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POLYMERS
POLYMERS
How are the chemical units joined together in Like beads on a string.
polymers?
What are the natural examples of polymers? Starch, cellulose, and DNA.
What are monomers in the context of polymers? Simple repeating units used for synthesizing
polymers.
What are polymer molecules also known as? Gigantic molecules or macromolecules.
How are the atoms bound together within each By covalent interatomic bonds.
polymer molecule?
Name some examples of natural polymers. Cellulose, starch, natural rubber, and DNA.
Name some examples of synthetic polymers. Nylon, polyethylene, polyester, Teflon, and epoxy.
How is polyethylene (PE) made? By the reaction of multiple ethylene molecules in the
presence of a catalyst.
What is the first step in the process of polyethylene Formation of an active center by the reaction
formation? between an initiator or catalyst species and the
ethylene monomer.
What is the final result of the addition of many The polyethylene molecule with a polymer chain
ethylene monomer units? structure.
What does the schematic representation of Repeat unit and chain structures.
polyethylene show?
What does the polymerization of vinyl chloride lead Polyvinyl chloride (PVC)
to?
What does the variable 'R' represent in the general Either an atom (e.g., H or Cl) or an organic group
form of a polymer? (e.g., CH3, C2H5, C6H5).
What is the structure of linear polymers? The repeat units are joined together end to end in
single chains.
How are the long chains of linear polymers They are flexible.
characterized?
What kind of bonding may exist between the chains Extensive van der Waals and hydrogen bonding.
of linear polymers?
Name some common polymers that form with linear Polyethylene, poly(vinyl chloride), polystyrene,
structures. poly(methyl methacrylate), nylon, and the
fluorocarbons.
What effect do side branches have on chain Reduces chain packing efficiency.
packing efficiency?
What is the difference between high-density HDPE is primarily linear, while LDPE contains
polyethylene (HDPE) and low-density polyethylene short-chain branches.
(LDPE) in terms of chain structure?
How would you describe the structure of low-density Contains short-chain branches.
polyethylene (LDPE)?
What is the consequence of irregular packing of Low density and tensile strength.
molecules in branched polymers?
What type of atoms or molecules are often used for Additive atoms or molecules
crosslinking?
What are the characteristics of materials that are Hard, rigid, and brittle
crosslinked?
What are the characteristics of multifunctional They form three-dimensional networks by making
monomers? three or more active covalent bonds.
What distinctive properties do network polymers Distinctive mechanical and thermal properties.
have?
How many synthetic polymers are presently known? More than 60,000.
What is the Degree of Polymerization (DP)? It is the number of monomer or repeating units (n) in
the polymer chain.
What is the purpose of using Degree of To calculate the average molecular weight of the
Polymerization (DP)? polymer.
What is a characteristic of thermoplastics? They can be melted and cooled multiple times.
What analogy can be used to explain the behavior Butter - it can be melted and cooled multiple times
of thermoplastics? to form various shapes.
What is a characteristic of thermosets? Once the final state is achieved, any additional heat
would lead to charring.
What analogy can be used to explain the behavior Bread - any additional heat would lead to charring.
of thermosets?
What are the two subdivisions of polymers based Thermoplastics and thermosets.
on behavior with rising temperature?
What are the two subdivisions of polymers based Thermoplastics and thermosets.
on behavior with rising temperature?
What happens to thermoplastics upon heating? They soften and later liquefy.
Is the process of softening and hardening of Yes, it is reversible and can be repeated.
thermoplastics reversible?
Can you name some examples of common PE, PS, PETE, PVC
thermoplastic polymers?
What are thermosets? Network polymers that do not soften upon heating
and become permanently hard during their
formation.
What happens to thermosets during heat The bonds fasten the chains together to resist chain
treatment? motions at high temperatures, preventing softening.
What are examples of thermosets? Vulcanized rubbers, epoxies, phenolics, and some
polyester resins.
How does the atomic arrangement in polymer More complex as it involves molecules instead of
materials compare to metals in the crystalline state? just atoms or ions.