1

Chapter 1

Structure of Atom

SOLUTIONS

ASSIGNMENT
1. Answer (1)

2KZe2
vn =
nh
vn  e 2
2. Answer (1)
3. Answer (2)
4. Answer (2)
Let percentage abundance of 3a be x.
9 3a  x + 2a (100 − x )
a=
4 100
 a = 25
5. Answer (2)
n–1=3n=4
p = 6 and q = 2
6. Answer (2)
7. Answer (4)
8. Answer (1)
9. Answer (4)
10. Answer (3)
 1 1
 = RZ2  2 − 2 
 n1 n2 

 = 0.31 107 m−1

  = 322.5 × 10–9 m
11. Answer (4)

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12. Answer (4)

From the graph,
Radial node = 1
Nodal plane = 1 (given)
So, it is 3p orbtial.
So, n + l = 4
13. Answer (2)
14. Answer (2)
According to Planck's,
E = nh
n = 1, 2, 3, ......
h  energy of one photon
So, energy can be 10, 20, 30, 40 ......
15. Answer (1)
16. Answer (4)
For nth orbit,
nh
mvrn =
2
nh
mv(n2 x) =
2
h
mv =
2nx

h
=  2nx = 8x
mv
n=4
17. Answer (1)
18. Answer (1)
19. Answer (1)
Maximum energy of photon in H-spectrum is observed when electron makes a transition from n →  to
n → 1. So, minimum wavelength is 912 Å.
20. Answer (3)
21. Answer (16)
n2
radius 
Z
9
R=K
1
16
R2 = K
3
R 27 16
=  R2 = R
R2 16 27

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22. Answer (7)

4th orbit has 4s, 4p, 4d and 4f sub-shells out of these 4f sub-shell has zero radial node.

1
Hence, number of electrons having zero radial node and ms value of − is 7.
2
23. Answer (4)

Z2
E
n2
24. Answer (300)

hc
E=


6.63  10−34  3  108

6.63  10−19 =


 = 3  10 −7 m
= 300 × 10–9 m
= 300 nm
25. Answer (2)

h
=
mv

m2
6.626  10 −34 kg  sec
 mv =
h
= sec 2
−10
 3.3  10 m

6.626  10−24
mv = = 2  10−24 kg m sec −1
3.3

1 2
Kinetic energy = mv
2

(mv )2
=
2m

( 2  10 )
2
−24

=
2  9.1 10−31 kg

= 2.18 × 10–18 J
= 21.8 × 10–19 J
Total energy = Ionization + Kinetic
absorbed energy energy

= (21.76 + 21.8) × 10–19

= 43.56 × 10–19 J

 2 times of 21.76 × 10–19 J

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26. Answer (548)

h
x.v 
4m
x = 2 × 52.9 × 10–12 m
6.63  10–34
v 
4  3.14  9.1 10–31  2  52.9  10–12

v  5.48  10 –4  109 m/s

v  548 km/s (Rounded off to the nearest integer)
27. Answer (4)
Since there is a single hydrogen atom, so only 5 → 4, 4 → 3, 3 → 2, 2 → 1 lines are obtained.
28. Answer (4)
48 3 −
Number of electrons in 22 X is 25.

Number of neutrons = 48 – 22 = 26.

 26 − 25 
% increase in the number of neutrons over electrons =   100 = 4%
 25 
 a=4
29. Answer (1)
Energy required for ionisation of Li2+ ion in its ground state
= 2.2 × 10–18 × 9 J
hc
E=


6.63  10−34  3  108

2.2  10−18  9 =


 = 1 10 −8 m

❑ ❑ ❑

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