物理冶金 Problem 12.

3 魏茂國

On the assumption that the self-diffusion coefficient of a simple cubic metal whose
lattice constant, a, equals 0.300 nm is given by the equation
D = 10-4e-200,000/RT, m2/s,
determine the value of the diffusion coefficient at 1,200 K and use this to determine
the mean time of stay, , of an atom at a lattice site. (R: 8.314 J/molK)

200 , 000 200 , 000

4 4
D  10 e RT
 10 e 8.3141200
 10  4 e  20.05  1.967  10 13 (m 2 / s )
2
 9 m 
 0 . 300 nm  10 
a2 a2  nm 
D      7 . 624  10 8
s
6 6D  m 
2
6  1.967  10 13 
 s 

1
物理冶金 Problem 12.7 魏茂國
~
With the aid of the data available in Table 12.2 and Fig. 12.14 determine D , the
interdiffusion coefficient, at the composition NA=0.625 using the following directions:
(a) Draw a tangent to the penetration curve at NA=0.625 in order to determine x/NA
at this composition. (b) With the aid of Simpson’s Rule, graphically integrate the data
in Table 12.2 from NA=0 to NA=0.625. (c) Using the results of the above, evaluate the
~
Matano equation for D letting the time, t, equal 50 hours. Compare your answer with
Fig. 12.15.

2
物理冶金 Problem 12.7 魏茂國

(a) N A 1 0
  298.5m 1
x m
1.15mm   2.2mm 10 3
mm
x 1 3
 1
 3 .35  10 m
N A 298.5m

3
物理冶金 Problem 12.7 魏茂國

(b)

N A
NA
N A1 xdN A  x0  4x1  x3  x5  x7  x9   2x2  x4  x6  x8   x10 
3
x1  x3  x5  x7  x9   1.82  1.07  0.72  0.52  0.27  10 3 m  4.4  10 3 m
x2  x4  x6  x8   1.35  0.87  0.62  0.39  10 3 m  3.23 10 3 m
0.0625
 0
0.625
xdN A   2.92  4 4.4  2 3.23  0.0710 3 m  5.64 10 4 m
3

4
物理冶金 Problem 12.7 魏茂國

1 x N A
(c) 1
   
~
D   N xdN A    3.35 10 3 m   5.64  10  4 m
2t N A A1 s
2  50hr  3600
hr
2
12 m
~
 D  5.25  10
s
The data given in Fig. 12.15 indicates that the diffusion coefficient is about:
~
11 m2
D  5.18  10
s

5
物理冶金 Problem 12.10 魏茂國
~
Determine the interdiffusion coefficient, D, for nickel in a 50 atomic percent Ni nickel-
gold alloy at 1173 K using the data plotted in Figs. 12.18 and 12.19.

6
物理冶金 Problem 12.10 魏茂國

cm 2 14  m 
2
D  8.24  10
*
Ni
10
 8.24  10  
s  s 
cm 2 14  m 
2
D *
Au  9.21 10 10
 9.21 10  
s  s 
 ln  Ni
1  N Ni  0.34
 ln N Ni
*   ln  Ni 
 
~
D  N Ni D Au
*
 N Au DNi 1  N Ni 
  ln N Ni 
 m2 
    0.5  8.24 10  0.34  2.97 10
~
 D  0.5  9.21 10 14 14 14
 
 s 