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Scts 4
Scts 4
JEE‐ADVANCE‐2010‐P1‐Model
Time: 3:00 IMPORTANT INSTRUCTIONS Max Marks: 252
CHEMISTRY
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N: 1 – 8) Questions with Single Correct Choice 3 -1 8 24
3
Sec – II (Q.N: 9 – 13) Questions with Multiple Correct Choice 0 5 15
Questions with Comprehension Type
Sec – III (Q.N: 14 – 18) 3 -1 5 15
(2 Comprehensions – 2 + 3 = 5Q)
Sec – IV (Q.N: 19 – 28) Questions with Integer Answer Type 3 0 10 30
Total 28 84
MATHEMATICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N: 29 – 36) Questions with Single Correct Choice 3 -1 8 24
3
Sec – II (Q.N: 37 –41) Questions with Multiple Correct Choice 0 5 15
Questions with Comprehension Type
Sec – III (Q.N: 42 – 46) 3 -1 5 15
(2 Comprehensions – 2 + 3 = 5Q)
Sec – IV (Q.N: 47 –56) Questions with Integer Answer Type 3 0 10 30
Total 28 84
PHYSICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N: 57 – 64) Questions with Single Correct Choice 3 -1 8 24
3
Sec – II (Q.N: 65 – 69) Questions with Multiple Correct Choice 0 5 15
Questions with Comprehension Type
Sec – III (Q.N: 70 –74) 3 -1 5 15
(2 Comprehensions – 2 + 3 = 5Q)
Sec – IV (Q.N: 75 –84) Questions with Integer Answer Type 3 0 10 30
Total 28 84
CHEMISTRY
SECTION – I
(SINGLE CORRECT CHOICE TYPE)
This section contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of which ONLY ONE is
correct
01. 5 mole H 2O l at 373 K and 1 atm is converted into H 2O (g) at 373 K and 5 atm. G
for this process is [Given: R 2Cal / K mol ].
A) Zero B) 1865 ln 5 Cal C) 3730 ln 5 Cal D) –3730 ln 5 Cal
02. Which of the following statement is not correct?
A) Thermodynamic principles do not provide any information regarding speed of a
reaction
B) There are examples of thermodynamically feasible reaction which are slow that
virtually no visible results are obtained.
C) The rate of reaction is proportional to the product of effective concentration of the
reacting species, each raised to a power which is equal to the corresponding
stoichiometric number of the substance in the chemical equation.
D) Order of reaction can be only experimentally determined
03. Which of the following is strongest acid?
H
N H
A) N H 4 B)
H H
H H
N
N
C) D)
Cl
CH3
Br
H3C CH CH3
CH3
CH3
(P) CH3
(Q) (R)
H
Identity the correct major product obtained in the above reaction is
N
N CH Ph HC Ph
H
A) OH B) OH
OH O
CH Ph C
Ph
C) N D) N
B) C F Si F
C) C Cl Si Cl
planar
D) Among tetrafluorides of S, Se and Te; SF4 is a solid, SeF4 a gas and TeF4 a liquid
08. Which of the following statements is incorrect?
(Given that: cycloheptatriene is abbreviated as ‘cht’ and the complexes
Ni CO cht , Ni CO cht and Cr CO cht follow 18 electron rule)
3 2 3
A) In CoCl3.6NH 3 , the primary valence of cobalt is satisfied by three Cl ions where as
in CoCl3.4NH 3 , two Cl ions satisfy both primary and secondary valences of cobalt.
B) cis and trans isomers of the complex CoCl3.4NH 3 have green and violet
colours respectively.
C) ‘cht’ ligand behaves as two electron donor, four electron donor and six electron donor
3 4
D) For the complexes Fe CN 6 and Fe CN 6 , the C – N stretching bands(in
3 4
cm 1 ) (corresponding to the highest energy) observed as Fe CN 6 Fe CN 6
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SECTION - II
(MULTIPLE CORRECT CHOICE TYPE)
This section contains 5 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of which ONE OR MORE is/
are correct
09. Following equilibria are established in three different equal volume containers.
Reaction I: X 2 g YO2 g X 2O g YO g ; Keq at 2000 K 4
CHCl3/KOH
B= C= D=
A)
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CONH2 NH2 NC
A= B= E=
B)
CONH2 CN NC
A= D= E=
C)
NH2 N 2 Cl
CN
B= C= E=
D)
11. Consider the following reaction sequence.
NO2
P
Q 2 T
R
S
H O
CH3 COOH
N2
P=Sn/HCl, R=HNO2 , S=
B) CH3
N2 Cl CH3
S= T= U 1) CH 3 CH 2 OH
, , 2) KMnO4 KOH ,
C) CH3
NO2 OH
Q=
, R=H 2 /Pd,ethanol , T=
COOH CH3
D)
O
12. A
2 B + other product(s)
‘A’ is complex ion of Co2 with six NO2 ligands. Then identify the correct statement(s)
regarding complex ion of B.
A) In the complex ion of B, Cobalt is in +3 oxidation state
B) Complex ion of B is a high spin complex
C) Complex ion of B exhibit linkage isomerism
D) Complex ion of B is paramagnetic
O O
CH3
CH2 COOH
(A)
Compound (A) was hydrolysed in aqueous acidic medium for some time. After an hour, a
mixture of compound (B) and (C) are obtained. Properties of (A),(B) and (C) are
summarized
(A) (B) (C)
Reaction with NaHCO3 Birsk efferrescance NO NO
Blue litmus Red NO NO
NaOI NO NO Yellow
NO NO Silver Mirror
Ag NH3
2
14. 4.4 gm of compound (C) was treated with iodine in aqueous basic medium. Assuming
100% yield of reaction, then the mass of tri-iodo compound formed is?
At.wt of I=127,At.wt of Mg=24, At.wt of Br=8
A) 39.40 B) 45.60 C) 60.70 D) 24.40
15. 0.1 mole of compound (B) was reacted with excess of CH3MgBr . Then the mass of
CH 3MgBr consumed for complete reaction is?
A) 25.30 B) 35.70 C) 15.20 D) 46.20
log K
O I /T
23. In how many reactions alcohol is obtained as a major product
aq NaNO +HCl
2
NH2 Br aq KOH
i) ii)
Cl
aq.KOH
alc.KOH
O CH2 CH3
iii) iv)
KMnO4
H3C CH CH3
H /H O
H3C C O Ph 2
v) CH3 vi) O
O
CH3 C O O
Dry NaBH4
Ca
Distillation 1 CH3MgCl
H3C C O NH 4Cl/H2O
2
vii) O viii)
H / CH OH
3
CH2
ix)
24. Number of reactions in which aldehyde can be obtained as one of the products
OH
Cu
CH3 CH2 300 C CH2 CH2 OH
PCC
i) ii) CH3
OH
2 H Pd
CH3 C Cl MnO
2
BaSO4
iii) O iv)
H3O
i DIBAL H ,lowtemp
NH
CH3 C N
ii H 2O
v) vi) CH3 CH
CH3
H OH
HIO
4
H OH
1 O3
CH3 CH CH CH3
CH3
2 Zn H 2O
vii) viii)
CH3
1 CrO2Cl2
2 H 2O
ix)
25. Observation I: 2CuSO 4 4KI p X a Y w Z
Observation II: 2CuSO 4 5KI q X b A u Z
Moles of Y obtained in observation I a
Moles of A obtained in observation II b
Then a b is___
(Given that: X is copper containing product and Y,A are iodine containing
products)
(Given that: p,q,w,u – moles of products obtained in both given observations)
26. The silicate anion in the mineral which is a chain of three SiO4 tetrahedral, that share
corners with adjacent tetrahedral. The charge of the silicate anion is ' x ' , then x is ___
27. Among Zn OH 2 , Sn OH 2 , Cu OH 2 , Fe OH 3 , Pb OH 2 and Al OH 3 ; the
number of hydroxides which are soluble in excess of NaOH solution is____
28. Permanganate titrations in presence of hydrochloric acid are unsatisfactory since
hydrochloric acid is oxidized to Cl2 .During the reaction between KMnO 4 and
x
hydrochloric acid, two moles of KMnO4 oxidises ‘x’ moles of HCl. Then the value of
2
is____
MATHEMATICS
SECTION – I
(SINGLE CORRECT CHOICE TYPE)
This section contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of which ONLY ONE is
correct
29. If the mean and variance of the frequency distribution
xi 2 4 6 8 10 12 14 16
fi 4 4 15 8 4 5
C)
22023 1 22023 2
D)
22024 1 22024 2
3 3
32. Locus of the mid-points of the chords of the hyperbola x2 y2 a2 that touch the
parabola y 2 4ax is
A) x 2 x a y 3 B) y 2 x a x3
C) x3 x a y 2 D) y 3 x a x 2
33.
If three numbers are chosen randomly from the set 1,3,32 ,...........,3n without
replacement then the probability that they form an non increasing geometric progression
is
3 3
A) if n is odd B) if n is even
2n 2n
3n 3n
C) if n is even D) if n is odd
n2 1
2 n 12
34. The number of arrangements of the letters of the word PROBLEMANIC taking all such
that neither starting with P, nor ending with C, nor M in the middle is
A) 8! (746) B) 8! (373) C) 9! (82) D) 10! (23)
35. Which of the following real curves is an orthogonal curve to
x2 y2
2024 (Assume they are intersecting).
a 2 2023 b 2 2023
x2 y2
A) 2024, 0,2023
a2 b2
x2 y2
B) 1, 0
2 2
a b
x2 y2
C) 1, 0, 2023
2 2
a b
x2 y2
D) 2024, 0, 2023
a2 b2
2
36. Given a function f x x x
A) f(x) is continuous at all integers
B) f(x) is continuous & differentiable at all integers.
C) f(x) is discontinuous at all integers except x = 1
D) f(x) is discontinuous at all integers except at x 1
3x 3x x
37. If f x tan 1 tan 1 , 0 x 3 , then which of the following is/are
2 3
3 3x
INCORRECT?
A) the least value of f(x) is B) the greatest value of f x is
3 4
C) the least value of f(x) is 0 D) the greatest value of f(x) is
3
38. If P, Q are two points on the line y mx 2m and A 2,0 ,B 0,2 two points so that
APB AQB / 2, then value of ‘m’ can be
1 1 1 1
A) B) C) D)
10 2 2 3
39. Let P x1, y1 and Q x2 , y2 , y1 0, y2 0 be the end points of the latus rectum of the
ellipse x 2 4 y 2 4 . The equations of parabolas with latus rectum PQ are
A) x 2 2 3 y 3 3 B) x 2 2 3 y 3 3
C) x 2 2 3 y 3 3 D) x 2 2 3 y 3 3
99 100
1 r 1 r
40. If S sin and R sin , then
r 0
100 200 r 1
100 200
2 2 2 2
A) S R B) S C) R D) S R
41. The volume of the parallelepiped whose coterminous edges are represented by the vectors
2b c , 3c a and 4a b, where a 1 sin iˆ cos ˆj sin2kˆ,
2 2 4 ˆ
b sin iˆ cos ˆj sin 2 k,
3 3 3
2 2 4
c sin iˆ cos ˆj sin 2 kˆ is 18 cubic units, then the values
3 3 3
of , in the interval 0, can be
2
2 4
A) B) C) D)
9 9 3 9
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SECTION – III
(COMPREHENSION TYPE)
This section contains 2 groups of questions. Each group has 2 & 3 multiple choice questions based on a paragraph. Each question has 4 choices A),
B), C) and D) for its answer, out of which ONLY ONE is correct.
Passage: I
Given that the system of equations x cy bz, y az cx, z bx ay has non-zero
solutions and at least one of the a, b, c is a proper fraction. (A proper fraction is a fraction
whose numerator is less than the denominator. A proper fraction always lies between 0
and 1)
42. a 2 b 2 c 2 is
A) 2 B) 3 C) 3 D) 1
43. abc is
A) 1 B) 1 C) 0 D) 0
Passage: II
Let A, B and C be three mutually exclusive events such that P A p1, P B p2 and
P C p3. Then, answer the following questions:
44. If p1, p2 and p3 are roots of 27 x3 27 x 2 ax 1 0, then value of a is
1
A) 3 B) 6 C) 9 D)
3
1 1 1
45. If p1 1 p , p2 1 2 p and p3 2 3 p , then range of p is
2 3 5
1 1 2
A) B) 1,2 C) 1, D) ,
47 3 3
1 1 1
46. If p1 1 3 p , p2 1 p and p3 1 2 p , then the set of values of p is
3 4 4
1 1 1 1 1 1
A) 1,0 B) , C) , D) ,
3 3 3 2 9 4
SECTION –IV
(INTEGER ANSWER TYPE)
This section contains 10 questions. The answer to each of the questions is a single digit integer, ranging from 0 to 9. The appropriate bubbles below
the respective question numbers in the ORS have to be darkened.
2 n30 n3 n2 n1
47. The number of distinct digits in ......... 1 are ___
n30 0 n29 0 n2 0 n1 0 n0 0
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48. If the number of real solution(s) of the equation given by
2023 2024 x 2 2023 x 2 2024 2025
2017 2018 x 2 2017 x 2 2018 2019 0 are , then the unit’s digit of
2006 2007 x 2 2006 x 2 2007 2008
A cos 1 sin
1
1
1
,
B cos tan 1 sin ,
2
C sec1 cos ec 1 1 1 .
Then the value of (5 A 2B C ) is equal to ___
50. If f x y f x f y xy 1 for all x, y and f 1=1 , then the number of solutions
of f n n, n N is
51. If area bounded by max x y , x y 2 is ‘k’ sq.units, then the value of ‘k’ is ___
52. If 2cot 2 cot 2 cot 2 cot 2 cot 2 cot 2 cot 2 cot 2 cot 2 1, then the value
of cos 2 cos 2 cos2
12
is equal to ___ (where . denotes GIF)
dx
53. The value of 4
2024
0 1 x
54. The integer nearest to lim x x x x x x x will be ___
x
dy 2 x y 1
55. If , y 1 1 , then the absolute value of the sum of all possible value(s) of
dx x 2 y 1
y 0 is ____
56. The number of possible real value(s) of ‘c’ for which the 2 real curves given by
2023 x 2 2023 y 2 4046 x 6069 y 2024 0 and x 2 y 2 c can be orthogonal is/are
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PHYSICS
SECTION – I
(SINGLE CORRECT CHOICE TYPE)
This section contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of which ONLY ONE is
correct
3
57. A block of mass kg is placed on a rough horizontal surface as shown in the figure. A
10
force of 1 N is applied at one end of the block and the block remains stationary. The
normal force exerted by the surface on the block acts ( g 10 m / s 2 )
F=1N
300
20 cm
B A
20 cm
A) through the centre of mass of the block.
B) through point A.
C) through point B.
D) through the point at a distance 5 cm. from A.
58. The decay constant of 198 Au is . The probability that a 198 Au nucleus will decay in
next one second will be
1
A) B) 1/ C) 1 e D) 1
59. White light is used to illuminate the two slits in Young’s double slit experiment. The
separation between the screen and the slits is D d . At a point on the screen directly in
front of one of the slits, certain wavelengths are missing. The missing wavelengths are
(here m = 0, 1,2,.. is an integer)
A)
d2
B)
2m 1 d 2
2m 1 D D
C)
d2
D)
m 1 d 2
m 1 D D
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60. A ball of mass ‘m’ and density is being released inside a fluid of density and
2
coefficient of viscosity .Find the net force on the ball when speed achieved by ball is
60% of the terminal speed.
A) 0.6mg B) mg C) 0.4mg D) 0.2mg
61. A convex lens of focal length f is places somewhere in between an object and a screen.
The distance between the object and the screen is x. If the numerical value of the
magnification produced by the lens is m, the focal length of the lens is:
A)
mx
B)
mx
C)
m 12 x D)
m 12 x
2 2
m 1 m 1 mx mx
62. A uniform solid cylinder of mass ‘m’ and radius ‘R’ is set in rotation about its axis with
angular velocity 0 , then lowered with its lateral surface onto a horizontal plane and
released. If coefficient of friction between the cylinder and the plane is equal to ' ' then
how long the cylinder will move with sliding
ω0 R ω0 R ω0 R ω0 R
A) B) C) D)
3μg 4μg 5μg 6μg
63. An object of specific gravity is hung from a horizontal thin steel wire(tension is
constant along the wire). The fundamental frequency of transverse standing waves in the
wire is 300 Hz. The object is immersed in water so that one half of its volume is
submerged. The new fundamental frequency (in Hz) is
1 2 2 2 1
A) 300 1 B) 300 C) 300 D) 300
2 2 1 2 1 2
64. Twelve persons are initially at the twelve corners of a regular polygon of twelve sides of
side a. Each person now moves with uniform speed V in such a manner that 1 is always
directed towards 2, 2 towards 3, 3 towards 4 and so on. The distance travelled by each
person before they meet is
2a 2a 2a a
A) B) C) D)
2 3 2 3 3 2 3
65. A metal cylinder of mass 0.5 kg is heated electrically by a 12W heater in a room at15oC .
The cylinder temperature rises uniformly to 25oC in 5 min and finally becomes constant
at 45o C . Assuming that the rate of heat loss is proportional to the excess temperature
over the surroundings.
a P
Q
r
3 r 2 GM 2
A) Pressure (p) caused by gravitational compression is 1
8 R 2 R3
3 r 2 GM 2
B) Pressure (p) caused by gravitational compression is 1
8 R 2 R 4
3 GM
C) Gravitational field Intensity at the centre is
2 R2
D) Gravitational field Intensity at the centre is zero.
68. Three blocks A, B and C are kept as shown in the fig. The coefficient of the friction
between A and B is 0.2, B and C is 0.1, C and ground is 0.0.The mass of A, B and C are 3
kg, 2 kg and 1 kg respectively. A is given a horizontal velocity 10 m/s, A, B and C
always remain in contact i.e., lies as in fig. The total work done by friction will be:
A
B
Smooth
C
69. A solid whose volume does not change with temperature floats in a liquid at 00 C . For
two different temperatures t1 & t2 of the liquid, fractions f1 & f 2 of the volume of the
solid remains submerged in the liquid. The coefficient of volume expansion of the liquid
is equal to
f1 f2 f1 f2 f1 f2 f1 f2
A) B) C) D)
f 2t1 f1t2 f1t1 f 2t 2 f 2t1 f1t2 f1t1 f 2t 2
3 vo
71. z-component of velocity becomes at time t =
2
2 m m m m
A) B) C) D)
Bo q Boq 2Bo q 4Bo q
72. Maximum z-coordinate of the particle is
3 mvo 2 3 mvo 2mvo mvo
A) B) C) D)
Boq Boq Boq Bo q
Passage – II:
A small, positively charged bead can slide on a circular, frictionless, insulating rod. A
point–like electric dipole ( P ) is fixed at the centre of the circle with the dipole's axis
lying in the plane of the circle. Initially the bead is on the plane of symmetry of the
dipole, as shown in the figure. The bead is slightly displaced along ring, tangentially with
initial speed very close to zero. (Ignore the effect of gravity, assuming that the electric
forces are much greater than the gravitational ones.)
Rod
Bead
p r
SECTION –IV
(INTEGER ANSWER TYPE)
This section contains 10 questions. The answer to each of the questions is a single digit integer, ranging from 0 to 9. The appropriate bubbles below
the respective question numbers in the ORS have to be darkened.
75. An ammeter of zero resistance and a volt meter are connected in series to a battery of emf
6.0 volt and certain internal resistance. When a resistance R is connected in parallel with
the voltmeter, the readings of the voltmeter becomes half of its initial reading and the
reading of the ammeter becomes 2 times to its initial reading (before R is connected).
Find the voltmeter reading in volt after the connection of the resistance
S R
A V
76. The wedge shown in the figure is fixed and smooth. A particle of mass m is released from
rest from A. Its collision at B is completely inelastic. Its speed when it reaches C is
xgh
. Find x
2
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m
600
B
h
300
C
77. In a two block system shown in figure (at t = 0 blocks are given the velocities).The
velocity of centre of mass of the system after 2 seconds (m/s)is______
(Assume 2kg block is sufficiently long and 1kg block remains on 2kg block)
Rough
1 kg 10 m/s
5 m/s 2 kg
Smooth
78. Two balls of masses 1 kg each are connected by an inextensible massless string. The
system is resting on a smooth horizontal surface. An impulse of 10 Ns is applied to one
of the balls at an angle 300 with the line joining two balls in horizontal direction as shown
in the figure. Assuming that the string remains taut after the impulse is given, the
K
magnitude of impulse of tension is 3 Ns. Find the value of K.
2
1 kg
10 Ns
1 kg 300
79. Two identical capacitors are placed side by side with a small gap between them as shown
in fig. V1 and V2 are potential difference across the two capacitors respectively. An
electron is projected from the end of upper plate of the left capacitor with velocity
2V1l 2e
v0 towards right as shown. Charge and mass of electron are ‘e’ and ‘m’
md 2
respectively. V2 is applied such that the electron just grazes the lower plate of right
capacitor horizontally while coming out of it. Assume that there is no gravity and no
V
collision of electron with any plate. What is the ratio 2 ?
V1
v0 l
V1 d V2
d
l l
force F (in N) = 5t where ‘t’ is time in second at an angle of 370 with the horizontal as
shown in figure. The coefficient of static friction of the block with the surface is one. If
the force starts acting at t = 0sec then the block starts to slide at time t = 10(x)sec. Find x.
[Take g 10ms 2 ].
F 5t
370
7kg
i1 LR
R0
82. 1.5mW of 4000A0 light is directed at a photoelectric cell. If 0.10% of the incident
photons produce photoelectrons, the current in the cell is B 107 Amp . The value of B
in nearest integer is.
83. A circuit draws a power of 550 watt from a source of 220volt, 50 Hz. The power factor of
the circuit is 0.8 and the current lags in phase behind the potential difference. To make
the power factor of the circuit as 1.0, capacitance of 15 nF will have to be connected
with it. Find the value of n to the nearest integer.
84. In a modified YDSE, the region between the screen and slits is immersed in a liquid
5 t
whose refractive index varies with time t as l until it reaches a steady state
2 4
3
value of 5/4 .A glass plate of thickness 36 m and refractive index is introduced in
2
front of one the slits. Find the instant of time (in s) when central maxima is at point O
located on the x-axis.
y
S1
d O x
S2
D 1m
d 2mm