxyt 10% én khi dung dich co miu vang. BY ngugi rdi ding pipet nhé tir tir axit clohydric 2N cho dén khi dung dich mat miu. Chuyén til ch dung dich trong céc vao binh cu dinh mite dung tich 500ml, them nude eft dén vach va lie cfin than. Dung dich JJ: « dinitrophenol bio hda trong nurée cit & nbigt 49 thedng. Dung dich IJ: Hoa tan 10g axit suofosalixilie trong 20ml nwéc cit, trung hoa bang dung dich amoni hydroxyt 10% dén pH = 2 nghia la khi nhd dung dich Ién gidy tam tropeolin 00 ma miu tim ehuy@n sang mau d6 nhat thi trang hoa da xong. Them nude eft dén 100ml. Gidy tm tropeolin 00 lam nh sau: Nhung gidy loc vao dung djch tropeolin 00 0,196. Bé khd trong khong khi khong co hoi axit va hoi amoniac. ¢) Pha cae dung dick méu dé vé duréng cong chudn Dung dich A: Hoa tan 8,610 phén sft bing nude cat trong binh cu dioh mic dung tich Lit, Axit hoa dung dich bang axit clohydric. Them muée cét dén vach. ml dung dich A Wong ting voi Lng sit. Dung dich B: 25m dung dich A pha thém nuoe efit dén 1 lit inh edu dinh mire. 1 ml dung dich B tuong tng vai 0,025mng sit. TCVN 138-64 Axit sunfurie aequytrang 418 Axit sunfurle acquy TCYN 138-64 Cac dung dich mu: Cho vao trong cdc binh edu dink mie dung tich 100m/ nhitng lwgng dung dich B sao cho hirgng s&t ohira trong eée binh khong duoc chénh nhau qué 0,tmg. Thém vao mi binh elu 50m! dung dich J. Lae du. ‘Trang hoa bing amoni hydroxyt 5% cho dén khi cé mau vang. Sau dé them 25ml dung dieh 1/7 di pha them muée edt dén vach. Khudy du, a2 yen 15 pluit, sau dé do trong may do mau quang dign, d) Céch do BB dung dich J vao cuvet ri dt vao may d@ xée dinh didm zaro cia mAy, Sau dé bit diu do ting dung dich mau. Ghi Id nhitng chi s6 cia dung cu. Cin cir vao 86 lign do duge a8 vé dwong cong chu’in (truc hoanh ghi sé mg, true tung ghi nhirng chi s6 eiia dung cu). Chit thieh: Khong drge dang dung djch 1 48 pha qua 1 ngay. ‘Miu cia dung dich bin trong 2 tun, Cin bio quan cac dung dich mndu rong chd (i. ¢) Céch ade dink ham long sét bling may Ding pipet liy 15ml axit cin thi cho vao cde dung tich 250ml di o6 sin 6Om/ nwoe eft, them Sil axit nitvie, dun sdi trong 5 —7 phat. Sau khi lim ngudi them vao ml dung dieh 1, trung hda bing dung dich amoni hydroxy! 10% cho dén khi xuiit bign miu vang. Lim ngugi rdi them axit clohydric 2 cho dén khi dung dich mit mau. Chuytn t&t cd dung dich vao binh cfu dinh mite dung tich 250ml, thém née cét dén vach, Ide chin than, Lay 50m! dung dich vita pha duge cho vao binh efu dink mire dung tich 100m, trung hda bing amoni hydroxyt 5% cho dén khi xuat hign mau ving. Cho vao 25ml dung dich JT. Thém nue cat dén vach va lac cin than. Dé yen 15 phat rdi méi bat dau do. Ham lugng (%) sat X, tinh theo céng thire: y trong a6: —*— — long siit tim duge tren dwong cong chudn, tinh 1000 bang g Y — khdi lngng rigng eda axit edn thi, tinh bling g/cm,Trang’ 75 TCVN 138-64 Axit sunturic sequy B. Phuong phép so miu bing mit Phuong phap nay ehi ap dung khi khong ob may do mau quang dign. a) Nguyen tde eka phurong phap So mau biing mit dung dich axit clin thir da tao than phire ehit miu dé nau voi ion sunfoxyanua véi mhu efia dung dich mau. b) Hea phim Asit nitrie HNOs, tink khi&t Joni I, 1} trong 1,40. Amoni sunfoxyanua NH,CNS, tinh khigt loai If, dung dich 5%. Rugu isoamylic CyH,,OH, tinh kbi& toai H. Phan sil Fe (S0,)2 (NH,).12H,0, tinh khiét loai 1; dung dich mau aigu ché nhw sau: Dung dich A: Hoa tan 0,861g phen sft bing nude eft rdi chuyén vao binh edt dinh mike dung tich 11it, Them 2— 3m axit nitric rdi pha nuée cét dén vach va Ide en than; Dung dich B: 10m! dung dich A pha nwée c&t d&n 100ml trong binh edu dink mize. Il dung dich B twong ing voi 0,0Lung sft. c) Céch tam Lay khoang Imi axit can thir vao lo can c6 nip da sy kho tn khdi lugng khong ddi va di biét trade kh6i lugng r8i cdn chinh xée d&n 0,0002g, Chuyén hét axit vira cin durge vao binh cau dinh mite dung tich 250m! d& c6 sin khodng 100m! nude cat. Pha thém nude edt dén vach va Ide clin than, Lily 25mi dung dich vira pha duge cho vao eée dung tich 100ml, thém Imi axit nitric. Bun s0i, lim ngudi. Chuy’n hét dung dich nay vao int ng so mau rdi them vao 5m! dung dich amoni sunfoxyanua va Me du, Trong mot@ng so mu khéc e6 mau sie va kich thre ging nh ng trén cho vao khoang 25ml nude edt, Im! axit nitric, 5ml dung dich amoni sunfoxyanua va whd dung dich B tir buret xudng, Wfc déu cho dén khi dung dich co miu gidng hur miu cia dung djeh trong 6ng kia.Trang 9/16 ——————— ee Axit sunfurio acquy TCVN 138-64 Chi thieh : 1. Phil dia chinh bing awéc oft dB th8 tich dang éjeh trong 2 Sng bing nhau rBi mGl so miu. 2, Nén cho thém vio méi Sng m@t lwong rugu isoamslic nh hau (5— 10m) d8 48 so sinh miu hon, 3, RhOng duge ding dung djch B pha di a8 Jau qué 1 ngdy. Ham long (%) sft X, tinh theo céng thire: x, = ¥:0,00001.250. 100 _ 0.0L. ‘ 25.6 G trong 46: — lwgng dung dich B d& chun, tinh bing ml; — lwgng axit can thir 43 cén, tinh bing g. 15. Xée dink ham trong elo (Cl) a) Nguyén tdc eda pheong phap So sdnh & duc cia dung dich axit clin thir sau khi da ding ion bac két tha {ap chit clo voi dung dich miu, b) Hoa phim Axit nitrie HNOs, tinh khiét loai II, dung dich 1: 10 (theo thé tich). Bae nitrat, tinh khidt logi I, dung dich 0,t. Natri clorua NaCl; dung dich m&u digu ehé nhu sau: Dung dich A: Can 0,824g natri clorua di sty khd trong 3 gir & 105—110°C, hda tan va pha lofing bing nue oft dén 1 lit trong binh cau dinh mite, Ac e&n than; Dung dich B: 10m] dung dich A pha nurse c&t d&n 100ml trong binh clu dink mite, lac ein than. Amt dung dich B trong teng voi 0,05mg clo. ¢) Gack lam Lay 11ml (khoding 209) axit clin thir, ehuyén hét vio mot Gng go mau dung tich 100 — 150ml d& c6 sin 50ml murde edt. Lic va lam ngudi. Them nude eft dén 100ml rBi cho vao 2ml dung dich axit nitric, 2m! dung dich bge nitrat, [Ac en than. Trong mét ng so miu khae o6 kich thug va mau sfc ging nhu éng trén, cho a them nude edt dén 100ml r8i cho vio 2ml itrat va lic cBn than.Trang 10/14 TCVN 138-64 | Att sunturle sequy San 20 phit dung dich cé axit cin thir khong duge duc hon dung dich kia. 16, Xée dink ham tong asen (As) @) Nguyen tiie ctia pheong phap Xéc dinh ham Iuong asen bing cich so mau ctia gidy {am thiy ngan II clorua di bj hydro asen Il tac dung voi miu cita giy mau. Hydro asen Ill dutge tao thanh do hydro méi sioh khit tap cht asen trong axit clin thir, b) Héa pham Axil sunfurie H,SO, tinh khiét [ogi I, 1} trong 1,84. Kém kim loai khong cd asen loai dung trong phan tich, toai hat. Thide IT clorun SnCly, tinh khiét loai II, dung dich 10% dit axit h6a bing axit clohydric khong chia asen. Rugu etylic C,H,0H di tinh edt, ndng 69 96% Thiyy ngin II cloraa HgCl, hoge thiiy ngan II bromua HgBrp, tinh khiét loai IT, dung dich 3% trong rurgu. Chi axetat Pb (CHCOO),. 3H,0, tinh khigt logi MI, dung dich 5%. Natri hydroxyt NaOH, tinh khiét loai Il, dung dich 2,5, Diasen irioxyt AsyOg tinh khi€t Joai 11; dung dich mau digu ch€ niur sau Dung dich 4: Hoa tan 0,1920g diasen trioxyt trong 25ml natri hydroxyt 2,5. Trung hoa b&ng axit sunfuric tinh khidt loai I, ri chuy8n h&t dung dich vao binh cu dink mie dung tich Lit, tiem nurée eft dén vgeh va lac fn than; Dung dich B: 10ul dung dich A pha nude eft dén th? tich Lit trong binh edu dinh mite, Ie cn than. 1 ml dung djch B twong ting véi 0,00Lmg asen. Gigy tm thiy ngan IT clorua hay thiy ngin IT bromua dia ch€ nhur sau: Nhdng giy loc vao dung dich thiy ngan Ielorua hoe thiy ngan II bromua trong 1 giv, vat ra ap vio gitta 2 tt gily loc sach, hong khé ngoal khong khi. Cit thanh ting bing rong 2— zn, dai d9 50mm. Bung trong Ip day kin. Giy tm chi axetat chun bj nbwr sau: Nhing gidy loc vao dung dich chi axetat tir 10—20 phat, vét ra dp vao glita 2 ta gityTrang 11/18 Axit sunfurie aequy TCYN 13 ay Joc sach, hong kho ngoai khong khi. Cat thanh tirng bang rong 8—9nun dai dd 50mm. Bung trong lo day kin. Bong thm chi axetat chun bi nbur sau: Nhdng bong hat nude vio dung dich chi axetat tir 10—20 phat, vot ra ép nhe ri dp vio gilka hai lo gidly loc sqch, hong khé ngoai khong khi. Bung trong lo day kin. ¢) Céch lim Xée dinh him hrong asen tién hinh trong dung cy nh hinh va, gdm: Lo I dung tich 30—40mi, 3 Sng thiy tinh II, IIL, IV n6i voi nhan bing cae nut cao su. Ong I) dong kinh trong khoding 15min dai 60 — 70mm, dung gidy tim chi axetat 48 hap thu HS. Ong 117 duéng kinh trong kho&ng 10mm, dai 50 — 60mm dag “bong thm chi axetat, Ong IV dwong kint trong 2—3mm, dai 50—6diin deng gidy thm thy ngan If clorna ho¥e thiy nyan II bromua. Lo Pityeng 40 — 15m. nude edt, 2—3 gigt, thiée If cloruay inl axit can thir,.5 — 6g kém hat. Lip nhanb cdc phn trén-vao migng.lo J. Troiig’r{ot ding ¢u khic fing gléng nhwe ° ‘tht cho vao lo J khoing 10—15ml nude cat, 2—3 gigt thige HI clorua, Smt axit sunfaric tinh khi¢t loai Il tf trong 1,84,5mu dung dich B néu ding dé xac dinh axil acquy loai I hay 10a dung dich B néti dung d2 xac dinh axit acquy toai Il, 5 — 6g kém hat. Lip nhanh ede phan trén vao migng lo J. Sau 1 — 1 gi¢’ rudi mau cha gidy tim thiy ngin If clorua hoje thiy ngan II bromua trong dyng cu co axit cin thi khong duge dim hon miu cia gidy dy trong dung cu kia. 17; Xée dink ham lrong oxyt nite (N03) a) Nguyen the cita phwong php Osyt via nite tao thahh hep chit miu hOng voi axit sunfanilic va a naphtylamin.Trang 12/16 TCVN 138-64 Axit sunfurle aequy So sdnh bfing m&t mitu cia dung dich oxit clin thir nay voi miin eda dung dich mau. b) Héa phdm Natri hydroxyt NaOH, tinh khiét loai I, dung dich 0,5 N. Assit sunfurie HeSO,, tinh khiét loai I, dung djch 0,5 N. Axit sunfanilic NH,CgH,SOgH, loi ding trong phan tich, dung dich 10gil. ‘2 naptylamin CyH;NB, loai ding trong phan tich, Phenolphtalein, dung dich 1% trong rurgu. Natri nitrit NaNO, tinh khit logi I, dung dich mia diéu ché hr sau Dung dich 4: Hoa tan 0,1816g NaNOy trong bink clu dink mite dn thé tich Lit bing nurée eft, le on than; Dung dich B: 10m! dung dich A pha nude edt dén thé tich lit trong binh eiu dink mite. Lée cin than. Amt dung dich B twong tng vi 0,002mg NzOy; Dung dich (:: 0,10009 @ naptylamin hda tan vo 100m! nde cfit néng, lam ngudi, them 6 — 10:nl axit axetic loai ding trong phan tich, ndng do 80% va git trong béng ti: Dung djch D: Tron hai thé tich bang nhau oiia dung dich C va dung djch axit sunfanilic 10g// tai voi nau. Chi duge ding dung djeh D vita moi pha. c) Cich lam Gan 20y axit cin thir chinh xéc dén 0,0lg trong lo can da | sily dén kh6i hung khong ddi va biét tree khoi long. Chayen hét axit may vao binh edu djnh mite dung tich 260ml da co sin 100 — 150ml nwée c&t, Lam ngudi, them murge edt dén vach va Hic edin than. Cho Sm! dung dich axit clin thit vita pha duge vao mot dng so mu, them 20nd nude oft, 2—3 gigt phenolphtalein ri tung hoa bing dung dich natri hydroxyt cho dén khi xuét hign miu hdng, nhé them 2—3 giot axit sunfurie tinh khiét loai I 0,5 N dén mit miu. Them Smif dung dich D, Ife cfn than va dd 15 —20 phat sau mei dem so miu voi dung djch mau. Trong mot ng so mau khdc cd mau s&c va kich théc giéng nh Sng trén,Trang 13/06 Axit sunturie aeauy TCYN 138-64 cho vio 25ml nude oft, 2—3 gigt dung djeh axit sunfurie tinh khiét logi I r3i dang microburet nhé vio 0,4ml dung dich B néu ding 48 xac dioh axit aequy loai Il, hoe 0,2ml dang dich B néu diang a8 xic doh axit acquy loai I, sau dé thém Smal dung djch D, Tae ohn than, BY 15 — 20 phat sau méi dem so miu voi dung dich cd axit clin thir & trén. Dung dich c6 axit cin thir khong duge dam miu hon dung dich mau, 18. Xée dink ede chdt Khit kali pemanganat a) Nguyén tée ca phuong phap Binh hrgng che chit khir c6 trong axit acquy bing s6 ml Kali pemanganat di bj khit. b) Hoa phim Kali pemanganat KMnOg, tinh kit loai I, dung dich 0,01. ©) Céch lam Cho 20ml axit cin thir vao 60m! mde eit trong mot Be thiiy tinh dung tich 150— 200ml, git dung dich & 60 ~ 70°C, Ding buret thém vio 8m dung dich kali pemanganat 0,01 N néur ding dé xac dinh axit acquy loai II, hote 4,5ml dung dich trén, néu diing d8 xic dinh axit acquy loai L. Miu cita kali pemanganat phai bén it nhat trong 5 phit. 19. Xée dink him legng kim toai nding a) Nguyén tie cia phurong phip Kae dinh ham lurgng cho phép ciia kim loai ning (khong ke chi va sit) trong axit acquy bing cuong do miu va do due & dang sunfua cia chang. ) Hoa phd Axit nitric HNO, tinh khiét loai 11, tf trong 1,40. Amoni hydroxyt NHOH, tinh khiét loai 11, dung dich 10%. Rurgu etylic CgHs0H, logi da tinh edt, ndng do 96%. Hydro sunfua HS, dang djch b&o hoa méi diu ché, hay natri sunfua Na,S. 9H,0, tinh khidt loai 11, dang djeh 2%, hoje amoni suntua, tinh khigt loai 1, dung dich 2%. btTrang 14/18 TCVN 138-64 Axit sunturie aequy ¢) Céch lam L&e ky miu axit cin thir ri ldy 25m vao chén str hay bach kim 4 say kho dén khéi lrgng khong di va biét true khéi Iwgng. Can chén co axit chinh xée dén 0,01g rdi dun can trén bép cat dén thé tieh 1 —1,5mil. Sau khi lam ngudi cho vio 20m! rugu etylic, lic du, day va a2 trong 3 — 4 gid. Loc két tia chi sunfat trén phéu loc sit x6p 86 4 da biét khdi lung. Rita két tia nhidu 18m bing rugu etylic (kholing Sm). Cho vai giot axit nitrie vao dung dich Ige, dun ding cho soi. Them tieng giot dung dich amoni hydroxyt vio dung dich dang dun cho dén khi 6 mii amoniac bée ra. DE ngudi, loc bd Két tia sit... Thém dung dich hydro sunfaa hay natri sunfua hofe amoni sunfua vao dung dich loc dén thé tich géip doi. Sau 20 phat ma dang dich nay khong adi miu va sinh két Uta thi axit aequy duge xem la dat yéu clu. 20. Xée dink ham lweng chi (Pb) Chi ap dung adi v6i axil acquy chita hoe chuyén ché trong ce loai toa thing hay ede thing chira cé lot chi. Céch lam Chi sunfat thu duge & muc 19 rita nhiu Kin bing axit sun- furie tinh khiét logi I dung dich 1: 10 trén phéu loc sir x6p ri lai rita tip bling rurgu etylic cho dén Ichi bét axit sunturic. Say Kho, can. Fir dé suy ra har heong cia chi sunfat. I. GHI NHAN HIEU VA BAO QUA: 21. Axit sunfuric acquy phai chia trong cae chai thiy tinh hole thai bing chit déo chin sxit: Ming chai phai day chit va nidnt kin. Méi chai phii doe ditt trong mdt ro hole thing ch&e ch&n, xung quanh va didi diy chai phai chen vat dgm mm. Ngoai ra, tay theo yén cau va théa thudn cia doi ben hia quan, axit sunfuric acquy co thé chira trong céc vd sanh cd tring men tt, hay ehuyén eho trong cdc toa thing c6 1ét chi. 22, M8i chai phai c6 mot nbain higu ghi: 1én don vj sin xndt, ten vA loai sin phim, ngay, thang, nam sn xual, khéi lugng tinh, 36 higu cia 16 hing va s6 higu elia tigu chufin na Mit ngoai méi ro hay thiing chira phai co ghi chi: «clin than, dé bing ». a | HN I = 157 8 — 250 cate