JEE (Main + Advanced) 2021 LEADER + ENTHUSIAST COURSE| CHEMISTRY, GRS-4 ‘SALT ANALYSIS. Matching List Type 1 x 3 Q. (Three list type questions) The following column I, Il, III represent the reactions between salt solutions and reagents which gives different colour of precipitate. Answer the questions that follow Column: - Salt in aqueous solution Column-II - Reagents Column-III - Colour of precipitate Column 1 Column = I Column 11 Salt in aqueous sol Reagen Colour of precipitate (NaS, (i) Cuso, (P) White precipitate All) NaS Gi) AgNO, (Q) Reddish Brown am Ka (ii) K.Cr,0, (R) Chocolate Brown (IV) K,{Fe(CN),] {iy) ZnSO, (S) Black precipitate BX Observe the following reactions= AgCl(s) + NH, => [Ag(NH).}g + Chg fas a) Which of the following set of codéis CORRECT about the ‘X” ? (A) On mixing of aqueous solution of (1) and (ii) and followed by heating gives (X) (B) Mixture of (I) and (iv) gives (S) which is identical with (X) (C) Mixture of (IV) and (i) gives (S) which is identical with (X) (D) On mixing of aquéous solution of (II) and (ii) and followed by heating gives (X) 2. CORRECT set of combination is- (A) dD, Gi), Q (B) (IID, Gi), (RY B.6.0) (D) AV), (i), (P) © Which of the following set of combination is INCORRECT? (A) CD, Gi), (S) BOO.) (©) AV), (iv), P) (D) ID), (iv), (P) Only Single Correct : (A. Which of the following reaction cannot take place in reality ? PD» SF + FO, + 6Ht —> 3F,+3H,O (B) SCI + ClO, + 6H* —> 3Cl, + 3H,0 (©) SBI + BrO, + 6Ht —> 3Br, + 3H,O (D) SI +10, + 6H* —> 31, + 3H,0 E — 1Guided Revision Plan ALLEN olet colour product di (A) [Ni(en),]"? + $0, —> BT Fe + 28,02 —> (©) $7+ [Fe(CN), NOP» —> (D) Nallag,) + Cl, water se Identify the correct statement (A) The ppt of BaCO, is insoluble in dil HCL (B) Hg(NO,), + Na,S > white ppt of HgS NE7Na,SO, + Ha(NO,), > yellow ppt of HgSO,.2HeO (D) HLS tums lime water milky ‘Anion which is protonated by dil. H,SO, but produce volatile product only with cone.H,SO, (not with 0, (B) PO, («© coe (D) SO> a than one may be correct : Which of the following metal sulphides are insolublein yellow ammonium sulphide (YAS), ;- LZ saaties 48) Cus Se 0 si 9. — Which of the following reagent(s) can show colour ghinge when SO, gas ispassed through it. (AT Bromine water ) Acidic potassium dichromate Solution idic ferric chloride solution (D) Chlorine water fethylene blue is an indicator widely used in acid-base titration , iti formed on mixing NH in ‘Mey (A) Na,SO, Bev, WF 50, (D) Feso, « _ Inwhich reaction(s) blood red colorations observed in product : NWFeSO, ae 5 Product, (BFRia,8,0, E>... $2 Product _@) nascar no, ty, 12 Prod Paragraph for Q.12 & Q.13 Chromyl chlorideis deep red brown coloured compound which is formed during qualitative analysis of chloride radical, Chloride salts (with some exceptions) produces chromy! chloride gas when reacted with K,Cr,O,(s) and cone. H,SO,. During chromyl chloride formation when chlorides saltis heated with cone. H,SO, + K,Cr,O, oxidation number of each Cr atoms: (A) Reduced to +3 (B) Reduced to +2 (C) Increased to +7 «DyDoes not change 13. Bromide salt when heated with cone.H,SO, + K,Cr,O, (A) Brown vapour of CrO,Br, is produced rown vapour of Br, is produced (C) Brown vapour of SO,Br, (sulphuryl bromide) is produced (D) Br’ salt does not react with K,Cr,O, 2 ——______.JEE-Chemistry Paragraph Q.14 to Q.16 Hg¢N0, : (A) He, (gy Excess KI (soluble complex) Ion ppt «© React with (x) reagent (D) ESSE (&) Orange turbidity Black ppt. ByH.O 44. Identify (A) ion - caycr or (Br (D)Cu* . Whats the hybridisation of central atom of (C) - i (A) dsp? (B) sp’? (spe (rp ‘\ 16. When X reagent undergoes hydrolysis then ~ (A) White turbidity of SbOCL is formed. (B) White turbidity of BiOl is formed. (©) White turbidity of BiOC1 is formed (D) None of these MATCHING LIST TYPE 17. Match the following(list:- List - I (Reaction) List I (Characteristic odour/product) (P) NOS. HCH () odd electron species SS eS0, Qs02 ee (2) Vinegar smell (R) HCO,e ALES (3) Yellowish-white turbidly (S) CH,COO® _ild1Ch, (4) Colourless gas comes out with brisk effervescence Code : ® Q@ B® A 4 °°3 1 2 GW 7 4 1 3 aot 34 4 oO 3 1 a2Guided Revision Plan ALLEN MATRIX MATCH 18. Match the column - Column-I (radical) Column-II (Correct characteristics) (A) Fe* TR (P) Produces white ppravith K,[Fe(CN),] B uP R (Q Produces soluble complex in_excess of NaOH solution Oct g ®) Gives redox reaction with Na,$,0, solution, DAY GR (S) Produces corresponding hydroxide with Na,S solution. (1) Produces brownish-red ppt. with CH,COONa lution, 19. Column-I (Acidie/basic radical) Column-II (characteristics) (A) NOD f CC (P) Gives brown ring test ®B) no, T (QGives brown ppt. with Nessler's reagent © NAY Qy (R) Gives black ppt. with (NH.),S @) Fe ¢ R (S) Gives red colouration with CH,COONa Integer Type : 20, How many of the following salton heating in bunsen burner flame gives characteristic green flame:~ ABEL, CaCl, LICL , NaCl , MgCl, (pF nan agi juin required : C107 —> Cry (i) MnO; + 10+ Mn, Sir Cr,0,°+H,S —>$+Cr* a H,O,+ MnO; —> 0, + Mn’ Inpresenceot precinct > permanent deep blue coloured compound. ‘Chromate solution + HO, + Find the change in,oxidation state of Cr-atom in the reactant and product. oALLEN JEE-Chemistry 13. 17. 18. 19. 20. Ans.(A) 2. Ans.(C) 3. Ans.(B) Ans.(A) F maximum show one covale! reality. so FO}-is not possible hence this reaction can not take place in Ans.(B) 6. Ans.(C) 7. Ans.(A) 8. Ans.(A,B,C) Ans.(A,B,C) 10. Ans.(B,C) 11. Ans(A,B,C,D) 12. Ans.(D) Ans.(B) 14. Ans.(B) 15. Ans.(D) 16. Ans.(C) Ans.(C) Ans.(A) - R, T ; (B) - P,Q; (C)- Q, S53 (D)-Q,S Ans.(A) - P, T; (B)- P, T;(C)-Q3(D)-R,S Ans.(1) 21. Ans.(4) 22. Ans.(0)