Revision date: 13/06/2017 Revision: 00

SAFETY DATA SHEET

AMIKIL 9004D

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name AMIKIL 9004D

1.2. Relevant identified uses of the substance or mixture and uses advised against
1.3. Details of the supplier of the safety data sheet
Supplier SICHEM LLC
Plot numbers 89-92
Musaffah Industrial Area
Abu Dhabi
United Arab Emirates
+97125559104
+97125542524

Contact person QHSE Manager

1.4. Emergency telephone number

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification (EC 1272/2008)
Physical hazards Not Classified

Health hazards Acute Tox. 4 - H302 Acute Tox. 2 - H330 Skin Corr. 1B - H314 Eye Dam. 1 - H318 Resp.
Sens. 1 - H334 Skin Sens. 1 - H317 Carc. 1A - H350 STOT SE 3 - H335

Environmental hazards Aquatic Acute 1 - H400

Classification (67/548/EEC or T;R23/25. R42/43. C;R34. Xi;R37. N;R50.

1999/45/EC)

2.2. Label elements

Pictogram

Signal word Danger

Hazard statements H302 Harmful if swallowed.

H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H330 Fatal if inhaled.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 May cause respiratory irritation.
H350 May cause cancer.
H400 Very toxic to aquatic life.

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Precautionary statements P201 Obtain special instructions before use.

P202 Do not handle until all safety precautions have been read and understood.
P260 Do not breathe vapour/ spray.
P261 Avoid breathing vapour/ spray.
P264 Wash contaminated skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P284 [In case of inadequate ventilation] wear respiratory protection.
P301+P312 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302+P352 IF ON SKIN: Wash with plenty of water.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water/ shower.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P308+P313 IF exposed or concerned: Get medical advice/ attention.
P310 Immediately call a POISON CENTER/ doctor.
P320 Specific treatment is urgent (see medical advice on this label).
P321 Specific treatment (see medical advice on this label).
P333+P313 If skin irritation or rash occurs: Get medical advice/ attention.
P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER/ doctor.
P362+P364 Take off contaminated clothing and wash it before reuse.
P363 Wash contaminated clothing before reuse.
P391 Collect spillage.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P501 Dispose of contents/ container in accordance with national regulations.

Contains GLUTARALDEHYDE 50%

2.3. Other hazards

SECTION 3: Composition/information on ingredients

3.2. Mixtures

GLUTARALDEHYDE 50% 10-30%

CAS number: 111-30-8 EC number: 203-856-5
M factor (Acute) = 10000000

Classification Classification (67/548/EEC or 1999/45/EC)

Acute Tox. 3 - H301 T;R23/25. C;R34. Xi;R37. N;R50. R42/43.
Acute Tox. 2 - H330
Skin Corr. 1B - H314
Eye Dam. 1 - H318
Resp. Sens. 1 - H334
Skin Sens. 1 - H317
STOT SE 3 - H335
Aquatic Acute 1 - H400

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

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SECTION 4: First aid measures

4.1. Description of first aid measures

Inhalation Move affected person to fresh air and keep warm and at rest in a position comfortable for
breathing. Keep affected person under observation. Get medical attention. Show this Safety
Data Sheet to the medical personnel.

Ingestion DO NOT induce vomiting. Get medical attention immediately.

Skin contact Remove contaminated clothing immediately and wash skin with soap and water. Get medical
attention immediately.

Eye contact Rinse immediately with plenty of water. Remove any contact lenses and open eyelids wide
apart. Get medical attention. Show this Safety Data Sheet to the medical personnel.

4.2. Most important symptoms and effects, both acute and delayed
4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor Treat symptomatically

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media The product is not flammable.

5.2. Special hazards arising from the substance or mixture

Hazardous combustion If involved in a fire the following may be released Carbon monoxide (CO). Carbon dioxide
products (CO2). Formaldehyde. Phosphorus oxides

5.3. Advice for firefighters

Protective actions during Fire-fighters should wear appropriate protective equipment and self-contained breathing
firefighting apparatus (SCBA) with a full-piece operated in positive pressure mode.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions Wear protective clothing as described in Section 8 of this safety data sheet.

6.2. Environmental precautions

Environmental precautions Do not discharge into drains or watercourses or onto the ground.

6.3. Methods and material for containment and cleaning up

Methods for cleaning up Absorb in vermiculite, dry sand or earth and place into containers. Use of water wash down
after spill clean is NOT recommended.

6.4. Reference to other sections

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Usage precautions Avoid contact with skin and eyes. Eye wash facilities and emergency shower must be
available when handling this product. Avoid eating, drinking and smoking when using the
product. Avoid inhalation of vapours and spray/mists. Provide adequate ventilation.

7.2. Conditions for safe storage, including any incompatibilities

Storage precautions Store in tightly-closed, original container in a dry and cool place.

7.3. Specific end use(s)

SECTION 8: Exposure Controls/personal protection

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8.1. Control parameters

Occupational exposure limits
GLUTARALDEHYDE 50%
Long-term exposure limit (8-hour TWA): WEL 0.05 ppm Sen 0.2 mg/m3(Sen)
Short-term exposure limit (15-minute): WEL 0.05 ppm Sen 0.2 mg/m3(Sen)
WEL = Workplace Exposure Limit

8.2. Exposure controls

Protective equipment

SECTION 9: Physical and Chemical Properties

9.1. Information on basic physical and chemical properties

Appearance Liquid.

Colour Colorless to pale yellow liquid.

pH pH (concentrated solution): 3.5 - 5.5

Relative density 1.000 - 1.040 @ @25°C

9.2. Other information

Other information No information required.

SECTION 10: Stability and reactivity

10.1. Reactivity
Reactivity There are no known reactivity hazards associated with this product.

10.2. Chemical stability

Stability Stable at normal ambient temperatures and when used as recommended.

10.3. Possibility of hazardous reactions

Possibility of hazardous None known Will not occur.
reactions

10.4. Conditions to avoid

10.5. Incompatible materials
10.6. Hazardous decomposition products
SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity - oral
ATE oral (mg/kg) 392.16

Acute toxicity - dermal

ATE dermal (mg/kg) 22,000.0

Acute toxicity - inhalation

ATE inhalation (gases ppm) 399.11

ATE inhalation (vapours mg/l) 2.0

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ATE inhalation (dusts/mists 0.2

mg/l)

SECTION 12: Ecological Information

Ecotoxicity The product contains substances which are toxic to aquatic organisms and which may cause
long-term adverse effects in the aquatic environment.

12.1. Toxicity
Toxicity Toxic to aquatic organisms

12.2. Persistence and degradability

12.3. Bioaccumulative potential
12.4. Mobility in soil
12.5. Results of PBT and vPvB assessment
12.6. Other adverse effects
SECTION 13: Disposal considerations

13.1. Waste treatment methods

Disposal methods Care must be considered to prevent the contamination of the environment from the use of this
product. It is the user's responsibility to dispose of unused material, residues and containers
in compliance with all relevant local, state and federal laws and regulations regarding
treatment, storage and disposal for hazardous and non-hazardous wastes.

SECTION 14: Transport information

14.1. UN number
UN No. (ADR/RID) 2922

UN No. (IMDG) 2922

UN No. (ICAO) 2922

UN No. (ADN) 2922

14.2. UN proper shipping name

Proper shipping name CORROSIVE LIQUID, TOXIC, N.O.S. (CONTAINS GLUTARALDEHYDE 50%, ALKYL
(ADR/RID) BENZYL DIMETHYL AMMONIUM CHLORIDE)

Proper shipping name (IMDG) CORROSIVE LIQUID, TOXIC, N.O.S. (CONTAINS GLUTARALDEHYDE 50%, ALKYL
BENZYL DIMETHYL AMMONIUM CHLORIDE)

Proper shipping name (ICAO) CORROSIVE LIQUID, TOXIC, N.O.S. (CONTAINS GLUTARALDEHYDE 50%, ALKYL
BENZYL DIMETHYL AMMONIUM CHLORIDE)

Proper shipping name (ADN) CORROSIVE LIQUID, TOXIC, N.O.S. (CONTAINS GLUTARALDEHYDE 50%, ALKYL
BENZYL DIMETHYL AMMONIUM CHLORIDE)

14.3. Transport hazard class(es)

ADR/RID class 8

ADR/RID subsidiary risk 6.1

ADR/RID classification code CT1

ADR/RID label 8

IMDG class 8

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IMDG subsidiary risk 6.1

ICAO class/division 8

ICAO subsidiary risk 6.1

ADN class 8

ADN subsidiary risk 6.1

Transport labels

14.4. Packing group

ADR/RID packing group II

IMDG packing group II

ADN packing group II

ICAO packing group II

14.5. Environmental hazards

Environmentally hazardous substance/marine pollutant

14.6. Special precautions for user

EmS F-A, S-B

ADR transport category 2

Emergency Action Code 2X

Hazard Identification Number 86

(ADR/RID)

Tunnel restriction code (E)

14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78
and the IBC Code

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations The Chemicals (Hazard Information and Packaging for Supply) Regulations 2002. No. 1689.
Control of Substances Hazardous to Health Regulations 2002 (as amended).
Dangerous Substances and Explosive Atmospheres Regulations 2002.
Health and Safety at Work etc. Act 1974 (as amended).
The Carriage of Dangerous Goods and Use of Transportable Pressure Equipment
Regulations 2009 (SI 2009 No. 1348) (as amended) ["CDG 2009"].

EU legislation EU Directives 67/548/EEC and 1999/45/EC (including amendments).

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Guidance CHIP for everyone HSG228.

Introduction to Local Exhaust Ventilation HS(G)37.
Workplace Exposure Limits EH40.
Safety Data Sheets for Substances and Preparations.

Authorisations (Title VII No specific authorisations are known for this product.
Regulation 1907/2006)

Restrictions (Title VIII No specific restrictions on use are known for this product.
Regulation 1907/2006)

15.2. Chemical safety assessment

International Chemical Inventories

SECTION 16: Other information

General information
The information given here is based on current knowledge and experience and describes the
product only with regard to its safety requirements. The data does describe the product's
properties. It is the responsibility of the user of the product to ensure to his satisfaction that
the product is suitable for the intended purpose and method of use. Since we cannot
anticipate or control the conditions under which this information and product may be used, we
make no guarantee that the precautions we have suggested will be adequate for all
individuals and/or situations. It is the responsibility of the user to comply with the requirements
of all applicable laws regarding use and disposal of this product. No warranty, either
expressed or implied, nor liability of any nature with respect to this product or to the data
herein is made or incurred hereunder.

Revision comments This is first issue.

Issued by QHSE Manager

Revision date 13/06/2017

Revision 00

SDS number 20313

Risk phrases in full
R21/22 Harmful in contact with skin and if swallowed.
R23/25 Toxic by inhalation and if swallowed.
R34 Causes burns.
R37 Irritating to respiratory system.
R42/43 May cause sensitisation by inhalation and skin contact.
R50 Very toxic to aquatic organisms.

Hazard statements in full H301 Toxic if swallowed.

H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H330 Fatal if inhaled.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 May cause respiratory irritation.
H350 May cause cancer.
H400 Very toxic to aquatic life.

This information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate
and reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or
completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.

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