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26 - 11 - 2023 - SR - Elite - & - Targe - Sol Key
26 - 11 - 2023 - SR - Elite - & - Targe - Sol Key
CHEMISTRY
31) 2 32) 4 33) 1 34) 3 35) 2
36) 3 37) 3 38) 4 39) 1 40) 2
41) 1 42) 1 43) 4 44) 4 45) 4
46) 4 47) 1 48) 3 49) 4 50) 4
51) 4 52) 64 53) 375 54) 6 55) 5
56) 3 57) 84 58) 5 59) 4 60) 7
MATHEMATICS
61) 2 62) 1 63) 4 64) 4 65) 1
66) 2 67) 1 68) 2 69) 3 70) 1
71) 3 72) 4 73) 2 74) 2 75) 1
76) 3 77) 3 78) 2 79) 2 80) 1
81) 7 82) 15 83) 1 84) 8 85) 5
86) 2 87) 27 88) 3 89) 8 90) 1
SOLUTIONS
PHYSICS
1. For isochoric process, ΔU = Q = msΔT
Here, m = 200 g = 0.2 kg, s = 4184 J/kg/K
ΔT = 60°C – 40°C = 20 °C
ΔU = 0.2 × 4184 x 20 = 16736 J = 16.7 kJ
2. Given that the process is isobaric.
Therefore, heat energy absorbed by the gas is ΔQ = nCPT …(1)
Also, work done by the gas is W = nRT = 10 J (given)…….(2)
Since, CP = (7/2) R for a diatomic gas
ΔQ = n(7/2) RΔT (Using 1)
ΔQ =(7/2)nRΔT =( 7/2) x 10 (Using 2)
ΔQ = 35 J
3. Internal energy and temperature are state functions
Pv x const
4. R
C Cv
1 x
5. Average velocity = displacement/ time
Average velocity = 2r/t = 2 x 1/1 = 2m/s
6. Initial momentum is zero since the ball is stationary
Momentum of 2kg is P1 = 2 x 8 = 16 kgm/s
Momentum of 1 kg is P2 = 1 x 12 = 12 kgm/s
Both are at right angles so the resultant will be P = √P12 + √P22= √256 + √144 = 20 kgm/s
the third piece will have a momentum in the opposite direction to make the net
momentum zero.
Therefore V = P/m = 20/0.5 = 40 m/s
7. Coefficient of kinetic friction, μ = tanθ[1 – 1/n2]
here θ = 450
and n=2
μ = tan 450[1 – 1/22]= 1 – ¼ = 3/4 = 0.75
8. Work done by a variable force w F .ds
Wherein F is the variable force and ds is small displacement F ax bx 2
Work done in displacing rubber through dx fdx
W ax bx 2 dx
L
w aL2 / 2 bL3 / 3
9. F=6t,m-1Kg,u=0
Now, F=ma=m(dv/dt)=1x (dv/dt)
v 3 1 0 3m / s
2
w 1/ 2 32 0 4.5 J
10. I0 = Icm + md2
I0 = (7MR2/2) + 6(M x (2R)2) = 55MR2/2
Ip = I0 + md2
Ip = 55MR2/2 + 7M(3R)2 = (181/2)MR2
11. Total kinetic energy after the collision = ½ mv12 + ½ mv22= 3/2(½ mv02)
v12 + v22= (3/2)v02 ——–(1)
By momentum conservation mv0 = m(v1+v2) ——–(2)
(v1+v2)2 =v02
v12+v22+ 2v1v2= v02
2v1v2 = – v02/2
(v1 – v2)2 = v12+v22 -2v1v2=(3/2)v02 + v02/2
v1 – v2 = √2 v0
Done with rotation
12. From Kepler’s law, T2∝ R3
2 3
T R
Therefore, 2 2
T1 R1
T1 =365 days, R1 R, R2 R / 2
2 3
T2 R / 2
365 R
T2 2 365 / 8
2
T2 2 16, 653
T2 129 days
13. The energy required is given by = GMm/R
= gR2 x m/R (∵ g = GM/R2)= mgR
= 1000 x 10 x 6400 x 103 = 64 x 109 J= 6.4 x 1010 J
14. In SHM,
Speed A2 x 2
at x 4, v (5)2 4 3
2
Acceleration a 2 x
at x 4, a 4 2
T
As is mass per unit length of the rope, then m / L As
dx mgx / L
g x
dt m/L
dx
gdt
x
L L
dx g dt
1/2
Integrating on both sides, we get x
0 0
20
t 2 L / g 2 2 2s
10
17. λmax/2 = 40 ⇒ λmax = 80 cm
18. Elastic energy per unit volume= 1/ 2 stress strain
Elastic energy = 1/ 2 stress strain volume
1 F / A L / L AL
2
1 F L 1 200 103
2 2
Elastic Energy=0.1J
19. 1 2
Fl / r y Fl / r y
1
2
1 1 2 2
2
2
2 / R 7 1.5 / 2 4
2 2
R 1.75mm
20. The linear speed of the liquid at the sides is rω. So, the difference in height is given as
follows
2gh = ω2r2
h = ω2r2/2g
here ω = 2πf
Therefore, h = [(2 x 2π)2(5 x 10-2)2]/(2×10) = 2cm
21.
Yashpatil TG~ @bohring_bot
27 x (4/3)πr3 = (4/3)πR3 Or r = R/3
Sec: Sr. Elite & Target(C-120, C-IPL & IPL-IC) Page 4
SRI CHAITANYA IIT ACADEMY, INDIA 26-11-2023 Sr. Elite & Target_Jee Main_CTM-07_Key & Sol's
Terminal velocity, v ∝ r3
Therefore, (v1/v2) = (R2/r2)
v1/v2= [R/(R/3)]2= 9
(v1/v2) = 9
22. (Imax/Imin) = (a1 + a2)2/(a1 – a2)2 = (1 + 3)2/(1 – 3)2 = 16/4 = 4
23. (1/15) + (1/-10) = 1/f
f = -30 cm
R = 2f = 2(-30) = -60 cm
24. Emission of photo-electron starts from the surface after the incidence of photons in about
10–10 sec
25. Let λm = Longest wavelength of light
(hc/λm) = Φ (work function)
λm= hc/Φ = (6.63 x 10-34) x (3 x108)/(4.0 x1.6 x10-19) = 310 nm
26. Magnetic field at the centre Bn 0l / 2rn
For a hydrogen atom, the radius of nth orbit is given by
rn n 2 / m h / 2 4 0 / e2
2
rn n 2
l e / T e / 2 rn / vn evn / 2 rn
Also vn n 1 l n 3
Hence, Bn n 5
27. The energy stored in the electric field produced by a metal sphere = 4.5 J
⇒ Q2/2C = 4.5 or C = Q2/2 x 4.5
Capacitance of spherical conductor = 4πε0R
4πε0R = Q2/(2 x 4.5)
R = (1/4πε0) x [(4 x 10-6)2/(2 x 4.5)] = 9 x 109 x (16/9) x 10-12 = 16 x 10-3 m = 16 mm
28. The power consumed when two resistance are in series combination is
V2/2R = 60 W ⇒ V2/R=120 W
When the two resistance are connected in parallel combination, power consumed is
2V2/R = 120(2)= 240 W
29. The magnetic dipole attains equilibrium under the influence of these two fields making an
angle 1 30 0 with B1and 2 750 300 450 with B2
For stable equilibrium, net torque acting on dipole must be zero
i.e T1 T2 0
T1 T2
mB1 sin 1 mB2 sin 2
B2 B1 sin 1 / sin 2 15mT sin 300 / sin 450 15mT 1/ 2 2 10.6mT 11mT
CHEMISTRY
31. As we move from left to right in a period ionization enthalpy increases gradually. But
ionisation enthalpy of fully and half-filled orbitals are higher than normal values due to
higher stability. Hence , the correct order will be B<A<D<C.
32. Acidic strength of different oxides of same element increases with increase in oxidation
state of element.
33. H 2O can form hydrogen bonding
34. PCl5 have axial bonds which are weaker the equational bonds. Because the axial bond are
s 2s
[ Pb 2 ] S 0.1 0.1
S 0.1
Now, K sp 8 109
[ Pb 2 ][ I ]2 8 109
0.1 (2 S ) 2 8 109
4 S 2 8 10 8 S 2 10 8 M
36.C)
( A) Q; B ( P ); C ( S ), D ( R )
NH 2
Ninhydrintest ( B )
R CH Violet colouration
O
COOH
OH
( Ninydrin),
OH boil
(B)
OH
CHO
O
CH 2 SO4
Violet colouration
Molish Test ( P )
( Molish reagent )
(C)
CH 2OH CHO
Ceric ammonium
nitrate ( s )[ CAN ]
50% CH 3COOH
( Benzyl alcohol ) ( Benzaldehydel )
(D)
dil .KMnO4 / OH / Cold ( R ) H
( PinK ) H
H
( Styrene)
Mn2 (colourless)
37. C)
Br
5 2
6 4 3
( I . p)
Br (h. p)
h. p high priority
l. p low priority
( h. p )
N ( I . p)
Since,h.p. groups are in opposite direction. So, E configuration will be assigned to double
bond at second position. Hence, full IUPAC name of given compound is 2E-2-bromohex-
2-en-4-yne. Hence , correct option is (C)
MX 4 M 4 4 X
38.
S 4S
K sp [ M 4 ][ X ]4
( S ) (4s )4 256S 5
39. Conceptual
40. Conceptual
41. Conceptual
45. On dilution concentration decreases, degree of ionization increases and Van’t Hoff factor
increases
h
46. x p
4
Where x is same for both electron and helium atom hence p will also be same because
right hand side of expression is constant.
47. Conceptual
N 2( g ) 3H 2( g ) 2 NH 3( g )
48.
(20 g ) (5 g )
20
Moles of N 2 mol
28
5
Moles of H 2 mol
2
Number of moles
Limiting reagent
Stoichiometric coefficient
20
For NH 3
28
5 5
For H 2
23 6
20 5
Clearly, so, N 2 is a limiting reagent.
28 6
1 mole of N 2 forms 2 mole of NH 3 .
20 20 20 10
So, mole of N 2 forms 2 1.42 mol.
28 28 14 7
49. T K f m
0.186 1.86 m
m 0.1
T K b m 0.512 0.1 0.0512]
CH 3
3
5
C CH 2 1
CHO
O CH 2 2
4 CH
CH 3
50. CH 3
( i ) O3
( ii ) Zn / H 2O
KO2 1 6 6 13
NO2 5 6 6 17
ClO2 7 6 6 19
NO 5 6 11
Among the given oxides which are diamagnetic are
Na2O, N 2O, SO2 , Cl2O.
Na2O 1 1 6 8
N 2O 5 5 6 16
SO2 6 6 6 18
Cl2O 7 7 6 20
% of N in25 mL 1M NH 3 will be
14 100
25 =63.63 % =64%.
1000 0.55
53 Given, K b ( H 2O ) 0.52 K kg mol 1
A2 B3 2 A3 3B 2
Tb 1.768
54. 6. b,c,d,e,f,h
55. I,ii,iii,v,vi
C2O 2 4 2CO2 2e 3
56.
3 4
1 molecule = 24 + 4 = 28 electrons
Total electrons = 28 x 3 = 84
Reductant = As2S3
58. 5 b,d,e,g,h
59. 4 B, C, D, E gives haloform test.
60. 7 : a,b,d,g,h,I,j
MATHEMATICS
62. Domain=co-domain
Pntvalue only.
64. For given Quad.to posses real roots its discriminant should be non-negative
Cos 2 p 4Sin p (Co s p 1) 0 We can observe that Cos 2 p 0,1 Cos p 0 x R
For discriminant to be always non-negative Sin P 0
p is 0,
65. Concept Based.
a+2=b
66. 2a b c and b, G1 , G2 , c G1 br , G2 br 2 , C br 3 .
y z
73. x y z 1 x
2 3
B , 2 ,3
2 3
O A 1,1,1
1
1 6
6 3. 14.
2 42
2.
74. l 2 m 2 1 m 21 l 2 m 1 l 2
Let y l m 1 1 l 2
dy 1
1 2l
dt 2 1 l2
dy 2l
0 1 0
dt 2 1 l2
1
1 1 l 2 l 2 2l 2 1
2
1 l
1
1
2
1
maximum value of l+m=1+ 1 l 2 = +
2
1 1 1 2
1 2.
2
2
2 2 2
sin
75. Given f ( ) sin(tan 1 ))
cos 2
sin
Len tan 1 y
cos 2
cos
sin
y
2cos 2 1
On tan ...(ii )
n
2
sin
2In n
On
tan
n
2
1 cos
I n
n cos 2
On n 2
2
I n 1 1 (2 I n / n)
[ from Eq.(i)]
On 2
On
In (1 1 (2 I n / n) 2 )
2
77. Let ABC be an equilateral triangle with vertex A(h,k) centroid G(0,0)
A(h, k )
(0, 0)
G
B D C
(a, b)
AD is to BC
Centroid of an equilateral triangle ratio is 2:1
(a,b) is foot of median on BC
a+b=2 (1)
Vertex(-2,-2).
15Cr 15 r 1 16 r
78. =
15Cr 1 r r
15
16 r 15 15 16 15 16 31
r2 16r r 16 120 16 40 31
2
r 1 r r 1 2 6
79. 3 x 2 4 y 2 36 3x 2 y 1
3
1 1
y log 2 x log 2 2 x 2 x
2 4
2
1
2 x
2
log 2 1
1
x
2
y 1
p ( x1 ,1) Q ( x2 ,1)
x 2 y 2 10, x 2 1 10
X 3
P(3,1)
OP 3i ˆj
OQ i ˆj , 2i ˆj
OP.OQ 4
OP.OQ 7
3 32 33 1
81. l lim18 2 4 6 .... 18 9
n
3 3 3 1
3 1
3
2 22 1
m lim12 2 4 .... 12 12
n
2 2 1
2 1
2
l m 9 12 21
7. Ans.
3 3 3
82. n
3 3 7k k I
3n 7 k 3
Now
3=3(mod7)
32 2 (mod7)
33 1 (mod7)
36 1 (mod7)
2 xy 2 dx ydx xdy 0
PQ PA PB
84. h 1 k 2 6 2 h 3 k 4
2 2 2 2
h 2 k 2 4 h 6k 3 0
a 2, b 3, c 3
So a b c 8
85.
Z max 15 x 10iy
Z min 15 x 40iy
S Z max Z min
S 50iy
S 50
5
5 Ans
10
iˆ ˆj kˆ
Also a c 1 1 1
0 1 1
ac 6
b. a c 2
Now required length of projection l
ac 6
Hence 3l 2 2
87.
Required area
2 2
x {( x x ( x
2 2
2)}dx 2)}dx
1 2
2 2 2 2
x3 x 2 x3 x 2
1
2 2
( x x 2)}dx ( x x 2)dx 2 x 2x
2 3 2 1 3 2 2
2 2 1 1 8 2 2
1 2 2 2 2 4 1 2 2
3 3 2 3 3
6 A 16 2 27 16 2 16 2 27
88.
x2 ( x2 y 2 ) 0
x 0x y 0
x y 0
n3
dx
89. f ( x)
2
3 4x 4 3x 2
1
x
t
1 3 4 3x 2
f ( x) tan 1 c
5 3 5 x2
f (0) 0, c
10 3
1 3
f (1) tan 1
5 3 5 10 3
1 5
f (1) tan 1
5 3 3
5 3
90.
1 1 1 1 4
......
14 24 34 44 90
4
1 1 1 1 1 1
4 4 4 ...... 4 4 4 ......
1 3 5 2 4 6 90
1 1 1 1
4
1 1 1
4 4 4 ...... 4 4 4 4 ....
1 3 5 2 1 2 3 90
1 4
4
1 1 1
4 4 4 ......
1 3 5 16 90 90
1 1 1 4 1 4
4 4 4 ...... 1
1 3 5 90 16 96