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Asset-V1 UTokyoX+UTokyo007x+1T2018+type@asset+block@Unit 15 Redox Titrations
Asset-V1 UTokyoX+UTokyo007x+1T2018+type@asset+block@Unit 15 Redox Titrations
Redox Titra,ons
Titra,on
Revisited
• The
analy,cal
method
that
determines
the
quan,ty
of
an
analyte
by
adding
a
,trant
Indicator
Analyte
+
Titrant
Product
1
18/06/06
Equivalence
point
The
amount
of
Fe
ions
=
the
amount
of
Ce
ions
[Fe2+]
=
[Fe3+]
Fe
ions
in
excess
Ve/2 Ve
Titra,on
Calcula,ons
• Before
the
equivalence
point
– System
dominated
by
Fe
ions,
all
Ce4+
reduced
to
Ce3+
2
18/06/06
Titra,on
Calcula,ons
• Before
the
equivalence
point
– System
dominated
by
Fe
ions,
all
Ce4+
reduced
to
Ce3+
Titra,on
Calcula,ons
• At
the
equivalence
point
– Ce4+
just
consumed
all
Fe2+
F
F
Fe2+
+
Ce4+
⇌ Fe3+
+
Ce3+
𝐾 ≅ 1016
F
-‐
x
F
-‐
x
x
x
3
18/06/06
Titra,on
Calcula,ons
• A>er
the
equivalence
point
– System
dominated
by
Ce
ions,
all
Fe2+
oxidized
to
Fe3+
[Inred]/[Inox] =
1/10
𝐸 = 1.147−𝑅𝑇/𝑛𝐹 ln1/10 =
1.206V
4
18/06/06
5
18/06/06
Gran Plot
X
axis
Slope
V
=
Ve
6
18/06/06
Gran
Plot
NOTE:
Part
of
this
slide
is
invisible.
Please
refer
to
the
lecture
videol
𝑉×𝑒↑−𝑛𝐹𝐸/𝑅𝑇
X
axis
Slope
=𝑉e×𝑒↑V
−
=
V𝑛𝐹
e
(𝐸ref−
𝐸↓Fe3+↑oD.
)/ 𝑅𝑇
Harris,
Quan,ta,ve
Chemical
Analysis,
9
ed.
th
−𝑉×𝑒↑−𝑛𝐹(𝐸ref−
𝐸↓Fe3+↑o )/𝑅𝑇
Take-‐home Message