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Solutions to JEE Advanced Full Length Test-1 |JEE 2023 | Paper-2 (Gen 3 to 7)

PHYSICS
K1 A TA  T1  K 2 A T1  TB 
1.(AD) Since heat current is same through both blocks, 
L L
K1TA  K 2TB
 T1 
K1  K 2
K 2TA  K1TB
Similarly, T2 
K1  K 2

Let us find the quantity T1  T2 

 K1  K 2 TA  TB 
K1  K 2
Since T1  T2 is clearly positive, T1  T2

T  TB TA  TB  K K   A TA  TB  
Heat current in both cases, H  A    1 2  
RTh L L  K1  K 2   L 

K1 A K2 A
   
2.(ABD) If a  b  a  b  0 . So (A) is true
Minimum number of non-coplanar vectors required to give zero resultant is 4. So (B) is true.
        
a.(b  c )  0  a , b , c are coplanar. (a  b  c ) can be zero if they form a triangle. So (C) is false.
     
a  b  0    0 or 180°. If   180 and | a |  | b | , then a  b  0 . So (D) is true.

3.(BD) K .Eupper  Klower

Particles in shaded region will have velocity less than v.

 2 R 2   R 2 v
vav   4  2
R 
v
4.(ABC) Let the initial temperature, pressure and volume on both sides be T0 , P0 and V0
The final pressure on both sides will be the same. Let this pressure be P
The final volume on the two sides is 1.1V0 and 0.9V0
The process on the right side is adiabatic. So,
5 5
P0V0 3  P  0.9V0  3  P  1.2 P0
Let the final temperature on the two sides be T1 and T2

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1.2 P0 1.1V0  1.2 P0  0.9V0 

Then, T1  T0  1.32T0  396 K And, T2  T0  1.08T0  324 K
P0V0 P0V0
For the right compartment, work done by the gas
3 3 
W2  U 2    1.2 P0  0.9V0   P0V0   0.12P0V0
2 2 
Also, work done by the gas in the left compartment, W1  W2  0.12 P0V0
Change in internal energy of the gas in the left compartment,
3 3
U1  U f  U i  1.2P0 1.1V0   P0V0  0.48P0V0
2 2
So, heat added,  Q   U1  W1  0.60 P0V0

Hence,   
Q   0.60  105 2  103  120 J

5.(ABC)
Initially at origin, slope is not zero, so the particle has some initial velocity but with time we see that slope is
decreasing and finally the slope becomes zero, so the particle stops finally.
As the magnitude of velocity is decreasing, velocity and acceleration will be in opposite directions.

V2 dV
6.(BC) ar  , at  
R dt
2
V 2 
anet     2  a net is not towards centre
 R 
 
MV 2
fr  , ft  M 
R
 f net  f r2  ft2  f net  ft and find f net  f r

7.(A) When the length of hanging part is x, the spring is elongated by x

xg  kx
 a
l
100 x  50 x
 (as   0.1 kg /cm  10 kg /m )  5x
10
vdv
8.(B) a  5x   5x
dx
v x

 
v dv  5 x dx
0 0
2 2
v 5x
  v  5x
2 2
Or by energy conservation
loss in GPE = Increase in EPE + Increase in KE
x 1 1
xg    kx 2  lv 2
2 2 2
So 50 x 2  25 x 2  5v 2  v2  5x2

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9.(B) Let M and R be the mass and radius of the earth respectively. If m be the mass of satellite, then escape
velocity from earth ve  (2 Rg )
v (2 Rg )
Velocity of satellite vs  e  ... (i)
2 2
 GM   R2g  R2 g
Further vs        vs2 
 r   Rh Rh
h = R = 6400 km
10.(A) Now total energy at height h = total energy at earth’s surface (from principle of conservation of energy)
m 1 m
 0  GM  mv 2  GM
Rh 2 R
1 2 GMm GMm
or mv   ( h  R)  v  gR
2 R 2R
11.(B) 12.(B)
In reference frame of truck, the angular momentum is conserved about P, i.e.,
2
Mv0 R  MvR  MR 2 … (i)
5

v  R …(ii)
On solving equation (i) and (ii), we get
5
v v0
7
Note that v is the speed in truck frame; in ground frame, the velocity is v0  (5v0 / 7)  2v0 / 7 towards the
right. The answer is independent of M or R.
1.(300) Power absorbed by earth = power emitted by earth.


e 4  Rs2 Ts4  Rs Rs

4r 2 
 Re2  e 4 Re2 Te4   Te  Ts
2r
 Ts
2  200 Rs
Ts
 Tc  = 300 K
20
2.(7) By work energy therem we use
1 2
mv0  mgl (1  cos 60)
2
v02  1
 (9.8)(5) 1  
2  2
v02  9.8  5
v02  49 ; v0  7 m/s

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3.(475)   1   2  3

 13 10 7  231107  231 107  475  107

4.(0.5)

1 2
h gt
2
2h 2h
t  1  2 g 1  h    h  0.5 m
g g

3RT2
V2 M2 T2 M1 M1 V
5.(2)    T2  2T1 & M 2   2 2
V1 3RT1 T1 M 2 2 V1
M1

6.(12) Consider pulleys as X, Y and Z as shown. The

block A is tied to two strings which pass over two
pulleys X and Y and B is connected to Z.
If mass A goes up by a distance x, point P and Q
also go up by distance x and pulley Y go down by
distance x.
Thus, the length ab and cd and the distance x by
upward movement of Q is 3x. So, B goes down by
1.5 x.
The same constraint relation applies to velocity
 1.5v A  18
18
vA   12 cm/s
1.5

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CHEMISTRY
1.(ACD)
2.(D)

8a a
3.(AC) TC   500   TB  1687.5K
27Rb Rb
b
Slope   0.005
RT
 b  0.1642 L mol 1
27
 a  500   0.0821 0.1642
8
 22.74L2 atm / mol2

4.(ABD)
(A) 2 atoms :[3  2, 2  1],[3  1]
3 atoms :[3  2, 2  1],[3  1],[3  1] or [3  2, 2  1]
(B) 4 atoms :[4  2, 2  1],[3  1],[3  1] or [3  2, 2  1]
[4  3,3  1],[4  1]
Maximum diff. lines = 6
4(4  1)
For He  ion: 6
2
(C) IE of Li 2  Transition energy of He 
(D) E  13.6  3eV  13.6 eV

 3B(g)  C(g); H  0; PTotal  1bar;

5.(BC) A(g) 

T = 400 K
(B) Inert gas addition at constant volume, does not affect the equilibrium
(C) G 400  0 and not G o400
(D) As volume , pressure  even though the equilibrium shifts forward

6.(ABD)
75.6n
(A) H  ;
n  1.8
n  2  H  39.79 kJ
(B) n  7  H  60.14 kJ
75.6
(D) lim H    75.6 kJ
n  1.8
1
n
1
7.(B) E


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8.(C)    0 for e  ejection

9.(B) 10.(A)
AcOH  OH   AcO   H 2O

3 3 –
510 moles 510 moles –
– – 5103 moles

1  5 103  
pH   pK w  pK a  log     8.85
2   0.1  
AcO  H 2SO 4 
 AcOH  HSO 4
5103 3 – –
3 2.510 2.5103

2.510 –
z
pH  pK a  5

11.(C) Chiral centre = 9

12.(B) Based on stability of free radical.

1.(6)

(i)

due to more electron withdrawing effect of Cl at para position then F

(ii)

(iii)

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(iv)

are different compounds

(v)

(vi)
has more enol content because of more electron withdrawing effect of C=O

group of this compound

(vii)

(viii)

2.(6)

Y must be 3 as I, II and III are the only distinct products

X  3[p, q, r]
 XY 6

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PV 2.46  5
3.(4) PV = nRT ; n    0.5
RT 24.6
Moles of carbon = 0.5(x)
28.4[0.845]
Now using mass % of carbon, 0.5(x) 
12
x4

4.(2) 4FeS2  11O2 

 2Fe2 O3  8SO 2
0.36 0.36
2
120 120
0.36 1 6  V
 2 2   V  2mL
120 1000
5.(142)

1 
    498  x 
2 
 [188  53]  [ 286  44]  286  188  53  44
 x  142

6.(768)
K sp (AgCl)  104 106  1010

K sp (Ag 2 CrO 4 )  (104 ) 2  8 10 4  8  1012

No. of moles of Cl  remaining in solution

 10  107  8  10 7
 2  107
1010
 [Ag  ]  7
 5 104
2 10
8  1012
 [CrO 24 ]  8
 3.2  105
25 10
 No. of moles of CrO 24 precipitated

 80 105  3.2 105

 76.8 10 5
 768 10 6
 = 768

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MATHEMATICS
r
100
 100 r   
8
1.(AC) Tr 1  Cr  5 6  2
 
 
r  0, 8, 16 , 24, 32, 40, ……. 96
r  16, 40, 64,88 Rational term

2.(BD) A- E1  E2  E3  5
4
1 1 1 C2  6
5! 5!
B. 5


1
2
1
1   15  10  25
2 3 2!2!2! 2!3!

299  2
3.(BCD) a  233 , b  265 , c 
3
4.(ABD)

5.(ABCD)
1 1 a a an 1
  n 1 n 1   …(i)
an 1an an an 1 an 1an an 1 an 1an an 1 an 1an 1
 (a) is correct.
a1  a2  1, a3  a2  a1  1  1  2
a4  a3  a2  2  1  3, a5  a4  a3  3  2  5 etc.
{an }2 is increasing sequence. So (d) is correct.
Also, an   as n   …(ii)
n n
1  1 1 
     
n  2 an 1an1 n  2  an1an an an 1 
 1 1   1 1   1 1   1 1 
        ...    
 a1a2 a2 a3   a2 a3 a3 a4   a3 a4 a4 a5   an 1an an an 1 
1 1
 
a1a2 an an1

1  1 1  1
  an1an1  nlim 
 a a
  1 1
 1 2 an an 1  
…(iii)
n 2

 (b) is correct.

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n n
an  a an 
   n   
n  2 an 1an 1 n  2  an 1an an an 1 
n
 1 1  1 1  1 1  1 1   1 1 
   an1  an1    a1  a3    a2  a4    a3  a5   ...   an1  an1 
n2

1 1 1 1
   
a1 a2 an 1 an 1

a 1 1 1 1 
  an1an n1  nlim  
 a
    11 0  2
 1 a2 an 1 an 1 
 (c) is correct.
n 2


6.(AC) (A) 0 x
4
tan x  cot x
Also ln(sin x)  0
(tan x)ln sin x  (cot x)ln(sin x )
 
(B) in  0, 
 2
cosec x  1
4ln cosec x  5ln cosec x
 
(C) in  0,  ,cos x  (0,1)
 2
ln cos x  0
1 1
Also 
2 3
ln(cos x ) ln(cos x )
1 1
   
2 3
 
(D) sin x  (0,1) x   0, 
 2
 sin x  sin10 x
12
7.(C) 11 seats remains vacant so for no two persons to be side by side, number of ways to form them is C10 10!

8.(D). Number of persons = 10, we have 5 groups (2 each) to be seated so that no two groups are together. Then
number of ways
12!
 (21  10  1)  10!   10!
5!7!
12!  10  9  8
  6  (12)!
5 432

9.(C) a  x  y  1  b  2 x  y  7   0
Family of line passing through point of intersection of 2 x  y  7  0, x  y  1  0   6, 5 
6
Required line  y  1   x  1
5
5 y  6 x  11

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10.(C)

 6, 5 , 5, 3

2
 y  3   2  x  5 
1
y  2x  7  0
 x  5  2   y  3 2    2 x  y  7   0
Common chord passes through (1, 2)
8  20  28   (3)  0
40

3
50 x 58 y 178
x2  y 2    0
3 3 3
11.(A) Roots are of opposite sign
af (0)  0
a(a  3)  0
a  (0,3)

12.(B) a( x  1) 2  x  3  0
n 1  t
at 2  t  2  0
1  1  8a
t 
2a
1  8a  4n 2  4n  1  (2n  1)2
Hence roots are rational

1.(6) Tk  k 3  n  1  k 2
k2
2
Tk  k  n  1  k 
2
 n  1 n  n  1 2n  1 n 2  n  1
Sn  
6 4
2 2 2
n  n  1  2 n  1 n  n  n  1  n  2 
  3  2  
2 12
S 6

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2.(2) x2  y 2  2x  4 y  1   6 x  6 y  4  0
x2  y 2  4  0
2 g1 g 2  2 f1 f 2  c1  c2  c1  c2  0
1  4   4  0
5
 ; LT  s1  4  2
4
1
3.(2) a1  1 a10  2  d 
9
g1  1 g10  2  r 9  2
1  4
h1  1 h10   reciprocal A.P.  d r  
5  9
a19  1  18d  3
1 1 4 1
  27   h28 
h28 1 9 13
a28  1  27 d  4
g19  g1.r18  4
1 4 1  6 16 
 1  18   h19  ; 13  9   2
h18 9 9

4.(2)  
2 cos 2 x  2  3 cos x  3  0 sin 3x  2sin x

 2 cos x  3   cos x 1  0 3sin x  4sin3 x  2sin x

3 1 1
cos x   , cos x  1 sin x  4sin3 x ; sin x  0, sin 2 x   sin x  
2 4 2
7 19
x ,
6 6

5.(3) P  x   ax 2  bx  c
P  x   P  x  1  2 x  1

 ax 2
  2

 bx  c  a  x  1  b  x  1  c  2 x  1

2ax  a  b  2 x  1
a  1, b  2
P  x    x2  2x  
2
P  x    x2  2x  2
P  1  3

VMC |JEE-2023 | Paper – 2 12 Solutions |JEE Advanced Full Length Test -1 | Gen 3 to 7
 Vidyamandir Classes

 4x  3 y 
6.(9) x   
 5 
4 x  3 y  5 x
9 x  3 y  0,  x  3 y  0
y  3 x, 3 x  2 x 2  27
2 x 2  3x  27  0
9
x  , (Rejected)
2
Diameter  9

VMC |JEE-2023 | Paper – 2 13 Solutions |JEE Advanced Full Length Test -1 | Gen 3 to 7