10. cr 12. Some Basic Concept of chemistry JEI Esse DVANCED EXERCISE lly To Be Discussed in Class SECTION - 1: NUMERICAL ANSWER BASED QUESTIONS Ifall the oxygen atoms from a mixture of 2 moles H,P,O,, 54-gms H,O and 98 gms H,SO, are taken and converted into Ozone , the the number of moles of Ozone gas formed will be: ‘The number of moles of carbon in 48 grams methane will be The number of moles of iron in a mixture of 144 gms FeO. and 320 gms of Fe,0, will be The number of moles of neutrons found in 2 gms of Oxygen atoms will be: Iffrom a sample of 160 gms SO, 6.023 x 10® molecules are removed, followed by removing 22.4 litres of the gas at STP then the mass of the remaining gas will be. 22nS + 30, —> 22n0 + 20, 1f Smol mixture of ZnS and O, is taken then what is the molof Oy in the mixture s that the maximum amount of SO, can be obtained 1f200 gms CaCO, is decomposed to form CaO and CO,, then through combustion thé number of moles of CH, required to form the same amount of CO, willbe The total number of atoms in 4 amu He and 36 amu H,0 will be. The ratio of the vapour density of O, to the vapour density of CH, willbe ‘The molality of 1 litre solution with y % (w/v) of CaCO, is 2. The weight of the solvent presentin thesolution is 450 q then, value of yis:[ALwt. : Ca = 40; C= 12: 0= 16) SECTION - 2: MATRIX-MATCH QUESTIONS Colunin-t Column-I (A) 82g each of Ogands (6) 2moles of Fe (B) 2 gam-molecule of Ky[Fe(CN},) (@ 3moles of ozone molecule (©. 144g of oxygen atom (9) one mole (D) From 168 gofiron, 6.022 x 10 atoms (s) 12 moles of carbon atoms of iron are removed, the ironleft Match the following: Column Column Il (A) gram-atom préentinone atom (2, 1 (B)_N,gramatom contains atom @ Ny (©) No.of protons in 1 gm molecule of Hy @ aN, (D) No.of electrons added to 32 gm O atom to convert it into O* ® Ne Match the following: Column Column It (A) 100 mlof 0.2 M AICI, solution (6) Total concentration of cation(s) = 0.12 M + 400 ml of 0.1 M HCI solution (B) 50 mlof 04M KCI + 50 mi H,0 (@ (80,2 =0.06M (©) 30mlof0.2MK,SO, +70 ml HO (@ ($0,21=25M (D} 200m124.5% (wiv) H,SO, ) (Cr]=02M 35}—JEE-Chemistry 14. Maich the following: Column I Column I (A) Zn(s) + 2HClaq) > ZnCh(s) + Ha(a) (0) 50% of excess reagent left above reaction is carried out by taking 2 moles each of Zn and HCI {B)_AgNO,(aq) + HCl(aq) > AgCis) +HINO(g) (q) 22.4 Lof gas at STPis liberated above reaction is carried out by taking 170 g AgNO, and 18.25 g HCI (Ag = 108) (C}_ CaCOa{s) > CaO{s) + CO,(a) {9 —Lmoles of solid (product) obtained. 100g CaCO, is decomposed D)_2KCIO,(s) > 2KCI(s) + 304(a) (9) HClis the limiting reagent 2/3 moles of KCIO, decomposed } ANSWERS + NUMERICAL ANSWER BASED QUESTIONS 1 2 @ 3 6) 4) 5. 0) i 6 8) ey a 0 2 6) 10. 2 i * MATRIX MATCH QUESTIONS 2 11. (A) (2), (B) - (ps). (C) -(q). (D)- (p) 12. (A)-(q). (B) -(5), (C)- (pl. (D)- (0) 2 43. (A) (ps) (B)- (8) (©) -(pa), (D)-) 44. (A)- (pars), (B) (po). (C) (ar). (D) (a)