www.hoahocmoingay.

com
www.hoahocmoingay.com
www.hoahocmoingay.com
www.hoahocmoingay.com
www.hoahocmoingay.com
www.hoahocmoingay.com
www.hoahocmoingay.com
www.hoahocmoingay.com
www.hoahocmoingay.com
www.hoahocmoingay.com
www.hoahocmoingay.com
www.hoahocmoingay.com
www.hoahocmoingay.com
www.hoahocmoingay.com
www.hoahocmoingay.com
www.hoahocmoingay.com
www.hoahocmoingay.com
www.hoahocmoingay.com
www.hoahocmoingay.com
www.hoahocmoingay.com
 www.hoahocmoingay.com

S 6 GIAO DQC VA ©AO T ^ O K I T H I CHQN HQC SINH G I OI LCfP 9 CAP THANH PHO
HA NOI NAM HOC 2016 - 2017

B E CHINH THLfC Mon: H 6 A H Q C

Ngay thi: 28/3/2017
Thai gian lam bai: 150 phut
(Be thi gSm 02 trang)
B 2 i l (3 diim)
1. Tir dung dich H 2 S 0 4 98% (kh6i lugng rieng 1,84 g/ml), dung djch HC1 5M, nuac ck va
ede dung cu can thiet, trinh bay each pha che de dugc 200 ml dung dich chua hon hgp H 2 S 0 4
lMvaHCHM.
2. Neu bien phap xu li moi truang trong truang hgp tau cha dlu gap su c6 va tran dau ra
bien.
3. Sue tu tu a moi khi C 0 2 vao 800 ml dung dich X g6m KOH 0,5M va Ba(OH) 2 0,2M.
Tim dilu kien cua a di thu dugc kh6i lugng kit tua Ion nhat.
Bhill (4diim)
1. Tien hanh thi nghiem voi cac muoi tan X, Y , Z, T thu dugc ket qua nhu sau:
Mau thu Thi nghiem Hien tugng
X hoac Z Tac dung vai dung dich chua chat Y Co ket tua tring
X hoac T Tac dung vdi dung dich chura chit Z Co khi C 0 2
X Tac dung voi dung dich chua chit T Co ket tua trdng
T Dun nong Co khi C 0 2
Biet: M x + M T = 252; M x + M z = 226; M z + M T = 266; M z + M Y = 328. Xac dinh cong thuc
cac mu6i X, Y, Z, T va viet cac phuang trinh hoa hoc minh hoa.
2. Cho thi nghiem dugc b6 tri nhu hinh ben.
a) Chi ro ch§ sai cua viec bo tri thi nghiem.
b) Sdp dat lai cac thiet bi va hoa chat de thi
nghiem hinh ben la dung, khi do viet phuang trinh
CuO'
hoa hoc xay ra va cho biet phan ung do thudc loai
phan urng hoa hoc nao? H,Q
3. Chon cac chit X i , X 2 , X 3 , X 4 , X 5 , X 6 thich hop va hoan thanh cac phuang trinh hoa hoc
sau:
(QX1+X2 - ^ N a 2 S 0 4 + BaS0 4 + C 0 2 + H 2 0.
(2) Xj + X 3 -> Na 2 S0 4 + BaS0 4 + C 0 2 + H 2 0.
(3) FeS0 4 + X , -> Fe 2 (S0 4 ) 3 + S 0 2 + H 2 0.
(4) X 2 + X 5 -> BaC0 3 + H 2 0.
(5) X 2 + X 6 BaC0 3 + CaC0 3 + H 2 0.
(6) X i + X 5 (du) -> BaS0 4 + NaOH + H 2 0.
Bhim (4,5 diim)
1. Cho 8,4 gam hon hgp A gom Al va Mg vao c6c chua 550 ml dung dich H 2 S0 4 1M (loang),
sau phan ung them tilp 500 ml dung djch B chua Ba(OH)2 0,4M va NaOH 1,6M vao c6c. Loc lay
ket tua dem nung den khli lugng khong d6i thu dugc 57 gam chat rin khan. Bilt cac phan ung
dlu xay ra hoan toan, tinh kh6i lugng moi chat trong h6n hgp A.

Trang 1/2
 www.hoahocmoingay.com

2. Thuc hien thi nghiem: Cho tu tu dung dich } s4moiAi(OH),

NaOH 1M vao clc chua 200 ml dung dich A1 2 (S0 4 )3,
khuly dlu de cac phan ung xay ra hoan. So moi kit tua
thu dugc ph\i thuoc vao thi tich dung dich NaOH theo
V (ml) NaOH
do thj hinh ben. Tinh nlng do moi cua dung dich
A1 2 (S0 4 ) 3 trong thi nghiqm tren.
Bai IV (4 diim)
1. Cho 20,55 gam kim loai bari vao 100 gam dung dich chura Fe(N0 3 )3 6,05% va A1 2 (S0 4 ) 3
8,55%. Sau khi cac phan tog xay ra hoan toan, loc bo kit tua thu dugc dung dich X. Tinh
nong do phan tram cua cac chit tan co trong dung dich X (coi nuac bay hai khong dang kl).
2. Dot chay hoan toan 1,08 gam hon hgp X glm hai chat huu ca A va B (A, B khac day
dong ding, trong do A nhilu han B mot nguySn tur cacbon). Sau ph2n tog chi thu dugc H 2 0
va 1,12 lit C 0 2 (dktc). Bilt Mx= 27.
a) Tim cong thto phan tu cua A va B.
b) Tinh phan tram khoi lugng cua moi chit trong X.
Bai V (4,5 diim)
1. H6n hgp X glm propilen (C 3 H 6 ), axetilen (C 2 H 2 ), butan (C 4 Hi 0 ) va hidro. Cho m gam X
vao binh kin (co xuc tac Ni, khong chura khong khi). Nung nong binh din phan tog hoan toan
thu dugc hon hgp khi Y . B i t chay hoan toan Y can V lit 0 2 (dktc) thu dugc hln hgp Z gom
khi va hai. Cho Z di tur tur qua binh dung H 2 S 0 4 dac, du thly khoi lugng binh tang 7,92 gam.
Hln hgp Y lam mat mau tli da 100 ml dung dich Br 2 1M (dung moi CC14). Biet 6,72 lit (dktc)
hon hgp X lam mat mau tli da 38,4 gam brom trong CC1 4 . Tim gia tri cua V.
2. Cho 12,4 gam hon hop A gom canxi cacbua va canxi tac dung hit vai nuac thu dugc 5,6
lit (dktc) hon hgp khi X .
a) Tinh phan tram khoi lugng cac chat trong hln hgp A.
b) Dan toan bo hon hgp X qua hot Ni nung nong mot thai gian dugc hln hgp khi Y.
Cho Y qua binh dung dung dich brom du (dung moi CC14) M y khli lugng binh dung brom
tang m gam va co 2,24 lit (dktc) hon hgp khi Z thoat ra khoi binh. Hon hgp Z co ti khli so vai
hidro la 4,5. Tim gia tri cua m.

Cho: H = 1; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; S = 32; CI =35,5; K = 39;
Ca = 40; Fe = 56; Br = 80; Ba = 137.

-Het-

Luu y: Can bo coi thi khong giai thich gi them.

Ho va ten thi sinh: S6 bao danh:

Trang 2/2
 www.hoahocmoingay.com

Sd GIAO DQC VA DAO TAO K Y T H I CHQN HQC SINH G l 6 l L 6 P 9 CAP THANH PH6
HANQI NAM HOC 2017-2018

DE CHfNH THUG M6n: HOA HQC

Ngdythi: 04/4/2018
Thdi gian lam bdi: 150phut
(Di thi gdm 02 trang)

B M I (3,0 diim)
^ 1. Hinh ve ben m6 ta thi nghifm dieu
che khi Z. Khi Z co the la khi ndo trong s6
vWZA
cac khi sau: H 2 , N H 3 , S0 2 , HCI. Viet
phuang trinh hoa hpc minh hpa va chi ro Dung djch X

cdc chit X, Y trong phan ung.

2. Gidi thich tai sao:
- Nude da kho thudng dupe dung de bao quan thpc phlm ?
- Khi C0 2 khong the dung de dap t i t cac dam chdy kim loai nhu Mg, AI ?
3. B i AgCl (mau trdng) ra ngodi dnh sdng, thay chuyen dan thdnh chit rln mau den. Giai thich
hif n tupng vd vilt phuang trinh hoa hpc minh hpa.
B M H (4,0 diim)
Y 1. Chpn cac chit phu hop vd vilt phuang trinh hoa hpc thpc hifn sa do chuyln hoa sau:
HQ . v . v

X(r)maudea " X 3 (di)mkvJng > X2(iJ)Hi&igciaa

(1): >M
(9)
HQ .V vV H2SO 4 <l|c,t 0 vv '
mausanh > I2(da)mauxanh ... > I3(r)maud6 ~ * 14 (ddjmiuxanli
(5)
(6) (7) (8)
Bilt phan t& khli cac chat thoamdn: MX+MY =167; MXi +MYi =396; MXj +MYj =226,5.
2. Chpn cac chat phu hop vd hodn thanh cdc phuang trinh hda hpc sau:
b
a) K M n 0 4 — A i + A 2 + 02T (0 )B* + B
2 » B a S 0 4 | + C 0 2 | +... + (1)

Ai+HCl d5c - Bi + BaCl2 • + BaS0 4 | + ... +... (2)

-> CI2T + .»+ ».+ .-(2)
B 2 + H 2 S0 4 + BaS0 4 l + C0 2 T + ... (3)
A 2 + HCI m U c i 2 t + ... +... (3)
B 2 + NaOH - » B 3 | + ... + ... (4)
Bum(4,0aim) . >
1. B i t chay hodn toan m gam donchat X (la chit rln mau do) trong oxi du thu dupe chdt rln Y
(chit Y tan trong nuac tao thanh mpt axit tucrng ting vdi Y). Cho toan bp chit r ln Y vdo 500 ml
dung djch chua hon hpp NaOH 0,5M va KOH 1M din khi cac phdn ung xay ra hodn todn, co can
dung djch sau phan ung, lam kho cdc chit thu dupe 47,24 gam chat r ln khan. Tim gia trj cua m.
2. Bft hai clc A, B co khli lupng blng nhau len 2 dia can, can d vj tri thdng blng. Cho 120
gam h6n hpp kali hidrocacbonat vd natri hidrocacbonat vao clc A; 85 gam b^c nitrat vao clc B.
Them tu tir 100 gam dung djch axit sunfiiric 19,6% vdo clc A; 100 gam dung djch axit clohidric
36,5% vdo clc B. Sau thi nghifm, can co d vj tri thdng blng khong ? Neu can khorig d vj tri thdng
blng thi can them,bao nhieu gam dung djch axit clohidric 36,5% vao clc ndo de can trd lai vj tri
thang blng ? (Gia thiet khi C 0 2 khong tan trong nude, bo qua qua trinh bay hai cda nude vd
hidroclorua).
Trang 1/2
 www.hoahocmoingay.com

BhiTV (4,0diim)
1. Cho ankan X tdc dpng vdi clo trong dieu kifn cd dnh sdng thu dupe khi hidroclorua va
26,25 gam hon hpp Y glm hai dan xult monoclo vd diclo. Lupng khi hidroclorua sinh ra dupe hda
tan hodn todn vao nude, trung hda dung dich thu dupe blng 500 ml dung dich NaOH 1M.
a) Tim cdng thdc phdn tii cua ankan X.
b) Dot chay hodn toan V lit (d dktc) ankan X blng oxi du, todn b f lupng C 0 2 sinh ra dupe hap
thy vao 250 ml dung dich Y chda dong thai Ba(OH)2 0,2M vd NaOH 0,32M thu dupe m gam ket
tda. Tim dieu kien cua V de m dat gid trj ldn nhlt.
2. Dot chay hodn toan 0,99 moi hon hpp X gom CH3COOCH3, CH 3 COOC 3 H 7 vd ba
hidrocacbon mach hd cdn vira du 3,81 moi 0 2 thu dupe C 0 2 vd 43,2 gam H 2 0 . Neu cho 0,165 moi
hon hpp X tdc dung vdi dung dich Br 2 du thi co bao nhieu moi Br 2 phdntimg?
BkiV (5,0 diim)
1. Hoa tan mft lupng hon hpp gom A l va A i 2 0 3 trong dung djch H 2 S0 4 Ioang vua du thu dupe
dung djch X trong dd co so nguyen tir hidro blng 1,76 i l n s6 nguyen tir oxi. Tinh ndng dp phan
trdm cua chit tan cd trong dung dich X.
2. Cho m gam Zn vdo dung dich chvra 0,1 moi AgN0 3 vd 0,15 moi Cu(N0 3 )2, sau mft thai gian
thu dupe 26,9 gam ket tua vd dung djch X chda 2 muoi. Lpc bo ket tua, them tiep 5,6 gam bf t sit
vdo dung djch X, sau khi cdc phan dng xay ra hodn todn thu dupe 6 gam ket tua. Tim gia tr} cua m.
3. Cho 5,102 gam hon hpp X glm hai muoi M 2 C 0 3 va MHC0 3 tdc dyng vdi dung djch HCI du,
din toan bf khi thodt ra vdo 500 ml dung djch Y glm KOH 0,024M vd Ba(OH)2 0,09M thu dupe
7,88 gam ket tua. Xdc djnh c6ng thuc vd tinh phln trdm khli lupng moi muli trong hln hpp X.

Cho: H =1; C = 12; N = 14; O = 16; Na = 23; A l = 27; P = 31; S = 32; CI = 35,5; K = 39;
Mn = 55; Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba = 137.

. Ret-

Luu y: Cdn b$ coi thi khong gidi thich gi them.

Hp va ten thi sinh: „ S i bao dank „

Gidmthjl: Gidmthj2:

Trang 2/2
www.hoahocmoingay.com
 www.hoahocmoingay.com

Powered by TCPDF (www.tcpdf.org)