SRI CHAITANYA IIT ACADEMY, INDIA 02-12-23_Sr.

Elite & Target _Jee-Main_RPTM-15_KEY & Sol'S

Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI
A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Sr. Elite & Target(C-120, C-IPL & IPL-IC) JEE-MAIN Date: 02-12-2023
Time: 09.30Am to 12.30Pm RPTM-15 Max. Marks: 300
KEY SHEET
PHYSICS
1) 3 2) 2 3) 2 4) 2 5) 3
6) 3 7) 1 8) 2 9) 4 10) 1
11) 3 12) 1 13) 2 14) 2 15) 4
16) 3 17) 2 18) 4 19) 4 20) 2
21) 5 22) 3 23) 3 24) 2 25) 2
26) 80 27) 8 28) 15 29) 4 30) 15

CHEMISTRY
31) 3 32) 4 33) 3 34) 4 35) 1
36) 4 37) 4 38) 1 39) 2 40) 3
41) 2 42) 3 43) 1 44) 4 45) 4
46) 4 47) 3 48) 1 49) 2 50) 2
51) 7 52) 0 53) 32 54) 8 55) 36
56) 10 57) 5 58) 62 59) 2 60) 4

MATHEMATICS
61) 3 62) 1 63) 3 64) 3 65) 2
66) 1 67) 2 68) 4 69) 4 70) 1
71) 2 72) 3 73) 2 74) 1 75) 1
76) 2 77) 3 78) 3 79) 4 80) 3
81) 6 82) 1 83) 15 84) 392 85) 0
86) 17 87) 169 88) 4 89) 33 90) 6

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 SRI CHAITANYA IIT ACADEMY, INDIA 02-12-23_Sr.Elite & Target _Jee-Main_RPTM-15_KEY & Sol'S

SOLUTIONS
PHYSICS
mvSin 2 m
1. r , T
Bq Bq
Bc
2. Ba  3/2
 x2 
1 
 R2 
 
3. Force between wires A and B = Force between wires B and C.
 0 I 2l
FBc  FAB 
2 d

As FAB  FBC

 0 I 2l
Net force on wire B Fnet  2 FBC  2
2 d
Fnet  I2
 0
l 2 d
4. The Direction of magnetic field due to both the wires AO and OC are out of the page of
paper due to wire OC.
 0i i
B sin 1  Sin2   0  Sin  90   / 2   sin 900   d  rSin / 2
4 d 4 d
0i
B 1  cos  / 2
4 rS in  / 2
0i
Due to both the wires, the net magnetic field is B  2  1  cos  / 2
4 rS in  / 2

0i 1  cos  / 2
B
2 rS in  / 2

   
  1 1 1  1 1     1 1  1  
5. B  0     .......  K     ........  K   0  K  K
2  1 4 16  2 8   2   1  1  2  1  
1
  4    4   

2 0 2 4  10 7
B 7
K   2  10 K  K  1.33 107 K
3 2 3 3

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 SRI CHAITANYA IIT ACADEMY, INDIA 02-12-23_Sr.Elite & Target _Jee-Main_RPTM-15_KEY & Sol'S

6.

i i
O

Bnet = 3B each Side

 0i  a  i 3
Bnet  3.
4 r
 Sin600  Sin600   r    3. 0 2 3  2 
4 a 2
 2 3

0i 18  107  3
Bnet  18   4.5  105 T 
4 a 4 3  10 2

7. M  M1  M 2   I r12  I r22

  0.4 2    0.3 2    40 
2
 30 
2

 I     K r1  
2
 r 
2

 100   100  
2
 100   100 

22  16 9  22 7
 9    K  9  K  1.96KAm2
7 100 100  7 100
8. A-II
b I
a
r
c d
I
0 I
Bab  (Out of the plane)
4 r
0 I
Bbcd   (Out of the plane)
4 r
0 I
Bdc  (Out of the plane)
4 r
0 I I
Bnet  Bab  Bbcd  Bde  1    1  0  2    Out of the plane
4 r 4 r
10 7  2
 2 
  2     2   105
2  10
B-I

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 SRI CHAITANYA IIT ACADEMY, INDIA 02-12-23_Sr.Elite & Target _Jee-Main_RPTM-15_KEY & Sol'S

c
r
O

a I e
I bd

0 I
Bab  Bde  (Out of the plane)
4 r
0 I
Bbcd  .2 (Into the plane)
4 r
0 I I 2  10 7  2
Bnet  Bab  Bbcd  Bdc   2  2  0   1    1  2   1105
4 r 2 r 2  10 2

C-IV

a b O d e
r
I
c
Bab  Bde  O (at the axis)

0 I
Bbcd  .   (Out of the plane)
4 r
0 I
Bnet  Bab  Bbcd  Bdc  0  0
4r
0 I 2
Bnet     10 7    105 T
4r 2  102
D-III
e

d
O
c
r
b a

0 I
Bab  . (Into the plane)
4 r
0 I
Bbcd   (Into the plane)
4 r
Bdc  0 (at the axis)

0 I 107  2    1
Magnetic filed at ‘O’ is Bnet  Bab  Bbcd  Bdc    1 
4 r 2  102
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 SRI CHAITANYA IIT ACADEMY, INDIA 02-12-23_Sr.Elite & Target _Jee-Main_RPTM-15_KEY & Sol'S

Bnet    1  105 T

9. Conceptual
10. Explanation:-In uniform magnetic field

 
F  q V  B . So F  V  a  V

So speed and kinetic Energy remain’s same.

mv 2mK
r 
qB qB
m
11. r
q
rp  m   2e 
   1
r  4m   e 

The α-particle and the proton will be bent in a circular path with the same radius.
1 d
12. I  .
R dt
dr
13. Here B=0.02T.  1mm / s  10 3 m / sec
dt
r  4cm  4 102 m e?
  BA  B  r 2 

d d  B r 
2
dr
e   B 2 r
dt dt dt
22
e  0.02  2   4  102  103  5  106 V  5  v
7
360  2 22
14. e  BAN  6  14  102  200   84  12  2   12  24  22
60 7
e  6336V
15. e  BlV
0.16  0.8  0.1 V
16
V  2m / s
8
16. 12 I
12  MI

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 SRI CHAITANYA IIT ACADEMY, INDIA 02-12-23_Sr.Elite & Target _Jee-Main_RPTM-15_KEY & Sol'S

BN2 A  MI

0 I   0 N1 I 
2r2
.N1 N 2 A  MI  B  
 2r2 

0
N1 N 2 r12  M
2r2

4  10 7  20  200     2  102 
2

2
 M  32  108 H
2  1000  10
17. P  Fv  BIlv  1.25  103  50  0.1  1W  6.25  103W  6.25mW
18. Co-efficient of mutual inductance M is given by
e1 
M   2
 di2 / dt  i1

 2 
e1i1

 25.0  10 3
  3.6   6 10 3
 6mWb
 di2 / dt  15

19. As the coil rotates, the magnetic flux linked with the coil (being B. A ) will change and
emf may be induced in the loop
20. Lenz’s Law gives the nature or polarity of induced emf or the direction of current.
21. F q V B  
ma  q V  B  
here a  B So a.B  0

 2i  x j  4i  5 j   0
8  5x  0
8
x
5
22.

O 300 d
300

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 SRI CHAITANYA IIT ACADEMY, INDIA 02-12-23_Sr.Elite & Target _Jee-Main_RPTM-15_KEY & Sol'S

0 In
B each = (sin 1  sin  2 )
4 d

0 In  3a  0 I n 1
B
3a
 Sin30 0
 Sin300   d  
2  4 3 a
2 2
2
4 
2
0 In
Beach 
2 3 a
Now, magnetic field due to one hexagon coil Bnet = 6 Beach
0 In  I 3 100  100 I
B  6  0 .  2000 3 0 .
2 3 a  a 5 
23.

I
B

I

Force F  BilSin
mgSin  Bil cos 

Bil Bi  l  0.15  30
Tan      3
mg g  m  10  0.15 3

Tan  3

  600  .
3
24. C  BIAN
C 106  2 
B  3 4
  102 T
IAN 180  10  10  2  200 36
25. Magnetic field due to solenoid is given by
B2 n2 I 2 n 4 I
B  0nI B  nI   2
B1 n1I1 2nI

B2  2B1

x'  2

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 SRI CHAITANYA IIT ACADEMY, INDIA 02-12-23_Sr.Elite & Target _Jee-Main_RPTM-15_KEY & Sol'S

26. Here we note that the field is a simultaneous function of y and t. Let us first calculate the
flux associated with the loop. For that let us consider a rectangular strip of length l,
thickness by at a distance y from the x-axis. Then the flux associated with strip is
at 2l 3  l2 
1 1
d  BdA  Bldy  d  at yldy     d  at  ydy   
2 2
  ydy  
0
2  0 2
y

B
l dy

O x
l

d
Now, according to Faraday’s Laws, we have e 
dt
27. Let the connector be displaced through dy, then
d  BdA  B  2 x  dy

d  dy 
e  e  B  2x   
dt  dt 

y  dy   y 
 e  2B    x  
k  dt   k 

y  dy 
 e  2 B     2ay 
k  dt 

y 8a
 e  2 B 2ay  e  By
k k
28. Conceptual
di
29. eL
dt
30. e  Blv  0.1 3  102  5  3  5  103  15mV

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CHEMISTRY
31. Lanthanides forms LnC2 , Ln2C3 , Ln3C type carbides.
32. Plutonium 5 f 6 7 s 2
Neptunium 5 f 4 6 d 1 7 s 2
Curium 5 f 7 6 d 7 7 s 2
Eienstenium 5 f 11 7 s 2
33. Secondary valency of PtCl2 .2 NH 3 is four, so no chloride ions are present

34. In the compounds [Co(NH3)5NO2]Cl2, the oxidation state of cobalt is +3 and here 5 NH3
ligand, a NO2 ligand are attached to the central atom. Therefore its name is
Pentaamminenitrito – N – cobalt(III) chloride

35. Fe2 4S 0 3d 6 it has no unpaired electrons.

36. Cu  H 2O 4  SO4 .H 2O it has only one hydrogen bonded water molecule .

37. K 4  Fe  CN 6   In Potassium ferrocyanide Fe has no unpaired electron hence diamagnetic.

K3  Fe  CN 6   in Potassium ferricyanide Fe has unpaired electron hence para magnetic.
38. Both statements I and II are correct
39. K 2  HgI 4  Nessler’s reagent
2
 Fe  H 2O 5 NO  brown ring complex
40. Complex with different ligands are heteroleptic.
41. Zr (40) and Hf (72) are in the same group. Because of lanthanide contraction they have
nearly same size
42. In lanthanide series there is a regular decrease in the atomic as well as ionic radii of
trivalent ions (M3+) as the atomic number increases. Although the atomic radii do show
some irregularities, but ionic radii decrease from La (103 pm) to Lu (86pm).

 Ni(CN ) 4 
2

43. EAN  28  2  2  4   26  8  34
and for other its 36

44. Sodium nitroprusside is Na2  Fe  CN 5 NO 

Oxidation number of iron is 2

2  x  5 1  0 X  2
45. Kjeldahl’s method is applicable to Aniline.
46. Dumas method is used for the estimation of nitrogen only.
230
47. Moles of N in N, N-dimethylaminopentane   2 moles
115
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45 17 1 45
 C7 H17 N  CuO  7CO2  H 2O  N 2  Cu
2 2 2 2
45
For (0.5) moles of number of moles of CuO required  2   45
2
48. Basicity of sulphuric acid is 2
1
Milli eq. of sulphuric acid taken = 80   2  32
5
2
Milli eq. of sulphuric acid used by NaOH = 40   16
5
Milli eq. reacted with NH3 =32-16 =16
16
% of N in the compound = 0.14   8%
2.8
49. In carius method, the halogen is precipitated as silver halide by heating the compound
with fuming HNO3 and AgNO3.
12 wt of CO2
50. % of C =   100
44 wt of compound

2 wt of H 2O
% of H=   100
18 wt of compound

% of O =100 - % of C + % of H=100−(20.04+6.66)=100−26.70
%∴O=73.29 %
51. Ziegler Natta catalyst Al (C2 H5 )3  TiCl4 3 4  7

52. Primary valency(x)=3

secondary valency(y) =6
53. Group III-B(Along with lanthanides and actinides)
54. K 2 SO4 . Al2  SO4 3 .24 H 2O
2
2 K  , 2 Al 3 and 4SO4 ions

55. EAN = Atomic number - Oxidation state + 2 * number of ligands

Atomic number of Iron = 26

Oxidation number = +2

no. of ligands = 6

EAN of Fe2+= 26 -2 + (2 x 6) = 36

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35.5 0.286
56. % of Cl =   100  10%
143 0.71
32 0.466
57. % of S =   100  5%
233 1.28
atomic mass of p mass of Mg 2 P2O7
% of p    100
mol. mass of Mg 2 P2O7 mass of compound
58.
62 0.222
% p   100  62%
222 0.10

 y y z  y
59. C2 H 7 N   2 x   CuO  xCO2  H 2O  N 2   2 x   Cu ………..(1)
 2 2 2  2
 y y z  y
Cx H y N z   2 x   CuO  xCO2  H 2O  N 2   2 x   Cu ……….(2)
 2 2 2  2
From (1) and (2), X=2, y=7 and z=1
60. Carius method is used in the estimation of sulphur in an organic compound

MATHEMATICS
61. S  1,2,3,4,5,6 nS   6

` the event A  4,5,6 n  A  3

the event B  1,2,3,4 n B  4

A  B  4

n  A  B  1

P  A  B n A  B 1
 P  A / B   
P B n  B 4

drawn two balls from 

62. Event E1   
bag I is both are black 
4
C2 2
P  E1   7

C2 7

3
C2 1
Event E2  both are red   P  E2   7

C2 7

C1  4C1 4
3
Event E3  one black , one red   P  E3   7

C2 7
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Let the event  After transforming balls from I to II the drawn ball from II is red
4 6
C1 2 C1 3
P  A / E1   10
 , P  A / E2   10

C1 5 C1 5

5C1 1
P  A / E3   
10C1 2

P  E1  P  A / E1 
 P  E1 / A  
P  E1  P  A / E1   P  E2  P  A / E2   P  E3  P  A / E3 
2 2
  4 4
75
  
2  2  1  3  4  1  4  3  10 17
     
75 75 7 2

6 1 5
63. PB  P  getting a total sum of 7 on a pair of dice    q A  1  PA 
36 6 6

3 1 11
PB  P  getting a total sum of 10 on a pair of dice    qB  1  PB 
36 12 12

Given that, A starts the game

P  B   P  B wins the game 

5  55  55  
2
5  1  5  11  5  1 
 q A PB  q AqB q A PB  ............          ..........  1      ..........
6  12  6  12  6  12  72  72  72  

 
5  a  5  1  5  72  5
      
72  1  r  72  1  55  72  72  55  17
 72 

1 2
64. Given that, the probabilities occurring of mark n is for n  2, 4,8,16,32 and for
n n
n  64 .

1 1 1 1 1 2 1
 p  2   , P  4   , P  8   , P 16   , P  32   , P  64   
2 4 8 16 32 64 32

Possible cases 2,2,4,64. And 8,16,16,32.

 1  1  1  2  1  1  1  1 
 Required probability           
 2  2  4  64  8  16  16  32 

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1  1  1 1  1  1  1  1  1  1  1 
        1      4 5 1  3 4 
16  32  8  16  16  32  16  32   8  16   2  2   2  2  
 

1  27  1  2 7  1
 9  7   16
2  2  2

65. Total letters =12

Those are 1S,1R,2I’S 1C, 1H, 3A’S,1T,1N,1Y are alike

10!
 Required probability  2!3!
12!
2!3!

1 1

12  11 132

66.  
P A  0.14

 
P  A   1  P A  1  0.14  0.86

 
P  B   1  P B  1  0.1  0.9

 
P  C   1  P C  1  0.05  0.95

Given that A,B,C are independent events

 P  Machine Running   P  A  B  C   P  A P  B  P  C    0.86 0.9  0.95

 0.7353
 P  Machine fail   1  0.7353  0.2647

67. For number not divisible by 4 and not having zero can be formed as:

No.of ways to form : All digits odd numbers =54

3 digits odd numbers +1 even no(4 or 8)= 53  8

2 digits odd no+2 even no=0

1 digit odd no +3 even =0

All even no = 24 (only 2 or 6 can be used)

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24 16
 Req probability = 
5  5  8  2 1641
4 3 4

68. S   H ,TH , TTH , TTTH ,TTTTH , TTTTT 

X  1, 2,3, 4,5

1
P  X  1  P  H  
2

11 1 1
P  X  2   P TH      2 
2 2 2 4

1 1
P  X  3    P TTH 
23 8

1 1
P  X  4    P  TTTH 
24 16

1 1 2 1
P  X  5  P TTTTH   P TTTTT   5
 5  5 
2 2 2 16

E  x    x.P  X  x 
1 1  1  1   1 
 1   2    3   4    5  
 2   4   8   16   16 
31
  1.9
16
x
1
69. P  x   K  x  1  
5

2K 3K
 P  0  K , P 1  , P  2 
5 52

 X has a P.d . f

 Sum of all probabilites  1

 1 1
2

 k 1  2    3    ........  1
 5 5 

 1 
 a  1   
dr  1 5  25  16
K  2
1 k     2  1 k   1 k 
1  r 1  r    1  1   16  25
1  5  1   
  5 
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1/2
 15  4
 5  P  X  1   5  P  x  0    5  k   5  
1/2 1/2 1/ 2
 5   4
   25  5

70.
3
P  A  , P A 
5
2
5
 
2
P  B  , P B 
3
1
3
 
   
Req probability  P A  B  P A  B  P  A P B  P A P  B     
 3  1  2  2  3  4 7
        
 5  3  5  3  15 15

71. Conceptual

72. A: n=12-8=4, m=8

n3 7 7
 8 2
 10 
2 2 1024

73. P  A'  B '   P  A'  P  B '   1  P  A  1  P  B    1  P  A  P  B   P  A P  B 

74. P  A  B   P  A  P  B   P  A  B   1

3 2 4
P  A  B   P  A  P  B   1   1 
5 3 15

P  A  B   min  P  A , P  B 

3
P  A  B 
5

P A  B
 P  A / B 
P B

4 2 9
 P  A  B   3 / 5 and  P  A / B  
15 5 10

3 2 5 3 4 5 4 3 5 4 3 5
75. = P WWR   P WBR   P  BBR   P  BWR   . .  . .  . .  . .
12 11 10 11 11 10 12 11 10 12 11 10

21

132

76. Conceptual
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77. Conceptual

78. P  A   0.25, P  B   0.50, P  A  B   0.14

P  A  B   0.25  0.50  0.14  0.61

 
 P A  B  1  P  A  B   1  0.61  0.39

79. If a number is to be divisible by both 2 and 3, it should be divisible by their L.C.M,

L.C.M of 2 and 3 is 6

 The numbers are 6,12,18……96.

 The total numbers are 16.

16C3 4
 Required probability = = .
100C3 1155

80. Let E be the event that atleast 4 White balls are drawn in the first six draws,

with replacement

Let E4 be the event that exactly 4 white balls are drawn

Let E5 be the event that exactly 5 white balls are drawn

And E6 be the event that exactly 6 white balls are drawn

If A is the event that out of the next two draws exactly one white ball is drawn, then
P  A  P  A  E4   P  A  E5   P  A  E6 

 P  E4  P  A / E4   P  E5  P  A / E5   P  E6  P  A / E6 
6C 412C2 2C112C1 6C512C1 1C111C1 6C6 2
 .   .0 
18C6 12C2 18C6 12C2 18C6 119

81. Let E  both are girls  GG n E  1

the event E1  the youngest is a girl  GB, GG n  E1   2

 E1  E2  GG

n  E1  E2   1

n  E  E1  1
 P  E / E1     0.5
n  E1  2
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5  15  10 1
82. Required Probability   p
30  30  30 36

 36 p  1

83. n  11, r 7

111
C 7 1 10C6 15 869 m
 Re quired probability  1  11 7 1
 1  1  
C 7 1
17C6 884 884 n

 m  n  869  884  15  15

84. n  S   64C3


n  E   4 3C3  4C3  5C3  6C3  7C3  2 8C3     392

n  E  392
PE  
n  S  64C3

85. Conceptual

5 1 4 2
86. PR   , PN   
10 2 10 5

2 1
PR  N   
10 5

 P  R  N   P  R  P  N   P  R  N 

1 2 1 542 92 7 p
      
2 5 5 10 10 10 q

p  q  7  10  17

87. Req probability = Probability of getting 4 non-ace cards in first four draws and getting an
12C4 1 12  11 10  9 1 1 1
ace in fifth draw      
13C4 9 13  12  11  10 9 13 k

k 2  132  169

88. P  A  0.4, P  B   0.2

Req probability  P A  B  
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
 P A B 
 1 P A  B
 1   P  A  P  B    A B 
 1   0.4  0.2 
 1  0.6
 0.4

89. In the 22nd century there are 25 leap years Viz 2100,2104…..2196 and 75 non-leap years

Consider the following events

E1=Selecting a leap year from 22nd century

E2=Selecting a non -leap year from 22nd century

A= There are 53 Sundays in the year of 22nd century

25 75
 P  E1   , P  E2  
100 100

2 1
P  A / E1   , P  A / E2  
7 7

Req probability  P  A  P  E1  P  A / E1   P  E2  P  A / E2 

5 r
   r  s  5  28  33
28 s

2!11! 2 1
90. Req probability    K
12! 12 6

1
 36 K  36    6
6

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