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| CHEMISTRY Class 1 | Allznone ‘The solubility of 2 jis is because w' hen apolecular motion of oe result some molecil iso, the dissolution of a sess, 50 heat is evolv with the incre san exothermic proc 3 Le-Chacelie’s principle ie he solubility should decrease. FS solution heat, equilibrinm si: ily oF a gas increases wis “In this method, the gas is guid under the high pressure caublicy of» yas. Te hag propor dthe upper part is gaseous ire T: Assume this system i.e. under these e5 entering and lc ‘increasing the pressur. he gas toa smaller of gascous particles per le toe race ar which th ‘of solution to enter ease until a new ‘afl inerease in the press its solubility inc fenty’s law states cording to Henry's law, py. ¢ = Ky 1 fe gas in uapour phase Fy dlobethd Bien odessa) o: Ki 282 ba (Significance of Henry's Law From the Ea, (i) it can be concluded that higher the value of K yy ata pressure, the lower is the solubility of che gas in the liquid Ky, values for both N. and O, increase with increase of temperature indicati with ine e of temperaruse Iris due to this reason that aquatic sp are more comfortable in cold water rather than in warm water EXAMPLE |2| At same temperature, H, is more soluble in water than He. Which of them has hia! Sol alue of Ky and why? has higher value of Kj, because ifthe gas has more solubility its Ky value will below Applications of Henry's Law Henry's law finds several applications in industries. It also explains many biological phenomena. These are as follows {i In the production of carbonated beverages To increase the solubility of CO, in soft drinks and soda water, the bottle is sealed under high pressure (ii) In deep sea diving, Scuba divers (deep-sea divers) breath air at high pressure under water. Increased pressure increases th solubility of atmospheric gases (like nitrogen) in blood. ‘When dives ually decreases resulting in the release of dissolved gases from blood. This leads to the for the blood, which blocks capillaries and gives rise co ar ailment called bends or decompression sickness. come towards surface, the pressure gr ation of bubbles of nitre To avoid bends, as well as, the toxic effects of high concentrations of nitrogen in the blood, the tanks used by scuba divers are filled wich air diluted with helium (11.7% helium, 56.2% nitrogen and 32,1% oxygen) For people living at high altitudes or climbers At high alkicudes, che partial pressure of oxygen is less than tha 3 nd level. This leads 0 low concentration of oxygen in Jand tissues of people living at high altitudes or climber quently, they feel weak both physically an. iofa medical condition known orundergo any chemical change B association or dissociation in the OPIC PRACTICE 2 | 10. Solutic pat does the slope o: ee “ P : the tine represent? tes 18, Mote acon of tien evens? (a) asta pressure of the 8 vapour phase (P) 19. te ple ection of nse SORES @ {e) Henry's law constant (Kis) ed 24 {@) Allof the above Ky value for Ar(), Os (@, HCHO (g) and CHA) ‘ane 40.39, 1.67, 183% 10 ‘and 0.413 respective! arrange these gases im ene Oder of their increasing solubility. NCERT Exempla: (@yHCHO = CH,

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