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105574 REP Z 0002 储罐规格
105574 REP Z 0002 储罐规格
Mansuriya Gas Field (100 MMSCFD Modular Surface Facilities) Cathodic Protection Design Report - CPF
FEED and PMC services
HOLDS
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Turkish Petroleum Overseas Company (TPOC) 105574-REP-Z-0002 Rev 0
Mansuriya Gas Field (100 MMSCFD Modular Surface Facilities) Cathodic Protection Design Report - CPF
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TABLE OF CONTENTS
HOLDS .....................................................................................................................................2
1 GENERAL ....................................................................................................................5
1.1 Introduction ..................................................................................................................5
1.2 Purpose & Scope .........................................................................................................6
1.3 Definitions ....................................................................................................................7
1.4 Abbreviations and Acronyms ........................................................................................7
1.5 Codes, Standards and Project Documents ...................................................................8
1.5.1 Industry and Other Standards .......................................................................................9
1.5.2 Project Documents........................................................................................................9
2 SCOPE OF WORK.......................................................................................................9
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Turkish Petroleum Overseas Company (TPOC) 105574-REP-Z-0002 Rev 0
Mansuriya Gas Field (100 MMSCFD Modular Surface Facilities) Cathodic Protection Design Report - CPF
FEED and PMC services
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Turkish Petroleum Overseas Company (TPOC) 105574-REP-Z-0002 Rev 0
Mansuriya Gas Field (100 MMSCFD Modular Surface Facilities) Cathodic Protection Design Report - CPF
FEED and PMC services
1 GENERAL
1.1 Introduction
Turkish Petroleum Overseas Company (TPOC), Kuwait Energy Company (KEC) and
Korea Gas Corporation (KOGAS) have signed an initial agreement with the Iraqi Oil
Ministry for the Mansuriya Field Development Project. The development plan is to
achieve 100 MMSCFD of dry gas production no later than May 2018 in Phase 1 and
to increase the production capacity to 320 MMSCFD as a part of Phase 2. The
scope of this project is to develop the field for Phase 1 for the full design life of the
project with considerations for future expansion to Phase 2 capacity.
The Mansuriya gas field is located in Diyala governorate approximately 45 km north
of Ba’quba city in Iraq. This location is about 100 km north-east Baghdad and south-
west of Hamrin Lake. The location of the field is provided in Figure 1.1.
The wellstream production is sour (contains approximately 2.5 mol% H2S and 2.5
mol% CO2) and will require acid gas treatment. The gas will be treated and exported
via pipeline to the new build power station at Mansuriya.
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Turkish Petroleum Overseas Company (TPOC) 105574-REP-Z-0002 Rev 0
Mansuriya Gas Field (100 MMSCFD Modular Surface Facilities) Cathodic Protection Design Report - CPF
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Turkish Petroleum Overseas Company (TPOC) 105574-REP-Z-0002 Rev 0
Mansuriya Gas Field (100 MMSCFD Modular Surface Facilities) Cathodic Protection Design Report - CPF
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1.3 Definitions
COMPANY Turkish Petroleum Overseas Company (TPOC)
CONTRACTOR EPC Contractor
SUBCONTRACTOR(S Means an organisation or organisations contracted by
and wholly responsible to CONTRACTOR for executing a
specific part of the WORK
VENDOR Means an organisation that has a contractual
arrangement with CONTRACTOR or a prospective
contractual arrangement with CONTRACTOR to supply
equipment, materials and/or services including
documentation
WORK Means all the work and services to be performed by
CONTRACTOR under a contractual arrangement with the
COMPANY
Must Defines a mandatory contractual or legal requirement or
action
Shall Defines a mandatory contractual requirement or action
Should Defines a desirable or recommended outcome or action
Will Defines an intended outcome or action
May Defines freedom of choice
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Turkish Petroleum Overseas Company (TPOC) 105574-REP-Z-0002 Rev 0
Mansuriya Gas Field (100 MMSCFD Modular Surface Facilities) Cathodic Protection Design Report - CPF
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ID Identification
INT. Internal
IR Voltage Drop
ISO International Standards Organisation
IUPAC International Union of Pure and Applied Chemistry
KEC Kuwait Energy Company
KOGAS Korea Gas Corporation
LP Low Pressure
LPG Liquid petroleum gas
Min. Minimum
MMO Mixed Metal Oxide
MMSCFD Million standard cubic feet per day
N/A Not Applicable
NACE NACE International formerly National Association of
Corrosion Engineers
No. Number
OWS Oily water system
PDB Positive Distribution Box
QTY Quantity
SI International System of Units
SRU Sulphur Recovery Unit
TBC To Be Confirmed
TGTU Tail Gas Treatment Unit
TPOC Turkish Petroleum Overseas Company
TR Transformer rectifier
T-T Tan-to-tan length
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Turkish Petroleum Overseas Company (TPOC) 105574-REP-Z-0002 Rev 0
Mansuriya Gas Field (100 MMSCFD Modular Surface Facilities) Cathodic Protection Design Report - CPF
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2 SCOPE OF WORK
The following tables provide a summary of the facilities to which cathodic protection
has been designed for.
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Turkish Petroleum Overseas Company (TPOC) 105574-REP-Z-0002 Rev 0
Mansuriya Gas Field (100 MMSCFD Modular Surface Facilities) Cathodic Protection Design Report - CPF
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(1) Diameters taken from doc 105574-PHS-C-0001, Design Philosophy for Underground Drainage.
(3) For cathodic protection design purposes, pipeline operating temperatures are assumed not to
exceed max. soil temperature, 35°C (see sec. 4.7).
(2) For cathodic protection design purposes, casing operating temperatures are assumed not to
exceed max. soil temperature, 35°C (see sec. 4.7).
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Turkish Petroleum Overseas Company (TPOC) 105574-REP-Z-0002 Rev 0
Mansuriya Gas Field (100 MMSCFD Modular Surface Facilities) Cathodic Protection Design Report - CPF
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Turkish Petroleum Overseas Company (TPOC) 105574-REP-Z-0002 Rev 0
Mansuriya Gas Field (100 MMSCFD Modular Surface Facilities) Cathodic Protection Design Report - CPF
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(1) Values given in table are derived from doc. 105574-EQL-P-0001, Equipment List.
(2) External CP not required as tanks are less than 6m in diameter and therefore constructed on
concrete slabs and not concrete ring beams.
(4) Internal CP not proposed, internal corrosion protection provided by a phenolic epoxy lining.
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Turkish Petroleum Overseas Company (TPOC) 105574-REP-Z-0002 Rev 0
Mansuriya Gas Field (100 MMSCFD Modular Surface Facilities) Cathodic Protection Design Report - CPF
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(1) Values given in table are derived from doc. 105574-EQL-P-0001, Equipment List.
(2) Vessels detailed in table are considered to be the only ones buried in sand. All other horizontal
vessels in on site are assumed to be either located above ground or in concrete pits but exposed
to air, i.e. not filled with sand.
(2) For cathodic protection design purposes, riser pipe operating temperatures are assumed not to
exceed max. soil temperature, 35°C (see sec. 4.7).
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Turkish Petroleum Overseas Company (TPOC) 105574-REP-Z-0002 Rev 0
Mansuriya Gas Field (100 MMSCFD Modular Surface Facilities) Cathodic Protection Design Report - CPF
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~ 40 ICCP (3)
(1) Number of road crossings in plant are based on assumptions made for as CPF layout is not
available at time of writing.
(2) Number of road crossings protected by ICCP and that by Pre-packaged anodes are based on
assumptions on expected size.
(3) Protection to casing pipe taken from bleeding CP current of existing ICCP system protecting
normally buried piping.
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Turkish Petroleum Overseas Company (TPOC) 105574-REP-Z-0002 Rev 0
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~ 50 ~ 750
Notes:
(2) Quantity of zinc ribbon anode per road crossing based on an assumed casing length of 15 metres.
(1) Values given are based on the requirements for a single tank, for multiple tanks the values are to
be increased accordingly e.g. Firewater Storage Tanks, 2 No. in total.
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Turkish Petroleum Overseas Company (TPOC) 105574-REP-Z-0002 Rev 0
Mansuriya Gas Field (100 MMSCFD Modular Surface Facilities) Cathodic Protection Design Report - CPF
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(1) Values given are based on the requirements for a single tank, for multiple tanks the values are to
be increased accordingly e.g. Firewater Storage Tanks, 2 No. in total.
(1) Values given are based on the requirements for a single vessel, for multiple vessels the values are
to be increased accordingly e.g. LPG Storage 6 No. in total.
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Turkish Petroleum Overseas Company (TPOC) 105574-REP-Z-0002 Rev 0
Mansuriya Gas Field (100 MMSCFD Modular Surface Facilities) Cathodic Protection Design Report - CPF
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~ 100 ~ 100
Notes:
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Turkish Petroleum Overseas Company (TPOC) 105574-REP-Z-0002 Rev 0
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CP Instant-OFF ‘IR free’ potentials are normally measured after disconnecting all
bonds and sacrificial anodes and instantaneously following switching OFF of all
transformer rectifiers. However, given the number of rectifiers and sacrificial anodes
to be installed on the buried piping, this is considered to be impractical. Therefore,
‘IR free’ potentials are to be recorded on the buried piping via CP polarisation
coupons installed at all test stations except those at rectifier drain points. Each
coupon is to be fitted with a ‘Reed’ switch which will allow instantaneous
disconnection of the coupon from the CP circuit, thus allowing an ‘Instant-Off’
potential to be measured.
Excess overprotection, that is values more negative than -1.20 Volts versus
copper/copper sulphate reference electrode, should generally not occur.
For in-plant areas, the complicated nature which often exists in conjunction with the
combination of materials used in some locations, can influence the potential levels. It
may therefore be necessary to allow some flexibility in the protection potential criteria
required. For example the 100 mV polarisation decay test method (ref.
NACE SP0169) may be used in congested areas or areas subject to cathodic
shielding to determine that adequate protection has been achieved, although it would
first have to be demonstrated that polarization decay measured after switching off a
particular rectifier was not influenced by other adjacent rectifiers which were still
energised.
Alternatively, the methods of verification cathodic protection criteria, as detailed in BS
EN 14505, may be selected.
4.3 Cathode Design Current Density
The cathode current densities used in the design are given in table 4.2.
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Turkish Petroleum Overseas Company (TPOC) 105574-REP-Z-0002 Rev 0
Mansuriya Gas Field (100 MMSCFD Modular Surface Facilities) Cathodic Protection Design Report - CPF
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(1) Applied current density for coated steel based on end of design life values, unless otherwise
stated.
(2) Applied coated current density value to be applied to temporary CP for buried piping.
(3) Coated current density value based on buried piping coated with a fusion bonded epoxy system.
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Turkish Petroleum Overseas Company (TPOC) 105574-REP-Z-0002 Rev 0
Mansuriya Gas Field (100 MMSCFD Modular Surface Facilities) Cathodic Protection Design Report - CPF
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(1) Soil resistivity values for soil based on a survey undertaken along the Naftkhaneh to Baghdad gas
pipeline project.
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Turkish Petroleum Overseas Company (TPOC) 105574-REP-Z-0002 Rev 0
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Where possible all CP cables from the anodes to the PDBs and from the PDBs to the
transformer rectifiers shall be run underground along the ‘anode’ trench. Cables will
be buried to a depth of at least 1m and shall have electrical warning tape laid above
them. Positive and negative cables from the transformer rectifier shall be armoured.
Above-ground concrete cable markers will be installed every 30m and at each
change of direction.
A total of 200 No. test facilities will be installed at selected locations along the buried
piping within the plant, to allow routine testing of the performance of the installed
system. Permanent reference electrodes and CP polarisation coupons will be
installed at all test facilities.
The steel reinforcement within the concrete is not included in the CP system;
however it is assumed that the buried piping will not be electrically isolated from
above ground piping and ultimately station earthing.
Therefore, current drain to concrete reinforcement and current drain to the plant
electrical earthing (assumed to be galvanised steel) is included in the CP system for
buried piping. The current demand by the concrete reinforcing steel and the earthing
electrodes is outlined in the design calculations as presented in Appendix 1.
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Turkish Petroleum Overseas Company (TPOC) 105574-REP-Z-0002 Rev 0
Mansuriya Gas Field (100 MMSCFD Modular Surface Facilities) Cathodic Protection Design Report - CPF
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Turkish Petroleum Overseas Company (TPOC) 105574-REP-Z-0002 Rev 0
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Where possible all CP cables from the titanium conductor bars to the AJB (once clear
of the tank bottom) and from the AJB to the transformer rectifier shall be run
underground. Cables will be buried to a depth of at least 1m and shall have electrical
warning tape laid above them. Positive and negative cables from the transformer
rectifier shall be armoured. Above ground concrete cable markers will be installed
every 30m and at each change of direction.
Monitoring of the cathodic protection system shall be through access tubes through
tank ring walls (to monitor tank periphery potentials), and a slotted monitoring tube
laid under the full diameter of the tank (to monitor tank bottom potentials).
Permanent reference electrodes shall also be installed within the sand in-fill beneath
the tank bottom, to provide additional cathodic protection monitoring facilities.
A single test facility will be installed opposite to where the cable tails for the
permanent reference electrodes exit from underneath the tank, to allow termination of
the cable tails. This test facility will also allow termination of a cathode sensing cable,
from the tank, to enable monitoring of the CP system.
Electrical isolation of the tank from piping off the tank will not be applied, however
due to the design of the CP system there will be no need to account for drain on the
CP system from concrete reinforcing or station earthing system.
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Turkish Petroleum Overseas Company (TPOC) 105574-REP-Z-0002 Rev 0
Mansuriya Gas Field (100 MMSCFD Modular Surface Facilities) Cathodic Protection Design Report - CPF
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A HDPE liner shall be installed within the concrete ringbeam, between the concrete
and the sand infill. This will provided a secondary containment barrier as well as
protecting the ring beam steel reinforcing from interference effects from the under
tank CP system.
Where possible, all test facilities, junction boxes and transformer rectifiers will be
installed in non-hazardous areas.
4.8.4 External Protection of Buried Vessels
Corrosion protection of the external surfaces of buried vessels, including those
supported on mounds then covered over and those installed in concrete chambers
then filled with sand, will consist of a coating system in accordance with Project
specification and a cathodic protection system.
Cathodic protection of buried vessels will be by MMO coated titanium anodes,
installed around the periphery of the buried vessel in anode strings/loops, a minimum
number of 2 anode loops per buried vessel to be installed. For vessels installed in
concrete chambers backfilled with sand, the CP anodes shall be installed within the
concrete chamber.
The system will use tubular MMO/titanium anodes with a petroleum coke backfill
within a steel canister. The titanium substrate shall be coated with a MMO layer of
sufficient thickness to achieve the design life at the maximum design current output.
The diameter of the tubular anode shall be 25 mm. The anodes will be connected to
a 10 mm2 conductor cable which will in turn be connected to a main 35 mm2 anode
loop feeder cable.
The anode-to-anode spacing per loop and anode loop-to-anode loop spacing being
dependent upon the vessel diameter and the soil resistivity. For the buried vessels,
an inter-anode spacing has been chosen to achieve the optimum potential shift on
the buried vessel. Sample potential shift calculations are given in Appendix 4 and a
summary is given in Table 4.6.
There will be 1 No. transformer rectifier dedicated to each buried vessel external CP
system, which will feed 1 No. PDB into which the anode loop feeder cables shall be
terminated.
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Turkish Petroleum Overseas Company (TPOC) 105574-REP-Z-0002 Rev 0
Mansuriya Gas Field (100 MMSCFD Modular Surface Facilities) Cathodic Protection Design Report - CPF
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Where possible all CP cables from the anode loop feeder cables to the PDB and from
the PDB to the transformer rectifier shall be run underground. Cables will be buried
to a depth of at least 1 m and shall have electrical warning tape laid above them.
Positive and negative cables from the transformer rectifier shall be armoured. Above
ground concrete cable markers will be installed every 30 m and at each change of
direction.
Monitoring of the cathodic protection system shall be through use of above ground
test facilities located at one end of the buried vessel. Permanent reference
electrodes and CP polarisation coupons shall be employed at each test facility to aid
potential monitoring; in addition a 3 inch dia. plastic pipe shall be installed directly
above the buried vessel, to enable a portable reference electrode to make direct
contact with the soil.
Electrical isolation of the buried vessel from piping off the structure will not be
applied. However, a fully bonded buried vessel will result in current drain from the
cathodic protection system to earthing, rebar, foundations etc., which will be
accounted for in the detailed design. Where direct connection between the buried
vessel and an earthing system is proposed then dc decouplers, such as polarisation
cell replacement units, will be installed in series between the buried vessel and the
earthing system.
Where possible, all test facilities, junction boxes and transformer rectifiers will be
installed in non-hazardous areas.
4.8.5 External Protection of Buried Fire Hydrant Piping
Buried fire hydrant piping will be protected against corrosion by the application of a
coating system in accordance with Project specification and a cathodic protection
system.
Cathodic protection of the Fire Hydrant buried piping will be by pre-packaged
galvanic ‘sacrificial’ anode. The galvanic anode will be installed horizontally, at piping
invert depth, with a maximum 2 m spacing from the piping. The galvanic anode will
be bonded to the piping via an above ground test facility.
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Turkish Petroleum Overseas Company (TPOC) 105574-REP-Z-0002 Rev 0
Mansuriya Gas Field (100 MMSCFD Modular Surface Facilities) Cathodic Protection Design Report - CPF
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The type of galvanic anode and the number and size will be based on meeting the
potential criteria as specified in section 4.2 and the current density requirements as
per section 4.3. Sample design calculations as presented in Appendix 5.
Monitoring of the cathodic protection system shall be through use of above ground
test facilities located adjacent to, but not in a position that interferes with the
operation of the hydrant system. Permanent reference electrodes shall be employed
at each test facility to aid potential monitoring; in addition a 3 inch dia. plastic pipe
shall be installed directly above the buried piping, to enable a portable reference
electrode to make direct contact with the soil.
Where possible, all test facilities will be installed in non-hazardous areas.
4.8.6 Internal Protection of the Firewater Storage Tanks
The internal wetted surfaces of firewater storage tanks will be protected against
corrosion by the application of a coating system in accordance with Project
specification and a cathodic protection system.
The cathodic protection system will be based on a suspended impressed current
anode system.
Note:
Other than firewater storage tanks, there is no further requirement to provide CP to tanks with a possible
water layer, corrosion protection will be provided solely by use of an internal lining, see Table 2.3 for
further details.
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Turkish Petroleum Overseas Company (TPOC) 105574-REP-Z-0002 Rev 0
Mansuriya Gas Field (100 MMSCFD Modular Surface Facilities) Cathodic Protection Design Report - CPF
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Where possible all CP cables from the PDB to the transformer rectifier shall be run
underground. Cables will be buried to a depth of at least 1m and shall have electrical
warning tape laid above them. Positive and negative cables from the transformer
rectifier shall be armoured. Above ground concrete cable markers will be installed
every 30 m and at each change of direction.
Monitoring of the cathodic protection systems (ICCP) for the water storage tanks
shall be undertaken by use of ‘through wall’ mounted permanent reference electrodes
(installed through the tank side wall). Cable tails from each permanent reference
electrode shall be brought down the side of the tank to terminate inside a test box
located at ground level. Permanent reference electrodes shall be approved to
withstand the environment they shall be used in. As an alternative and to cover for
possible failure of the permanent reference electrodes, use of roof-top access holes
to allow insertion of a portable reference electrode shall be employed. It should be
noted that accessing the roof top is considered an increased safety hazard and so
should only be used in the event of failure of the permanent reference electrodes.
Electrical isolation of the tank from piping off the tank will not be applied.
Where possible, all test facilities, junction boxes and transformer rectifiers will be
installed in non-hazardous areas.
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Turkish Petroleum Overseas Company (TPOC) 105574-REP-Z-0002 Rev 0
Mansuriya Gas Field (100 MMSCFD Modular Surface Facilities) Cathodic Protection Design Report - CPF
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TEMPORARY CATHODIC PROTECTION DESIGN USING ZINC ALLOY ANODES - IN-PLANT BURIED PIPING
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Temperature Corrected Current Density Requirements Current Density Correction For Elevated Temperature Service
Final 'temp
correctd'
Item No. Fire Hydrant Riser Riser pipe Surface Current Current Anode Calc No. of
Dia Dia Len. Area Density Required I Output Weight Anodes
in m m (m2) (mA/m2) (mA) (mA) (kg) Required
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CATHODIC PROTECTION DESIGN Sheet: Cathodic Protection Current Requirement Calculation By: PAN 22/02/13
PERMANENT ICCP Facility: 100mm dia. Buried Piping Checked By:
Plant: Mansuriya Refinery Rev: 0
Drawing
Line Description Line Ø (m) Length (m) S.A. (m²) Current (A)
Oily Water System (OWS) or Closed Drain (CD) lines 0.1 200 63 0.06
0 0 0.00
0 0 0.00
0 0 0.00
Totals = 200 63 0.06
Facility: Concrete Reinforcing Steel
2.00 Current Density For Coated Steel at End of Life (mA/m2 ) **
Qty Length (m) Width (m) Depth (m) S.A. (m²) Current (A)
10 15.0 0.3 0.3 182 0.36
0.0 0.0 0.0 0 0.00
Totals = 182 0.36
Facility: Electrical Earthing
50 Current Density (mA/m2 ) **
a) CP Arrangement
TR
PDB PDB
No. of individually cable tailed anodes evenly spaced No. of individually cable tailed anodes evenly spaced
3) Anode Resistance
b) Resistance to Earth, Multiple Anodes (Baeckmann, Schwenk, Prinz; Cathodic Corrosion Protection, 1997, p544, section 24.2)
Interference Factor (F ) :
Where; F 1 ln 0.66n
r = Soil Resistivity, (Wcm) s Ra,V
R = Single Anode Resistance, (W)
s = Anode Spacing, (cm)
n = No. of Anodes in Groundbed, (n)
R
Total resistance of n anodes (R n ) : Rn Fn
n
c) Calculations
PDB 1 PDB 2
TR Locations per Drawings, Cable Length Take Offs as Follows; Entries from input sheet
Anode Cabling Resistance For Anodes In Parallel Calculated Using Following Expression; 1/Rc = 1/R1 + 1/R2 + 1/R3 + . . . 1/Rn
2
Main Positive Header Cable Gauge (mm ) = 35
Main Positive Header Cable Length (m) = 100
Resistance (Ω/m) @ 25 deg. C= 0.000548
Main Positive Header Cable Resistance, Rp = 0.05481 W
Anode Cabling Resistance For Anodes In Parallel Calculated Using Following Expression; 1/Rc = 1/R1 + 1/R2 + 1/R3 + . . . 1/Rn
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A Total of 20 Anodes Are Required For Design Purposes. Anodes Will Be Designed To Operate at Maximum (including contingency) 120% Output
Case 1 - 10m Single Sided Spacing. Protection to Midpoint Between Two Adjacent Anodes (seven anode contribution considered)
G E 1000cm C A B D F
W
Horizontal distance from anode to a given point on the structure (cm), =
Anode Distance (cm) to W Shift
Anode A 522.0 0.160V Contibutions >50mV
Anode B 522.0 0.160V Contibutions <50mV
Anode C 1,507.5 0.067V
Anode D 1,507.5 0.067V
Anode E 2,504.5 0.041V
Anode F 2,504.5 0.041V
Anode G 3,503.2 0.030V
Total shift (-V) = 0.566V wrt Cu/CuSO4 ref electrode
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Natural potential (-V) = 0.500V wrt Cu/CuSO4 ref electrode
Applied potential (V) = -1.066V wrt Cu/CuSO4 ref electrode
Turkish Petroleum Overseas Company (TPOC) 105574-REP-Z-0002 Rev 0
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Case 2 - Single Sided Spacing. Protection to Directly Opposite an Anode (seven anode contribution considered)
F D 1000cm B A C E G
X
Anode Distance (cm) to X Shift
Anode A 150.0 0.249V
Anode B 1,011 0.096V
Anode C 1,011 0.096V
Anode D 2,005.6 0.051V CP POTENTIAL RANGES (steel in soil) **
Anode E 2,005.6 0.051V The target IR free potential value for protection shall be:-0.85 to -1.2 Volts versus Cu/CuSO4 half-cell
Anode F 3,003.7 0.035V
Anode G 3,003.7 0.035V
Total shift (-V) = 0.614V wrt Cu/CuSO4 ref electrode
Natural potential (-V) = 0.500V wrt Cu/CuSO4 ref electrode
Applied potential (V) = -1.114V wrt Cu/CuSO4 ref electrode
Design life for an impressed current distributed anode system is given by:
AnodeMaxCurrentDensi ty
AnodeLife DesignLife
AnodeOperatingCurrentDensity
Where:
Maximum Allowable Anode Current Density = 67 A/m2
Actual Anode Operating Current Density = 25.46 A/m2
Project Design Life = 30 Years
DL = Design Life, (years) 79 OK Meets project Design Life requirements (30 years)
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PERMANENT CATHODIC PROTECTION DESIGN USING ZINC ALLOY ANODES - CASING PROTECTION AT RDX
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Temperature Corrected Current Density Requirements Current Density Correction For Elevated Temperature Service
to = 30 oC
Initial Coating Breakdown = 100% (initial) (average) (final)
Initial Current Requirement = 31.81 mA If : io = 3.000 3.000 3.000 mA/m²
35 o
t' = C
Mean Coating Breakdown = 100% o 30 o
t = C
Mean Current Requirement = 31.81 mA
i' = 3.375 3.375 3.375 mA/m²
Final Coating Breakdown = 100% (initial) (average) (final)
End of Life Current Requirement = 31.81 mA
Final
'temp
correctd' No. of Total No. of
Item No. RDX No. Carrier Pipe Casing Pipe Surface Current Current Anode Calc No. of anodes anodes
Dia Dia Len. Area Density Required I Output Weight Anodes per test based on
in m m (m2) (mA/m2) (mA) (mA) (kg) Required post 2 No. TP's
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CATHODIC PROTECTION DESIGN - IN PLANT ROAD CROSSINGS, CARRIER PIPES INSIDE CASINGS
Calculation of anode requirements for protection of carrier piping inside cased road crossings utilising zinc ribbon anodes.
Actual
Carrier Carrier Length of
Pipe Pipe Calculated Ribbon to
/Casing Surface Current Current Anode Current Current Length of be
Carrier Locn Ø Length Area Density Required Output Supplied Calc. Weight Ribbon Casing Length Installed
2
Pipe (in) (m) (m) (m²) (mA/m ) (mA) (mA/lin.m) (mA) (kg) Required (m) (m) (m)
Total = 15
Zn anode alloy weight 1.8 kg/m Anode Output 1.1 Vcse Anode Width 1.6 cm
Design life 30 Years Resistivity 1319 W.cm Anode Width 2.2 cm
Anode capacity 738 Ah/kg Alloy Density 7,100 kg/m3 Anode Insert Ø 0.32 cm
Anode utilisation 0.85 Anode Length 1 m
Anode life can be calculated from the formula L = (Anode Weight X Capacity X Utilisation) / (8,766 X Current Demand)
Mean anode alloy weight required = (L X 8,766 X Current Demand) / (Capacity X Utilisation)
Alloy weight required (kg) = See Calc. Weight Column in Spreadsheet
Start of Life;
Resistance of 1m of Zinc Ribbon where: Ra = Anode Resistance (W) r= 1.210 cm
Ra = (/(2L))x(ln(4L/r)-1) = Soil Resistivity (W.cm) Ra = 10.08 W
(modified Dwight) L = Length of Anode (cm)
r = Effective Anode Radius (cm) = (Anode Circumference / 2pi)
The potential has been taken as -850 mV vs. a Cu/CuSO4 half cell for design purposes, if the natural potential of the line is more negative there will be corresponding reduction in current demand from the anode.
Current output of Zn ribbon anode in site conditions can therefore be calculated from V over the anode resistance to earth
Anode open circuit potential - pipe design protective potential / Anode resistance to electrolyte
Anode current = 0.025 Amps per linear metre
Alloy length required at start of life = (Start of Life Current Demand) / (Start of Life Anode Current Output)
Length of Zn Ribbon Required = See Length of Ribbon Reqd - Initial in Spreadsheet
End of Life;
At the end of life, it is assumed that 85% of the anode weight has been consumed;Weight of Zn Alloy remaining at end of life = (1-U) x1.8 kg = 0.27 kg Effective Anode Ø at End of Life = 0.73 cm
Length of Zn ribbon at end of life = Linitial - (0.1*U*Linitial) = 0.915 m
Resistance of 1m of Zn Ribbon where: Ra = Anode Resistance (W)
Ra = (/(2L))x(ln(4L/r)-1) = Soil Resistivity (W.cm) r= 0.364 cm
L = End of Life Length of Anode (cm) Ra = 13.57 W
r = Effective Anode Radius (cm)
The potential has been taken as -850 mV vs. a Cu/CuSO4 half cell for design purposes, if the natural potential of the line is more negative there will be corresponding reduction in current demand from the anode.
Current output of Zn ribbon anode in site conditions can therefore be calculated from V over the anode resistance to earth
Anode open circuit potential - pipe design protective potential / Anode resistance to electrolyte
Anode current = 0.018 Amps per linear metre
Alloy length required at end of life = (End of Life Current Demand / End of Life Anode Current Output) OR (Calc Weight Reqd / anode unit weight) - whichever is the greater
Length of Zn Ribbon Required = See Length of Ribbon Reqd - Final in Spreadsheet Calculation By: PAN 25/02/13
Checked By:
Rev: 1
Page 39 of 63
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CATHODIC PROTECTION DESIGN Sheet: Cathodic Protection Current Requirement Calc. By: PAN 25/02/13
Facility: Aboveground Storage Tank External Checked By:
(Permanent CP System)
Rev: 0
Plant:
i 0.25 t 't
Temperature Correction Factor Cuts in @ Temperature of (t°) °C 30
Temperature Corrected Current Density (i') mA/m2 32.50 i ' i
10
Coating Breakdown Factor (cbf) Initial % 10.00 Base current density incl. coating breakdown
Coating Breakdown Factor (cbf) Mean % 20.00 Base current density incl. coating breakdown
Coating Breakdown Factor (cbf) Final % 30.00 Base current density incl. coating breakdown
Initial Current Requirement mA 3,686
Mean Current Requirement mA 7,372 I req SAtan k i 'cbf
Final Current Requirement mA 11,058
Project Design Life yrs 30.00 Doc: ZZ-PE-GEN-G20-0001
Max soil resistivity (anode resistance check) ohm.m 500.00 Doc: ZZ-CE-GEN-PHL-0006
Min soil resistivity (voltage gradient check) ohm.m 150.00 Doc: ZZ-CE-GEN-PHL-0006
Anode buried depth m 1.00 Assumed
MMO current capacity (soil/no coke) - Manufacturers data for 50
mA/lin.m 42.0 Based on Anode Manufacturers data for : 50 year design life
year design life
MMO max current capacity (soil /no coke) - corrected for project
mA/lin.m 70
design life
MMO ribbon width (W ribbonanode) mm 6.35 Based on Anode Manufacturers data
MMO ribbon thickness (Thribbonanode) mm 0.60 Based on Anode Manufacturers data
MMO ribbon equivalent dia. (Dia ribbonanode) mm 4.425 = (anode cross section perimeter) / π
MMO ribbon internal resistance for 1m length (Rintribbon ) ohms 0.14000 Based on Anode Manufacturers data
Ti conductor bar width (W conductor ) mm 12.70 Based on Anode Manufacturers data
Ti conductor bar thickness (Thconductor ) mm 0.90 Based on Anode Manufacturers data
Ti conductor bar internal resistance for 1m length (Rintconductor ) ohms 0.04199 Based on Anode Manufacturers data
Current output based on calc length & Final Current Requirement mA/lin.m 10 = (final current reqd) / (calc total length of anode reqd)
OK CHECKSUM to ensure calc final anode current output is LESS THAN anode max current output
Page 41 of 63
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b) Cable Resistances
Outside Ambient Temperature = 25 DegC
2 Resistance (Ω/m) @ 25 DC Current
Conductor Size (Awg or mm ) Resistance (Ω/m) @ 20 deg.C
deg.C Rating (A)
AWG10 0.00335 0.00341 30 Relation between cable resistance and temperature (US Dept
of Commerce, Nation'l Bureau of Standards Handbook 100, pg
AWG8 0.00210 0.00214 45
14, Table 3)
AWG6 0.00132 0.00135 65 Cable Resistance Figures
AWG4 0.00083 0.00085 85 From NACE Corrosion
Rt Rti 1 ti t t i
AWG3 0.00066 0.00067 100 Eng's Ref Book, 2nd Ed'n.; p
AWG2 0.00052 0.00053 115 109.
AWG1 0.00041 0.00042 130 Where:
10 0.00183 0.00187 45 Rt = Resistance at temperature, t (Ω/m)
16 0.00115 0.00117 65 Rti = Resistance at 20degC temperature (Ω/m)
25 0.000727 0.000741 85 αti = Temp. coefficient @ 20degC = 0.00383
35 0.000524 0.000534 115 Cable Resistance Figures t= Temperature (degC)
50 0.000387 0.000394 150 From Vendor data. ti = Initial temperature (20degC)
70 0.000268 0.000273 185
95 0.000193 0.000197 230
Resistance of 1No. Power Feed Cable (ohms) 0.09325 W = (cable resistance) x (cable length)
Resistance of 5No. Power Feed Cables in Parallel (ohms) 0.01865 W = (cable resistance) x (cable length) / (No. of cables in parallel)
Resistance of Main Positive Cable (ohms) 0.02670 W = (cable resistance) x (cable length)
Resistance of 1No. Main Negative Cable(s in Parallel) (ohms) 0.02670 W = (cable resistance) x (cable length) / (No. of cables in parallel)
Total Resistance of All Cables (ohms) 0.072 W = sum of cable resistances (power feed + positive + negative)
Page 43 of 63
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Max. Soil Resistivity Min. Soil Resistivity Min. TR current rating safety factor over CP current requirement : 10.0%
Min. Current Requirement Calc. for End of Design Life (sec 1) A 11.058 11.058
Min. Current Required to Meet Potential Shift Requirements (sec 6) A 12 40 Adjust current value to obtain min. potential shifts as detailed in Sec 6.
Min. TR Voltage Rating (incl Back EMF) V 17.2 19.3 = (total circuit resistance) x (largest current requirement)
Circuit Resistance Allowable (R=V/I) W 4.0 1.2 = (Proposed TR Voltage Rating - Back EMF) / (Min. Current Reqd)
Calc. Total Circuit Resistance W 1.437 0.482
(Transformer Rectifier Sizing OK ) (Transformer Rectifier Sizing OK )
I t r 0.5L 0.5L
Ur = Potential shift from a single horizontal anode (V) 2 2 2 The Potential Shift For a Single HorizontalAnode (Ur) As Given By Baeckmann/Schwenk ;
Where;
Ur ln (based on the formula by Baeckmann/Schwenk in Handbook of Cathodic Corrosion Protection, eqn 9 page 539)
I = Anode current output (Amps) 2L t 2 r2 0.5L2 0.5L where d, anode dia, L, anode length and
ρ = Soil Resistivity, (W.m) t, anode depth below surface
L = Anode Length, (m)
t = Burial depth of anode, (m)
r = Distance from anode to tank surface, (m)
Page 44 of 63
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Potential at Min Anode to Tank Distance, V x cse V -1.083 -1.083 = (natural potential + voltage gradient oppos. anode)
Potential at Max Anode to Tank Distance, V x cse V -1.051 -1.051 = (natural potential + voltage gradient between anodes)
Calculation
Anode resistance to earth for Lconnec wire (Ra-Lconnec) Ohms 270.84 81.25 Using same formula as detailed in Sec 3) CP System Circuit Resistance
Anode conductance to earth for Lconnec wire (Ga-Lconnec) Siemens 0.0037 0.0123 = 1 / (Ra-Lconnec)
Linear Conductance of MMO Wire Anode (glinear ) S/m 0.0018 0.0062 = 2 x (Ga-Lconnec) / (2Lconnec)
Attenuation constant (α) 0.0161 0.0294 = sqrt ( rlinear x glinear )
Potential attenuation on MMO ribbon at mid-point between
% 0.05% 0.17%
conductor bar connections
= 1 - ( 1 / (cosh(α x (2Lconnec / 2) ) ) ) - expressed as a percentage
Proposed conductor bar Proposed conductor bar
spacing of 4m is OK spacing of 4m is OK
Page 45 of 63
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CATHODIC PROTECTION DESIGN Sheet: Cathodic Protection Current Requirement Calculation By: PAN 22/02/13
Facility: Mounded Bullets - LPG Storage Bullet Checked By: 0 00/01/00
Plant: Mansuriya Refinery Rev: 0
Drawing
Vessel Description Vessel Ø (m) Length (m) S.A. (m²) Current (A)
LPG Storage Bullets (0-V-22 01 A/D) 3.75 26.25 373.71 3.53
0 0 0.00
0 0 0.00
0 0 0.00
Totals = 26 374 3.53
Facility: Concrete Reinforcing Steel
2.00 Current Density For Coated Steel at End of Life (mA/m2 ) **
Qty Length (m) Width (m) Depth (m) S.A. (m²) Current (A)
0 15.0 0.3 0.3 0 0.00
0.0 0.0 0.0 0 0.00
Totals = 0 0.00
Facility: Electrical Earthing
50 Current Density (mA/m2 ) **
3) Anode Resistance
a) Horizontal Anode Resistance to Earth, Single Anode (Baeckmann, Schwenk, Prinz; Cathodic Corrosion Protection, 1997, p544, section 24.2)
b) Resistance to Earth, Multiple Anodes (Baeckmann, Schwenk, Prinz; Cathodic Corrosion Protection, 1997, p544, section 24.2)
ln 0 . 656 n
Interference Factor (F ) :
Where; F 1
ρ = Soil Resistivity, (Ω.cm)
s R a ,h
Ra,h = Single Anode Resistance, (Ω)
s = Anode Spacing, (cm)
n = No. of Anodes in Groundbed, (n)
R
Total resistance of n anodes (R n ) : Rn Fn
n
c) Calculations
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TR Locations per Drawings, Cable Length Take Offs as Follows; Entries from input sheet
Anode Cabling Resistance For Anodes In Parallel Calculated Using Following Expression; 11 12 13 14 15 16 17 18 19 20
1/R c = 1/R1 + 1/R2 + 1/R3 + . . . 1/R n 2 2 2 2 2 2 2 0 0 0
0.00191 0.00191 0.00191 0.00191 0.00191 0.00191 0.00191 0.00191 0.00191 0.00191
Resistance of Anode Cables, Rc = 0.00022519 W 0.0038 0.0038 0.0038 0.0038 0.0038 0.0038 0.0038 0.0000 0.0000 0.0000
Positive Anode Feeder Loop Cable Gauge (mm2 ) = 35
Positive Anode Feeder Loop Cable Length (m) = 110
Resistance (Ω/m) @ 25 deg. C= 0.000548
Positive Anode Feeder Loop Cable Resistance, Raf = 0.06029 W
Anode Cabling Resistance For Anodes In Parallel Calculated Using Following Expression; 11 12 13 14 15 16 17 18 19 20
1/R c = 1/R1 + 1/R2 + 1/R3 + . . . 1/R n 2 2 2 2 2 2 2 0 0 0
0.00191 0.00191 0.00191 0.00191 0.00191 0.00191 0.00191 0.00191 0.00191 0.00191
Resistance of Anode Cables, Rc = 0.00022519 W 0.0038 0.0038 0.0038 0.0038 0.0038 0.0038 0.0038 0.0000 0.0000 0.0000
2
Positive Anode Feeder Loop Cable Gauge (mm ) = 35
Positive Anode Feeder Loop Cable Length (m) = 110
Resistance (Ω/m) @ 1 deg. C= 0.000548
Positive Anode Feeder Loop Cable Resistance, Raf = 0.06029 W
Page 49 of 63
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A Total of 34 Anodes Are Required For Design Purposes. Anodes Will Be Designed To Operate at Maximum (including contingency) 120% Output
2 2
Case 1 - 2m Single Sided Spacing. Protection to Midpoint Between Two Adjacent Anodes (seven anode contribution considered - from one side of mounded bullet)
G E 200cm C A B D F
Horizontal distance from anode to a given point on the structure (cm), = Loop 1 Loop 2 W
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Case 2 - Single Sided Spacing. Protection to Directly Opposite an Anode (seven anode contribution considered - from one side of mounded bullet)
F D 200cm B A C E G
X
Loop 1 Loop 2
Anode Distance (cm) to X Shift Shift
Anode A 100.0 0.186V 0.098V
Anode B 224 0.098V 0.092V
Anode C 224 0.098V 0.092V
Anode D 412.3 0.055V 0.078V CP POTENTIAL RANGES (steel in soil) **
Anode E 412.3 0.055V 0.078V The target IR free potential value for protection shall be:-0.85 to -1.2 Volts versus Cu/CuSO4 half-cell
Anode F 608.3 0.038V 0.065V
Anode G 608.3 0.038V 0.065V
Total shift (-V) = 0.567V 0.568V wrt Cu/CuSO4 ref electrode
Natural potential (-V) = 0.500V 0.500V wrt Cu/CuSO4 ref electrode
Applied potential (V) = -1.067V -1.068V wrt Cu/CuSO4 ref electrode
Design life for an impressed current distributed anode system is given by:
AnodeMaxCurrentDensi ty
AnodeLife DesignLife
AnodeOperatingCurrentDensity
Where:
Maximum Allowable Anode Current Density = 67 A/m2
Actual Anode Operating Current Density = 5.99 A/m2
Project Design Life = 30 Years
DL = Design Life, (years) 334 OK Meets project Design Life requirements (30 years)
Page 51 of 63
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PERMANENT CATHODIC PROTECTION DESIGN USING ZINC ALLOY ANODES - FIRE HYDRANT RISER PIPIES
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Temperature Corrected Current Density Requirements Current Density Correction For Elevated Temperature Service
Final 'temp
correctd'
Item No. Fire Hydrant Riser Riser pipe Surface Current Current Anode Calc No. of
Dia Dia Len. Area Density Required I Output Weight Anodes
in m m (m2) (mA/m2) (mA) (mA) (kg) Required
Page 54 of 63
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CATHODIC PROTECTION DESIGN Sheet: Cathodic Protection Current Requirement Calc. By: PAN 26/02/13
Facility: Aboveground Storage Tank Internal Checked By:
(Permanent CP System)
Rev: 0
Plant:
Page 56 of 63
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V(r → ∞ ) = Potential rise above an arbitrary remote earth in the electrolyte at a point r (metres) away from the anode.
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Anode Resistance (ohms) Ra 8.67 8.67 8.67 8.67 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
d) Anode String
Cable Resistance per anode string (ohms) 0.0373 0.0373 0.0373 0.0373 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
Cable Resistance per anode power feed (ohms) 0.0267 0.0267 0.0267 0.0267 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
Anode resistance per string (ohms) 8.6669 8.6669 8.6669 8.6669 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
Total Resistance per String (ohms) 8.7309 8.7309 8.7309 8.7309 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
= (cable res. per string) + (anode res. per string)
Overall Anode String Resistance For Anodes In Parallel Calculated Using Following Expression; 1/RL,all = 1/R1 + 1/R2 + 1/R3 + . . . 1/Rn Resistance of All Anode
Resistance of All Anode Loops in One PDB, RL, all = ohms 2.18 Loops
1 8.730936
d) Main Positive Cable 2 4.365468
Main Positive Header Cable Gauge mm2 35 3 2.910312
Main Positive Header Cable Length m 50 4 2.182734
Conductor Resistance Ω /m 0.00053 5 #DIV/0!
Main Positive Header Cable Resistance (Rp ) Ohms 0.02670 = (cable length) x (cable resistance) 6 #DIV/0!
7 #DIV/0!
e) Main Negative Cable 8 #DIV/0!
Main Negative Header Cable Gauge mm2 35 9 #DIV/0!
Main Negative Header Cable Length m 50 10 #DIV/0!
Conductor Resistance Ω /m 0.00053
Main Negative Header Cable Resistance (Rn ) Ohms 0.02670 = (cable length) x (cable resistance)
Circuit Resistance Allowable (V=IR) Ohms 2.400 = (TR Voltage Rating - Back EMF) / (TR Current Rating)
Actual Circuit Resistance Ohms 2.236 (Therefore Rectifier Sizing OK )
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A Total of 8 No. MMO Tubular Anodes Are Required For Design Purposes. Anodes Will Be Designed To Operate at Maximum Output (including contingency) of : 20%
Taken from Vendor data of 150A/m2 for 40yrs for MMO in water and
Maximum Allowable Anode Current Density A/m2 100.000
extrapolated for Project design life of 30yrs
Maximum Allowable Anode Current Output = Amps 7.980
Max. Operating Anode Current Output = Amps 3.00 (Therefore Anode Operating Current Output is OK)
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Cathodic protection for the above shall be as per the details provided in the following
Project documents:
105574-REP-Z-0003 – Cathodic Protection Design Report Pipeline
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