-1-

Battle Field Papers 01 - 25

l,dm iu;=,s;;dj .eg`M
Battle Field 01 (06 - c)
3 3
01. ldur WIaK;ajfha § I2 c,Sh ødjKhlska 150 cm yd CCl4 100.0 cm iuÕ fyd|ska fid,jd iu;=,s;;djhg
m;aùug ;nhs. I2 j,ska 75% la CCl4 l,dmhg ksiaidrKh jQfha kï CCl4 yd c,h w;r I2 ys jHdma;s ix.=Klh KD
.Kkh lrkak.

Battle Field 03 (06 - b)

-3 3 3
02. tla;rd WIAK;ajhl oS 1.2 moldm jQ NH4OH ødjKh 50cm la CHCl3 50cm la iu`. ñY% lr iu;=,s;;djhg
t<öug bv yßk ,oS' iu;=,s;;djhg t<eö miq c,Sh ia;rh fjka lr thg ;kql MgCl2 ødjKh ìxÿ jYfhka
2+ -7 -3
tl;= lr ,oS' wjlafIamhla ,eîu wdrïN jk úg ødjKfha Mg (aq) idkaøKh 4.7 x 10 mol dm nj ksÍCIKh
úh.
-5 -3
NH4OH ys Kb = 1.8 x 10 moldm
-11 3 -9
Mg(OH)2 ys Ksp = 1 x 10 mol dm
(i) fuu l%shdj,sfha mej;sh yels iu;=,s;;d wjia:d i|yd iólrK bosßm;a lrkak'
(ii) c,Sh ia:rh yd CHCl3 ia;rh w;r wefudakshd jHdma;sh i|yd oS we;s WIAK;ajfhaoS jHDma;sh ix.=Klh KD
fidhkak'

Battle Field 04 (06 - c)

03. A iy B jdIamYS,S øj 02 ñY% l< úg mßmQ¾K ødjKhla idohs' fuu ñY%Kh tys jdIamh iu`. iu;=,s;;djhla
we;slr .kS' A iy B f.a ix;Dma; jdIam mSvk PA0 yd PB0 o jdIam l,dmfha A iy B j, ujq, Nd. ms<sfj,ska
XA1 iy XB1 o jdIamfha uq¨ mSvkh P o fõ'

1 1
1 1− XA XA
(i) = 0 + 0
nj fmkajkak'
p PB PA

(ii) PA0 iy PB0 ms<sfj,ska 3 x 104 Pa iy 2 x 104 Pa o jdIamfha B j, ujq, Nd.h 0.6 la o kï jdIamfha uq¨ mSvkh
.Kkh lrkak'
(iii) jdIAmfha A iy B j, wdxYsl mSvk .Kkh lrkak'
(iv) ixhq;sh iu`. jdIam mSvk úp,kh iy ;dmdxl úp,kh fjk fjku o< m%ia;dr .;lr kï lrkak'

Chemistry - Ujith Anjana Hemachandra [fojk msgqj n,kak'

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Battle Field 05 (06 - b)

θ θ
04. (i) tla;rd WIAK;ajhl oS A yd B øj foll ix;Dma; jdIam mSvk ms<sfj,ska PA yd PB ne.ska fõ' tu
WIAK;ajfha oS A yd B øj ñY%Kh mßmQ¾K f,i yeisf¾' øj ñY%Kfha A yd B ujq, Nd. XA yd XB kï tu
ñY%Kh iu`. iu;=,s;j mj;sk jdIam l,dmfha A ys ujq, Nd.h

o
X AP A
o o nj fmkajkak'
XA P A + X BP B

(ii) 300 K ysoS X(l) yd Y(l) j, ix;Dma; jdIam mSvk ms<sfj,ska 40 Kpa yd 60 Kpa ne.ska fõ' 300 K ys X ys ujq, 3
la yd Y ujq, 02 la wvx.= ñY%Kh tajdfha jdIam iu`. iu;=,s;j mj;S'

a. X ys jdIam mSvk md;kh fldmuKo @

b. X ys jdIam mSvkh .Kkh lrkak'
c. jdIam l,dmfha X ys ujq, Nd.h .Kkh lrkak'

Battle Field 07 (06 - c)

05. (i) A yd B hk ñY% øjj,ska iE§ mßmQ¾K ødjKhl A hk øjHhg wod<j rjq,a kshuh oelafjk .‚;uh
m%ldYkhla ,shkak'
(ii) ;dmdxlh ms<sfj,ska TA yd TB jk A yd B kï øj fol ´kEu wkqmd;hlska ñY% jk w;r mßmQ¾K
ødjKhla idohs' A yd B iukaú; ujq, wkqmd;h 2:3 jk x kï ødjKhl iuia; jdIam mSvkh 2.8 x
104 Pa fõ' A yd B ys iu ujq,sl ñY%Khla jk Y kï ødjKhl iuia; jdIam mSvkh 3.0 x 104 Pa
fõ.

Battle Field 10 (06 - b)

3 3 -3 3
06. ldur WIaK;ajfha § CHCl3100cm iy c,h 80cm la wvx.= ma,dial=jlg 1 mol dm ødjKhlska 20cm la
3
tl;= lrk ,§' ma,dial=fõ ;sfnk oE fydÈka ñY% lrk ,§' ma,dial=fõ we;s c,Sh NH3 ia:rfhka 25cm la
-3 3
iïmQ¾Kfhka WodiSklrKh i|yd 0.2 mol dm HCl ødjKhl 20cm la jeh fõ'

(i) CHCI3 yd c,Sh ia:drj, NH3idkaøK .Kkh lrkak'

(ii) ldur WIaK;ajfha § H2Oyd CH3CIl,dm w;r NH3 jHdma;sh i|yd jHdma; ix.=Klh .Kkh lrkak'
-3 3 3
(iii) 0.1 mol dm NiSO4 ødjKhlska 25 cm iu. c,Sh NH3 ødjKhlska 25 cm la ñY% lrk ,§' fuhska ieÿKq ;o
3
ks,a meye;s ødjKh CHCI3100cm iu. fyd¢ka fid,jd iu;=,s;;djhg t<öug i<iajk ,§' CHCI3
3 -3 3
iaa:rfhka 25 cm l we;s wefudakshd WodiSk lsÍu i|yd 0.02 mol dm HClødjKhlska 20 cm la jeh úh'
3 -3
;o ks,a meye;s c,Sh ia:rfhka 25 cm l we;s wefudakshd WodiSk lsÍu i|yd 1.2 mol dm HClødjKhlska
3
7.6 cm la jeh úh' my; tAjd .Kkh lrkak'
I. CH3CI ia:rfha NH3 idkaøKh .Kkh lrkak'
II. c,Sh ia:rfha we;s ksoyia NH3 idkaøKh .Kkh lrkak'
III. c,Sh ia:rfha we;s iuia; NH3idkaøKh .Kkh lrkak'
2+ 2+
IV. Ni whkhg NH3wKq ix.; ùfuka iEfok ixlS¾Kfha iQ;%h [Ni(NH3)6] nj fmkajkak.

Chemistry - Ujith Anjana Hemachandra [;=kajk msgqj n,kak'

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Battle Field 11 (06 - a,b)

(07) a. A kï ldnksl ixfhda.h c,h iy CCl4 iuÕ m%;sl%shd fkdlrhs' T WIaK;ajfha § c,h yd CCl4 w;r A ys
CCl[A]
jHdma;sh i|yd jHdma; ix.=Klh KD = 4
fõ'
[A] (aq) = 16 - 0
A ys ujq, 0'1 la wvx.= c,Sh ødjK 100.00 cm3 la iy A ys ujq, 0'4 la wvx.= CCl4 ødjK 50.00 cm3 m%;sldrl
fnda;,hlg tl;= lr T WIaK;ajfha mj;ajd .kakd ,È'
I. tu WIaK;ajfha § moaO;sh iu;=,s;;djhg m;aùu i|yd tys ljrla isÿfõo hkak iqÿiq .Kkh
lsÍulska wfmdaykh lrkak'
II. iu;=,s;;djhg m;a jQ miq CCl4 ia:rfha we;s A ys ujq, m%udKh .Kkh lrkak'
b. X yd Y hk øj foflys ñY%K mßmQ¾Kj yeis f¾' 25 oC WIaK;ajfha we;s X ujq, 2.1 la iy Y ujq, 3.9
la we;s X yd Y øj ñY%Kh iuÕ iu;=,s;j mj;sk jdIamfha jdIam mSvkh 2.4 ´ 104 Pa fõ' tu jdIam
l,dmfha Y ys ujq, Nd.h 0.25 ls'
ii. 25 oC § X yd Y j, ix;Dma; jdIam mSvk .Kkh lrkak'
ii. X yd Y ñY%K j, uq¿ jdIam mSvkh øj l,dmfha ixhq;sh wkqj úp,kh jk wdldlrh jdIam mSvk ixhq;s
m%ia;drhlska olajkak'
iii. 25 oC WIaK;ajfha we;s" jdIamh iuÕ iu;=,s;j mj;sk ñY% øjfhys X ujq, 0.2 la o Y ujq, 0.3 la o we;'
tys uq¿ jdIam mSvkh .Kkh lrkak'

Battle Field 13 (05 - b)

(08). c,h iy laf,darf*daï (CHCl3) w;r wefudakshd ys jHdma;s ix.=Klh ks¾Kh lsÍu i|yd isÿl<
mÍCIKhl § c,Sh wefudakshd iy laf,darf*daï mßud folla m%;sldrl fnda;,hlg f.k fyd¢ka
fid,jd ldur WIaK;ajfha § iu;=,s; ùug ;nk ,o' iu;=,s; moaO;sfha c,Sh ia:rfhka 10 cm3 l we;s
wefudakshd iïmQ¾Kfhka WÞiSk lsÍug 0.25 mol dm-3 jQ HCl ødjKhlska 32.8 cm3 jeh úh' laf,darf*daï
ia:rfhka 25 cm3 l we;s wefudakshd iïmQ¾Kfhka u WÞiSk lsÍug 0.05 mol dm-3 jQ HCl ødjKhlska
16.4 cm3 jeh úh'
ii. ldur WIaK;ajfha § c,h iy laf,dafrf*daï w;r wefudakshd j, jHdma;s ix.=Klh .Kkh lrkak'
ii. wefudakshd laf,darf*daï j, Èhjk jdg jvd c,h ;=< fyd¢ka Èhjkafka wehs±hs myokak'
iii. 0.025 mol dm-3 CuSO4 ødjKhla m%;sldrl fnda;,hlg f.k thg jeämqr c,Sh wefudakshd iy
laf,darf*daï mßud folla ñY% lr ldur WIaK;ajfha § iu;=,s;;djhg m;a ùug bv yßk ,È' iu;=,s;
moaO;sfha c,Sh ia:rfha uq¿ wefudakshd idJøKh 0.400 mol dm-3 jk nj o laf,darf*daï ia:rfha uq¿
wefudakshd idJøKh 0.012 mol dm-3 jk nj o fidhd .kakd ,È'
1. c,Sh ia:rfha we;s ksoyia wefudakshd idJøKh .Kkh lrkak'
+2
2. [Cu(NH3)n] ixlS¾Kfha n ys w.h .Kkh lrkak'
3. c,Sh yd laf,darf*daï ia:rj, wefudakshd idJøK ks¾Kh lsÍug HCl wï,h iuÕ wkqudmkh
lsÍfï § Tn úiska ms<smeÈh hq;= lreKq folla i|yka lrkak'

Battle Field 14 (06 - b/ii)

(09). A yd B ñY% ù mßmQ¾K ødjKhla idohs' 298 K ys 2 mol lska iy B 3 mol lska iukaú; ødjKhl uq¿ jdIam
mSvkh 6.4 ´ 104 Pa fõ' fï WIaK;ajfha § ixY=oaO A ys jdIam mSvkh 5.0 ´ 104 Pa fõ'
i. 298 K § ixY=oaO B ys jdIam mSvkh .Kkh lrkak'
ii. 298 K § mj;sk by; ødjKh iuÕ iu;=,s;j mj;sk jdIam l,dmfha A yd B ys ujq, Nd.
.Kkh lrkak'
iii. by; moaO;sfha jdIam mSvk ixhq;s jl%fha o< igykla w¢kak'
^tys uq¿ jdIam mSvkh PAB, A yd B ys wdxYsl mSvk PA yd PB úp,khka o ±laúh hq;= h'&

Chemistry - Ujith Anjana Hemachandra [y;rjk msgqj n,kak'

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Battle Field 15 (06 - b)

10. NH3 ødjK 25 cm3 lg 0.10 mol dm-3 CuSO4 25 cm3 la oud thg CHCl3 25 cm3 la tla lr idÞ .kakd ,o
moaO;sh i,luq' fuu moaO;sh iu;=,s;;djhg m;a jQ miq CHCl3 ia:rfha 25 cm3 wkqudmkh lsÍug
0.020 mol dm-3 HCl 30 cm3 la jeh úh' c,Sh ia:rfha 25 cm3 la wkqudmkhg 1.0 mol dm-3 HCl 20 cm3 la jeh
úh' fuu WIaK;ajfha § H2O yd CHCl3 w;r NH3 ys jHdma;s ix.=Klh 25 la jQ úg"

ii. CHCl3 ia:rfha mj;sk ujq, .Kk

ii. c,Sh ia:rfha mj;sk NH3 ujq, .Kk fidhkak'
iii. c,Sh ia:rfha mj;sk Cu2+ whk NH3 iuÕ ix.; ixlS¾Khla idÞ we;akï tu ix.; ixlS¾Kfha
iQ;%h .Kkh lrkak'
iv. iEfok ixlS¾Kfha j¾Kh l=ula o@
v. fuys § Tn isÿlrk Wml,amkhla ,shkak'

Battle Field 17 (05 - a,b,c)

11.(a) (i) mßmQ¾K ødjKhla hkafkka l=ula woyia flf¾ o?

(ii) ksh; WIaK;ajfha oS ixjD; moaO;shl jdIam l,dmh iu`. iu;=,s; j mj;sk tlsfkl m%;sls%hd fkdlrk A
yd B j,ska hq;a mßmQ¾K oajHx.S ødjKhla i,lkak' moaO;sfha mj;sk ish¨ u .;sl iu;=,s;;d ,shd
olajkak'
(iii) by; A iyNd.S jk .;sl iu;=,s;;djfha bosß m%;sls%hdj iy miq m%;sls%hdj i`oyd YS>%;d m%ldYk ,shkak'
(Ndú; lrkq ,nk mo y`ÿkajkak')
o
(iv) ta khska PA = PA . xA hk m%ldYkh jHq;amkak lrkak.
fuys PA - A ys wdxYsl jdIam mSvkh
o
PA - A ys ix;Dma; jdIam mSvkh
xA - øj l,dmfha A ys ujq, Nd.h
3
(b) A yd B øjj,ska V (V = 0.8314 dm ) ne.ska f.k mßudj 100.8 V jk f¾pkh lrk ,o Ndckhlg tl;= lr
5
iu;=,s; ùug bv yßk ,oS' 300K oS iuia; jdIam mSvkh 3.00 x 10 Pa fõ. 300K oS A yd B øjj, ujq,sl mßud
-2 3 -1 -2 3 -1
ms<sfj,ska 8.314 x 10 dm mol yd 4.157 x 10 dm mol ne.ska fõ' A yd B j,ska hq;a ødjKh mßmQ¾K f,i
yeisf¾'
(i) ñY% lrk ,o A yd B ys ujq, m%udK fjk fjku .Kkh lrkak'
(ii) jdIam l,dmfha A ys ujq, Nd.h 0.2 kï A yd B ys wdxYsl jdIam mSvk fjk fjk u .Kkh lrkak.
(iii) jdIam l,dmfha mßudj 100 V f,i Wml,amkh lr jdIam l,dmfha A yd B ys ujq, m%udK fjk fjku
.Kkh lrkak'
(iv) 300K oS A yd B ys ix;Dma; jdIam mSvk fjk fjk u .Kkh lrkak.
(v) A yd B øj iïmQ¾Kfhka u jdIamSlrKh jk mßos by; moaO;sfha WIaK;ajh jeä lrk ,oS' túg A jdhqj
muKla A(g) ⇌ 2C(g) f,i Nd.sl f,i ú>gkh fõ. fufia moaO;sh iu;=,s; jQ úg 403.2K WIaK;ajfha oS
iuia; mSvkh 1.4 x 106Pa úh.
(I) moaO;sfha uq`M jdhq ujq, ixLHdj .Kkh lrkak.
(II) 403.2K ys oS tla tla ixrplfha wdxYsl mSvk .Kkh lrkak'
(III) 403.2K ys oS by; (v) ys iu;=,s;;dj i`oyd iu;=,s;;d ksh;h KP .Kkh lrkak'

Chemistry - Ujith Anjana Hemachandra [miajk msgqj n,kak'

 -5-

3
(c) X hk j,a kdYlh ñY% ùu ksid c, idïm,hlaBattlewmú;%
Field j
05we;'
(09 tu
- a)wmú;% c,h 200 cm l idïm,hlska X bj;a
3
lsÍug ie,iqï lrk ,o mÍlaIKhla i`oyd Tng vhst;s,a B;¾ 150 cm la imhd we;. imhk ,o B;¾ m%udKh
3
50 cm ne`.ska fhdod .ksñka wkqhd; ksiaidrK ;=klska isÿ lsÍug n,dfmdfrd;a;= fõ' wod< WIaK;ajfha oS B;¾
yd c,h w;r jHdma;s ix.=Klh 16 la fõ' (j,a kdYlh B;¾ udOHfha jvd fyd`oska øjKh fõ')
(i) c,h yd B;¾ w;r X jHdma; ùug wod< iu;=,s;h yd KD i`oyd m%ldYkh ,shkak.
(ii) m<uq ksiaidrKfhka miq c,fha b;sß jk X m%udKh wdrïNl m%udKfha Nd.hla f,i m%ldY lrkak.
(iii) wkqhd; ksiaidrK ;=klg miq B;¾ ;=<g ksiaidrKh jQ X m%udKh m%;sY;hla f,i olajkak.
(iv) by; .Kkfha oS Tn úiska i,lk ,o Wml,amk folla i`oyka lrkak'

Battle Field 25 (06 - b)

θ θ
12. (i) tla;rd WIAK;ajhl oS A yd B øj foll ix;Dma; jdIam mSvk ms<sfj,ska PA yd PB ne.ska fõ' tu
WIAK;ajfha oS A yd B øj ñY%Kh mßmQ¾K f,i yeisf¾' øj ñY%Kfha A yd B ujq, Nd. XA yd XB kï tu
ñY%Kh iu`. iu;=,s;j mj;sk jdIam l,dmfha A ys ujq, Nd.h

o
X AP A
o o
nj fmkajkak'
XA P A + X BP B

(ii) 300 K ysoS X(l) yd Y(l) j, ix;Dma; jdIam mSvk ms<sfj,ska 40 Kpa yd 60 Kpa ne.ska fõ' 300 K ys X ys ujq, 3
la yd Y ujq, 02 la wvx.= ñY%Kh tajdfha jdIam iu`. iu;=,s;j mj;S'

a. X ys jdIam mSvk md;kh fldmuKo @

b. X ys jdIam mSvkh .Kkh lrkak'
c. jdIam l,dmfha X ys ujq, Nd.h .Kkh lrkak'

Chemistry - Ujith Anjana Hemachandra