化數 homework (CH4) 解答

 nB 
1. The viral equation of state of a gas at low pressure is pV  nRT 1  .
 V 
dp
Find at constant T and n (assume B is also a constant) (10%)
dV

2. Differentiate by rules:
2 x
(i) ln   (5%)
 3 x 

2
3
(ii) x 2 e 2 x (5%)

(iii) sin x cos x (5%) ;

 y  sin x cos x  u  
du d
u  sin x,  cos x;   cos x,   sin x
dx dx
dy d du
u   sin x  ( sin x)  cos x  cos x   sin 2 x  cos 2 x
dx dx dx

ln x
(iv) (5%).
x

dy
3. (i) x  y ln xy , find (5%)
dx

dy
(ii) x  2 y 2  3 y  1, find (5%)
dx

d ln p H vap dp pH vap

4. Show that the equations  2
and  are equivalent
dT RT dT RT 2
expressions of the Clausius-Clapeyron equaition. (10%)
5. Find a general formula for the nth derivative of cos 2 x . (10%)