ADHYAY Batch ISOMERISM LECTURE -5

of sphybrid
bitterson. Types of Projections
①
jying-wedge projection(wedge-dash)
② -

projection
Fischer

③ Newman
projection
④ horse
saw
projection
①
fying wedge projection.
mill-
going away from
the
9

-6
viewer.

f ⑪-
coming
towards the
viewer

② Fischer
projection:

3
6
horizontal line
squarents
aka atom

&verticle
coming
out word.

refreements
petat
line atom

I higher
oxidized carbon inside the
going
*
plane.
top
the
 all
oxidized.
" highest
-
-

CHO -
O

I
an
:I
OH

going away
HO H

conf .
-

CH2 the C20H

-
forviewer
D-aly maldehy
de --
geycraldehyde.
⑰
Dor has
nothing
do
to
optical
with rotation.

-e)

13 CH3 C13

H On
H On "
/
no-H

HO H o

in-
-

-.........

H OH
113 CH3
ature
irical)
-
u non
experimposable
- each
images of
mirror
↓ other
not the mirror (pair enantioners).
images of
they
are

other so are called dialtbowess.

yeach they
 ③ Newmann
projection: -

n-n
Hec
H
-
-H
C
-
H "
H
H
Sin &

-H -
H

H H

Si -
Got H
-
in
>

H
H -H - H -H
H

Istaggered
n form.
Eclipsed form
2,413
CH5-CH2-CH2-CH3 13
H
1
-- -H
I 2 -
n M

gen i)t
CH3

-it
H -H
n 3
H -
H H

I
fully eclipsed form Gauche
ferm
partially
eclipsed
Foot 60

C3 C 13

I s)
in
t
*
- -
L
- -
-H
u -
H
H

ni ↳
partial y eclipsed Antifa
Gauche
fam Anti>
General
stability
order
Gauche,
partially eclipsed fully eclipsed.
⑭Now
of following
write the
stability
I also order the

①
CH2-C2 ② CH2-CH2 B CHerCH2
In on IIf I'l

igaphau)
(a) (inag)
or
(ingas)
⑭ CH2-CH2
In Now
⑤ CHICH2
koon on ⑧
E (a)pH
=
2

C) 13
pH
=

· ⑧ --
↳1
① C-CH2
on on glycol.
ethyl ene intramoleculat
-1._n ↑Bonding.
->
o O

H
H
join
-H -
H
-

oot/
H
2

-
, Got
S
-

↑
/Ent
fully eclined
"aauch fam
partially
food OH
eclipsed

order
stability (3G>PIE) FEX
-morg,
-
- H
form.
-
anti
FE.
Actual
order:
-G7A) P.E.) -
H
- - H
di
 CH2
If you tryto

⑥
Rotate thisbond

a H
H
IFin will break bond.

no"s n
H

⑦ I /

↓
no
!
H H
a
neI
I
② ④
-

↓
① ③

In -
-
H.
n CH2
 unations
conf of cyclohexane:-
projection
Howarth
5)
①
fam
[I
Chair
from ②
Halfchair

- ③
↳
a
Boatform twist boat
form. Ilo
In
general stability
order

chair twist boat? Boat>

A C
half chair

C
⑤ 2
⑪

e8 --
e 2

-
-
e
-③ 2

④ ②
A

a a

(1,2) (9.9) - trans and anti

(1,2) (e,e) => trans but not anti
(I, (9,e)- is
(1,2) (e,a) =>
is (1,4) (9,9) trans manti
=

(1,4)(e.e) trans wanti

=

(13) (9,9) in (1,4) (9,2) cis

syn
or
=

(1,3) (e,e) = is (1,4) (e,a) is

-

-
-

(1,37 (9-2) => trans

(113) (e,9) - trans
 I 51
H M13
E
3 2

(13) diaxial
-

ins
6 iepulsions.

01
- (more stable).

43
Y
I
⑪
Eb ② ③
[]us
E dr
1
④ Saw Horse
H
conformations?
4 -
H
--n
* /
H
-

i 4 -
H
saw horse
projection

H
I
H

I
I
1
H -H -
H

--
H
mature
me
of organic compounds'--
Itis
I
based
upon the CIP
-
Rule:
A

f6- Right-
4 C R- toward clockwise
direction
M
a. R - Rectus

A
S- towards
left-anticlockwise
/1
2 C C "
' sinister direction

·
S-

when the dash is then

wedge given
ever
*

should
always
the be below the
priority
lowest

plane
If it is
prevent
not below
plane
the

we will
do
interchanges
of
then even no a

aling
itbelow the
plane before naming,
 aD
I
⑭
t
G
I
C-
③
d
anticlockwise -
-
s

8
3

13
·
kowe
↳ C
-

Hill -
Bu

cu
daue
the
I
-q In thiscase the lowest
priority
is notbelow the
plane.
%
a
2 C I
11) -
I
43
Bu

⑨ ↳ 1st
C
d
↑
Hill
28
- IC
IC Bu

Interchange d

than one cassonispresentingthechaithen

*
Imove
below the
lowent
prinity
calculate
is

Ros
the
plane.
nomenclature
simply according
you get
Rule & the
write what
of
to CIP revers

as anner
a
By
I1 ③
-Da should be R/ But
- ② &-It
② lowest
the
prinity
④
a "Bu which it
is is above
place
the

correct
so the would be $
 in
⑭
o
on

calculation
of number
of
stroisomers.-

①
y compound
the
Then Total
is
unymmetrical 2"
of Hello isomers
no =

centre
of stereogenic
n - no or area.

symmetrical
②
If
the
compland is

then total steleolomess=

n -1
g4-1
of
no 2 +

p 1 =

if his even

if odd
his
=