19 AUG 21 (2020-22) CHEMISTRY

(XII) LALIT TUTORIALS (XII)

Time :- 60 Min. COORDINATION COMPOUND Mark :- 180
1. In the compound, lithiumtetrahydrio aluminate (III), the 13. Which of the complex ions given below can have the
ligand is largest number of isomers ? (en = ethylenediamine)
a) H+ b) H c) H− d) none of these a) [Co (NH3)4 Cl2]+ b) [Co (C2 O4) (en)2]+
2. Which one is most likely structure of CrCl3.6H2O if 1/3 of c) [Cr (NCS)2 (NH3)4]+ d) [Cr (NH3)4 (en)]3
total chlorine of the compound is precipitated by adding 14. The complex ion which has no ‘d’ electrons in the central
AgNO3 to its aqueous solution metal atom is :
a) CrCl3.6H2O b) [Cr(H2O)3Cl3].(H2O)3 a) [MnO4 ]− b) [Co(NH3 )6 ]3+
c) [CrCl2(H2O)4].Cl.2H2O d) [CrCl(H2O)5]Cl2.H2O
c) [Fe(CN)6 ]3− d) [Cr(H2O)6 ]3+
3. Which order is correct in spectrochemical series of
ligands? 15. The geometry of the complex compound [Pt(NH3)2Cl2] is
a) square planar b) pyramidal
a) Cl− < F− < C2O42− < NO2− < CN−
c) tetrahedral d) octahedral
b) CN− < C2O42− < Cl− >NO2 −< F− 16. The IUPAC name of K3[Fe (CN)6] is
a) potassium hexacyano ferrate (III)
c) C2 O42− < F− < Cl− < NO2− < CN−
b) potassium hexacyano ferrate (II)
d) F− < Cl− < NO2− < CN− < C2O42− c) potassium ferricyanide
4. The total number of geometrical and optical isomers for d) hexacyano ferrate (III)
the complex ion dichlorobis-(ethylenediamine)rhodium 17. The more stable complex ion is
(III) ion is a) [Fe(OH)3 ]3− b) [Fe(Cl)6 ]3−
a) 6 b) 4 c) 2 d) 3
c) [Fe(CN)6 ]3− d) [Fe(H2O)6 ]3+
5. CuSO4 dissolves in NH3 due to the formation of
a) Cu(OH)2 b) Cu[(NH3)4]SO4 18. The metal present in vitamin B12 is
c) Cu[(NH3)4(OH)2 d) CuO a) iron b) cobalt c) magnesium d) manganese
6. A complex with the composition [MA2B2]X2 is found to 19. The geometry of Ni(CO)4 and Ni(PPh3)2Cl2 are
have no geometrical isomers. Both A and B are a) both square planar
monodentate ligands. The structure of the complex is b) tetrahedral and square planar
a) linear b) square planar c) both tetrahedral
c) tetrahedral d) octahedral d) square planar and tetrahedral
7. The two complexes PtCl4.2NH3 and PtCl4.2KCl do not give 20. The IUPAC name of K3[Al(C2O4)3] is
precipitates of AgCl when treated with AgNO3. a) potassium alumino oxalate
The conductance studies indicate zero and three ions per b) potassium trioxalato aluminate (III)
mole of the complexes respectively in their solutions. c) potassium aluminium (III) oxalate
The structure of these complexes are d) potassium trioxalato aluminate (VI)
a) [Pt(NH3)2 Cl4], K2[PtCl6] 21. Which one of the following octahedral complexes will not
b) [Pt(NH3)2] Cl4, K2[PtCl6] show geometrical isomerism? (A and B are monodentate
c) [Pt(NH3)2 Cl2]Cl2, [K2 PtCl4]Cl2 ligands)
d) [Pt(NH3)2 Cl4], K2[PtCl5]Cl a) [MA5B] b) [MA2B4] c) [MA3B3] d) [MA4B2]
8. The two complexes given below are 22. The number of unpaired electrons in the complex ion
[CoF6 ]3− is
a) zero b) 2 c) 3 d) 4
23. A 0.001 molal aqueous solution of PtCl4. 4NH3 in water had
a freezing point depression of 0.0054oC. If Kf for water is
1.80, the correct formulation for the above molecule is
a) [Pt (NH3)4 Cl3]Cl b) [Pt (NH3)4 Cl2]Cl2
a) geometrical isomers b) position isomers c) [Pt (NH3)4 Cl2]Cl3 d) [Pt (NH3)4 Cl4]
c) optical isomers d) identical 24. The magnetic moment of K3[Fe (CN)6] is found to be 1.7
9. The phenomenon of optical activity will be shown by (B) BM. How many unpaired electron (s) is/are present per
molecule?
a) 1 b) 2 c) 3 d) 4
2−
25. In [NiCl4 ] , the number of unpaired electrons are
a) 1 b) 2 c) 3 d) zero
26. Which of the following is considered to be an anticancer
species? (C)

10. In the complex ion MLn+ n+

6 , M has five d-electrons and L is
a strong field ligand. According to crystal field theory, the
magnetic properties of the complex ion correspond to how
many unpaired electrons ?
a) 0 b) 1 c) 2 d) 3 27. The correct order of magnetic moments (spin only values
11. The shape of Fe(CO)5 is in B.M.) among the following is
a) octahedral b) square planar a) [MnCl4 ]2− > [CoCl4 ]2− >[Fe(CN)6 ]4−
c) trigonal bipyramidal d) square pyramidal b) [MnCl4 ]2− >[Fe(CN)6 ]4− >[CoCl4 ]2−
12. The brown ring test for NO3− is due to the formation of
c) [Fe(CN)6 ]4− >[MnCl4 ]2− >[CoCl4 ]2−
complex ion with the formula
a) [Fe(H2O)6]2+ b) [Fe(NO)(CN)5]2+ d) [Fe(CN)6 ]4− >[CoCl4 ]2−  [MnCl4 ]2−
c) [Fe(H2O)5NO]2+ d) [Fe(H2O)(NO)5]2+

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13 JULY 21 (2019-21) GT – 3 CHEMISTRY

28. When one mole of each of the following complex salts is 45. The coordination number and oxidation number of X in the
treated with excess of AgNO3, which of them gives compound [X (SO4)(NH3)5] will be
maximum amount of AgCl? a) 10 and 3 b) 1 and 6 c) 6 and 2 d) 6 and 4
a) [Co(NH3)6]Cl3 b) [Co(NH3)5Cl]Cl2 46. The crystal field spilitting energy for octahedral ( 0 ) and
c) [Co(NH3)4Cl2]Cl d) Na2[PtCl6] tetrahedral (Dt) complexes is related to
29. Which of the following complex species does not involve 4 1
inner orbital hybridization? a)  t = 0 b)  t = 0
9 2
a) [CoF6 ]3− b) [Co(NH3 )6 ]3+
4
c) 0 = 2  t d) 0 =  t
c) [Fe(CN)6 ]3− d) [Cr(NH3 )6 ]3+ 9
30. The number of chloride ion/s produced by complex 47. A similarity between optical and geometrical isomerism is
tetraamminechloroplatinum (IV) chloride in an aqueous that
solution is a) each gives equal number of isomers for a given
a) four b) two c) one d) three compound
31. Which of the following is potassium ferricyanide b) if in a compound one is present then so is the other
a) K4[Fe(CN)6] b) K3[Fe(CN)6] c) both are included in stereoisomerism
c) K3[Fe(CN)3] d) K3[Fe(CN)4] d) they have no similarity
32. Which of the following is an outer orbital complex as well 48. In the coordination compound K4 [Ni (CN)4], the oxidation
as diamagnetic in behaviour. state of nickel is
a) [Zn(NH3 )6 ]2+ b) [Cr(NH3 )6 ]3+ a) 0 b) + 1 c) + 2 d) –1
49. Which one of the following is an inner orbital complex as
c) [Co(NH3 )6 ]3+ d) [Ni(NH3 )6 ]2+ well as diamagnetic in behaviour ?
33. [Co(NH3 )4 (NO2 )2 Cl exhibits a) [Zn(NH3 )6 ]2+ b) [Ni(NH3 )6 ]2+
a) Linkage, geometrical and optical isomerism
c) [Cr(NH3 )6 ]3+ d) [Co(NH3 )6 ]3+
b) Linkage, ionization and optical isomerism
c) Linkage, ionization and geometrical isomerism (Atomic number : Zn = 30, Cr = 24, Co = 27, Ni = 28)
d) Ionization, geometrical and optical isomerism 50. The ligands in anticancer drug cis-platin are
34. In which of the following complexion, the central metal a) NH3, Cl − b) NH3, H2O
atom is in a state of sp3d2 hybridization −
c) Cl , H2O d) NO, Cl −
a) [CoF6 ]3− b) [Co(NH3 )6 ]3+
c) [Fe(CN)6 ]3− d) [Cr(NH3 )6 ]3+
35. Which of the following complexes is likely to show optical
activity ?
a) trans – [Co(NH3 )4 Cl2 ]+ b) [Cr(H2O)6 ]3+
c) cis – [Co(NH3)2en2]3+ d) trans-[Co(NH3)2en2]3+
36. In photography, Na2S2O3.5H2O is used
a) in reduction of Ag metal from AgBr
b) for the conversion of AgBr into silver thiosulphate
c) for the conversion of AgBr into silver sulphate
d) for the conversion of AgBr into soluble thiosulphate
complex
37. The formula of sodium nitroprusside is
a) Na 4[Fe(CN)5NOS] b) Na2[Fe(CN)5NO]
c) NaFe[Fe(CN)6] d) Na2[Fe(CN)6NO2 ]
38. Trunbull’s blue is
a) ferricyanide b) ferrous ferrocyanide
c) ferrous cyanide d) ferriferrocyanide
39. Tollen’s reagent is
a) [Ag(NH3)2]+ b) Ag2O
c) [Cu(OH)4]2- d) Cu2O
40. The coordination number and the oxidation state of the
element E in the complex [E (en)2 (C2O4)]NO2, where en is
ethylenediamine, are respectively
a) 6 and 3 b) 6 and 2 c) 4 and 2 d) 4 and 3
41. The value of the spin only magnetic moment for one of the
following configurations is 2.84 bohr magneton.
The correct one is
a) d3 (in weak as well as in strong fields)
b) d5 (in strong ligand field)
c) d4 (in strong ligand field)
d) d4 (in weak ligand field)
42. Nickel (Z = 28) combines with a uninegative monodentate
ligand X − to form a paramagnetic complex [NiX 4 ]2− .
The number of unpaired electron(s) in the nickel and
geometry of this complex ion are, respectively
a) two, square planar b) one, tetrahedral
c) two, tetrahedral d) one, square planar
43. Which of the following complex has a shape different from
others ?
a) [Zn (NH3)4]2+ b) [Ni (CO)4 ]
c) [Cu (CN)4] 3- d) [Cu (NH3)4]2+
44. In case of [Ti (H2O)6] ion, the net CFSE value will be
3+

a) –0.4  0 b) 0.6  0 c) Zero d) 0.2  0

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