Xuuus Bnn.

1( l )

yAK628.s43.31

A JIIO M OKPEMHI,IEBhI E OJIOKYJISH T bI- K OAT YJI.flHTbI B

rrPor{EccAX BoAooqHCTKr,r
M.A.Bo;rxona", A.fl.He4yronb, C.B"An4pneHKot,A.B.Kaftcnub,A.IO.IflorHHa,
ullepucxari
rocy.(apcrBexnuftyunnepcnrer.6 I 4600,r. flepur, yn.Eyxnpera,I 5
"Ecrec'rseHHoHayruuIHHcrrryr nfy. 614990.r. fleplru, y,r. fenxenr, 4
E-mail: margo@psu.ru

Paecvompeubtsonpacu nepepa6omxuanpwoKpeMHueloeocbtpbn c 4enbtunoxyveuun aoduQu-

quposaHHozoStoxynanma-KoarytntHma
u ucno-rbsogeHun
eeos npo4eccaxeodoouucmxu.

Krrc.reeure cJroBa:Sloxyurxl KoarynrHTlrrxeJrbre MeraJJrbr;3KoJroruf,

Bnenenne npHMepeoqHcTxl{npHpoAHbrxBoA IIOKEBaHO, qro 3a

cqer onruMr.t3arlnr.r
Moxno yBeJrrrr{HBars
e$Qexrlrn-
Ilo.iryrenNe qacroi BoAbrrBrrrercr saxHoft sxo- Hocrb orrrcrKn Bo4brua30-50 % l2l.
.norprqecxofi npo6neu ofi . B rexnolorulit BoAoorr[crxl,r
r.r Bo.{ono4roToBr(HruHpoxo np}rMeHrrroTcs peareHT- A.nmuoxpeMHHeBbre Snory;rxnrrr-
flble Meronbl. 3ro o6rgcncercg reM, qro 6o:tnrrgcr- Koar_YirnHru (AKTDK)
BO npupoaHb,rxri cToqHblxBoA, KpoMeKpyrrHon[c-
rIeFcHbIXnplrueceE, BbrAeJueMbrx B coopyxeur4rx SomuroE nparcrxr{ecKrlftnurepec npercraBJrrer
MexaHnqecxoii orllcrxn, colepxar roHKo.rIHc[epcHbte[puMeHeHL{e peareHToB HOBOTOIIOKOJTeH]I' - aJITMO-
coeAHHeHfir, r.r3BJ.rer{eHne Koropbrx :$$errusHo cr4;rrKarlblx $loxynruror-KoaryJrflHroB (ASFK), n
roJ[,Ko [ocJre ]{x yKpynHeHr4rc rroMoltlbloKoaryJnH- KOTOpbTX HC[On63yeTCr KaKarroMllHi,teBiur.
Tax [I cH-
roB rr Sloxy;rrHron, obecneunaarculuxyailireHue JII{KarH€urcocraBJrrroular cblpbr.
Pearenru ASFK
opranr4qecKi.rx14rreopmur.FlecKux 3arpr3HeHHE no4sl, rB,.rflr.orcro,uHofi n: HeMHorr4x6nuapHux KoMno3r,r-
ocaxaeHr.{eKoJlJroH.uHbrx H TpyAHooKr.tcJrreMbrx gac- qn[, n
cocraB Koropbrx Bxo,urr rorrbxo HeopraHrrqe-
rnu []. Koary.nnHrua $,roxymHrbr c aaBHaxnop crt,te KoMrroHeHTbr: KoarynxHr - cy,rr$ar €urroMHHH.,{
rtpnMeusrucb [pr{ fio/IroroBxe BoAbr A,'tr xo3riicr- u asuoHuuri $aoxlurrr - axrnBHarKpeMfir4eBaf, Kr{-
BenHo-iruTbeBblx HyxA, qro o6lxcsxercfl Lrxerrcoxoft crora. IlepcneKrflBHocrb ASFK cpanHnreJrtHo c Apy-
e$$errHnuocrbto r{ npocrorofi ilcrtoxb3oBalvfr. rr,rMi4xoMno3HTaMr{ efo yHnBepcrrnb-
orrpeAeJrreTc.r{
B nocle.uHlle foAbt IlotBlilrlocb 6omuroe tlncro HocrLro la srlcoxoi :$SexrunHocrb]o npu perueHnr{
pa6or. nocBflrrlexHbrxu3yqeEr'ttcBJrHfl r{rt pa3rr.{q
Hbrx pa3lHqHblx 3a.{at{: ocBeTIieHHe 14 OqI'ICTXa BOA OT
xoaryrtHToB, $,roxylnnroB Ii rexHoJ.torHr{ecKI,IX tta- B3BerrreHHbrxi{acrlrr.L oT pacTBopHMbrx r.r Manopac-
paMelpoBHx [pr,lMeHeHur ua r$QexrrBnocrb orilrcr- TBOpHMbIXOpraHuqecKfix Beu{ecTB, oT i,toHoB MeTaJI-
KHnpripoArrbrx Boa oT Ar{cnepcHbrxu pacTBopeHHbrx l o a r r . a .
[1].
sarpx:xenufi. K HeaocrarKaM cepHoKnclrorllbrx pacrBopoB
I{ari;lensue 3aKoHo MepHocrr.rilpr.rMeHeHH.rrKoary- ASFK, noJryqeuHbrx nr ne$e.nuuoablx xBocroB. or-
JrrHToBu SnoryiranroB B BoronoaroroBKeHe BcerAa HOC,ITCTO[pe.{eneHHble TpyAHocTl{, BO3HHKanirIHe
MOX(HOIIepeHeCTIr Ha OqHCTKy CTOqHSIXBCA H3-3a [pH lpaHcnoprEpaBKe, r.{ orpaHneHHocrb cpoKa ero
Kapilr4HanbHLlxpa::ruvuft npupo4HLrx H crortnlrx BoI r.rcnoJrb3oBannr (n reveHre Hecxo.nbKl{x cyroK pac-
no coAepxaHur.o r! xtrMtrqecKoMy cocTaBy 3afprr3He- rrop @aoxylrHra-Koaryrsnra flpeBpaqaercs B reJrb H
girfi. B ro xe BpeMt I{ccneAoBaHH-rIMno or{Hcrxe
reprer cnon cnoficrsa) [3,4].
croqHbrx BoA c nplrMeHeHlteMKoarynrr{ToB u $loxy-
nrHToB He yllenflercri troJlxttoro BHHMaHrlf. Koary,rx-
tlug o6uqno paccMa'rpr{Baercsxar ncnouorarelluufi lloly.renne MoAn$uqupoBaunoro
[poqecc !,rrtr HHreHcn$uxauxu pa6orbr coopyxeuNii AKOK
MexaHur{ecxofr oqucrxn: orcroftHuxos, Q.'loraropor,
Qu.nrrpon. M uo rre IaccreAoBare;tfi ofpaHr{rrHBarorct flo:rouy aKryarbHblM rBJrrerct nol,tcK HoBlrx
KoHcrarauuefi Qaxra yBerur{eHlrs oS$exrueHocrN pearenroB uoAo6uoro rvna u oflpe.qeJreHrne
ycnootfi
oqHcrKH BoAbI, B xoropofi HcnoJrb3yror peareuTEr H Hx r,lcrroJrL3oBa*Hfl..
Hauu ncc,reAoBaHbr pa3rfiqHbre
He paccMarpuBalor npo6aeuul, cBr3aHHbre c rrx Bbr- cnoco6u noryqeHur aJrroMoxpeMHneBoro $noxymn-
6oportl, ycJroBrrrMu rrpoBe,rleHur flpouecca, xorfl Ha Ta-KOaryJrflHTaHa OCHOBenpUpOAHOTO -
Mr.rHepilJra

@ Bomona M.A., He4yror A.H., AHgprreHKo

C.B.,Kaftcr.rn
A.8., Jlslnua A.I0., 201i
109
 M.A.Bonrcos
a, A.H.Hedyzoe, C.B.Andpueute. A.B.Kailcuu. A.IO.Jliluug

aeQernna.B pa6orax E.H.KpyruHuuofi c coanropa- Ha sQ$exruaHocrb oqr{crxll crorrHbrxBoAc npn-

uu [5] paspa6orascnoco6 o6pa6orxuueSe,nuHa cep- MeHeHfieMxoaryirlHToB u QloxylxHroB oxinblBaer
nofi rscrorofi, n peay.nrrareqero o6paryercx cepHo- BJII,I'HHE HC TOJIbKO BI{A PEATEHTA, HO H CrO AO3A, YC-
xuclornufi pacrBop iurroMoxpeMHr{eBoro $loxynxn- roBHrI noAarrn, rn.qpoAnHaM[qecKueyc.noanr Sop-
ra-KoaryrrnTa (<DK), nuercr{rft BbrrueyKa3aHHbreMnpoBaHuco6paryrourxcq xJronbeB,MeroA ocBerjre-
HEAOCTATKI,I. Hnr cto.{Hoil noAu. OAHaxoAo3apearegTargJlrercfl
Haun parpa6oraH uonufi cnoco6 [onyqeHxt oAHr{Mr,t3npHopHreTHbIX napaMeTpoB,oT xoToporo
tploxyrr Hra-xoaryJrrHranr ne$elnHa [6]. O6pa6or- 3aBHcr4T tQSexrr.rrHocrbero rrpEMeHeHEr.
xy HerSeluuoBoroKoHrIeHTpara BeAyr KorrrleuTpr{po- Ha uo4elrHrrx pacrBopax, coAepxaulux xeJre3o
eansofi cepuofi xnclorofi rtpu coorHorueHr{r,t KoMno- (III), uauu 6rura u:yreua creneHb ocaxgexu.r (n:-
HeHToB,o6ecneq[saroqux nonf{enle 20 - 30 %- aleveHux) E,Yo nowoy Fe'- s 3asllcHMocrHor Jlo3br
Horo BoAHoro pacrBopa $noxynrHra-KoarynqHra. AKOK r.{ BpeMeHr.rorcrar.rBaHr.tro6pa:ylouruxca
ObeasoxusaHr,rexouqexTpr,rpoBaHnoro Bo.rlHoropac- x;IorrbeB.OcaxAenue xeJre3anpoBo,rlnnr{B Mepabrx
mopa $,roxyntxTa-Koaryirrgra Ao non)4{€Hurrcyxoro rlxju{HApax o6rerrlou 500 u.n, KoropLre 3a[oJrHrJru
rpoayKra Beayr ynapHBaHr.reM no.u BaKyyMoMrrpH I,ICCJreAyeMbrM pacTBOpoM, npE [epeMeruHBaHrrH BHO-
TeMrreparypeHltxe ror{Kx KHrreHHflBoAbLAJlroMoK- cHJInpa3Jrr{rrnbre KoJIHqecrBaAKOK H AonoJrHXTeJlb-
peuuuemrft QloxylrHr-xoarynrnT, nuaelennufi no Ho BBoAHJrra:oo6pa:nyo arolrBnpyrouylo ao6aBKy,
pa:pa6orauHofi HaMH MeroluKe (aatree AKOK), :areu QuxulpoB:ull creneHb ocaxaenuJr xeJre3aBo
rrpeAcraBJrrerco6ofi 6erroe BeuecrBo B fpar{yJrax, BpeMeHr.r. Onpe.ueaexnefipoBoAr.rnu $orouerprvecxu
pacTBopHMoeB BoAe, qTO nO3BOirreTnpHMeHrrTb c
^c1ur$ocannui.lroaoft Kncnorofi. Kouqesrpauur
AK@K KaKB nopouxoo6pa:nolr cocrorHr{H,raK lr B Fe'- r ncxo4Hofi npo6e BoabrcocraBns.ta4,6 urln.
BnAepacrBopac onpeAeJreHHoft xonqerrrpaqueft. CoAepxaHre xeJre3aB ocaxAeHHoftSopue BbrrincJrr-
JrHtro pa3H]Iuen rcxoAxoE BoAeH flocJleee orcral-
HccneAosaHne 3SSeKTrrBHoclH Banr.r.f,.
Hruepexr-a [poBonuJrr.tc r.rHTepBaJloM 10 rrlnn.
MoAH$rrUHpoBaHHoro AKOK BoAHufi cJroft He SN,rrrpoaanr. Pe:yltraru npeg-
craBJreHbr n ra6lntle ].
Crenegr or{HcrKHBo.ublyBen}rqr{Baerctc pocroM
.[rr cpanneuux :$Sexrr,rBHocra <DK n AKOK
AO3bIp€areHTacHaqaJla6urcrpo, a noToM MeI,,'reHHo
rrpoBep.rrJrr.rl.lx 4eitcrsue KaK Qloxylrxroe-
H, Haquxar c Hexoropofi BeJllrqfiHbr, :$$exr oqucrxr{
xoaryirrlHToB no cJreayrotutrM froKrBaTeJrflM:MyT-
He MgHJI€Tct.Onrnua.'rrnofr c.{Nraeicfl Ao3a, npu
AOCTb. IIBCTHOCTb II MACqOBbIE KOHIICHTPAIIUI,TXCJIC3A
KoropoX Aocruraerct MaKcHM;urbHo nosuoxunfi :Q-
(III) n eoae. HcturaHur npoBoAHJrH c 4o6aa,renuelr
g - $exr orncrxlt BoAbrnc .{aHHoMynoxatarelro. Kax
OK nure pacrBopa,a AK@K B BrrAepacrBopa
BHAHor,t3pe3yrbraroB ra6a.l a.ur oqr{crKn Bonbror
n;Ili B rropouxoo6paruou cocrotunr.l, qro pacurrpnno
HoHoBxe.re3a (IIl) Ha 70 - 90o/oAocraroqiro 0,4 -
Bo3Moxuocru ero lprMeHexr.rr. K odpa:uarrl roaur
0,8 rlr AKOK, BpeMr orcrafiBaHns.c yBerlrqeHueM
Ao6anrqnu (DK u AK@K pa:ln rHofi Kon[enrpaur4i4,
KogqenTpaur4r{ peareHracoKparqaercr,{o 20 uus.
6ap6orapoaa,rgBo3AyxoMnpo6u B reqegr4eonpeAe-
JTeHHO|O BpeMeHr,rr.r KoHTpojlr,tpoBa/rn rroKa3aTelH
KartecTBano rr,rrloBbrMMeroAHKaM.onpe.ueleHUe
- fljiK: 1,5vr/r
noKinareJrr MyrHocrn npoBoAHJrH Qorouerpuuecxx
- nyreM cpaBneHlrr npo6 nccrlegyelvrofinoAn co
craHAaprnbrMr.rcycrreH3rurMnKaoJrHHa.Petylrmru
r.BMepeunti[pe,{craBJteHurua pnc.l. Hr pncyrxa
BHAHo!rlro orITI.IMtuILHat Ao3a OK ant .Ilocruxexlul
Myraocrr,r,paoxoft 1,5 r'lrh Jrexr.lrr HHreprale or 23
no 30 Mr Al2O3ir, a arrr AK@K - or 25 ao 35 r'lr
Al2O3/n. ilpEseAeHHrteAaHHbIenoxa3blBalor.rrro
[pHMeHeHr{eAKOK no3BoJ'rfleraocrr.lqb raxofi xe
crenenr{ oarucrKri.Kax rrpfi rrpHMeHeHHr OK. I4s npo-
Be.[eHHLrxHaM]r r.tcclreAosaHxiluo :$Sexrr.rBHocrr{
o6ecqreuHuaHns s o6egxene3r{BarurBoAbronpeAe-
xeHo, rtro nprl KoxueHTpaqusOK u AK@K panuoft
30 - 40 ur AI2O3/,rrtBernocrbBo.abr.{ocrrraer fl.{K,
a creneHbocax.[eHr.{txeJre3acocraBJrrer80 - 90 o/a
rpn Ao3eAKOK pannofi 35 - 45 ur AI2O3/I, a (DK
upn raxofi xe Ao3e or{HruaerroJrbKoua 50 - 70 Yo.
Taxuu o6pa:ou, nolyreuHuil uo Hosofi TexHoJrornu, 4 2 0 4 0 6 0
AKOK o6laAaer sHcoxofi KoafyJlupyrouefi u $.no-
,{osaxoarymHra,Mr AI2O3/I
xy,nxpyroueil aKrr.rBHocrbro.
Puc.1. 3asucnMocrbM).Tnocrr.to.rnulaeMofiBo.ubror
.lo3brKoarynffHTa

110
 Ta6,rnuaI
Crenenr ocax,rleHncxeJre3a(8, oh ) B 3aBHcHMocrHor Ao3btAKOK H BpeMeHH OTCTAHBaHI|R
npo6noEu

{o:a AK{DK B [epecrrereHi KonueurpauNr

ur Al'O./n AKOK, r/.rr t, MnH D -oAepxaHnexeJre3as ro,qe,Mr/.r E,oh

l0 0,08 3,03 34.17

2A 0,071 2,65 42,29
5,6 0,1 30 0,071 2,65 44.73
40 4,062 ) 7'' 49,61
50 0,060 a.L+ 51,24
t0 0,071 2,65 42,29
20 0,067 ) 5 45,55
| 1,2 o) 30 0,053 1,98 56,92
40 0,043 1,6 65,05
50 0,039 l,45 68,30
l0 0,051 1,9 58,55
2A 0,036 1.34 70,74
22,4 0,4 30 4,026 0,97 78,97
40 0,019 0,71 84,55
50 0,016 0,59 85.99
t0 0,022 a,E2 82,12
20 0,011 0,41 90,99
44,8 0.8 30 0,010 0,37 91,87
40 0,01r 0,41 91,06
50 0,007 0.26 91,97
10 0,020 0,74 83,74
2A 0,010 0,37 91,87
67,2 l ) 30 0,008 0,29 93,49
4A 0,008 0,29 93,49
50 0,009 011 92,69

OAnurur.r3ocHoBabrxHopMr.ipyeMbrx noxasarerefi crD rlBer, ellrraHHrrft [pncyrcrBueM B BoAe xorJro_

xaqecrBa o.rNuaeMoff Bo.qbl tBJlflercfl uBerHocrb.
I-{rerHocrr aoAu o6uquo o6ycloaleHa npncyrcrBn-
eM oKpalueHHbrxopraHr{qecKr{xBeulecrB (rnaBHbr}{
o6parou ryMxHoBbrxxHcJror,cBr3aHHhrxc ryMycoM
nouru). Ha uaeruocrb BoALrcHJrbHoBjrurer npucyr-
cTBI{eXeJle3aH Apyrfix MeTaJ.uroB
B BLIAeeCTecTBeH-
Hbrx npnMece{.tvuru s xaqecrBenpoAyKToBKoppo3r.rn
[7]. Crovuue BoAbrHeKoropbrxflpeAnpr{mnfi raxxe
MOryT IPI,IAABATb AOBOJIbHO HHTCHCUBH}TO OKPACXY
sore. Pa3nuqalor( I,rcrr,rHHHiqner>, o6yc,ron,renHrrfi
TonbKopacrBopenHlrMn.BeruecrBaMu, l{ (Kaxyrrlufi_ .{H0uur.rpoBannoro AK<DK rrpu orrncrxe croqHbrxBoA
I,IAHbIX H B3BCIUEHHbIX I{ACTI,Iq, COOTHOIuEHI{g MCXAY
xoropbrMHB 3HaqrrreJrbHo[uepe onpeAemrorcs Be_
rN,rr.rHofipH. Bucorax uBernocrh BorFryxyrnaer ee
opraHoJrenr[qecxnecsoEcrBa Il oK€I3brBaer orpurla-
TeJrbHoeBJIItrHueHa pa3BnTr.re BoaHbIx pacrexxft u
xr.rBoTHbrx opraHLr3MOBB pe3yJrbraTepe3KorocHHXe_
Hl{t KOHUeHTpaUUU pacTBopeHHoroKncJropoAaB Bo-
ge, roroprri pacxoAyerc,rHa oKucJIeHHe coe4r.rnerufi
xeJre3aH ryMycoBbrxreuecra [8].
Hauu npouepena eQ$exr[Bnocrb Aeficrsus ]ro-

nl
rlenJlr.oJro3Ho-6yuaxuoroxou6usara (II6K) ro pa3- [po6a, u.n ; V - o6r€u BoAbrnocJle xoaryJrruhu,
rHqHbrM rroKiBareJI{M:uBerHocrb, trlyrxocrr, (poc- MJr.
nsnrrrl Art aHaJH3a,
$ar-aonu u Ap. Tadtwua2
I-{eernocrr Boabl onpeAelrln SoroMerpnqecxu 3$$exrnnHocrn oqHcrK14(8, oA) croqxof;
nyreM cpaBHeHnr npo6 ucnuryelrofi xllAKocrll c sosH IIEK or QocQar-noHon
pacrBopaMr.r, uBer upupo.uuofrro4u
HMHrHpyroIIII,IMx
no xpoMoBo-xo6amronofiruxare (puc. 2). HcxoaHoe KoxueHrpauur
3HarreH6e rlBerHocrgnpo6u BoAbrcocraBr.rlo 195,3o. D eno C, ur/n E,yo
AK<DK.rin

0 (ucxoAnar
0.580 77,40 0,00
noo6a)
0,1 0,400 54,00 29,87
0,2 0,383 51,00 33,77
150
0,3 0,260 35,00 54.55
o5 0,147 20.00 '14,03

$ roo 0,8 0.013 2.00 97,4A

:r

o\
rrl

Y - ^
- O U
I
2A 4Q 60 80
,{osa AK@K B fiepecqere Ha Al2O3 rur/;l
()
ocr h uBerHocraoquulaevofi Borr,ror
Prlc.2. 3asr-rcr.rrvr
Y
.xorlt $roxy.,rxHTa-KoaryrtHTa
U
IIo AaHHoi 3aBr,rcl4Mocru-Bn.{tio, ttro Hoprv{arnB-
HOe 3HaqeHHeTIBeTHOCTH (20") AOcrxraercr frpr4 A03e
AKOK B repecriere xa AI2O3 45 - 60 urln.
Ooc$ar-Hoxu B BoaHbrx pacrBopax ofipe.rteJrrnu 0,0 0.1 02 0,3 0,s 0,E !.0
Qorouerpnuecxn. flpqnuxr rrleroea:$orouerpnue-
cxlrft ueroa onpereneHuflMaccoBoExonueHTpaunlr ,{osaAKOK,ria
$ocSar-nouoB ocHoBaHHa lrx B3arrMo.ueficrBun B Puc.3. B;ruruuekoHrleHrpaqlru
AKOK H&H3BreqeHfie
KncJroficpe.rlec irao.nN6Aarou aMMoHr{rl.r o6pa:oea- (E %) Qoc$ar-lioHoB
H3cro.{Hoftsortr
nneu $oc$opHo-Morn6AeHonofirereporroluKHcJlo-
Tbl, Koropa.sBoccraHaBirHBaercg acxopofiHoBofiKil- HaH6olee r@SexrnaHar oqucrKa urroMoxpeM-
cnoroE B npHcyrcrBnH cypbMr{Ho-BHi{HoK}tcitoro xa- HgeBbrMS,roxylrnrou-Koary.lurHToMaocrr.rraercn B
Jrlrr Ao $oc@opuo-raorn6AenosoroxoMrurexearoJ'ry- uHrepBaqeKoHueHTpaqnfi 0,3 - 0,8 rll n cocraBJrser
6oro qnera. Maxcrlayu cBerorrornoueHutcoolBer- 55-98%.
crByer aJrr.rneBoirribrl, : 690 nru. OrtpeAeilxror$oc- 3Q$exrr.ioHocru uoluQuqrpoBaHHoro $;roxy-
Qar-noHn npn MaccoBofixoHueHrpaulru or 0,05 ao I JrflHTa-Koaryr.rrHTa
HccneAoBaHa npH or{HcTKenpoH3-
lrLn. Ecnr.rMaccoBarKoHrreHTpauar $oc$ar-noHon r BO,IICTBEHHbIXCTOqHbIX BOA, COAEPXATIUX ItOHbI ME.
aHaJrr43upyeMofi npo6e npeBbrrrraerBepxHrororpanu- raruroB,HanpnMepMeaH,xene3a u 4p. (llpo6u crov-
uy, ro aolrycKaercrrpa36aBnsHnenpo6u ao perura- Hoil BoAbr 3aBoAa HM. O.3. fi:epxuncxoro.
MeHrupyeMoro Anana3oHa"3QSexrHenocrr AKOK 0 4 . 0 4 . 2 0 1r0. )
no orrr4crr(eor Qoc$ar-roHoB llpoBepeKaHa cro.{Hofi OnpeAeresaeHoHoBueau (II) ocHoBanoHa r4x
roae II,EK (ra6x.2, pNc. 3) Koxueurpaqran Soc$ar- glauuo.ueftcrBnr,rc AH3TlrnAHTHoKap6aMaroM Ha-
nonoa (rtrrh) nocJreoqHcrKHpaccqr,rrr,rBaror no Sop- rpnr B cla6o-auuuar{HoMpacrBopec oSpa3oBaHH-
uyre C=(X*50)/V, rae X - xouuenrpaqrf; Ooc$ar- eM Ar.r3rr{JrAuTr.roxap6aMara MeAE xe.rrro-
I.loHoB,naftAeuHar no rpaAyl{poBor{HoMyrpa$r.rxy, xopnrrneBofoqrera.,(lr ycrpaueHnr Meurapuero
ur/n; 50 - o6r€ru, Ao xoroporo 6rura pa:6aaleHa BJII,Tf,HHT xeJre3a x xecr(ocrn no.[u ao6aalnor
pacrBop raprpara xanlrr-Harpnr (cernerona colr).

tt2
flpu urerHocrr.rBoabr6olee 20o npo6y o6ecunevu- or r.roHoB xeJre3a(III), npuveu nAK (0,3 urAr) 4oc-
Baror nepcy.nrrlarou aMMoHHr. Srcnepuuerru rr{raercn yxe rrpn KourleHTpaqfiuAKOK 0,1 r/rt.
npoBoalrJrlrB r{uJrrnApax:x 200 ul npo6u roarr Taxuu o6pa3oM,rurroMoKpeMHueBbrfi $.rrorynrnr-
Ao6aBnrnu pa3rfirrHbleKoHrlenrpaunnAKOK unn KoaryJrlHT,noly'renxnfi Ha ocHoBenpnpo.qnorocbr-
BBoAHJTT{2 o/o-sttitpacrBopAKOK, flepeMerxHBaLnl.r,
pra ueQelnHa, no cBor{M cnoficmau He ycrynaer
6ap6ornponaaH Bo3AyxoM, trocJre orcrarlBaHlrt H3BeCTHbTM iKH,qKHM aJ-rIOMOKpeMHHeBhrMtp,roxymH-
iurlrKBory {orouerpnporalu rpu }, 430 HM raM-KoaryJrrHraM. Moantbsuupogannufi AKOK
(ra6r. 3). r.rMeerprr.rlnpenMyuecrr (oauo H3 KoropLrx * Hc-
Ta6:rr.rua3 noJrb3oBaHne ero xaK B Br.rAepacTBopa,TaK r{ B Br{Ie
SQSerrunxocrn oqHcrKu (8, o/o)npoMbrrxfleH- nopourxa), a raxxe ox o6laAaer a$rfexrHrHuun
Hofi croqHoil BoAbror noHoB meau (Il) oqnuanIIIHMH cBof crBaMI,tB orHoIIreHHI,tpffinllrqHblx
rr.rnoB3a{pfl3HtroruuxBerrIecTB.
KorrrecrB( AosaAKOK
B nepecqere CoAepxauue
AKOK, D l:o E,% End;ruorpa$uuecnnfi cnncorc
HA MT 'le.uu(II), ur/l
r/n
Al"O./n
xonq. Cu (ll) ).644 l. llazyu4oe H,H., Heu4uueuxo FO.il., @entucmoe
[4cxoAHax 1,43 0
,[.1O. HaaorexHororun B npoueccax oqucrxr{ Bo-
0.1 6,0 ),l9l 0,44 10,6{
w ll C6. re3. aoKJr.Ha) {.-rexHo-orlrq. cex[]rft
4,2 12,0 ).071 0,15 t8,2( Mex4ynapo.qxoro $opyma rro HaHorexHoJrorurM
0,4 24,A \,041 0.09 16,8( <Rusnanotech08D.2008.c. 609 - 6l l.
0,8 48,0 >,03i 0,07 18,5 2. fenwautlee C.B. , Heuaee LI.A., fandypuua "rT.B.
1,6 96,0 ),03i 0,07 t7.4: Oqucrxa npor.r3BoAcrBeHHr,lx crorrHbrxBoI Koary-
Jr{HraMHu Qloxy.nrHrauu ll M.: ABC,2008.272
Kax BuaHo lr3 pe3yJlbraroB Hcc;reAoBanr.rt c.
(ra6l. 3) eQ$exrnnHocn AKTDKaocrarorrHoBbrcoKa 3. KpyuuuuuaH.E., EarowuasA.E., Kynux A.8., Tu-
fi Aocrr{raeT80 - 90 %0,npu HeBbrcoKHx KoHqeHTpa- .MaweaaH.A., Konecuuxos8.A., Kanycmnncrcuti
rxrx AKSK. n.C, O\ucrxa crorrHbrx BoA anloMor(peMHHeBbIM
3$$exrunHocrb oqncrxu croqHbrxBoa or HoHoB Q,roxy,rxnrou-KoarymHToMl/ Sxonorus, fi npo-
xerre3a (III) npoaoarJru rro Mero.(y, orlrcaHHoMy Poccan.2001. ffs 3 . C.19 - 22.
MbrrrrJreHHocrr
4. Kpyuuuuua H.f. AKOK xax aJrLrepHarr{Ba 'rpaffr-
nurue (crp. 4). Pe:y,rrrarbr npeacraBJreHbr
Ha puc" 4.
100 U}IOHHbIM KOAryIf,HTAM B TIPOqECCAXBOAOOTII1CTKH
i, BoaorroAroronxu ll 3xolornx [por{3BoAcrBa.
2006.Ne2.C.46- 50.
5, Cnoco6 rroJryr{eHIlr rLlroMocr.Hr.rKarHoro
KoaryJuri-
80
\9 ra: rrar.225838Poccuficxax(Deaepaunx, MnK'C
ir) 01F/56 / Kpyvr.rxnHaH.E., Typnnep 8.H., Jlucrcx
F.C., Kuu B.; raau. 26.11.A2; orry6r.20.03.04.
F " w"
P
O
'
Elorr.ltrs8.
6.Cnoco6 noJI)IeHLtf; tuIIoMoK?eMHHeBoro $noxy-
rf,HTa-KoarynruTau cnoco6 oriucrKu c ero no-
Morrlbio BoaH: nar. 2388693 Poc. OeAepa{ux:
MnK C01B 33126,C0rF 7l'74, C02F 1152I Kyn-
r't pf,BtIeBfl.f., HeAyroBA.H., Ps6os B.A., Bo;rxosa
M.A., Kaftcuu A.8., Koporaer H.M., (oprnu
A.M.; 3arrBn.28.07.08; ony6,r.10,05.10.6ron.
Ne13.
7. \OCT P 52'769- 2007.Boaa.Mero.{u orpenene-
0,0 0,'1 0,2 0,3 0,5 0,6 1.A Hlrf,uBeruocrx.Bse,r.2AA7- 1A- 26, M.: Cras-
,{osaAKOK,r/n .uaptrxQopu, 2007.10c,
8 , lyceea 7.8., lyceoa T.B., Xomyneaa
M.8., Buuuu-
Puc. 4. CreneHb oqncrlrH (E, 7o) cro.ruofi so.qsl B 3aBficlt-
uenrcoB.H. Kax opraHH3oBarb o6ulecrBeHHtrft
Mocrn or KoHuegrparrnrl AKOK. (Hcxo,uxar Kor{ueHrpauur
(lil) 0,8vrh) MoHnropuHr:pyKoBoAcrBoarr o6uecrBexHbrx
xerre3a
opraxi-raunf;noApea.M.B. Xoraesofr.2-eutr,.,
Kax aIrAno I,l3AaarpaMMbr,AocraroqHo 0,1 - 0,5
uc[p. M.: Couraarso-3xorornrecKuficoros,
r/n AKOK 4nr r$$exrusHoft o.rt,rcrxncrounofi no4n 1998.256 c.

il3
 ALYUMOKREMNTEVYEFLOCCULANTS.COAGULANTSIN
WATER TREATMENT PROCESSES

M.A. volkova",A.N. Nedugovb,

s.v. Andrienko',A.v. Kaisinb,A.u. Larinar

"PermStateUniversity.15,Bukirevst.,Perm,614990
oNatural-scientifiin
c stitutePSU.4,Genkelja st.,perrn,6 | 4900
E-mail:margo@psu.ru

Thisarticledescribeshow recyclingaluminum-siliconraw materialto producea modifiedfloccu-

lant-coagulantandits usein watertreatmentprocesses.

Keywords:flocculant;
coagulant;
heavymetals;ecology

1t4