1

NEET CRASH COURSE – 3.O

ATOMIC STRUCTURE DPP-02

1. Photoelectric effect shows

(1) particle-like behaviour of light 9. Which of the following sets of quantum number is
(2) wave-like behaviour of light correct for an electron in 4f orbital?
(3) both wave-liked and particle-like structure of (1) n = 3,  = 2, m = –2, s = + 1/2
light
(4) neither wave-like nor particle like behaviour of (2) n = 4,  = 4, m = –4, s = – 1/2
light (3) n = 4,  = 3, m = +1, s = + 1/2
2. Ultraviolet light of 6.02 eV falls on aluminium surface (4) n = 4,  = 3, m = +4, s = + 1/2
(work function = 4.2 eV). The kinetic energy (in joule)
of the fastest electron emitted is approximately 10. For a d-electron, the orbital angular momentum is
(1) 3 × 10–21 (2) 3 × 10–19 (1) 6(h / 2 ) (2) 2(h / 2 )
(3) 3 × 10 –17
(4) 3 × 10–15
(3) h/2 (4) zero
3. The threshold wavelength for photoelectric effect on
sodium is 5000 Å. Its work function is 11. The correct designation of an electron with n = 4, l = 3,
m = 2 and s = 1/2 is
(1) 4 × 10–19 J (2) 1 J
(3) 2 × 10–19 J (4) 3 × 10–10 J (1) 3d (2) 4f
(3) 5p (4) 6s
4. The wavelength of a cricket ball weighing 100 g and
12. The electrons identified by n and l
travelling with a velocity of 50 m/s is
(i) n = 1, l = 1 (ii) n = 4, l = 0
(1) 1.3 × 10–28 m (2) 1.3 × 10–37 m
(iii) n = 3, l = 2 (iv) n = 3, l = 1
(3) 1.3 × 10 m–34
(4) 1.3 × 10–30 m
can be placed in order of increasing energy, from
lowest to highest
5. If the uncertainty in the position of an electron is zero, (1) (iv) < (ii) < (iii) < (i)
the uncertainty in its momentum be (2) (ii) < (iv) < (i) < (iii)
h (3) (i) < (iii) < (ii) < (iv)
(1) zero (2)
2 (4) (iii) < (i) < (iv) < (ii)
h
(3) (4) Infinity
4 13. The correct set of quantum numbers for the unpaired
electron of chlorine atom is
6. If uncertainty in the measurement of position and n  m
momentum of an electron are equal then uncertainty in (1) 2 1 0
the measurement of its velocity is approximately (2) 2 1 1
(1) 8 × 1012 ms–1 (2) 6 × 1012 ms–1 (3) 3 1 1
(3) 4 × 10 ms
12 –1
(4) 2 × 1012 ms–1 (4) 3 0 0

7. For each value of , the number for ms values are 14. Presence of three unpaired electrons in phosphorous
atom can be explained by
(1) 2 (2) n (1) Pauli’s rule (2) Uncertainty principle
(3) 2 + 1 (4) n –  (3) Aufbau’s rule (4) Hund’s rule

15. Which electronic configuration does not follow the

8. A subshell with n = 6,  = 2 can accommodate a Pauli’s exclusion principle?
maximum of (1) 1s2, 2s2 2p4 (2) 1s2, 2s2 2p4, 3s2
(1) 10 electrons (2) 12 electrons (3) 1s2, 2s2 (4) 1s2, 2s2 2p6, 3s3
(3) 36 electrons (4) 72 electrons
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Answer Key

1. (1) 9. (3)
2. (2) 10. (1)
3. (1) 11. (2)
4. (3) 12. (1)
5. (4) 13. (3)
6. (1) 14. (4)
7. (3) 15. (4)
8. (1)

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