SIERRA LEONE MUSLIM CONGRESS SENIOR SECONDARY SCHOOL KISSY MESS-MESS FREETOWN IRST TER, LION — DECEMBER 2019 CHEMISTRY - SSS 1 (TIME; 2 hours) TON = Answer all questions 1, (a) Ifyou fill a glass to the brim with ice water and the ice melts what will happen? (b) What is the most common isotopes of hydrogen? (c) You can't live without water! What is its chemical formula? (d) The symbol of HE, NA, LI, mG, o nE, SI, P, CA. h, show the error in each symbol and why? (©) How many moles of carbon [c] are in | mol of sucrose [CigH220))]? [C= 12,H=1, O=16) (f) How many carbon {c} atoms are in | mol of sucrose? (g) How is the molecular mass and the mol ar mass of a compound similar and how are they o different? * (h) Why might the expression “1 mol of nitrogen” be confusing? What change would remove any uncertainty? * _ (i) Calculate the maximum numbers of moles and grams of HS that can form when 158g of aluminum sulfide reacts with 131g of water: AhS3 + HO. —> AI (OH)3+ FS fAl=27 O=16 Hel $=32 Sectior ver four (4) Question 1. (@) Calculate the molar mass and the molecular mass of the following compounds. (@CuSOs.5H20 ii) (NH) 3 PO. (iii) MgS0y.7H0 Civ) Ca (CoH303)2 Ca=40 P=31 “e ; Mg=24 Cu=64 ‘2 a N=14 C=12 (b) Caleulate each of the following quantities (i) Mass in grams of 0,52mol of KMnO, (ii) Mass of Oxygen atoms in 8.18g of Mg (NOs)s (iil) Number of oxygen atoms in 8.1 x 10 g of CuSOeSH,0 Gv) Number of moles and formula units in 57.9 of sodium per chlorate. {») Number of sodium jons per chlorate ions, Cl atom, and oxygen atoms in masé of compound in 1b (iv), , (Ca=24,0=16,H= 1, Mg=24N=14, K =3) (©) (Propane is widely used in liquid form as For 75.3g of propaine [CsHs], calculate (a) The moles of the compound + (b) the ‘grams of carbon (@) Hemoglobin, a protein in red blood cells, caries oxygen gas [Os] from the lungs to the body's cells. Iron (as famous ion, Fe makes up 0.033 mass % of hemoglobin, Ifthe molar mass of hemoglobin is 6.8 x 10% ‘g/mol, how many Fe** ions are in one molecule? ' [C= 12, = TFe* 56, 0 16]; * @ fuel for barbecue grills and camp stores. t2. (a) In the process of balancin, Al+Ch—> AICh | Student I write: Al + Cl; —+ AI Ch Student Il writes; Al + Ch +Cl —» alc, janicat III writes: 2A1 + 3Cl; —» 2AlCl; Wi approach of student I valid, Student Il, Student Mex; i : 5 lain. (b) te sialanes equations for cach of the following: by inserting the correct Coefficient in () — (CN)2+ — Ho, ii) — Casio, + HF—» (iii) — CH3NH; + — 0, —» (iv) — B;0;+ —Na0, —> — Na, BO; + —— () — PO + 1:0 —+ — typo, “P* #20 (©) Convertthe following into balanced equations (i) When Beryllium is heated in oxygen gas. It melts and forms solid Beryllium oxide ii) When solutions of calcium chloride and sodium phosphate are mixed, « solid caletam Phosphate forms and sodium chloride, (iii) Liquid disilicon hexachloride reacts wit » chloride gas, and hydrogen gas. (iv) When nitrogen dioxide is bubbled into water, Baseous nitrogen monoxide is released, (d) Predict the product of the following reactant ? (i) Calcium and oxygen gas —» (ii) Hydrochloric acid and sodium hydroxide —» ‘ (ii) Hydrogen gas and iodine gas —» (iv) Calcium, hydroxide and nitric ana——» 3. (a) Hemoglobin is 6.9% heme [Cs4Hsz Fe N04] by mass, To remove the heme, hemoglobin is treated with acetic and NaCl to form hemin [C3,Hy2N,OsFeCl]. At acrime scene, a blood sample contains 0.45g of hemoglobin (i) How many grams of heme are in the sampie?. Gi) How many moles of heme? (iii) How many grams of Fe? . (iv) How many grams of hemin could be formed for a forensic chemist to measure? [C=12,N= 14, O= 16, H=1,Fe= 56] . . (b) Manganese is akey component of estremely hard steel, The elewient occurs naturally in many oxides, A $42.3g sample of a manganese oxide has on Mn: O-ratio 1:1.42 and consists of braunite (Mn;Os) and manganosite(Mn.O],»° (i) What mass of brunite and manganosite are in the Ore? (ii) What is the ratio Mn”* Mn** in the ore? Mn = 55 5 O=16 ig the equation — H:C,0,+ — nny — SiFi+ — CoF)+— H,0 — CO;+ —H,0+—+ —N, ith water to:form solid silicon dioxide, hydrogen a solution of nitric acid forms and (©) 1.0g of a oxide of A contained,0.5g of A, 4.0g of another oxide of A contained 1.6g of A. show which law was illustrated-above and How? (0=16] © =. a 4 (a) (i) 5.2g ofCaCOs when heated produced 1.99g of carbon dioxide and the residué'CaO left behind weighs 3.2g. Show that-these results illustrate the law of conservation of, mass. ae ii i i 1.6% Hp. -If the law of constant proportion is true, (ii) Ammonia contains 82.655 Nz and 17. ‘the I then the mass of zinc required to give,10g Ammonia will be3. [Ca = 40, 0 = 16, C= 12,N~14] (b) A hydrocarbon is a compound comprised of carbon and hydrogen atoms, An unknown hydrocarbon is found to contain 85.7% carbon and an atomic mass of 84.0g/mol. What is its molecular formula? [C= 12, H = 1}, (c) A gas sample is found to contain 39, 10% carbon, 7.67% hydrogen, 26.11% oxygen, 16.82% phosphorus and 10.30% fluorine. If the molecular mase ig 184.1 g/mol, what is the molecular formula? (d) A 1.50g sample of hydrocarbon undergoes complete combustion to produce 4.40g of CO2 and 2.70g of H2O. What is the empirical formula of this compound? In addition its molecular weight has been determined to be about 78. What is the molecular formula? [H= 1, C= 12,0= 16] (@) In a titration experiment 22.50cm? of an acid solution A containing 10.6g NaHSOs per dm’ reacted with 25.0cm’ of solution B containing Xg of NaOh per dm? The equation for the reaction is: from the information given above, calculate the: i) Concentration of A in moldm™? Concentration of B in moldm~? Value of X (iv) Mass of NaySO, formed during the reaction [Na= 23, H= 1, S = 32, O= 16] (b) A is a solution of tetraoxo sulphate (vi) acid B is a solution of sodiumtrioxo carbonate contains 3.95g in 750cm of solution. If 22.70cm* of the tetroxosulphate (vi) and neutralized 25.0cm* of sodium trioxo carbonate (iv). Calculate the: . ¥ @__., Concentration of B in gém ~? (ii) Concentration B in moldm~? (ii), Concentration of A in moldm~* (iv) Concentration of A in gdm -3 so {v) ‘Calculate the number of hydroxomiam irons which could be obtained from + the result Sb (iii) : The equation for the reaction wo a HQ + NazCO; —» HzCOs +NazSO, F = 18,998, N = 14, Cu = 64, Mg =24Ca=40,P = 31, H=1,0=16,$=32,C= atneeaeet *| Mn = 54.9 Al =27,K = 39.1. .