SAMPLEPAPERSESSI

ONENDI
NG2019-
20

Bl
uePr
int
Cl
assXI
Subj
ect
:Chemi
str
y
SA SA
Long
-
I -I
I T
V answ
(2 (3 o
Uni
t Tit
le/ S er
m m t
No. chapter A quest
ar ar a
(
1mar
k) i
ons
ks ks l
(5)
) )
SomeBasi c
1 Conceptsof 2(
1) 1(
1) - -
Chemistr
y
2 St
ruct
ureofAt
om 4(
1) - 1(
3) -
15
Classif
icati
onof
Element sand
3 2(
1) 1(
2) - -
Peri
odicit
yin
Properti
es
Chemi calBondi ng
4 andMol ecular 1(
1) 1(
2) 1(
5)
Structure
StatesofMat ter:
5 1(
1) 1(
2) - -
GasesandLi quids 21
Chemi cal
6 1(
1) - 1(
3) -
Ther mody namics
7 Equi
l
ibr
ium 1(
1) - - 1(
5)

8 RedoxReact
ions 2(
1) - 1(
3) -

9 Hy
drogen 2(
1) 1(
2) - -
16
10 s-
BlockEl
ement
s 2(
1) 1(
2) - -

11 p-
BlockEl
ement
s - - 1(
3) -
Organic
Chemi
stry:Some
12 1(
1) - 1(
3) -
basi
cPrincipl
es
andTechniques
13 Hy
drocar
bons 1(
1) 1(
2)- 1(
3) 1(
5) 18
Envi
ronmental
14 1(
3) -
Chemist
ry
20(
1) 7(
2) 7(
3) 3(
5) 70
 SAMPLEPAPER(
2019-
20)
CLASS:
XI
SUBJECT:
CHEMI
STRY
Ti
meal
lowed:
3hour
s
M.
Marks:70
Gener
alI
nst
ruct
ion:
-
(
1)Al
lquest
ionsar
ecompul
sor
y.
(
2)Quest
ionno.1t
o20ar
eVSA/obj
ect
ivet
ypequest
ionsandcar
ry1mar
keach.
(
3)Quest
ionno.21t
o27ar
eshor
tanswerquest
ionsandcar
ry2mar
kseach.
(
4)Quest
ionno28t
o34ar
eal
soshor
tanswerquest
ionsandcar
ry3mar
kseach.
(
5)Quest
ionno.35t
o37ar
elonganswerquest
ionsandcar
ry5mar
kseach.
(
6)Usel
ogt
abl
esi
fnecessar
y.Useofcal
cul
ator
snotal
l
owed.

1 Outofi
ceandwat
erwhi
chonei
sheav
ier
?Why 1
OR
Per
hydr
oli
sthet
radenameofwhi
chchemi
cal
speci
es.
2 Whathappenswhenquickl
i
mei
sheat
edwi
thsi
l
icawr
it
e 1
chemi
calreact
iononl
y?
OR
Asol
uti
onofsodi
um car
bonat
eisal
kal
i
ne.Why
?
3 Wr
it
etheLawofChemi
cal
Equi
l
ibr
ium. 1
OR
Def
inebuf
fersol
uti
ons.
4 Whati
stheoxi
dat
ionst
ateofKi
nKO2? 1
5 Wri
teI
UPACnamesoft
hegi
venor
gani
ccompound: 1
(
CH3)3CCH2C(
CH3)
3.
6 Gi
veI
UPACnameoft
heel
ementwi
that
omi
cno.
117. 1
OR
Wr
it
eanexampl
eofamphot
eri
coxi
de.
7 Gi
vet
heor
bit
aldesi
gnat
ioni
fa)n=3&l
=2 1

8 Condi
ti
onofspont
anei
tyi
s 1
(
a)∆H<O (
b)∆G<O (
c)∆S<O (
d)∆U<O
9 Gi
vet
henumberofnodei
n3d. 1
10 Wr
it
ePaul
i
’sexcl
usi
onpr
inci
ple. 1
11 Thehy
bri
disat
ionst
ateofCl
F3i
s 1
a)SP3 (
( b)SP3d (
c)SP3d2 (
d)Sp3d3
12 Gi
vet
he%ofcar
boni
nC2H5OH. 1
13 Whi
chi
smor
econcent
rat
ed?1M or1m f
oraqueoussol
uti
ons. 1
14 Theel
ementhav
eat
omi
cnumber23,
SoI
t’
sgr
oupi
s…………. 1
15 Wri
tet
her el
ati
onbet
weenpr
essur
edensi
tyandmol
armassof 1
ani
dealgas.
16 Whi
chi
snotshowi
ngi
deal
gasr
elat
ionshi
p; 1
(
a)PV=nRT (
b) P=CRT (
c) PV=w/
mRT (
d)
P=dRT
17 Wr
it
enameofr
adi
oact
ivei
sot
opesofHy
drogen. 1
18 ThepHofaqueoussol
uti
onofNaCl
is; 1
(
a)5 (
b) 6 (
c)7 (
d)4
19 Whi
chi
smor
ecov
alent
;Al
Cl3orMgCl
2? 1
OR
Whi
chi
smor
esol
ubl
einwat
er?Al
Cl3orMgCl
2?

20 Numberofpi
elect
ronsi
nbenzene; 1
(
a)5 (
b) 6 (
c)3 (
d)4

OR
Wr
it
eHuckel
’
srul
e.
21 Acompoundcont ai
ns4.07%hy dr
ogen,24.
27%carbonand 2
71.
65%chl or
ine.I
tsmolarmasses98.96g.Whatar
eit
s
empir
ical
andmol ecul
arfor
mulas?
22 Gi
vesui
tabl
ereasonf
ort
hef
oll
owi
ngst
atement
: 2
i
)NaCl
hashi
gherboi
l
ingpoi
ntt
hanKCl
.
i
i
)Al
kal
imet
alsar
egoodr
educi
ngagent
.
OR
Wr
it
ethechemi
cal
react
ioni
nvol
vedi
nfol
l
owi
ng:
i
)Sodi
um met
ali
sdr
oppedi
nwat
er?
i
i
)Sodi
um per
oxi
dei
sdi
ssol
vedi
nwat
er
23 Whatdoyouunder
standby(
i)el
ectr
on-def
ici
ent
,and(
ii
) 2
el
ect
ron-
ri
chcompoundsofhydr
ogen?Expl
ainwit
hsui
tabl
e
 exampl
es.
24 Whytheelect
rongai
nent
hal
pyofchl
ori
nei
shi
ghert
han 2
f
luor
ine?
25 Whyparani
tr
ophenol
hav
ehi
gherboi
l
ingpoi
ntt
hanor
thoni
tr
o 2
phenol
.
26 Wr
it
eanyonechemi
cal
react
ionf
orf
oll
owi
ngnamer
eact
ion: 2
i
)Wur
tzr
eact
ion
i
i
)Fr
iedel
craf
tal
kyl
ati
on.
OR
Dist
ingui
shbet
weenfol
lowi
ngpai
rofcompoundont
hebasi
sof
chemicalt
est[
anyone]
.
i
)Et
hane&Et
hene
i
i
)Benzene&Et
hene
27 Whatwil
lbethepressureofthegaseousmixtur
ewhen0.
5Lof 2
H2at0.8barand2.0Lofdi oxy
gen(O2)at0.7barar
e
i
ntr
oducedina1Lv esselat27°C?
28 whatdoyoumeanbyGreenChemist
ry?Wr
it
eany2useof 3
Gr
eenChemist
ryi
nday
-to-
dayLif
e.
29 Gi
ver
easonsf
orf
oll
owi
ng: 3
(
i)[
SiF6]
-2i
sknownwher
eas[
SiCl
6]–2notknown.
(
ii
)Di
amondi
scov
alent
,yeti
thashi
ghmel
ti
ngpoi
nt.
(
ii
i)COi
spoi
sonous.
30 Defi
neentropyandfi
ndthesi
gnof∆Hand∆S (
posi
ti
veor 3
negat
ive)f
orthereact
ion
Cl
2(
g)-
--
--
--
--
→2Cl
(g)
31 (
a)Writ
etheelectronicconf
igur
ationofCu. 3
(
b)Expl
ainthesignif
icanceofHeisenber
g’suncer
tai
nty
pri
nci
ple.
32 Bal
ancet
her
edoxr
eact
ioni
naci
dicmedi
um; 3
2- 3+
Cr
2O7 + SO2 -
--
--
--
--
--
→ Cr +SO42-+H2O
33 Compl
etet
hef
oll
owi
ngr
eact
ions: 3
C6H5OH+Zn→ _
___
___+_
___
___
__
C6H6+Cl
2AnhyAl
Cl3_
___
___
_+_
___
___
___
_
C6H5COONa+Sodal
i
meheat_
___
__+_
___
___
___
34 Def
inef
oll
owi
ng: 3
 (
i)Posi
ti
veResonanceEf
fect(
+Ref
fect
)
(
ii
)Hy
perconj
ugat
ion
(
ii
i)
Dif
fer
ent
ial
Ext
ract
ion
OR
(i
)Whyanorgani
cli
quidvapor
izesatat
emper
atur
ebel
owi
ts
boil
i
ngpoi
ntinit
ssteam
di
sti
l
lat
ion?
(
ii
)Whyisitnecessar
ytouseacet
icaci
dandnotsul
phur
icaci
d
f
oraci
dif
icat
ionofsodium
ext
ractf
ort
est
ingSul
phurbyl
eadacet
atet
est
?
(
ii
i)Wr
it
ethemet
hodofpr
epar
ati
onofl
assagi
ne’
sext
ract
35 (
i)Def
inef
oll
owi
ngt
erms: 5
(
a)Lat
ti
ceent
hal
py(
b)BondOr
der
(
ii
)Dr
awt
heshapeandwr
it
ethehy
bri
disat
ionoff
oll
owi
ng
(
a)Cl
F3(
b)SF4(
c)XeF4
OR
(i
)whatyoumeanbyt er
m‘ Hybr
idi
sat
ion’
.Wr
it
eimpor
tant
condi
ti
onsforhy
bri
dizat
ion.
(
ii
)Compar
ether
elat
ivest
abi
l
ityoft
hef
oll
owi
ngspeci
eswi
th
t
hehel
pofM.Odi
agramsand
i
ndi
cat
ethei
rmagnet
icpr
oper
ti
es;
O2,
O2
+O2
-(
super
oxi
de
36 (
i)Def
ineHomogenousEqui
l
ibr
ium. 5
(
ii
)Der
iver
elat
ionbet
weenKpandKc.
(i
i)PCl
5,PCl3andCl2areatequi
l
ibr
ium at500Kandhav
ing
concent
rat
ion1.59M PCl
3,1.
59M
Cl
2and1.
41M PCl
5.Cal
cul
ateKcf
ort
her
eact
ion,
PCl
5⇌ PCl
3+
Cl
2
OR
(
i)wr
it
eBr
önst
ed-
Lowr
ytheor
yofaci
dbase.
(i
i
)Thespeci
es:H2O,HCO3-,
HSO4-andNH3canactbot
has
Bronst
edaci
dsandbases.
Foreachcasegi
vet
hecor
respondi
ngconj
ugat
eaci
dand
 conj
ugat
ebase.
(
ii
i)Der
iveI
oni
zat
ionConst
ant
sforaWeakDi
-basi
cAci
d.
37 (
i)Whyisbenzeneext
raor
dinar
il
yst
abl
ethoughi
tcont
ains 5
t
hreedoubl
ebonds?
(i
i
)Howwouldy
ouconv
ertt
hef
oll
owi
ngcompoundsi
nto
benzene?
(
a)Et
hyne(
b)Hexane
Wr
it
echemi
cal
equat
ioni
neach.
OR
(i
)WhyisWur t
zr eact
ionnotpr
efer
redforthepr
epar
ati
onof
al
kanescontai
ningoddnumberofcar bonatoms?I
ll
ust
rat
eyour
answerbytaki
ngoneexampl e.
(
ii
)Wr
it
echemi
cal
equat
ionsf
ort
hef
oll
owi
nghy
drocar
bons:
(
a)combust
ionr
eact
ionofBut
ane
(
b)Addi
ti
onofHBronPr
openei
nthepr
esenceofPer
oxi
de
(
c)Hy
drat
ionofet
hyne
 SAMPLEPAPERSESSI
ONENDI
NG2019-
20
MARKI
NGSCHEME

1 Wat
erduet
ohi
ghdensi
ty 1
OR
hy
drogenper
oxi
de
2 CaO+Si
O2→ CaSi
O3 1
OR
NaOHi
sst
rongerbaset
hancar
boni
caci
d(weakaci
d)
3 atagi vent emper ature,
theproductofconcentrat i
onsofthereacti
on 1
productsr aisedtot her
especti
vestoichi
omet r
iccoef f
ici
enti
nt he
balancedchemi cal equati
ondividedbytheproductofconcent rat
ions
ofther eactantsr aisedtothei
rindivi
dualst
oichiomet r
iccoef
fici
ents
hasaconst antvalue.Thisisknownast heEquilibri
um LaworLawof
Chemi calEqui li
brium.
Or
Cor
rectdef
ini
ti
on
4 +1. 1
5 2,
2,4,
4-Tet
ramet
hyl
pent
ane 1
6 Ununsept
ium 1
OR
Anyamphot
eri
coxi
de
7 3d 1
8 Opt
ionb 1
9 2 1
10 Cor
rectdef
ini
ti
on 1
11 Sp3d 1
12 12/
44*
100=27.
2% 1
13 1M 1
14 5 1
15 P=dRT/
m 1
16 Opt
iond 1
17 Tr
it
ium 1
18 Opt
ionc 1
19 Al
Cl3 1
OR
MgCl
2

20 Opt
ionb 1
21 2

22 i
)NaCl
hashi
ghLat
ti
ceent
hal
py 2
i
i
)lowi
oni
sat
ionent
hal
py
OR
NaOH&H2i
sfor
med
NaOH&H2O2i
sfor
med
23 i
)elect
ron-def
ici
ent
:hastoof
ewelect
ronsf
orwr
it
ingi
tsconv
ent
ional 2
Lewisstr
uctur
e.ExDibor
ane(B2H6)
(i
ii
)el
ect
ron-r
ich:El
ect
ron-
ri
chhydr
ideshaveexcesselect
ronswhi
ch
arepr
esentaslonepair
s.El
ementsofgroup15-17for
m such
compounds.(NH3has1-lonepai
r,H2O–2andHF–3l onepai
rs)
24 Cor
rectexpl
anat
ionofel
ect
ron-
elect
ronr
epul
sion 2
25 I
tisduetointer
molecul
arhydr
ogenbondi
nginparani
tr
ophenol
and 2
i
ntr
amolecularhydr
ogenbondi
nginort
honit
rophenol
26 2RX+Na(
dryet
her
)→ R-
R+2NaX 2
C6H6+RX(
AnhyAl
Cl3)→ C6H5R+HX
Or
2
i
)Bay
er’
stestoranyot
her
i
i
)Bay
er’
stestoranyot
her
27 P=P1V1+P2V2/
V 2
P=0.
8x0.
5+2x0.
7/1
Cal
cul
ati
on
P=1.
8baroranyot
hermet
hod
28 Cor
rectexpl
anat
ion/
def
ini
ti
on 3
29 i
).si
xlar
gechl
ori
dei
onscannotbeaccommodat
edar
oundSi
4+duet
o 3
l
i
mi t
ati
onofi
tssi
ze.
(i
i
)Diamondhasathree-
dimensi
onalnet
worki
nvol
vi
ngstr
ongC—C
bonds,whi
char
everydif
fi
cultt
obreakand,
int
urnhashi
ghmelt
ing
point
(i
ii
)Iti
sdeadl
ypoi
sonousduetohigherstabi
l
ityofi
tshaemogl
obi
n
complexascompar
edtothatofoxy-haemoglobi
ncomplex
30 Cor
rectdef
ini
ti
onandchangei
nent
ropyandent
hal
pywi
l
lbeposi
ti
ve. 3
31 Cor
rectel
ect
roni
cconf
igur
ati
onandcor
rectsi
gni
fi
cance. 3
2-
O2+2H+- 3+
32 Cr
2O7 +3S --
--
--
--
--
→ 2Cr +3SO42-+H2O 3
33 i
)Benzene&Zi
ncoxi
de 3
(
ii
)Chl
orobenzene&HCl
(
ii
i)Benzene&sodi
um car
bonat
e

34 (i
)Posi
ti
veResonanceEffect(+Reff
ect
):t
het r
ansf
erofel
ect
ronsis 3
awayfr
om anatom orsubsti
tuentgr
oupattachedt
otheconj
ugated
syst
em.
(i
i
)Hy perconj
ugati
on:del
ocal
isati
onofᵟelectr
onsofC—Hbondofan
al
kylgroupdir
ectl
yatt
achedtoanat om ofunsatur
atedsy
stem ort
oan
atom wit
hanunsharedpor bi
tal
.
(i
i
i)Di
fferent
ialExt
ract
ion:Ext
ract
ionofcompoundt
akespl
acebased
ondif
ferenceinsolubi
l
ity
OR
(
i)I
nst
eam di
sti
l
lat
iont
hemi
xtur
eboi
l
swhensum ofv
apourpr
essur
e
 ofwaterandorgani
cliqui
dbecomesequaltoatmospher
icpr
essur
e.
Andthevapourpressureofwat
eri
shightheref
ore
(
ii
)ifsul
phur
icaci
disusedl
eadacet
atei
tsel
freactwi
thsul
phur
icaci
d
t
oform whit
epptofl
eadsul
phat
e
35 (
i)(
a)TheLatt
iceEnt
halpyofani
oni
csol
i
disdef
inedast
heener
gy 5
r
equir
edtocomplet
ely
separ
ateonemol
eofasol
i
dioni
ccompoundi
ntogaseousconst
it
uent
i
ons.
(b)BondOr
derisgi
venbyt
henumberofbondsbet
weent
het
wo
atomsinamolecul
e
(
ii
)(a)Tshapedsp3d(
b)SeeSawsp3d(
c)Squar
epl
anersp3d2
OR
(i
)theat
omi
corbi
tal
scombi
net
ofor
m newsetofequi
val
entor
bit
als
knownashy
bri
dorbi
tal
s.
Unli
kepur
eorbi
tal
s,t
hehy
bri
dor
bit
alsar
eusedi
nbondf
ormat
ion.The
phenomenoni
sknown
ashy
bri
disat
ion.
I
mpor
tantcondi
ti
onsf
orhy
bri
disat
ion
(
i)Theor
bit
alspr
esenti
nthev
alenceshel
loft
heat
om ar
ehy
bri
dised.
(i
i)Theorbi
tal
sunder
goi
nghy
bri
disat
ionshoul
dhav
eal
mostequal
energy.
(i
i
i)Promot i
onofel
ect
roni
snotessent
ial
condi
ti
onpr
iort
o
hybr
idisat
ion.
(i
v)I
tisnotnecessar
ythatonl
yhal
ffi
l
ledor
bit
alspar
ti
cipat
ein
hybr
idi
sat
ion.I
n
somecases,evenf
il
ledor
bit
alsofv
alenceshel
ltakepar
tin
hybr
idi
sat
ion.
(
ii
)MO’
sforal
lthemol
ecul
es,
36 (
i)al
lther
eact
ant
sandpr
oduct
sar
eint
hesamephase. 5
(
ii
)Der
ivat
ion
(
ii
i)Wr
it
ingcor
rectf
ormul
a,v
aluei
nfor
mul
a,cal
cul
ati
on,
resul
t
Kc=1.
79
OR
(i
)Accordi
ngt
oBr önst
ed-
Lowr
ytheor
y,aci
disasubst
ancet
hati
s
capabl
eofdonat
inga
hy
drogeni
onH+andbasesar
esubst
ancescapabl
eofaccept
inga
hy
drogeni
on,
H+.I
n
 shor
t,aci
dsar
epr
otondonor
sandbasesar
epr
otonaccept
ors.
(i
i)Correctconj
ugateaci
d( H3O+,H2CO3, H2SO4andNH4)and
conjugatebase(HO-,
CO3--,
SO4--andNH2-)
(
ii
)Der
ivat
ionwi
thal
lst
apes
37 i
)Thepr
esenceofdel
ocal
i
sedπel
ect
ronsi
nbenzenemakesi
tmor
e 5
st
abl
e.
expl
anat
ionbydi
agr
am

(
ii
)
(
i)Forahydrocarbonofoddnoofcar
bon,
wehav
etot
akedi
ff
erent
t
ypesofhalo-al
kanes,by
whi
chami
xtur
eofpr
oduct
swi
l
lfor
m.
(
ii
i)Cor
rectr
eact
ions