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FIITJEE

ALL INDIA TEST SERIES


FULL TEST – VI

JEE (Main)-2023
TEST DATE: 19-01-2023

ANSWERS, HINTS & SOLUTIONS


Physics PART – A
SECTION – A

1. B
Sol. Applying energy conservation:
mgh = mLf
L 80 cal / gm
h f 
g 10 m / s 2
80  42  1000 J / kg  336  103  N  s2
    33.6 km
10 m / s2  10
  kg

2. D
2
Sol. v1g  vg
3
3
v 2 g  v g
4
v1  v2  2vm
1  2
 m
2
   2 
v 1  g  v g
 2 
v   3g 4g 
  v g
2  2 3 
12
v  v
17

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AITS-FT-VI-PCM(Sol.)-JEE(Main)/2023 2

3. B
T T
Sol. As P  nR so PA  nR 0
V 2V0
4T0
and PB  nR
3V0
PB 8
 
PA 3

4. C
Sol. Resonant frequency of an L-C-R circuit is given by
1
r 
LC
So, resonance frequency does not depend on resistance of circuit and frequency of supply.
To increase resonance frequency, we have to reduce inductance or capacitance of circuit. As
capacitance reduces when capacitors are connected in series
1 1 1
(i.e.   ), another capacitor in series to increase resonant frequency.
Cseries C1 C2

5. A
Sol. As, refractive index,
speed of light in air

speed of light in medium
So, speed of light in a medium
c
v

Hence, for medium A and B,
c c
vA  and vB 
A B
Time taken by light to cross some
 dis tance 
thickness x is  speed 
 time 
x x
t1  and t 2 
(c /  A ) (c / B )
B  x  A  x
Hence, t 2  t1  
c c
x
 t 2  t1  ( B   A )
c
 1
Now, given, A 
B 2
 B  2 A
and t 2  t1  5  1010 s
substituting these values, we get
x
5  1010   2 A   A 
c
c
 x  5  1010 
A

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3 AITS-FT-VI-PCM(Sol.)-JEE(Main)/2023

c
But  vA
A
 x  (5  1010  v A )m

6. D
Sol. Assume potential at point D is equal to zero. As we know 0V R2 = 3 i2
B C
potential of all points on a plane wire are equal, so potential at 24 V
B will also be equal to 0 V. Also potential difference across R1 = 2
i3
cell is 24 V, so potential at A will be 24 V. Similarly, potential R3 = 6
i1
at C is also 24V.
24 V
Using Ohm's law for branch AB, A D
V  VB 24  0 24 V 0V
i1  A   12 A Assume
R1 2 potential
For branch CB,
V  VB 24  0
i2  C   8A
R2 3
For branch CD,
V  VD 24  0
i3  C   4A
R3 6
By KCL for junction C,
i  i2  i3  8  4  12 A

7. C
Sol. As per Einstein’s photoelectric equation
hf 
vS   …(i)
e e
If f is doubled, new stopping potential,
2hf 
VS  
e e
 hf    
= 2      2VS  [from equation (i)]
 e e e e
Which is more than double or an increase of more than 100%

8. B
Sol. When a charged particle enters a region of a uniform
magnetic field, such that the angle it makes with the u
vT =
direction of B  90°, then it follows a helical path as 2
shown below
Radius of helix,
mv  mu A
R  …(i) O
qB 2qB
u
v|| =
2

pitch

Where, v = Component of velocity perpendicular to field.


Also, pitch, P = Displacement along field in one revolution (OA)

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AITS-FT-VI-PCM(Sol.)-JEE(Main)/2023 4

u 2m
= v||  T   (ii)
2 qB
P
Dividing equation (ii) by equation (i),  2
R

9. A
a P Cavity
Sol. Field inside spherical cavity in a sphere =
30 + + +
Where a = distance between centres of sphere and cavity. + + + + + + +
Direction of field is along line joining centres as shown in + + + + + + + +
figure. + + + + + + E+ + +
R + + + + + + + + +
  + + + + + + + + +
2 R
So, field inside cavity will be E =    (as shown) + + + +Q+ + + +
30 60
+ + + + + + +
Under influence of field, electron will accelerate down with + + +
acceleration,
eE  Re Charge density 
a  …(i)
m 60m
As electrons move from P to Q, striking the cavity at Q, its displacement will be equal to
PQ = R= s …(ii)
1 2
So, by using, s  ut  at , we get
2
1  Re 2
R 0 t [using equation (i) and (ii)]
2 60 m
120 m
 t
e

10. B
Sol. At time t, distances moved by sliders GH and EF will           
G B
be 3vt and vt respectively as shown.  A         
Therefore, area of loop ETHD will be vt           
 E         F
A = 3vt( vt) =3 vt -3v2t2           
v
dA            
  3v  6v 2 t …(i)   vt    3v      
dt
          
At the instant, the loop is square, its two sides will be           C
equal. Therefore, D H
          
 3vt
3vt    vt  t 
4v
…(ii)
By Faraday's law, emf induced in the loop
d d(B0  A) dA
   B0
dt dt dt
 B0 (3v  6v 2 t) using equation (i)
   
 B0 3v  6v 2    using equation (ii)
  4v  
3B0 v
=  1.5 B0 v
2

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5 AITS-FT-VI-PCM(Sol.)-JEE(Main)/2023

11. D

Sol. [F]  [Ar 2r]
ˆ  [Ar 2 ]

[F] MLT 2
[A]  2  2
= [ML1T2]
[r ] L

12. B
Sol. Between t = 0 and t = 2, acceleration has same sign which increases speed. At t = 2 sec.
Direction of acceleration is reversed and speed starts decreasing.

13. B
Sol. T = MB  aB but T is also equal to MAaA
 MBaB = MAaA
 6  1.5 = 4  aA
2
 aA = 2.25 m/s

14. B
Sol. f = mg and N = mA f
So, N = mg
a
mA = mg (For Amin, f is max)
g m
 A=
 N

mg

15. B
Sol. At 45, at = ar = 9
v2 v2
 9
r 4
v = 6 m/s
Now, 6 = 0 + 9t
2
t = sec
3
16. C
Sol. Conserving energy between points A and B, A
R  1
mg   R(1  cos )   mv 2
4  2 R/4 N
Also at point B, N = 0
B
mv 2
So, mgcos  
R
1 1  mg
 (1  cos )  cos 
4 2
5 3 O
 cos 
4 2
5
cos  
6

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AITS-FT-VI-PCM(Sol.)-JEE(Main)/2023 6

17. B
Sol. Kapil and the boat can be considered as one body of mass mb = (65 + 100) = 165 kg. Note that
the centre of mass of the system remains unchanged since no external force acts on the system.
Let mS be the mass of Sachin and xb and xS be the displacements of the combined body of
mass mb and Sachin respectively with reference to the centre of mass. Then use the equation
mS xS  mb xb  0 , to get the answer.

18. A
Sol. T  (2m)2  mg
g
  5 rad/s
2

19. A
Sol. If friction acts backwards then  will increase and vcm will decrease hence violating pure rolling
condition and if friction acts in forward direction the  will decrease and v cm will increase again
violating pure rolling condition hence no friction acts.

20. D
3
MR2
2 
Sol. 2  2
MgR g

SECTION – B

21. 9
Sol. To find through infinite plane-1, let us construct an infinite plane-2 at
same distance from q on other side. If electric flux through plane-1 is ,
then flux through plane-2 will be also .
By Gauss’s Law
q
total  2  q
0
q 1 9  109
    4.5  109
20 80 2
b=9

22. 2
Sol. Magnification of the object
f f 1
m  
f  u f  (f ) 2
As velocity component of image along axis is given by
vi  m2 v0
2
 1 3
 vi     4 cos30   cm/s
2
  2
Also velocity component of image perpendicular to axis is given by
1
vi  mv 0   4 sin30  1 cm/s
2
Therefore, net velocity of image is
3 7
  v i2  vi2 
v net 1  cm/s
4 2

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7 AITS-FT-VI-PCM(Sol.)-JEE(Main)/2023

23. 5
Sol. Consider FBD of blocks. x
For mass m, using F = ma, we get A B
T  mg = ma …(i)
Similarly for mass 2m, we get
2mg T = 2ma ...(ii)
From Equation (i) and (ii), T
4mg
T= …(iii)
3 Massless
From FBD of pulley, pulley
8mg T
T = 2T = T
3 T
Therefore, frequency of vibration of wire in a T
fundamental mode, a
1 T 1 8mg
f1   mg
2  2x 3
Also, frequency of vibration of air in 1st 2mg
overtone (3rd harmonic)
3v 3v 3v
f2   
4 4x 2x
2
As, resonance implies frequencies are equal
1 8mg 3v
i.e., f1  f2   [using Eq. (v) and (vi)]
2x 3 2x
27v 2 27(0.2  103 )(400)2 54
 m   kg
8g 8  10 5

24. 8
Sol. Lets construct a cone as shown. By field Electric field
picture,  through lateral surface is zero.
q
 sec tion  cone  inside + + +
0
+ + + + + +
2 + + + + + + + +
1  R   R 
      + + +R/2
+ + + + + +
3  2  2
 + + + + + + + + +
0 + + + + + + + + +
O
  + + + + + + + + +
 Q   1 R3  + + + + + + + +
      + + + + + + +
 4 R3   3 2 2  + + + + + +
3 Q
=    + + +
0 8 20

25. 6
Sol. Frequency of revolution of electron,
Z
v0 2
f
v
 n  v0z
2r n2 2r0n3
2r0
z
Number of revolutions in time t will be

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AITS-FT-VI-PCM(Sol.)-JEE(Main)/2023 8

v 0 z2 t
N  ft 
2r0n3
As we know, Bohr's radius
r0 = 0.53 Å = 0.53  1010 m
v0 = Bohr's speed = 2.2  106 m/s
Putting these values in Eq. (ii), we get
2.2  106  12  108
N 10 3
 8  106
2  3.14  0.53  10  2
Comparing with given value, we get x = 6
26. 5
Sol. Time period of a pendulum is given by

T  2
g
4 2 
 g
T2
 g   T
   100    100  2  100  1  2  2  5%
 g max  T

27. 2
Sol. For two perpendicular magnets of magnetic moment M0 and moment of inertial each, equivalent
magnetic moment,
M  2M0 …(i)
N 2 M0

M0

S N

M0

S
and total moment of inertia
I = 2I0 ...(ii)
Also, time period of oscillation of magnet in magnetic field is given by
I
T  2 ... (iii)
MB
Time period of the system, using
Equations (i), (ii) and (iii), we get
2I0 2I0
T  2  2 ...(iv)
2M0B M0B
Also, using Equation (iii) time period of single magnet,
I
T   2 0 …(v)
M0B
Dividing Equation (v) by Equation (iv), we get
T 1 T 321/4
 1/4  T   1/4  1/4  161/4  2s
T 2 2 2

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9 AITS-FT-VI-PCM(Sol.)-JEE(Main)/2023

28. 1
Sol. LC = 1 MSD 1 VSD
19 MSD
 LC = 1 MSD  MSD =
20 20
 MSD = 20  LC = 20  0.05 = 1 mm

29. 10
Sol. Given, focal length of two thin biconvex lens, f 1 = f2 = f = 15 cm
Using lens Maker's formula for first lens, 1 = 1.2
1  1 1 
 (g  1)   
f1  R1 R2 
1 1 1  1 1 g = 1.5
  (1.5  1)     
15  R R  15 R f1 f2
 R = 15 cm
 Focal length of combination is given as
1 1 1 1
   …(i)
f eq f1 f2 f3
Where, f1 = f 2 = f = 15 cm f3
1  1 1  2  1
and  (1  1)     (1.25  1)     30
f3  R R   R 
 f 3 = 30 cm
Hence, from Equation (i), we get
1 1 1 1 3 1
    
feq 15 15 30 30 10
 f eq = 10 cm
30. 25
Sol. Comparison of emfs of two cells using the experiment of potentiometer is given as
e1 I1

e2 I2
Where, I1 and I2 are their corresponding balancing length.
3 75
  (since, I1 = 75 cm given)
2 I2
 I2 = 50 cm
 difference in balancing length
= I1  I2 = 75  50 = 25 cm

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AITS-FT-VI-PCM(Sol.)-JEE(Main)/2023 10

Chemistry PART – B
SECTION – A

31. C
Sol. Carboxylic acids are more acidic than alcohol. Electronic effects also influence acidity.

32. A
Sol.
LiNH2 2LiNH
H C C CH2OH   H C C CH2 O  C C C CH2 O

C2H5 Br


H3 O C C CH2 O
CH3CH2 C C CH2 CH2OH  CH3CH2

33. D
Sol. P2 O5  2HNO3  N2 O5  2HPO3
P2 O5  2HClO 4  Cl2 O7  2HPO3

34. C
Sol. O O
+
N(C2H5)2 
CH3 I N CH3

Et Et

NaHCO3 MeOH

O O
+
N CH3
Et Et

35. D
Sol. Fact

36. A
Sol. Gd   Xe 4f 7 5d1 6s2
Gd3    Xe  4f 7
  n  n  2   7 7  2   7.9 BM

37. C
Sol. Highest the CFSE of compound, highest is the enthalpy of hydration.

38. B
Sol. Smaller the size of orbital extent of back bonding is more.

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11 AITS-FT-VI-PCM(Sol.)-JEE(Main)/2023

39. A
Sol. On increasing pressure CO2 gas condeses to liquid.

40. D

Sol.  XeF5  is sp3 d3 hybridized.

41. B
Sol. Viable particualte are minute living organisms that are dispersed in the atmosphere.

42. B
Sol. Molar mass of NaCl = 58.5 g
117
Moles of NaCl 2
58.5
In a unit cell = 4 NaCl
1
Total number unit cell   Number of NaCl
4
1
  2  6.02  1023
4
= 3  1023

43. A
Sol.
(a)
OAc
OTs O OAc OAc
O NaOAc / AcOH

  a
CH3 

O CH3 O OAc OAc
(b)
(b)
OAc

44. B
Sol. From the question,
Cu  CN3  0.1 M and CN    0.2 M
 4  
3
K instab . Cu  CN 4  6.4  1015  0.1
 
 Cu   
 4 4
CN 
 
 0.2 

 4  10 13 M
K SP  Cu2 S  2.56  1027
Now, S2    2
 2
Cu 
   4  10 
13

 1.6  102 M
K a  H2 S 1.6  1021  0.1
 H     1010 M
S 2   1.6  10 2
 
and pH = 10.0.

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AITS-FT-VI-PCM(Sol.)-JEE(Main)/2023 12

45. B
Sol. Cl  H2 SO 4  HCl   Colourless   HSO 4

46. C
22 me4
Sol. R
 40 2 h3 c
Rm
 m 3m  3
Here, m becomes  m    , then R becomes R.
 4 4  4

47. B
dz 168
Sol. At Boyle’s temperature, 0T  480 K .
dp 0.35

48. A
1
x x 1
Sol.  K.P n  log  logK  .logP
m m n
From question, logK  0.3010  log 2  K  2
1
And  tan 45o  1  n  1
n
x
  2  P  2  0.2  0.4
m

49. A
Sol. OMe OMe OMe
H
Br
NaNH /liq. NH
NH2
2 3
 
 
NH2
H NH2
Benzyne
intermediate

OMe
OMe OMe
H CuCN, 
NaNO /dil. HCl
2
 

CN
NH2 N2Cl

50. C
Sol. Benzene sulphonyl chloride  Ph  SO2 Cl  is known as Hinsberg reagent.
O
O
O S Ph
O H Cl S Ph
O
O

Sulphonic ester

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13 AITS-FT-VI-PCM(Sol.)-JEE(Main)/2023

SECTION – B

51. 4
Sol. O O O O O O O
O O

O3 , H2 O2 HO H O
O   O 3
 

HO 

O O O O O O
O O O

52. 289
K Ea  1 1 
Sol. log 2    
K1 2.303R  T1 T2 
T1  300 K K 1  1.6  103 , T2  350 K
2.303 100
t 90%  log
K2 10
= 289 s.

53. 123
Sol. 2H  O2  2e  H2 O2 G1o
2e  2H  H2 O2  2H2 O G2o
4H  O2  4e  2H2 O G3o
G1o  Go2  Go3
 2  0.70    2  1.76   4  x
Eo3  1.23
100x = 100 × 1.23 = 123

54. 5
Sol. A.xH2 O  A  xH2 O
25 16
250 M
25 16

250 M
M = 160
x = 5.

55. 273
Hfusion 80  18  x
Sol. Sfusion  
T 273
x = 5.46 mole
50x = 273

56. 7
V1 C  /T 500 / 283
Sol.  1  1 1  7
V2 C2 2 / T2 94 / 373

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AITS-FT-VI-PCM(Sol.)-JEE(Main)/2023 14

57. 3
Sol. Malachite, Sphalerite and Calamine are the principal ores of copper and zinc.

58. 5
Sol. NH2
N C
C N Adenine
HC
C CH
N N
H

59. 6
Sol. Cl Cl OH OCH3

 i HNO
3 2 4 /H SO  ii NaOH, 150o C  iii CH
3 I
  
 

NO 2 NO 2 NO 2

 iii Conc. H2SO 4

OCH3
SO 3H

NO 2

60. 3
Sol. C C C C C ,C C C C C, C C C C
Cl Cl C Cl

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15 AITS-FT-VI-PCM(Sol.)-JEE(Main)/2023

Mathematics PART – C
SECTION – A
61. A
2ae SP SP 2a
Sol.  1  2 
sin      sin  sin  sin   sin 
sin      y
e=
sin   sin 
P
1
1
1 e   2 1
 tan   tan   
1 e 2  2  1 1 3  
2 x
S2 S1
  
Also cot    cot    cot  
2 2  2
    2ae
= cot   cot   cot    3cot  
2 2 2  2

  
  
 
cot    cot    2cot  
2 2 2
62. A
n  n2  1
Sol. dn 
2
n 1
lim  n  dn   
n 

2 n  n 1 2
 2 2

63. C
dy dx
Sol.   0  xy = c
y x
c = 16
xy = 16
L.R. = 8 2

64. C
Sol. f(x) + f(x) = 8

65. B
Sol. f(3.14) = 4  3.14 = 0.86
y

y=1
y=x 2x 4x
x2
x
1 0 1 2 3 4

66. B

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AITS-FT-VI-PCM(Sol.)-JEE(Main)/2023 16

Sol. (x2 + 1) ex = y  (x + 1)2 exdx = dy

67. A
6
Sol. xi = 1   xi  6
i 1
6
yi = 1   y i  6
i 1

68. D

dx y
Sol. Req. area = 2  2
=  sq. units
1  x  1 1 1

x
x=1

69. A
Sol. lim f  x   
x 1

70. B
Sol. x2  k  0
k<0
x2 + x + 1  0

71. B
Sol. Number of solutions 2

72. A
 2n1 2n1 
Sol. An =  
n 1
 2 2n1 
det(An  I) = (2n1  1)2  (2n1)2 = 1  2n

73. B
3
Sol. Trace (A ) = 123
74. A
Sol. Reflexive, transitive but not symmetric
75. B
Sol. E

 2 3
A B C D

76. A

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17 AITS-FT-VI-PCM(Sol.)-JEE(Main)/2023

2
Sol.   xi  x   250
250
2   25
10
6 5
Co-efficient of variation is =  100   100  10%
x 50

77. C
78. C
Sol. y = (tan1(5x)  tan1(x)) + (tan1x + tan1(2/3))
dy 5

dx 1  25x 2

79. C
0
Sol. I=  sin tdt  cos  ln2   1
 ln 2

80. C
Sol. y = mx
3m  3
 6
m2  1
m = 32 2
SECTION – B
81. 44
(sin )x
Sol. f() =
(sin )x  (cos ) x

89
89
 f    2
1

82. 35
  9
Sol. v1  v 2  3  cos2 = 1
5  sin2

=
4
 = 0 
 v1 and v 2 are collinear
2(sin   cos  ) 1
 
sin  cos 
tan = 2 2
3tan2 + 4tan2 = 3 + 4(8) = 35
83. 23
Sol. ( + 2, (3 + 2), 2 + 5) lies on 2x  3y + 4z = 16   = 7
P = (9, 23, 19)
For Q : x = 0
+2=0
 Q = (0, 4, 1)
PQ = 9 14

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AITS-FT-VI-PCM(Sol.)-JEE(Main)/2023 18

84. 2
Sol. P(A  B) = P(A) + P(B)  P(A  B)
3
0.8 = 0.5 + p  0  p = 0.3 =
10
P(A  B) = P(A).P(B)
0.8 = 0.5 + 9  0.59
3
0.3 = 0.5q  q =
5
q
2
p
85. 10
3x 3x 4y 4y 4y
Sol. 3x + 4y =    
2 2 3 3 3
AM  GM
3x  4y
 2
5
86. 4
Sol. |PA  PB|  AB
|PA  PB| to be maximum, P must be the intersection of line joining A and B and 2x + 3y = 5
2
h=
5
7
k=
5
6  14
3h + 2k = = 4.
5

87. 24
x y z 1
2   3   5  2 3 5
Sol.  2 3  5    x  y  z 10
 2 3 5
10 2 3 5 
2 3 5 2 3 5
 x y z  2 .3 .5
N = 22.33.55
Number of odd divisors = (3 + 1) (5 + 1) = 24
88. 0
Sol. 1523 + 2323
= (19  4)23 + (19 + 4)23
= 2[(19)23 + 23C2(19)21(4)2 + ….. + 23
C22.19(4)22]
89. 49
Sol. (x + 4)2 + (y  5)2 = 1
(4 + cos, 5 + sin)
(x + 2)2 + (y  3)2
= (cos  2)2 + (sin + 2)2
= 9 + 4(sin  cos)
a = 94 2
b = 94 2
90. 1
Sol. x = y = z = 1

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