SEC: JR_*CO-SC Date: 19-02-22

Time: 3 Hrs Max. Marks: 198

19-02-22_JR.IIT_STAR CO-SC (MODEL-B)_JEE ADV_WAT-40_SYLLABUS
PHYSICS: PRESENT WEEK (80%): Electric flux, Gauss Law, Properties of
conductors, Conducting spheres induced charges & Energy density &
Electrostatic pressure, self energy of spherically charge distributed
bodies
PREVIOUS WEEK (20%): Electric potential energy, potential relation
between field and potential, conservation of energy and potential due
to various continuous charge distributions, complete electric dipole
(Exclude: Gauss law, properties of conductors, electro static pressure,
electro static self energy.)
CHEMISTRY: PRESENT WEEK (80%): Electrochemistry: Galvanic Cells, Nernst
Equation, Oxidation, Reduction, Strength of Oxidsing and reducing
agents, electrochemical series, Concentration cells
PREVIOUS WEEK (20%): Benzene: Preparations reactions of benzene
and alkyl benzenes, Electrophilic aromatic substitution, mechanism of
halogenations, nitration, sulphonation, nitrosation, alkylation and
acylation, General EAS ,directive influence of groups and activating –
deactivating groups
MATHEMATICS: PRESENT WEEK (80%): Parabola: Equation of Parabola, Equation of
Parabola ( Standard from, Foci, Directrix, Eccentricity, Parametric
form), Tangent and its Properties, Chord of contact
PREVIOUS WEEK (20%): Family of Circles, Angle between two
Circles, Common chord, Chord whose midpoint is given, Direct,
Transverse, Pair of tangents
Narayana IIT Academy 19-02-22_JR.IIT_*CO-SC(MODEL-B)_JEE-ADV_WAT-40_Q’P
CHEMISTRY MAX.MARKS: 66
SECTION – 1 (Maximum Marks: 18)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONLY ONE of these four option is the correct answer.
For each question, choose the correct option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If only the correct option is chosen.
Zero Marks: 0 If none of the option is chosen.(i.e the question is un answered)
Negative Marks: -1 In all other cases.

19. The solution of nickel sulphate, in which a nicked rod is dipped, has been diluted
10times. The potential of the nickel electrode
 2.303RT 
  0.06 
 F 

A) decreases by 60 mV B) increases by 30m V

C) decrease by 30mV D) increases by 60mV
20.

Product of this reaction is:

21. Given standard electrode potentials

Fe 2  2e   Fe; E 0  0.44 V ....(i )

Fe3  3e   Fe; E 0  0.336 V ....(i )

The standard electrode potential E0 for Fe3  e  Fe2 is

A) 0.476 V B) 0.404V C) 0.404V D) 0.772V

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Narayana IIT Academy 19-02-22_JR.IIT_*CO-SC(MODEL-B)_JEE-ADV_WAT-40_Q’P
22.  2 Ag  S 2 in a
Calculate the cell potential of a cell having reaction: Ag 2 S  2e 
solution buffered at pH=3 and which is also saturated with 0.1 M H2S. For
H 2 S : K1  108 and K 2  1.1 10 13 , K sp ( Ag 2 S )  2  10 49 , E Ag
0

/ Ag
 0.8

A) 1.7658 B) 0.1658 C) 0.9658 D) 0.9658

23. Acetic acid has K a  1.8  104 where formic acid has K a  2.1104 What would be the
magnitude of the emf of the cell

0.1M acetic acid  0.1M formic acid 

Pt  H 2  Pt  H 2  at 250 C ?
0.1M sodium acetate 0.1 M sodium formate

A) 0.032 Volt B) 0.063 Volt C) 0.0458 Volt D) 0.055 volt

24. Consider the cell Ag ( s ) AgBr ( s ) Br  (aq ) Cl   aq  AgCl ( s ) Ag ( s ) at 250C. The solubility
product constants of AgBr & AgCl are 5 1013 &11010 respectively. For what ratio of
- -
the concentration of Br & Cl ions would the emf of the cell be zero ?
A) 1: 200 B) 1:100 C) 1: 500 D) 200 :1

SECTION - 2 (Maximum Marks : 24)

This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which
are correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.

25. Which among the following statement (s) is/are correct?

A) If E A0 n / A is negative , H+ will be reduced to H2 by the element ‘A’

B) Compounds of (Zn, Na, Mg) are reduced by hydrogen (H2) where as those of noble
metals (Cu, Ag, Au) are not reducible
C) If E A0 n / A is positive, An+ will be reduced to A by H 2

D) M M n H  H 2  Pt  will be spontaneous if EM0 n

/M
is negative

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Narayana IIT Academy 19-02-22_JR.IIT_*CO-SC(MODEL-B)_JEE-ADV_WAT-40_Q’P
26. Electrote potential data are given below

Fe3  aq   e   Fe 2  aq  ; E 0  0.77V

Al 3  aq   3e   Al  s  : E 0  1.66V

Br2  aq   2e   Br   aq  ; E 0  1.08V

Based on the given data which statements is/are true?

A) Fe2+ is stronger reducing agent than Br 

B) Fe2+ is stronger reducing agent than Al

C) Al is stronger reducing agent than Fe2+

D) Br- is stronger reducing agent than Al

27. For the reducing of NO3 ion in an aqueous solution, E 0 is +0.96V. Values of E 0 for some
metal ions are given below:
V  s  E 0  1.19V ....(i )
V 2  aq   2e  Fe3  aq   3e  
 Fe  s  E 0  0.04V .....(ii )

 Au  s  E 0  1.40V .....(iii )
Au 3  3e  Hg 2  aq   2e 
 Hg    E 0  0.86V .....(iv)

The pair (s) of metals that is oxidised by NO3 in aqueous solutions is (are):
A) V and Hg B)Hg and Fe
C) Fe and Au D) Fe and V
28. Which of the following reactions are least possible by Friedel-Craft acylatoin as per
expectation?

A) B)

C) D)

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Narayana IIT Academy 19-02-22_JR.IIT_*CO-SC(MODEL-B)_JEE-ADV_WAT-40_Q’P
29. Peroxodisulphates salts  Na2 S2O8  are strong oxidizing agents used as leaching agents
for fats, oil etc. Given
O2  g   4 H   aq   4e   2 H 2O    E 0  1.23V

S 2O82  2e   2SO42  aq  E 0  2.01V

Which of the following statements is (are) correct?

A) Oxygen gas can oxidize sulphate ion to per-oxo disulphate ion  S2O82  in acidic
solution
B) O2  g  is reduced to water

C)Water is oxidized to O2

D) S2O82 ions are reduced to SO42 ions

30. In which of the following reaction, tert-butyl benzene is formed as major product?

A) B)

C) D)

SECTION - 3 (Maximum Marks : 24)

This section contains SIX (06) questions. The answer to each question is a NUMERICAL VALUE
For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
numeric keypad in the place designated to enter answer. If the numerical value has more than two decimal
places truncate/round- off the value to TWO decimal places.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
31. Cu 2  aq   Zn  s   Cu  s   Zn 2  aq  ; E 0  1.1V

Zn 2  aq   2e   Zn  s  ; E 0  0.76V
2
Cu 2  aq   4 NH 3  aq   Cu  NH 3 4   aq  ; K eq  1020 is:
2.303RT
If  0.06 , then the E 0 of following reaction
F
2
Cu  s   4 NH 3  aq   Cu  NH 3  4   aq   2e  is

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Narayana IIT Academy 19-02-22_JR.IIT_*CO-SC(MODEL-B)_JEE-ADV_WAT-40_Q’P
32. A zinc electrode is placed in a 0.1M solution at 250C.Assuming that the salt is 20%
dissociated at this dilutions, calculate the electrode potential. E 0  Zn 2 Zn   0.76V .

33. From the standard potentials shown below , calculate standard potential of BrO3 / Br2

1
BrO3 
0.54V
 BrO  
0.45V
 Br2
2

34. Calculate E 0 for the following reaction at 298K ,

Ag  NH 2  e  

 Ag  2 NH 3

 0.7991V , K diss.  Ag  NH 3 2   6.02 108

0 
: E Ag 
/ Ag  

35.

Find the molecular weight of ‘P’

36. The standard reaction potential of AgCl/Ag electrode is 0.2 V and that of silver
electrode (Ag+/Ag) is 0.79V. The maximum amount of AgCl that can dissolve in 106 L
of 0.1M AgNO3 solution is (in milli moles)

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Sec: JR.IIT_*CO SC(MODEL-B) WAT-40 Date: 19.02.22
Time: 3 Hrs 2020_P1 Max. Marks: 198
KEY SHEET
PHYSICS
1 D 2 C 3 C 4 A 5 A
6 B 7 CD 8 ABD 9 ABD 10 CD
11 ABC 12 BC 13 7.91 14 1.05 15 18.00
16 1.00 17 56.00 18 4.00

CHEMISTRY
19 C 20 D 21 D 22 B 23 B

24 A 25 ACD 26 AC 27 ABD 28 BCD

29 CD 30 ABCD 31 0.28 32 -0.81 33 0.52

34 0.37 35 106 36 1

MATHEMATICS
37 A 38 B 39 D 40 C 41 B

42 D 43 AC 44 BD 45 AD 46 BD

47 ABC 48 AC 49 6 50 9 51 5

52 48 53 4 54 2
Narayana IIT Academy 27-02-22_JR.IIT_*CO-SC(MODEL-B)_JEE-ADV_WAT-41_Q’P
CHEMISTRY Max.Marks:62
SECTION – I
(SINGLE CORRECT CHOICE TYPE)
This section contains 4 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out of which ONLY ONE is correct.
Marking scheme +3 for correct answer , 0 if not attempted and -1 in all other cases.
19. Which of the following aqueous solution will not liberate Hydrogen gas at cathode

A) AlCl3 B) MgCl2 C) AgNO3 4) ZnSO4

20. The standard electrode potentials, E 0 of Fe3 / Fe 2 and Fe 2 / Fe at 300 K are 0.77V
and 0.44 V , respectively. The E 0 of Fe3 / Fe at the same temperature is

A) 1.21 V B) 0.33 V C) 0.036 V D) 0.036

 Sn 2 
21. For an electrochemical cell, Sn  s  Sn  aq, xM 
2
Pb  aq, yM  Pb  s  , the ratio
2

 Pb 2 

When this cell attains equilibrium is

 
 Given : ESn2 / Sn  0.14V , EPb2 / Pb  0.13V ,
0 0 2.303RT
 0.06   Anti log  0.33  2.14
 F 

A) 4.3 B) 1 C) –2.15 D) 2.14

22. Given below are the half-cell reactions Mn 2  2e  

 Mn E 0  1.18V

Mn 3  e  
 Mn 2 E 0  1.51V

The E 0 for 3Mn 2 

 Mn  2 Mn 3 will be

A) 2.69V ; the reaction will not occur B) 2.69V ; the reaction will occur

C) 0.33V ; the reaction will not occur D) 0.33V ; the reaction will occur

SECTION – II
(MULTIPLE CORRECT CHOICE TYPE)
This section contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out of which ONE OR MORE is/ are correct.
Marking scheme +4 for correct answer , 0 if not attempted and -1 in all other cases.
23. The molar conductivity of aq.NaCl solution varies with concentration as
 m   m  b C .Here  m &  m are molar conductivity at concentration C and at infinite

dilution respectively and ' b ' is constant. Consider the data

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Narayana IIT Academy 27-02-22_JR.IIT_*CO-SC(MODEL-B)_JEE-ADV_WAT-41_Q’P
Molar concentration (M)  m
2 1 
 S cm mol 
 
1 10 4 150
0.4  10 3 
9  104 50
Y 75
Select the correct statement(s).

A)  m for NaCl is 200 S cm 2 mol 1 B)  m for NaCl 400 S cm 2 mol 1

C) Value of X is 100 D) Value of Y is 2.5 105

24. Which of the following electrodes are used as a reference electrode?

A) Hydrogen electrode with 2 atm pressure of H 2 and 2 M and HCl at 200o C

B) Saturated calomel electrode

C) F2  g  / F  aq  electrode

D) Standard hydrogen electrode

25. The E 0 for the following reaction is given below


i) M  M   e  ; E 0  4.2V ii) A 
e
 A1 ; E 0  3.2V

iii) B   B  e  ; E 0  5.0V iv)C 
e
 C1 ; E 0  4.7V

v) D 
e
 D1 ; E 0  4.2V

Which of the following electrolyte cannot be used for electro refining of the metal M?

A) MA B) MB C) MC D) MD

26. Consider the half cell : Ag 2 S  s   2e  2 Ag  S 2 . If reaction occurs at pH  3 and

saturated with 0.1 M H 2 S At 25o C , the following data is given

 Ka1  H 2 S 108
 Ka 2  H 2 S 1013
 K  Ag S
sp 2
1 10 49
0 0.8V
EAg  / Ag

Ecell at 250 c Xv
The correct statement (s) is/are

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Narayana IIT Academy 27-02-22_JR.IIT_*CO-SC(MODEL-B)_JEE-ADV_WAT-41_Q’P
A) If P H . of reaction is 2 then e.m.f of reaction increases (assume all other parameters
are same)

B) If temperature of reaction increases ( P H is maintained at 3 by external factor) then

E 0 and E both of the reaction always increases

C) If temperature of reaction increases ( P H is maintained 3 by external factor) then

E 0 increases but E may or may not increase

D) If temperature of reaction increases ( P H is maintained at 3 by external factor ) then

E increases but E 0 may or may not increase

27. Which substance is obtained in the solution on electrolysis of aqueous CuSO4 solution
using graphite electrodes?

A) Cu  OH 2 B) Na2 SO4 C) H 2 SO4 D) H 2O

28. A conductivity cell contain aqueous solution of NaCl . If this solution is diluted, then
which of the following is/are changed?

A) Conductivity (K) of solution B) Molar conductivity   m  of solution

C) Concentration of solution D) Conductance of solution

29. The increase in equivalent conductivity of a weak electrolyte with dilute is due to:

A) Increase in degree of dissociation and decrease in ionic mobility

B) Decrease in degree of dissociation and decrease in ionic mobility

C) Increase in degree of dissociation and increase in ionic mobility

D)Decrease in degree of dissociation and increase in ionic mobility

30. The molar conductance of HCl , NaCl and CH 3COONa are 426, 126 and 91 1 cm 2 mol 1
respectively. The molar conductance for CH 3COOH is-

A) 561 1cm 2 mol 1 B) 391 1cm 2 mol 1

C) 261 1cm 2 mol 1 D) 612 1cm 2 mol 1

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Narayana IIT Academy 27-02-22_JR.IIT_*CO-SC(MODEL-B)_JEE-ADV_WAT-41_Q’P
SECTION – III
(NUMERICAL VALUE ANSWER TYPE )
This section contains 6 questions. The answer to each question is a Numerical values comprising of positive
or negative decimal numbers (place value ranging from Thousands Place to Hundredths place).
Eg: 1234.56, 123.45, -123.45, -1234.56, -0.12, 0.12 etc.
Marking scheme : +3 for correct answer, 0 in all other cases.
31. How many expressions are correct for an electrochemical cell?
 E 
(i) S  nF  cell 
 T  P
 G 
(ii) G  H  T  
 T  P
 H   Ecell 
(iii) Ecell    T  
 F   T  P
(iv) H  nF ECell (when temperature coefficient is zero)
 G 
(v) S    
 T  P
(vi) dG  Vdp  SdT
32. Molar conductivity of a solution of an electrolyte AB3 is 150 Scm 2 mol 1 . If it ionizes as
AB3  A3  3B  , its equivalent conductivity will be  in S cm 2 g equiv 1 

33. The conductivity of a saturated solution of AgBr at 298K is 8.5 107 S cm 1. If Ag  and
Br  are 62 and 78 S cm 2 mole 1 respectively, then solubility of AgBr is 6.07  10  x . Find
the value of x.
34. The conductivity of 0.20 M solution of KC1 at 298 K is 0.0248 S cm1 . Calculate its
molar conductivity.
35. No: of faradays required to deposit 9 gm of Aluminum, when 5 moles of fused AlCl3 is
electrolysed
36. Consider a 70% efficient hydrogen – oxygen fuel cell working under standard
conditions at 1 bar and 298K. Its cell reaction is
1
H 2  g   O2  g   H 2O  l 
2
The wok derived from the cell on the consumption of 1.0  103 mol of H 2  g  is used to
compress 1.00 mol of a monoatomic ideal gas in a thermally insulated container. What
is the change in the temperature (in K) of the ideal gas?
The standard reduction potentials for the two half-cells are given below.
O2  g   4 H   aq   4e  2 H 2O  l  , E 0  1.23V ,
Use F  96500 C mol 1 , R  8.314 J mol 1K 1

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Sec: JR.IIT_*CO SC(MODEL-B) WAT-41 Date: 27.02.22
Time: 3 HRS 2019_P1 Max. Marks: 186
KEY SHEET
PHYSICS
1 B 2 A 3 A 4 A 5 A
6 ABC 7 ABD 8 ABC 9 ACD 10 ABC
11 A 12 BC 13 0 14 4 15 9
16 6 17 4 18 4

CHEMISTRY
19 C 20 C 21 D 22 A 23 AC

24 BD 25 AD 26 AC 27 C 28 ABCD

29 C 30 B 31 4 32 50 33 6

34 124 35 1 36 13.32

MATHEMATICS
37 C 38 A 39 A 40 C 41 ABCD

42 BCD 43 AC 44 AC 45 ACD 46 BC

47 BCD 48 ACD 49 9 50 3 51 8

52 3 53 8 54 5
Narayana IIT Academy 27-02-22_JR.IIT_*COSC(MODEL-B) _WAT-41_Key&Sol’s

CHEMISTRY
19. Discharge potential for Ag is lower than H 


E 0 Fe3 / Fe2  2 E 0 Fe2 / Fe

20. E Fe3 / Fe 
0

3
0.77  0.88

3
0.11

3
 0.036 V
21. Ecell  0 at equilibrium
E 0 cell  0.01
 Sn 2  0.01
log  2
 Pb 2  0.06
 Sn 2 
 2.14
 Pb 2 

 ERe d  EOxi   1.18   1.51  2.69V

0 0
22. Ecell
1
23. 150   m  b 104  2 .....(i)
1
X   m  b  0.4 103  2 .....(ii)
1
50    b  9 10

m
4 2
 .....(iii)
1
75   m  b  y  2 .....(iv)
Solving (i) & (iii), we get
 m  200 and b  5000
Putting values of  m and b, we get
X  100 S cm 2 mol 1 and Y  6.25 104 M
24. Conceptual
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Narayana IIT Academy 27-02-22_JR.IIT_*COSC(MODEL-B) _WAT-41_Key&Sol’s
25. Conceptual
26. For reaction
Ag 2 S  2e    2 Ag  S 2
2.303RT
E 0  0.8  log K SP
2F
2.303RT 2.303RT
E  E0  log K SP  log  S 2 
2F 2F
2.303RT K
E  E0  log 2SP
2F  S 
27. Conceptual
28. NaCl is strong electrolyte. On dilution conductivity (K) decreases whereas molar conductance and
equivalent conductance increases (due to decrease in interionic attractions). Also concentration
decreases as volume increases
29. Conceptual
30.  CH 3COOH   CH 3COONa   HCl   NaCl
 91  426  126
 391 ohm 1 cm 2 mole 1
31. statement (i), (ii), (v) and (vi) are correct
dG  Vdp  SdT
 G 
   S
 T  P
G  H  T S
 G 
 H  T  
 T  P
  E  
 H  T  nF   
  T  P 
 E 
 H  nFT  
 T  P
32.  m   e  nfactor
33. Solubility  6.07  106 mole / hit
Ksp   6.07  106 
2

 36.85  1012 mole 2 / hit 2

1000
Solution:  AgBr  KAgBr 
N AgBr

 Ag  
 Br   8.5  107 
1000
N
8.5 107  1000
N
140
N  S  6.07  106
1000
34.  K
M
1000
 0.0248 
0.2
 0.0124 1000  124 ohm 1cm 2 mole 1

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