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05 08 2023 SR - Super60 Sterling&Nucleus BT Jee Main RPTM 01 Q.paper
05 08 2023 SR - Super60 Sterling&Nucleus BT Jee Main RPTM 01 Q.paper
.
Question Answered for Marking Question Cancelled for Marking
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
6. Use Blue / Black Point Pen only for writing particulars / marking responses on the Answer Sheet. Use of pencil is
strictly prohibited.
7. No candidate is allowed to carry any textual material, printed or written, bits of papers, mobile phone any electron
device etc, except the Identity Card inside the examination hall.
8. Rough work is to be done on the space provided for this purpose in the Test Booklet only.
9. On completion of the test, the candidate must hand over the Answer Sheet to the invigilator on duty in the Hall.
However, the candidate are allowed to take away this Test Booklet with them.
10. Do not fold of make any stray marks on the Answer Sheet
Name of the Candidate (in Capital): ________________________________________________
Admission Number:
Candidate’s Signature:________________ Invigilator’s Signature: ________________
SRI CHAITANYA IIT ACADEMY, INDIA 05-08-23_ Sr.Super60_ STERLING&NUCLEUS_BT _Jee-Main_RPTM-01_Q.P
05-08-23_Sr.Super60_ STERLING&NUCLEUS_BT _ Jee-Main_RPTM-01_Test Syllabus
PHYSICS : Thermal physics: Thermal expansion of solids, liquids and gases; Calorimetry, latent heat; Heat
conduction in one dimension; Elementary concepts of convection and radiation; Newton’s law of
cooling; Ideal gas laws; Specific heats (Cv and Cp for monoatomic and diatomic gases); Isothermal
and adiabatic processes, bulk modulus of gases; Equivalence of heat and work; First law of
thermodynamics and its applications (only for ideal gases); Second law of thermodynamics,
reversible and irreversible processes, Carnot engine and its efficiency; Blackbody radiation:
absorptive and emissive powers; Kirchhoff’s law; Wien’s displacement law, Stefan’s law. Mean
free path, Experiments: Plotting a cooling curve for the relationship between the temperature of a
hot body and time, Specific heat capacity of a given (i) solid and (ii) liquid by method of
mixtures, Specific heat of a liquid using calorimeter
CHEMISTRY : Nomenclature, Isomerism: Structural, Stereo, Hybridisation of carbon ; bonds, shapes of simple
organic molecules, structural and geometrical isomerism; Optical isomerism of compounds
containing upto two asymmetric centres, (R,S and E,Z nomenclature excluded) IUPAC
nomenclature of simple organic compounds(only hydrocarbons, mono-functional and bi-
functional compounds) Conformations of ethane and butane (Newman projections)
Column-I Column II
1) A 2) B 3) C 4) D
4. Power radiated by a black body is P0 and the wavelength corresponding to maximum
energy is around 0 . On changing the temperature of the black body, it was observed that
256
the power radiated becomes P0 .The shift in wavelength corresponding to the maximum
81
energy will be
1) 0 2) 0 3) 0 4) 0
4 2 4 2
5. In similar calorimeters, equal volumes of water and alcohol, when poured, take 100 and 74 s
, respectively, to cool from 50C to 40C . If the thermal capacity of each calorimeter is
numerically equal to volume of either liquid, then calculate the specific heat capacity of
alcohol (given: the relative density of alcohol as 0.8 and specific heat capacity of water as
1cal / g / C ).
1) 0.8cal / gC 2) 0.6cal / gC 3) 0.9cal / gC 4) 1cal / gC
6. A body cools in 7 min from 60C to 40C .What will be its temperature after the next
7 min ? The temperature of surroundings is 10C .
1) 28C 2) 25C 3) 30C 4) 22C
7. Statement 1: In natural convection, the fluid motion is caused due to density difference
produced by temperature gradient.
Statement 2: In forced convection, the fluid is forced to flow along the solid surface by
means of fans or pumps.
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SRI CHAITANYA IIT ACADEMY, INDIA 05-08-23_ Sr.Super60_ STERLING&NUCLEUS_BT _Jee-Main_RPTM-01_Q.P
1) Statement 1 is true but statement 2 is false.
2) Statement 1 is true, statement 2 is true; statement 2 is the correct explanation for
statement 1.
3) Statement 1 is true, statement 2 is true; statement 2 is not the a correct explanation for
statement 1 .
4) Statement 1 is false but statement 2 is true.
8. A gas is filled in the cylinder shown in the figure. The two pistons are joined by an
inextensible string. If the gas is heated, the pistons will:
V2 V2
1) = constant 2) = constant
T3 T
3) VT 3 = constant 4) V 2 T = constant
15. A gas undergoes a process in which its pressure p and volume V are related as Vp n =constant,
the bulk modulus for the gas in this process is
1 1
1) np 2) p 3) 4) pn
n n
Q
16. Find the molar heat capacity in a process of a diatomic gas if it does a work of when a
4
heat of Q is supplied to it.
1) R 2) 2R 3) 3.33 R 4) 5.25 R
17. An ideal gas consists of a large number of identical molecules. Absolute temperature of the
gas is T (in kelvin), molecular weight of gas is M and R is gas constant. Match the
statements given in column-I with column-II and Choose correct option
Column-I Column II
(a) Root mean square speed of (p) RT
molecules is greater than M
(b) Most probable speed of (q) RT
1.5
molecues is smaller than M
(c) Average velocity of a molecule (r) RT
2
is smaller than M
(d) Speed of a molecule may be (s) RT
2.5
greater than M
1) A-PQ B-QRS C-RS D-PQRS 2) A-PQ B-S C-PQRS D-PQRS
3) A-PQ B-QS C-PQ D-RS 4) A-PQ B-QRS C-PQRS D-PQRS
0
18. At 0 c ( Zero degree Celsius ) a black body emits :
1) QBC 2) QA 3) DE 4) FG
20. Isochoric change is represented by
P P
1) 2)
O T O T
P P
3) 4)
O T O T
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If answer
is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
21. A lead bullet penetrates into a solid object and melts. Assuming that 50% of its kinetic
energy was used to heat it, N 100 m/s is the initial speed of the bullet. The initial
temperature of the bullet is 27C and its melting point is 327C . Latent heat of fusion of lead
2.5 104 J kg and specific heat capacity of lead 125 J kg K .Then find value of N
22. In figure, a cyclic process ABCA of 3 moles of an ideal gas is given. The temperatures of the
gas at B and C are 500 K and 1000 K respectively. If the work done on the gas in process
CA is 2500 J then find the net heat absorbed or released by an ideal gas in kilo joules. Take
R = 25/3 J/mol-K
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SRI CHAITANYA IIT ACADEMY, INDIA 05-08-23_ Sr.Super60_ STERLING&NUCLEUS_BT _Jee-Main_RPTM-01_Q.P
23. A steel rod of length 1m rests on a smooth horizontal base. If it is heated from 0C to 100C,
24. The density of carbon dioxide gas at 0 C and at a pressure of 1.0 105 newton metre2 is
1.98 kg m3 . Take Pressure is constant. Find the root mean square velocity of its molecules in
m/s at 0C .
25. A Carnot engine, whose efficiency is 40% , takes in heat from a source maintained at a
temperature of 500 K . It is desired to have an engine of efficiency 60% . Then, the intake
temperature for the same exhaust (sink) temperature must be – (in Kelvin)
7
26. An ideal diatomic gas undergoes a process in which its internal energy relates to the
5
volume as U V , where is a constant, then Find the work performed by the gas to
increase its internal energy by 100 J .(in terms of joule)
27. A cubical box of side 1 m contains helium gas (atomic weight 4 ) at a pressure of 100 N / m2
. During an observation time of 1s an atom travelling with the rms speed parallel to one of
the edges of the cube , was found to make 500 hits with a particular wall, without any
collision with other atoms. Take R 8.31J / mol K and k 1.38 1023 J / K .
Evaluate the temperature of the gas.(in Kelvin) (Round off to nearest integer)
0C to 100C . Another rod B of a different metal of length 40 cm expands by 0.040 cm for
the same rise in temperature. A third rod C of 50 cm length is made up of pieces of rods A
and B placed end to end expands by 0.03 cm on heating from 0C to 50C . Find the
difference of the lengths of each portion of the composite rod (in cm)
29. Ice at 0C is added to 200 g of water initially at 70C in a vacuum flask. When 50 g of ice
has been added and has all melted the temperature of the flask and contents is 40C . When a
further 80 g of ice has been added and has all melted the temperature of the whole becomes
30. An ideal gas is taken through a cyclic thermodynamic process through four steps. The
amount of heat involved four steps are Q1 = 6000J, Q2 = –5000J, Q3 = –3000J and Q4 =
H H
1
CH 3
1) fully eclipsed 2)Gauche conformation
3) partially eclipsed 4) Staggered conformation
33. The correct statement(s) about the following compound
H 3C OH HC CH CH CH OH CH 3 is______
1) It has total 6 stereoisomers
2) If the stereochemistry about the double bond is trans, the number of enantiomers possible
is 4
3) If the stereochemistry about the double bond is cis, the number of enantiomers possible
is 4
4) All the above.
CH 3
CH 3
H 3C CH 3
1) 2)
CH 3
CH 3
H 3C
3 CH
3) 4)
35. The number of stereoisomers possible for 2,3-dichloro butane is____
1)2 2) 3 3)4 4)5
36. Which of the following is not meso 2,3-butanediol?
CH 3 OH
H C OH H C CH 3
H C CH 3 H C CH 3
1) OH 2) OH
CH 3 H
HO C H HO C CH3
H C CH 3 H C OH
OH 3 CH
3) 4)
37. The most stable conformation of ethylene glycol is___
1) Anti 2) Gauche 3) Partially eclipse 4) fully eclipsed
HC CH
3) 3 4) 3
1) CH 2 CH CH 2 OH 2)
OH
CH 3 CH 2 C CH 3
3) 4)
OH
CH 3
40. The IUPAC name of is
CH CH CH COOC H
3 2 2 5
42. IUPAC name of is_____
1)2-ethyl –ethyl acetate 2)Ethyl-2-methyl butanoate
3)Ethyl-3-methyl butanoate 4)2-methyl butanoic acid
2 3
43. The ratio of the number of sp, sp & sp hybrid orbitals in the compound
CH 3 CH C CH C C CH 3 is___
1) 1:1:1 2)2:2:1 3)3:2:1 4)3:3:4
44. Assertion(A):The boiling point of Cis-2-butene is more than trans-2-butene
Reason(R): All trans isomers have zero dipole moment.
1) Both A&R are true and ‘R’ is the correct explanation of A.
2) Both A&R are true and ‘R’ is not the correct explanation of A
3) A is true but R is false
4) A is false but R is true
45. The correct statements in the following is(are)___
I) IUPAC name of pyruvic acid is 2-oxo propanoic acid.
II) Lactic acid is optically inactive
III)Functional isomer of propanoic acid is methyl ethanoate.
1) Only I 2)I&II 3)I,II&III 4)I&III
46. Column-I(Compound) Column-II(Common name)
A) CH 3 OH P) Malonic acid
B) CH 3 CH 2 4 COOH Q)Carbolic acid
COOH
O
1) O 2)
O
3) 4) O
49. Identify the correct statement(s)
I) All carbon atoms in acetamide are sp3 hybridized
H C OH
CH 3
50. Assertion (A): The compound is optically inactive
CH 3
H
Cl
C C
H Br , CH CH 3 2
,
H H 3C H 3C
H H
H ,O O, O
OH Ph
N
N NH
C
OH
C O O
H N
1 x x
1) 2 n cos ec 2 n cos ec 2 x 2) cos ec 2 n
cos ec 2 x
2 2 2
1 x 1 x
3) 2 n cos ec 2 n cos ec 2 x 4) 2 n cos ec 2 n cos ec 2 x
2 2 2 2
1 1
66. lim is equal to
h0 h·3 8 h 2h
1 4 16 1
1) 2) 3) 4)
12 3 3 48
f ( x) 5
67. Let f : R R be a function such that for some p 0, f ( x p ) for all x R .
f ( x) 3
Then, period of f is
1) 2p 2) 4p 3) 3p 4)5p
x2 9
for x 3 . If f (x) g(x) for all real values of x ,
68. Let f ( x) x 3 and g ( x ) x 3
k for x 3
then the value of k is equal to
1) 0 2) 3 3) -6 4) -4
69.
Let f ( x) [k ]2 5[k ] 4 x3 6{k}2 5{k} 1 x (tan x)(sgn( x)) , be an even function for
all, x R where [.] denotes G.I.F and {.} denotes fractional part function .Then the sum of all
possible values of 'k’
17 31 35 53
1) 2) 3) 4)
6 3 3 6
1
70. If f (x) is an even function and satisfies the relation x 2 f ( x) 2 f g ( x) , where g(x) is
x
an odd function, then f (5) equals to
50 49 52
1) 2) 3) 0 4)
73 75 37
log (1 x ) x 1
71. lim e is equal to
x0 2 x
x
1 1
1) 2) 3) 1 4) -1
2 2
2x 1
77. The function f ( x) [ x]cos , where [.] denotes the greatest integer function, is
2
discontinuous at
1) all x 2) all integer points
3) no x 4) x which is not an integer
x
78. f ( x ) max ,| sin x |, n N has maximum points of non-differentiability for x (0, 4) , then n
n
can’t be______
1) 4 2) 2 3) 5 4) 6
79. Which of the following function is differentiable at x 0
1) cos x x 2) cos x x 3) sin x x 4) sin x x
80. Consider [·] and {·} denote the greatest integer function and the fractional part function,
respectively.