Sec: JR.

IIT_*COSC(MODEL-B) WAT-30 Date: 03-12-23

Time: 3 Hrs 2019_P1 Max. Marks: 186
KEY SHEET
MATHEMATICS

1 A 2 B 3 D 4 A 5 ABD

6 CA 7 B 8 B 9 AD 10 B

11 ABCD 12 AD 13 3 14 4 15 2

16 9 17 2.5 18 8

PHYSICS
19 D 20 C 21 A 22 A 23 BCD

24 ABCD 25 BCD 26 BC 27 AD 28 AC

29 AD 30 AB 31 2.17 32 1743 33 1.57

34 1.73 35 0.38 36 298.8

CHEMISTRY
37 A 38 D 39 A 40 B 41 AB
42 A 43 BCD 44 BC 45 AC 46 BCD

47 AB 48 AC 49 4 50 5 51 6

52 3 53 4 54 10
Narayana IIT Academy 03-12-23_JR.IIT_*CO SC(MODEL-B)_JEE-ADV_WAT-30_KEY&SOL
SOLUTIONS
  MATHS
1. A vector in the plane of b and c is
       
  
b   c  i  2 j  k   i  j  2k
 

 d .a 2
Its projection on a is  = 
a 3

2. i  x  3 y  4 z   j  x  3 y  5 z   k  3x  y   i   x   j   y   k   z 
Comparing and solve x, y and z
  0, 1

3. AE = vector component of q on p

AE 
 p.q  p  q  r   p.q  p
 p. p   p. p 

4. a  1,3sin 2  makes an obtuse angle with the z-axis
 sin 2  0
 
Since b and c are orthogonal

 b.c  0.................(1)
 tan 2   tan   6  0  tan   3 or  2
If tan   3 , then
2 tan  3
sin 2  2
  0 , which is not possible (from(1))
1  tan  5
 tan   2
2 tan  4
Again tan 2  2
 0
1  tan  3
Also sin 2  0

 2 lies in the third quadrant  lies in the second quadrant
2

 sin is valid and    4n  1   tan 1 2
2

5 a    i  j  j  k 
   
 

6.

1  x 2 sec 2 x
7. f '( x)  2
1  x tan x 

 cos x  x  cos x  x 
2
cos 2 x 1  x tan x 
f '( x0 )  0  cos x0  x0
Also f '( x) changes sign from + ve to –ve a cross x0
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 x0 is a point of local maxima
 
The function cos x  x is shortly decresing in  0, 
 2
 
 f  x  has exactly one point of maxima in  0, 
 2

8. Let O be the again. Then

   
h  a
 b 
c 
So, HA  HB  HC
     
  
 ah  bh  ch   

 2h
 
 2OH  2 HO

9. M  cos t  sin
2 2
t  2aˆ.bˆ sin t cos t 

 1  aˆ.bˆ sin 2t is max at t =
4
1 1
aˆ  bˆ
uˆ  2 2  aˆ  bˆ
aˆ bˆ aˆ  bˆ

2 2

10. AB  2iˆ  10 ˆj  11kˆ and AD  iˆ  2 ˆj  2kˆ

AB.AD
Angle ‘  ’ between AB and AD is cos  
AB AD
2  20  22 8 17
   sin   
15 3 9 9
Since,     90
17
 cos    cos  90     sin   
9

 2   4 
11. cos x  cos   x   cos   x   0 and hence,
 3   3 
 2   4  3cos 3 x
f  x   3cos x cos   x  cos   x 
 3   3  4
   
12. 
Given that 3 4q  3r  2q  3r

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   6 
 10q  12r  q   r...........(i )
5
   5
(i ) p  4q  3    q (by using (i ))
 6
 3 
p q
2
   
 p  q and directions of p and q are same
  6   
(ii ) p  4  r   3r
 5 
 9 
p r
5

2 3
13. a  b  c  0  a .b  b .c  c .a  
2
2 2 2
Now, a  b  b  c  c  a  9
2 2 2
Given a  b  b  c  c  a  9  a  b  c  0  a  b  c  0

14.

15.
A

B D C

T
      
OA, OB, OC , OT are P.V of a, b, c, t
  
a  b  c R
   
OA  OB  OC  OH  
 P.V
    of H is a  b  c , since D is the midpoint of HT we have
a b c t 
 a
2
    
 AT  2a  AT  2a  2 a  2 R
 AT  2 BC

OD  OB OA  OC
16. OX  , OY 
2 2

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OA  OC OD  OB
XY  OY  OX  
2 2


 OA  OD    OC  OB 
2
DA  BC

2
a  ka 1  k  a
XY  
2 2
1 k
XY  a
2
1 k 4 1 k 8
4 .17    1 k 
2 17 2 17
9
k 
17

17.

1 1
2 2

18.
 a  1 
 b  1 a2 1 b2 1 a b  a 2 1 b2 1  4  a b 2
     2    4  . . .   4 .   8
b a b b a a b a  b b a a b a
Where a  tan 2  , b  tan 2 

PHYSICS
19. Adiabatic process.
20. In an isobaric process Q : W : U  C p : R : Cv
m
21. U T for AC means Ac is isothermal. 
means BC is isochoric.
V
AB is hyperbolic means U   cons means TV = constant means PV2 = constant
22. In an adiabatic compression temperature and hence nRT =PV also increases
23. In an adiabatic processed Q = 0 and hence dw = - du. In an isothermal process T =
constant and du= 0
24. Work done by a cyclic process is positive if the process is represented by a clockwise
loop. Work done by = area enclosed by the loop
RT RT
25. P  means straight lines through the origin with slope represent constant
M M
temperature lines .   Constant means volume also constant.
26. T  kV 2  TV 2  C is polytropic process
TV x 1  C , x  1
nRT nR3T0  R R 
W  Q  n   T
1 x 2  r 1 x 1 
27. CO2 is linear molecule similar to diatomic.
For mixture Cp, Cv are of diatomic.

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Cv , C p of mixture is weighed mean which must lie between the extreme values.
 Cv , C p odf component gases must lie on either side of the values of mixture.
28. V2  V1 / 2 . Use WD formulae for 3 process.
29. C p  Cv  R  Gas is real.
Gases tend to be ideal at high temp and low pressures.
Gases tend to be real at low temp and high pressures.
nR nR nR 3 3
30. V C P T T 2 or T
V V V
If T 2  x or T 3  x the graph will be as shown.
nRT PV  PV 81PV
31. u  nCv T   2 2 1 1 0 0
r 1 r 1 2
W = Area under graph  81PV 0 0
117 PV0 0
Q = W  u  ………… (1)
2
C
Q  nC T  nRT   27PV 0 0 ……….. (2)
R
Solve (1) & (2)
V
32. W  nRT n 2
V1
 1 8.3 300  0.7
 83  7  3  1743 J
 R2 
33. W = Area enclosed    1.57
2 2
34. As system is isolated processes are adiabatic
2
TV r 1  C , r  1 
f
35. Net work done, W = Area enclosed
 3  105 J
Heat supplied Q = heat supplied during AB and BC
nRT PV  PV 3
QAB  nCV T   2 2 1 1  105 J
r 1 r 1 r 1
QBC  WBC  u BC
PV  PV
= Area under  2 2 1 1
r 1
1
  5  105    105 J
r 1
2
QAB  QBC  Q  5  105   105
r 1

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5
W 3  10
 
Q  2  5
5    10
 r 1
For r maximum,  is maximum.
5
Max r 
3
  0.38
36. PV =RT
T  324  V 2 . Eliminate V or T to get P  f T  or f V 
dP dP
 0 or  0 for p to be minimum.
dT dV

CHEMISTRY
ka
37. NO 2 group is EWG and p is lower than meta and para nitro phenols.
38. Alkanes are lower acidic than alkynes
39. In pyridine lp of electron at N-atom not involving in resonance
40. Conceptual
41. Aromatic maines are less basic than aliphatic amines
42. In test Butyl cation carbon bearing +ve charge has one vacant p-orbital hence it is   p
(empty) hyper conjugation.
43. Conceptual
44. Conceptual
45. Conceptual
46. Electron donating group can decrease acidic nature of phenol
47. Conceptual
48. Conceptual
49. Conceptual
50. Conceptual
51. Conceptual
52. 5,6,7 Numbered molecules have greater pka than Benzonic acid
53. H 2O, HF,CH 3CH 2OH,CH 3CH 2SH
54. Conceptual

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