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DRONA NEET 2023

Aldehydes, Ketones & Carboxylic Acids DPP-02

1. In the Cannizzaro’s reaction the intermediate that will

be the best hydride donor?
Ph −CHO LiAlH
3. ⎯⎯⎯⎯
OH/ 
→ ⎯⎯⎯⎯
4 → [X],

(1) Product (X) in this reaction is:

(1)
(2)

(2)
(3)

(3)

(4)

(4)
2. Product of following reaction is:

NaOH 4. In the given reaction,

+ conc. NaOH ⎯⎯⎯⎯⎯⎯
Ethanol water
→?
Heat

(1)
(Y) is:

(2)
(1)

(3)

(2)
(4)

(3)

(4)
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O CH3 9. In the reaction

|| |
5. KOH, H 2O
CH3 C CH 2 CCHO ⎯⎯⎯⎯⎯ → Product (C7 H10O) :
| 
CH3

(1)

(1) (2)

(2)

(3) (4)
(3)

6. In the scheme given below, the total number of

(4)
intramolecular aldol condensation products formed
form “Y” is:

⎯⎯⎯⎯⎯
1. O
3
→ Y ⎯⎯⎯⎯⎯
1. NaOH(aq)
→ 10. In the given reaction
2. Zn, H O 2. Heat NaOH/ 
2
(A) + (B) ⎯⎯⎯⎯→ C6H5 − CH = CH − CHO
(A) and (B) will be
(1) C6H5CHO and HCHO
(2) C6H5CHO and CH3CH2—CHO
H  /H O (3) C6H5—CH2—CHO and CH3CH2—CHO
+ CH 3MgBr ⎯⎯⎯⎯→ P ⎯⎯⎯
→
2 HBr
7. (4) C6H5—CHO and CH3—CHO

Q ⎯⎯⎯ 2 → R ⎯⎯⎯⎯→ S, S is
M HCHO
Ether  H /H 2O
11.

(1)
Product of the reaction is

(2)
(1) (B)

(3)

(4)
(3) (4)

8. Acetaldehyde reacts with semicarbazide, product will

be
12. A compound with molecular formula C3H6O, not
(1) CH3CH = NNH—CO—NH2 gives silver mirror with Tollen’s reagent but forms
(2) CH3CH = NCONHNH2 oxime with hydroxyl amine. Compound will be
(3) CH3CH = NHNH2 (1) CH2 = CH—CH2—OH
O (2) CH3CH2CHO
|| (3) CH2 = CH—O—CH3
(4) CH3 — C — NH — CONH 2 (4) CH3COCH3
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13. In the following reaction, product P is 15. In the given reaction

O
||
H2
R — C — Cl ⎯⎯⎯⎯⎯ →P
Pd − BaSO 4
(1) RCH2OH (2) RCOOH A will respectively be
(3) RCHO (4) RCH3
(1) (2)
14. Arrange the following compounds in decreasing
order of nucleophilic addition reaction (3) (4)
O
||
(I) H — C — H
O
||
(II) H3C — C — H
O
||
H
(III) 3 C — C — CH3

(IV)
(1) II > IV > III > I
(2) I > II > III > IV
(3) IV > III > II > I
(4) II > III > IV > I
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Answer Key
1. (4) 9. (4)
2. (3) 10. (3)
3. (1) 11. (2)
4. (2) 12. (4)
5. (3) 13. (3)
6. (1) 14. (2)
7. (2) 15. (2)
8. (1)
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Hints & Solutions

1. (4) 6. (1)
Conceptual
2. (3)
We know that Cannizzaro reaction is a chemical 7. (2)
reaction, which include the base induced
disproportion of two molecules of an aldehyde to 8. (1)
form a carboxylic acid and a primary alcohol.
9. (4)
3. (1)
10. (3)

11. (2)

12. (4)

13. (3)

14. (2)

15. (2)

4. (2)
Hell-Volhard Zelinsky reaction.
5. (3)

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