Major Test - 1 (Paper 2)

@JEEAdvanced_2024
(Academic Session: 2022 - 2023)

ONLINE CLASSROOM CONTACT PROGRAMME
JEE (MAIN + ADVANCED)

PHASE # I to VII
MAJOR TEST : 2
DATE : 05-03-2023
(PAPER : 2)
PATTERN : ADVANCED COURSE : NURTURE
READ THE INSTRUCTIONS CAREFULLY

Important Instructions:
1. This paper contains a total number of 54 questions.
2. The Questions appearing in the paper are based on Physics, Chemistry and Mathematics.
4. Duration of the test is 3 hours.
Your Hard Work Leads to Strong Foundation

 Digital
Corporate Address : One Biz Square, A-12 (a), Road No. 1, lndraprastha Industrial Area, Kota - 324005 (Raj.)
+91-9513736499 | +91-7849901001 | wecare@allendigital.in | allendigital.in
@JEEAdvanced_2024
Nurture Course/Phase-1 to 7/05-03-2023/Paper-2
PART-1 : PHYSICS
SECTION–I : (Maximum Marks : 24)
• This section contains EIGHT questions.
• For each question, enter the correct numerical value of the answer using the mouse and the
on-screen virtual numeric keypad in the place designated to enter the answer. If the
numerical value has more than two decimal places, truncate/round-off the value to TWO
decimal places.
• For each question, marks will be awarded in one of the following categories:
Full Marks : +3 ONLY if the correct numerical value is entered
Zero Marks : 0 In all other cases.
1. In given figure, an ideal gas is trapped between a mercury column and the closed end of a
uniform vertical tube. The upper end of the tube is open to the atmosphere. Initially the
lengths of the mercury column and the trapped air column are 12 cm and 50 cm
respectively. When the tube is tilted slowly in a vertical plane through an angle of 30° with
x
horizontal then the new length of air column is m. Find x . Assuming the temperature
41
to remain constant. (Patm =76 cm of Hg)
2. A closed tube in the form of an equilateral triangle of side  = 3m contains equal volumes
of three liquids which do not mix and is placed vertically with its lowest side horizontal.
Find 'x' (in meter) in the figure if the densities of the liquids are in A.P.
3. The specific heat of a substance varies with temperature according to c = 0.2 + 0.16 T +
0.024 T2 with T in °c and c is cal/gk. Find the energy (in cal) required to raise the temp of
2g substance from 0° to 5°C
 Digital www.allendigital.in [1]

@JEEAdvanced_2024
Target : JEE (Main + Advanced) 2024/05-03-2023/Paper-2
4. A person standing on the top of a cliff 30 m high has to throw a packet to his friend
standing on the ground 40 m horizontally away. If he throws the packet directly aiming at
125 20
the friend with a speed of m/s. Packet falls at a distance m from the friend. Here
3 α
α is an integer. Find α . [Use g = 10 m/s2].
5. A swimmer jumps from a bridge over a canal and swims 1 km up stream. After that first
km, he passes a floating cork. He continues swimming for half an hour and then turns
around and swims back to the bridge. The swimmer and the cork reach the bridge at the
same time. The swimmer has been swimming at a constant speed. How fast does the water
in the canal flow in km/hr.
6. The rear side of a truck is open and a box of 40 kg mass is placed 5 m away from the open
end as shown in figure. The coefficient of friction between the box and the surface below it
is 0.15. On a straight road, the truck starts from rest and accelerates with 2 ms–2. Find the
distance (in m) travelled by the truck by the time box falls from the truck. (Ignore the size
of the box).
7. Three identical uniform rods, each of length L and mass M, are joined to form a rigid
equilateral triangle. Its radius of gyration about an axis passing through a corner and
L
perpendicular to the plane of the triangle is where n is :
n
8. A uniform rod of mass m and length L is suspended with two massless strings as shown in
the figure. If the rod is at rest in a horizontal position the ratio of tension in the two strings
T1/T2 is:
T1 T2
3L/4
L
[2] www.allendigital.in  Digital

@JEEAdvanced_2024
SECTION–II : (Maximum Marks : 24)
• This section contains SIX multiple choice questions.
• Each question has four choices (A), (B), (C) and (D) out of which ONE or More Than One are
correct.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks : +2 If three or more options are correct but ONLY two options are
chosen, both of which are correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen
and it is a correct option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks : –2 For incorrect answer
9. An air bubble in a water tank rises from the bottom to the top. Which of the following
statements are true ?
(A) Bubble rises upwards because pressure at the bottom is less than that at the top.
(B) Bubble rises upwards because pressure at the bottom is greater than that at the top.
(C) As the bubble rises, its size increases.
(D) As the bubble rises, its size decreases.
10. The wires A and B shown in the figure, are made of the same material and have radii rA and
rB. A block of mass m kg is tied between them : If the force F is mg/3, one of the wires
breaks.
(A) A will break before B if rA < 2rB

(B) A will break before B if rA = rB
(C) Either A or B will break if rA = 2rB
(D) The lengths of A and B must be known to decide which wire will break

@JEEAdvanced_2024
11. A heavy particle is tied to the end A of a string of length 1.6 m. Its other end O is fixed. It
revolves as a conical pendulum with the string making 60o with the vertical. Then (g = 9.8
m/s2)
4π
(A) its period of revolution is sec.
7
(B) the tension in the string is double the weight of the particle
(C) the speed of the particle = 2.8 3 m/s

(D) the centripetal acceleration of the particle is 9.8√3 m/s2.
12. Time taken by the projectile to reach A to B is t. Then the distance AB is equal to –
u
B
60°
30°
A
ut 3 ut
(A) (B) (C) 3 ut (D) 2 ut
3 2
13. A block of mass M with a semicircular track of radius R rests on a horizontal frictionless
surface. A uniform cylinder of radius r and mass m is released from rest from the top point
A. The cylinder slips on the semicircular frictionless track. The distance travelled by the
block when the cylinder reaches the point B is :
M( R − r ) m(R − r ) ( M + m)R
(A) (B) (C) (D) none
M +m M +m M
14. In the figure shown a uniform rod of mass m and length  is hinged. The rod is released
when the rod makes angle θ = 60° with the vertical.

@JEEAdvanced_2024
3 3g
(A) The angular acceleration of the rod just after release is
4
19mg
(B) The normal reaction due to the hinge just after release is
8
3g
(C) The angular velocity of the rod at the instant it becomes vertical is
2
7
(D)The normal reaction due to the hinge at the instant the rod becomes vertical is mg
4
SECTION–III : (Maximum Marks : 12)

• This section contains FOUR questions.
• Each question has matching lists. The codes for the lists have choices (A), (B), (C) and
(D) out of which ONLY ONE is correct
• For each question, marks will be awarded in one of the following categories :
Full Marks : +3 If only correct answer is given.
Zero Marks : 0 If no answer is given.
15. A cylindrical isotropic solid of coefficient of linear expansion α and density ρ floats in a
liquid of coefficient of volume expansion γ and density d as shown in the diagram
Column I Column II
(I) volume of cylinder inside the liquid remains constant (P) γ = 0
(II) volume of cylinder outside the liquid remains constant (Q) γ = 2α
d
(III) Height of cylinder outside the liquid remains constant (R) γ = 3α
ρ
d
(IV) Height of cylinder inside the liquid remain constant (S) γ = ( 2α + α )
ρ
d
(T) γ = α
ρ
(A) I → P, II → R, III → S, IV → Q (B) I → P, II → T, III → S, IV → Q
(C) I → P, II → R, III → T, IV → Q (D) I → R, II → P, III → S, IV → Q

@JEEAdvanced_2024
16. A copper rod (initially at room temperature 20°C) of non-uniform cross section is placed
between a steam chamber at 100°C and ice-water chamber at 0°C.
 dQ 
(I) Initially rate of heat flow   will be (P) maximum at section A
 dt 
 dQ 
(II) At steady state rate of heat flow   will be (Q) maximum at section B
 dt 
 dT 
(III) At steady state temperature gradient   will be (R) minimum at section A
 dx 
(IV) At steady state rate of change of (S) minimum at section B
 dT 
temperature   at a certain point will be (T) same for all section
 dt 
(A) I → P, II → T, III → Q, IV → R (B) I → P, II → R, III → Q, IV → T
(C) I → P, II → T, III → Q, IV → T (D) I → R, II → T, III → Q, IV → P
17. A block of mass m = 1 kg is at rest with respect to a rough wedge as shown. The wedge
starts moving up from rest with an acceleration of a = 2 m/s2 and the block remains at rest
with respect to wedge. Then in 4 sec of motion(if θ = 30º & g = 10 m/s2) work done on
block.
m a
µ
Column-I Column-II
(I) By gravity (in magnitude) (P) 144J
(II) By normal reaction (Q) 32 J
(III) By frictional force (R) 160 J
(IV) By all the forces (S) 48 J
(T)52 J

@JEEAdvanced_2024
(A) I → R, II → P, III → S, IV → T (B) I → R, II → P, III → S, IV → Q
(C) I → Q, II → P, III → S, IV → R (D) I → R, II → S, III → P, IV → Q
18. Column-I Column-II

(I) Angular displacement (P) Axial vector
(II) Angular momentum (Q) It is directed along the axis of Rotation and
normal to the plane
(III) Torque is zero (R) Moment of linear momentum
7
(IV) In pure rolling. K.E. (S) mv2 of sphere at any point is
10
(T) Angular momentum is constant
(A) I → Q,R, II → P,Q,S, III → T, IV → S (B) I → P,Q, II → P,Q,R, III → S, IV → T
(C) I → P,S, II → P,Q,R, III → T, IV → S (D) I → P,Q, II → P,Q,R, III → T, IV → S

@JEEAdvanced_2024
PART-2 : CHEMISTRY
decimal places.
Θ
1. Find number of H replaced by D when below compound is kept in OD / D2O solution for
long time
O
2. In how many of the following cases, the negative charge is delocalised?

⊝
CH2
⊝ ⊝
⊝
(i) (ii) (iii) (iv)
⊝
⊝
⊝
O O
CH3
⊝
(v) (vi) (vii) (viii)
⊝ ⊕
O Θ
(ix) CH3—CH2—CH—N (x) CH2 — F
O⊝
3. Total number of geometrical isomers in the given compound are
C=CH–DC=CD–HC=C

@JEEAdvanced_2024
∆
4. Na2B4O7 → NaBO2 + B2O3
NaBO2 + H2O2 + H2O → compound A(aq)
In compound A the sum of oxidation states of all the oxygen atoms is X. Then the value of
|X| is
5. How many of the following compounds are planar as well as non polar compound :
(a) C3O2 (b) CH2=C=CH2 (c) BF3 (d) CCl4
(e) SF6 (f) XeF4 (g) IF5 (h) IF7
(i) SF4 (j) ClF3
6. The reaction of nitrogen with hydrogen to make ammonia has ∆H = – 92 kJ.

N2 (g) + 3H2 (g) → 2NH3 (g)
What is the value of |∆U| (in kJ) if the reaction is carried out at a constant pressure of 40
bar and the volume change is – 1.25 litre.
7. On mixing equal volumes of 0.1 M AgNO3 & 0.8 M KCN solutions, what % of original Ag+ is
in the form of free Ag+ ions ? Given : Kd of [Ag(CN)2]– = 10–18. Report your answer after
multiplying it by 4.5 × 1016. (A ssume no hydrolysis of any ion)
8. 1 mole of CCl4 vapours at 77°C occupies a volume of 35.0 L.If van der Waal’s constant are
a = 20.39 L2 atm mol–2 and b = 0.1383 L mol–1, calculate compressibility factor Z under, low
pressure region
• Each question has four choices (A), (B), (C) and (D) out of which ONE or More Than One
are correct.
9. Which compound(s) is/are soluble in aqueous NaOH :

@JEEAdvanced_2024
(A) (B) (C) (D)
10. Diborane undergoes unsymmetrical cleavage reactions with :

(A) dimethylamine (B) ammonia at low temperature
(C) methylamine (D) carbon dioxide
11. Which of the statement(s) are correct ?

(A) There is a single bond in FO+
(B) The F and O are further apart in FO− than in FO+ .
(C) There is a double bond in FO− .
(D) It would take more energy to break F–O bond in FO+ than in FO− .
12. Which of the following elements will gain one electron more readily in comparison to
other elements of their group ?
(A) S(g) (B) N(g) (C) O(g) (D) Cl (g)
13. Which of the following are correctly matched?

(A) Basic strength Cs2O < Rb2O < K2O < Na2O < Li2O
(B) Stability of peroxides Na2O2 < K2O2 < Rb2O2 < Cs2O2
(C) Thermal Stability of bicarbonates LiHCO3 < NaHCO3 < KHCO3 < RbHCO3 < CsHCO3
(D) Thermal stability of hydrides CsH < RbH < KH < NaH < LiH
14. If element 25X+Y has spin magnetic moment 1.732 B.M then
(A) number of unpaired electron = 1 (B) number of unpaired electron = 2
(C) Y = 4 (D) Y = 6

• Each question has matching lists. The codes for the lists have choices (A), (B), (C) and (D)
out of which ONLY ONE is correct
[ 10 ] www.allendigital.in  Digital

@JEEAdvanced_2024
15.
List-I List-II
H3C – CH2 – O – CH2 – CH3
(P) (1) Chain isomer
and CH3 – O – CH2 – CH2 – CH3
(Q) CH3 – CH2 – OH and CH3 – O – CH3 (2) Geometrical isomer
CH3 – CH2 – CH2 – CH3 and CH3—CH—CH3
(R) | (3) Positional isomers
CH3
Me Cl Me H
(S) and (4) Metamer
H H H Cl
(5) Functional group isomer
P Q R S
(A) 4 5 1 2
(B) 3 4 1 2
(C) 1 2 3 4
(D) 4 3 4 2
16.
List-I List-II
Br
Ph
(P) Ph NaI
(1)
Acetone
Br
(Q) Ph EtO– Ph Ph
EtOH/∆ (2)
F
⊕ ⊝
(R) N OH
∆ (3) PhCH = CH–CH3
 Digital www.allendigital.in [ 11 ]

@JEEAdvanced_2024
(S) + ⊝
OH
(4)
N
∆
Ph
(5)
P Q R S
(A) 2 5 4 1
(B) 2 3 1 4
(C) 3 4 2 1
(D) 3 2 1 4
17. Match the list for the following reaction started with NH2COONH4(s) only :
NH2COONH4(s)   2NH3(g) + CO2(g)
At equilibrium partial pressure of NH3 and CO2 are respectively then :
List-I List-II
(1) pNH3 × pCO2
2
(P) Partial pressure of NH2COONH4(s)
(Q) Kp (2) pNH3 + pCO2
(R) Total pressure at equilibrium (3) (p

2
NH3 )
× pCO2 × ( RT )
−3
(S) KC (4) Zero

2
(5) 2pCO2
The correct option is :
P Q R S
(A) 4 1 2 3
(B) 3 1 2,5 4
(C) 4 1 5 3
(D) 1 4 3 2,5
18.
List-I List-II
(P) A process carried out infinitesimally slowly (1) Adiabatic
(Q) A process in which no heat enters or leaves the system (2) ΔE = 0,ΔH = 0
(R) A process carried out at constant temperature (3) Reversible
(S) Cyclic process (4) Isothermal

@JEEAdvanced_2024
(5) Isobaric
P Q R S
(A) 3 1 4 2
(B) 2 5 3 4
(C) 3 1 2 3
(D) 3 5 2 4

@JEEAdvanced_2024
PART-3 : MATHEMATICS
decimal places.
a+ b
1. If largest real root of the equation x4 – 5x3 + 6x2 – 5x + 1 = 0 can be expressed as
c
a + b+c
(a, b, c are natural numbers in lowest form), then the value of is
4
( )
200
2. If number of terms in the expansion of 180 + 3 432 having integral coefficients is n,
n
then the value of is
4
3 10 21 36 55
3. If S = + + + + + .....∞ then S is equal to :
5 52 53 54 55
89
a a+b
4. If ∑ cos (k°) =b (where a, b is co-prime integers), then
k =1
6
20
equals to-
5. Let the number of three-digit numbers in which digit at the unit place and at the hundred's
k
place are less than digit at ten's place be k then what will be the value of .
25
6. If B is reflection of A(1, 5) about line 3x + 4y = 0 and C is reflection of B about line 4x – 3y = 0,

then area of triangle ABC is equal to -
7. Number of ways in which two distinct natural numbers can be selected out of first 100
N
natural numbers so that sum of their cubes is multiple of 8 is N, then is equal to
100
8. Let two parallel lines L and L' with positive slope are tangent to the circle S: x2 + y2 + 64 = 2x
+ 16 y. If L is also tangent to the circle S' : x2 + y2 – 2x + 2y = 2 and the equation of L' is
( )
a a x − by + c − a a = 0 where a,b, c ∈ N , then
a +b+c
4
is equal to

@JEEAdvanced_2024
• Each question has four choices (A), (B), (C) and (D) out of which ONE or More Than One are
correct.
9. If a, b, c > 0, such that a2 + b2 + c2 = 27, then-

(A) maximum value of (a + b + c) is equal to 9
(B) maximum value of abc is equal to 27
1 1 1
(C) minimum value of + + is equal to 1
a b c
1 1 1
(D) maximum value of + + is equal to 1
a b c
10. If α and β are the roots of the equation x2 – 6x – 4 = 0, then

(
α17 + β17 − 4 α15 + β15 ) is a-
(α ) −2
2
8
+ β8 17
(A) real number

(B) composite number
(C) prime number
(D) rational number
11. If circle S : x2 + y2 + 2gx + 2ƒy + c = 0 is orthogonal to x2 + y2 + 4x + 2y + 3 = 0 and passes

through point of intersection of circles S1 : x2 + y2 = 1 and S2 : x2 + y2 + 2x + 2y + 1 = 0, then
(A) intercept on x-axis by S = 0, is 1 unit
(B) intercept on y-axis by S = 0, is 1 unit
(C) g + ƒ + c = 1
(D) g + ƒ + c = 2
@JEEAdvanced_2024
12. Let ƒ(x) is a polynomial in x defined as ƒ(x) = (1 + x + x2)(1 + x)5(1 + x2)5, then -
(A) coefficient of x17 in ƒ(x) is 1
(B) coefficient of x16 in ƒ(x) is 6
(C) coefficient of x15 in ƒ(x) is 11
(D) coefficient of x in ƒ(x) is 6
13. Consider three distinct lines

x + λy + 6 = 0
2x + y – 3 = 0
λx + 2y + 5 = 0
let m denotes number of possible values of λ for which given lines are concurrent and n
denotes number of possible values of λ for which given lines do not form a triangle, then
(A) m = 2
(B) m = 3
(C) n = 6
(D) n = 7
tan θ tan2θ tan22 θ tan2n θ

14. If ƒ(n,
= θ) + + + .... + , then which of the following is/are true -
cos2θ cos22 θ cos23 θ cos2n +1 θ
 π
(A) ƒ  2016,  = −1
 4
 3π 
(B) ƒ  2016, =1
 4 
 π
(C) ƒ  2016,  = 1
 4
 3π 
(D) ƒ  2016, = −1
 4 

• Each question has matching lists. The codes for the lists have choices (A), (B), (C) and (D)
out of which ONLY ONE is correct
@JEEAdvanced_2024
15. Let (1 – x + x2)30 = a0 + a1x + a2x2 + a3x3 + ......... + a60x60.
Match List-I with List-II and select the correct answer using the code given below the list.
LIST-I LIST-II
(I)  a20 − a12 + a22 − a32 + .......  (P) 0
 
 a30 
(II)  a + a + a + .......  (Q) 1
4  0 230 4 
 (3 + 1) 
(III)  a + a + a + .......  (R) 2
6  1 3 305 
 (1 − 3 ) 
(IV) a0a1 – a1a2 + .......... (S) 3
(T) 4
(A) (I)→(Q); (II)→(R); (III)→(S); (IV)→(P)

(B) (I)→(P); (II)→(R); (III)→(S); (IV)→(Q)
(C) (I)→(Q); (II)→(R); (III)→(P); (IV)→(S)
(D) (I)→(S); (II)→(R); (III)→(Q); (IV)→(P)
16. Match List-I with List-II and select the correct answer using the code given below the list.
LIST-I LIST-II
(I) If ab2c3, a2b3c4, a3b4c5 are in A.P., where a,b,c ∈ R+ (P) 22
then minimum value of (a + b + c) is
(II) The diagonals AC and BD of a rhombus intersect (Q) 17
at E(5,6). If A(3, 2) and equation of diagonal BD is
x + 2y = c, then c is equal to
(III)  π   3π   5π  (R) 3
The value of 64sin   sin   sin   is
 14   14   14 
equal to
(IV) In ∆ABC, if tanAtanB = 2, tanA + tanB + tanC = 6, (S) 8
then value of 10(sin2A + sin2B + sin2C) is equal to
(T) 5
(A) (I)→(P); (II)→(Q); (III)→(S); (IV)→(R)

(B) (I)→(R); (II)→(S); (III)→(Q); (IV)→(P)
(C) (I)→(R); (II)→(Q); (III)→(S); (IV)→(P)
(D) (I)→(P); (II)→(R); (III)→(S); (IV)→(Q)

@JEEAdvanced_2024
17. L1 : 3x + y = 0
L2 : 4x + 3y + 5 = 0
Consider family of straight lines.
L1 + λL2 = 0; λ ∈ parameter.
LIST-I LIST-II
(I) thrice of absolute value of y-intercept of line (P) 2
having slope −
[ π + 1]
[e + 1]
(where [.] represent greatest integer function)
(II) Square of maximum distance of point (2, –6) (Q) 4

from any member of family is
(III) If locus of foot of perpendicular drawn from (R) 5

(0,0) to any member of family is x2 + y2 + ax + by,
then (a + b) is
(IV) If (α, β) be the image of (0 ,0) with respect to L2, (S) 10
then (α2 + β2) is
(T) 13
(A) (I)→(R); (II)→(S); (III)→(P); (IV)→(Q)
(B) (I)→(R); (II)→(S); (III)→(T); (IV)→(Q)

(C) (I)→(Q); (II)→(S); (III)→(P); (IV)→(R)
(D) (I)→(Q); (II)→(S); (III)→(T); (IV)→(R)

@JEEAdvanced_2024
18. Let S1 and S2 are two-unit circles with centre at C1(0,0) and C2(1,0) respectively. Let S3 is
another circle of unit radius, passes through C1 and C2 and its centre is above the x-axis. The
equation of common tangent to S1 and S3 which does not pass through S2 is ax + by + 2 = 0.
LIST-I LIST-II
(I) The ordinate of centre of circle S3 is (P) 1

2
(II) The value of a is equal to (Q) 3
2
(III) The value of (a2 – b) is equal to (R) 3
(IV) The abscissa of centre of circle S3 is (S) 4
(T) 5
(A) (I)→(Q); (II)→(R); (III)→(S); (IV)→(P)

(B) (I)→(Q); (II)→(S); (III)→(R); (IV)→(P)
(C) (I)→(R); (II)→(Q); (III)→(S); (IV)→(P)
(D) (I)→(R); (II)→(T); (III)→(S); (IV)→(P)

@JEEAdvanced_2024
PART-1 : PHYSICS
ANSWER KEY
Que. 1 2 3 4 5 6 7 8
Section-I
Ans. 22 1 8 3 1 20 2 2
Que. 9 10 11 12 13 14
Section-II
Ans. BC ABC ABCD A B ABCD
Que. 15 16 17 18
Section-III
Ans. A C B D
SOLUTIONS
1. Ans. (22)
Initial pressure of gas Pi = P0 + hρg
final pressure of gas P2 = P0 + h cos 60° ρg
for air column
P1 V1 = P2 V2
⇒ (P0 + h ρg) A × 50 = (P0 + ρg h cos 60°) A × x
(76 + 12)50 88 × 50 2200
x= = = cm.
(76 + 6) 82 41
2. Ans. (1)
( ρ + 2d ) x sin60 + ρ( − x ) sin 60º = (ρ + d) ( – x) sin 60 º + ρx sin 60º
on solving
 3
x= = =1
3 3
3. Ans. (8)
dQ = mcdT
Q = ∫ dQ = ∫ mc dT
Q = ∫ 2( 0.2 + 0.16T + 0.024T 2 ) dT

Q = 2 [0.2 × 5 + 0.08 × 25 + 0.008 × 125] = 2[1 + 2 + 1] = 8 cal

@JEEAdvanced_2024
4. Ans. (3)
30 3
In ∆ABD tan θ = =
40 4
Let time taken be 't' in x-direction
x = ux t
x = ucosθ t
125 4 100
x= × t ⇒ x= t............ (1)
3 5 3
In y-direction
1 2
y = uy t + gt
2
1 2
30 = usinθ t + gt
2
125 3
30 = × t + 5t2
3 5
t2 + 5t – 6 = 0
(t + 6) (t – 1) = 0
t = 1 sec. ..................... (2)
from (1) and (2)
100
x=
3
100 20
∴ packet is short by a distance of 40 – = m.
3 3
5. Ans. (1)
Let Vw = u & Usw = v
Time taken by swimmer to go from M to O and O to B = time taken by float to reach B from
M.
Vw = u
Brigde
A M O
Vs = v v−u
1 km
2

@JEEAdvanced_2024
v −u
1+
1 2 = 1
= +
2 v +u u
1 2+ v −u 1
⇒ + =
2 2(v + u) u
(v + u + 2 + v − u ) 1
⇒ =
2(v + u) u
⇒ (2v + 2) u = 2(v + u)
⇒ 2vu + 2u = 2v + 2u
u = 1 km/hr
6. Ans. (20)
µmg
ablock = = µg = 0.15 × 10 = 1.5
m
aT = 2
ST – Sb = 5
1 1
⇒ aT t2 – aB t2 = 5
2 2
1 2
⇒ t [2 – 1.5] = 5
2
⇒ t2 = 20
1
ST = aT t2
2
1
= × 2 × 20 = 20 m.
2
7. Ans. (2)
MΙ of the system w.r.t an axis ⊥ to plane & passing through one corner
ML2  ML2  3 L 
2
ML2
= + + +M   
3 3  12  2  


@JEEAdvanced_2024
2ML2  ML2 3ML2 
= + + 
3  12 4 
2ML2 10 ML2 3
= + = ML2
3 12 2
3
Now ML2 = 3k2M
2
L
k= .
2
8. Ans. (2)
τA = 0
3L L
T1 × – mg = 0 ....(1)
4 2
2mg
T1 =
3
T1 + T2 = mg ....(2)
mg
T2 =
3
T1 2
=
T2 1
9. Ans. (BC)
PV = constant
(Assumed isothermal process)
10. Ans. (ABC)

mg
Stress in wire B =
3πrB2
4mg
Stress in wire A =
3πrA2
mg 4mg
if = either wire will break.
3πrB
2
3πrA2

@JEEAdvanced_2024
11. Ans. (ABCD)
T cos 60o
60o

60o T /2
 3/2
V
T sin 60o
mg
T 3 mv 2
= ........(1)
2 ( 3 / 2)
T
= mg .......(2)
2
Hence T = 2 mg , So (B) holds
From (1) & (2) V2 = 3 g/2
3 ×9.8 ×1.6
∴ V=
2
∴ V = 2.8 3 m/s . So (C) hold
(3 g / 2)
ac = V2/r = = 3 × g = 9.8 3 m/s2
( 3 / 2)
∴ (D) holds
2πr 2π 3 / 2
t= =
v (3 g / 2)
t = 4π/7 ∴ (A) holds.
12. Ans. (A)

Horizontal component of velocity
u
uH = u cos 60° =
2
AC = AB cos 30°
u  3
⇒= t AB  AB ut / 3
⇒=
2  2 
 

@JEEAdvanced_2024
13. Ans. (B)
when cylinder reaches pt B.
then block get shifted by x
∴ but since than there is no ext
force therefore com remain at its position
m(R – r )
[(R–r) – x]m = Mx ∴x=
M +m
14. Ans. (ABCD)
 m2
(A) mg sin 60° = α
2 3
3 3g
α=
4
mg
(B) N2 – mg cos60° = 0 ⇒ N2 =
2
α
mg sin 60 – N1 = m
2
3 m 3 3g
mg – . = N1
2 2 4
mg 3
N1 =
8
2
 mg 3   mg 2 19mg
N= N +N = 2
1
2
2   +   =
 8   2  8

@JEEAdvanced_2024
 1 1 m2 2
(C) mg (1 – cos 60°) = Iω2 = ω
2 2 2 3
3g
ω=
2
mω2
(D) N – mg =
2
7
N= mg
4
15. Ans. (A)

Mg
(I) Buoyant force = Mg = constant = Vsubdg ⇒ Vsub = .
dg
volume of displace fluid = constant
∴ density of fluid must be constant.
(II) (Vsolid – Vsub) = constant
 M  M γ∆T d
⇒  Vsolid – solid  = constant V × 3α ×∆T = ⇒ γ = 3α
 ρliquid d ρ
 
(II) Ahin dliquid = A(hin +hout) ρsolid = M (mass of solid)
M M M
hout = – hin = – = constant
Aρsolid Aρsolid Adliquid
M(1 + 3α∆T ) M (1 + γ∆T ) M M

– = −
A(1 + 2α∆T ) ρ A(1 + 2α∆T ) d Aρ Ad
d
γ = 2α + α
ρ
(IV) Ahin dliquid g = Buoyant force = constant = Mg
d
A0 (1 + 2 α ∆T) hin = constant
1 + γ∆T
M
hin = (1 + (γ – 2α) ∆T)
A0d
γ = 2α

@JEEAdvanced_2024
16. Ans. (C)
(a) Initially more heat will enter through section A due to temperature difference and no
heat will flow through section B because initially there is no temperature difference.
 dQ 
(b) At steady state rate of heat flow   is same for all sections
 dt 
dQ dT dT 1  dQ 
(c) At steady state = kA or =  
dt dx dx kA  dt 
dT
is inversely proportional to area of cross-section. Hence is maximum at B and
dx
minimum at A
(d) At steady state heat accumulation = 0
dT
So = 0 for any section.
dt
17. Ans. (B)
N = m (g + a) cos θ = 6 3N
f = m (g + a) sin θ = 6 N
mg = 10 N
1 2
Now, S = at = 16m
2
∴ WN = N.S cos θ = 144J
Wf = f. s sin θ = 48 J
|Wg| = mg.s = 160 J
Wnet = Wg + WN + Wf
= – 160 + 144 + 48 = 32 J
18. Ans. (D)
All axial vectors are directed along the axis of rotation and normal to plane
For (B) angular momentum
→ → →
L=r ×p
It is an axial vector
→
dL
→
For (C) τ =
dt

@JEEAdvanced_2024
→
when L = constants
τ=0
For (D) and (S) in pure rolling consist translatory and rotatory motion both.
(K.E.) total (K.E.)total = (K.E.)r + (K.E.)t
1 1
= I ω2 + mv2
2 2
1 2 1 v2
= . mR2ω2 + mv2 ( ω2 = 2 )
2 5 2 R
7
= mv2
10

@JEEAdvanced_2024
PART-2 : CHEMISTRY
ANSWER KEY
Que. 1 2 3 4 5 6 7 8
Section-I
Ans. 7 5 4 12 3 87 50 0.98
Que. 9 10 11 12 13 14
Section-II
Ans. ABCD ABC BD AD BCD AD
Que. 15 16 17 18
Section-III
Ans. A A A A
SOLUTIONS
SECTION–I
1. Ans. (7)
2. Ans. (5)
5 (i, ii, iv, vi, ix)
3. Ans. (4)
Unsymmetrical compound with 2 stereocentres has 4 geometrical isomers.
4. Ans. (12)
2NaBO2 + 2H2O2 + 6H2O 
→ Na2[(OH)2B(O–O)2B(OH)2] sodium peroxoborate
2–
–2 –1 –1 –2
H—O O—O O—H
B B
H—O O—O O—H
–2 –1 –1 –2
X = [(–2) × 4 + (–1) × 4] = –12
Hence |X| = 12
5. Ans. (3)
C3O2, BF3, XeF4 are planar as well as non polar.
6. Ans. (87)
∆H = ∆U + 40 × (– 1.25) × 100
∆U = – 92+ 5
∆U = – 87 kJ;
|∆U| = 87 kJ
@JEEAdvanced_2024
7. Ans. (50)
[Ag + ]free (0.3)2 5
10–18 = ⇒ [Ag+]free = × 10–18 M
(0.05) 9
5
× 10–18
% of Ag+ (Ag+%) = 9 × 100 × 4.5 × 1016 = 50%
0.05
8. Ans. (0.98)
Under low pressure region, V is high
(V – b) ≈ V
 a 
 P + V 2  V = RT ;
 
a
PV + = RT
V
PV a
+ =1
RT RTV
PV  a 
∴Z= = 1 −
RT  RTV 
20.39
Z=1– = 0.98
0.0821 × 350 × 35
SECTION–II
9. Ans. (ABCD)
Compound which is more acidic then H2O is soluble in aq. NaOH.
10. Ans. (ABC)

Diborane undergoes unsymmetrical cleavage reactions with 1° Amine, 2° amine and
Ammonia.
11. Ans. (BD)

In FO+ total no. of electrons = 16, so bond order will be 2.
In FO− total number of electrons = 18, so bond order will be 1.
12. Ans. (AD)

In oxygen group : Sulphur has maximum Electron affinity.
In halogen group : Chlorine has maximum electron affinity
Nitrogen has lowest electron affinity in its group.
13. Ans. (BCD)

(A) Basic strength Cs2O > Rb2O > K2O > Na2O > Li2O
14. Ans. (AD)
@JEEAdvanced_2024
n(n + 2) = 1.732
Number of unpaired electrons, n = 1.
25X : [Ar] 4s23d5
For having one unpaired electron, 6 electrons are to be removed (2 from 4s & 4 from 3d).
∴ Y = 6.
SECTION–III
15. Ans. (A)
(P) Metamer
(Q) Functional group isomer
(R) Chain Isomer
(S) Geometrical Isomer
16. Ans. (A)

List-I List-II
Br
Ph
(P) Ph NaI (2)
Acetone Ph Ph
Br
⊝
Ph EtO
EtOH/∆
F (5) Ph
(Q) (Hoffmann
elimination)
⊕ ⊝
(R) N OH
∆ (4)
(major)
(Hoffmann elimination)
(S) + ⊝
OH (1)
N
∆
17. Ans. (A)

NH2COONH4(s)  
 2NH3(g) + CO2(g)
p – –
– 2p p
at equation PT = 3P ⇒ PNH3 + pCO2 ∆ng = 3 – 0
=3

@JEEAdvanced_2024
( )( )
2
Kp = K p = pCO2 PNH3
∆ng
K P = K C (RT)
( ) ( P ) ( RT )
2 −3
K C = PCO2 NH3
18. Ans. (A)

(P) A process carried out infinitesimally slowly : Reversible.
(Q) A process in which no heat enters of leaves the systems: Adiabatic
(R) A process carried out at constant temperature: Isothermal.
(S) Cyclic process : ∆E = O, ∆H = O.

@JEEAdvanced_2024
PART-3 : MATHEMATICS
ANSWER KEY
Que. 1 2 3 4 5 6 7 8
Section-I
Ans. 2.50 8.50 1.25 11.45 9.60 20.24 15.37 3.50
Que. 9 10 11 12 13 14
Section-II
Ans. A,B,C A,B,D A,B,C A,B,D A,C A,B
Que. 15 16 17 18
Section-III
Ans. A C A A
SOLUTIONS
1. Ans. (2.50)
Divide equation by x2
 1 1
x2 − 5 x +  + 2 + 6 =
0
 x x
2
 1  1
 x + x  − 5 x + x  + 4 =
0
   
1
Let t= x +
x
t 2 − 5t + 4 = 0 ⇒ t = 4;t = 1 (not possible)
1
x+ =
4 ; x2 – 4x + 1 = 0
x
x=
2 + 3; x =
2− 3
largest root = 2 + 3
2. Ans. (8.50)
( ) ( )
200− r r
Tr +1 = 200Cr 180x 3
432
200− r x
200− r 200− r 200− r
= 200
Cr 2 .3 .5 2
.x 2r.3r. 2 3
r
2 3
coefficient = 200Cr 2200.3200.5100 r
5 2
r must be a multiple of 6 and take values between 0 to 200

∴ 34 terms

@JEEAdvanced_2024
3. Ans. (1.25)
3 10 21 36 55
S= + + + + + .....∞
5 52 53 54 55
S 3 10 21 36
= + + +
5 52 53 54 55
subtracting
4 3 7 11 15 19
s= + + + +
5 5 52 53 54 55
4 3 7 11
2
s= 2 + 3 + 4
5 5 5 5
subtracting
16 3 4 4 4
s = + + + + .....
25 5 52 53 54
4
3 52 3 1
= + =+
5 1− 1 5 5
5
16 4
s=
25 5
5
s=
4
4. Ans. (11.45)
S = cos61° + cos62° + ..... cos688°+cos689°
S = (cos61° + cos689°) + (cos62° + cos688°)+ ....... cos645°
1
S = (cos61° + sin61°) + (cos62° + sin62°)+ ....... (cos644° + sin644°) +
8
 3   3   3  1
S =  1 − sin2 2°  +  1 − sin2 4°  + ......  1 − sin2 88°  +
 4   4   9  8
3 1
S 44 − sin2 2° + sin2 4° + .....sin88° +
=
4 8
3 1
S=
44 −
4
[ 22] +
8
221
S= ⇒ a + b= 229
8

@JEEAdvanced_2024
5. Ans. (9.60)
Let three-digit number be x y z
x, z < y
Let x, y, z are all distinct and none of them is 0 = 9C3 (2)
If z = 0, 9C2
If x = z, 9C2
∴ Total number = 2 . 10C3
6. Ans. (20.24)
3x+4y=0
A(1,5) B
4x–3y=0
46 22
=AS = , BC
5 5
7. Ans. (15.37)
x3 + y3 = 8λ
(I) x, y both even → all favorable
50C2
50 × 49
=
2
(II) x, y both odd
category Number
of numbers
(i) 8λ + 1 → 1, 9,......97 → 13
(ii) 8λ + 3 → 3, 11,......99 → 13
(iii) 8λ + 5 → 3, 13,......93 → 12
(iv) 8λ + 7 → 7, 15,......91 → 12
x ∈ (i) y ∈ (iv) → (13 × 12)
x ∈ (ii) y ∈ (iii) → (13 × 12)
Ans. 25 × 49 + 312 = 1537

@JEEAdvanced_2024
8. Ans. (3.50)
Let equation of transverse common tangent L with positive slope is

4 2
( y −=
5) 2 2 ( x − 1) [As, slope ⇒ tanθ = =2 2 ]
2
Suppose equation of tangent L' which is parallel to L is 2 2 x − y =λ
2 2 (1 ) − 8 − λ
So, = 1 ⇒=
λ 2 2 − 11,2 2 − 5
8+1
∴ Equation of L' is
(
2 2x − y + 11 − 2 2 =
0 )
a + b + c 14
So, a = 2 ; b = 1; c = 11 gives = = 3.50
4 4
9. Ans. (A,B,C)
a2 + b2 + c2 a + b + c 3
≥ ( abc ) ≥
1/3
≥
3 3 1 1 1
+ +
a b c
10. Ans. (A,B,D)

α17 – 6α16 – 4α15 = 0
β17 – 6β16 – 4β15 = 0
adding (1) and (2)

@JEEAdvanced_2024
11. Ans. (A,B,C)

S : S1 + λS2 = 0
x2(1 + λ) + y2 (1 + λ) + 2λx + 2λy + λ – 1 = 0
 S is orthogonal to x2 + y2 + 4x + 2y + 3 = 0
∴ 2g.2 + 2ƒ.1 = 3 + λ – 1
∴λ=1
∴ S : x2 + y2 + x + y = 0
12. Ans. (A,B,D)

Coefficient of
(A) x17 → x2.x5.x10 → 1
x 2 x 4 x10 → 5
(B) x16 → 6
x x5 x10 → 1 
1 x5 x10 → 1 

x x 4 x10 → 5 
(C) x → 2 3 10
15
 21
x x x → 10
x 2 x5 x 8 → 5 

1.x.1 → 5 
(D) x → 6
x.1.1 → 1
13. Ans. (A,C)

1 λ 6
For concurrency 2 1 −3 =
0
λ 2 5
⇒ 3λ2 + 16λ – 35 = 0 ⇒ (λ + 7) (3λ – 5) = 0

5
⇒ λ = −7, ⇒ m = 2
3
for not forming triangles either lines are parallel or concurrant
1 λ 2 1 
= ⇒ λ= 2, = ⇒ λ= 4
2 1 λ 2 
n = 6
1 λ 
= ⇒ λ2 = 2 ⇒ λ = ± 2
λ 2 

@JEEAdvanced_2024
14. Ans. (A,B)

tan θ sin θ
= = tan2θ − tan θ
cos2θ cos2θ cos θ
tan2θ
= tan4θ − tan2θ
cos22 θ
Thus
tan θ tan2θ tan2n θ
+ + ... + = tan2n +1 θ − tan θ
cos2θ cos22 θ cos2n +1 θ
ƒ(n,θ) = tan2n+1θ – tanθ
Now check.
15. Ans. (A)

(1 – x + x2)30
= a0 + a1x + a2x2 +.........+ a60x60 ...(1)
x → –x
(1 + x + x2)30 = a0 – a1x + a2x2 + .... + a60x60
1
x→
x
(1 + x + x2)30
= a0x60 – a1x59 + ....... + a60 ...(2)
Multiply (1) and (2)
(1 + x2 + x4)30
= a0 + a1x2 + a2x4 + ..... + a60x120 ...(3)
(P) (a 2
0 − a12 + a22 − a32 + ....... )
= coff. of x60 in (1 + x2 + x4)30 = a30
 a20 − a12 + a22 − a32 + ....... 
  =1
 a30 
(Q) Put x = 1 & –1 (1) add
2(a0 + a2 + .....) = 1 + 330
4(a0 + a2 + .......)
=2
330 + 1
(R) Put x = 1 & –1 in (1) and subtract 2(a1 + a3 + .......) = 1 – 330
(S) a0a1 – a1a2 + ..........
is coeff. of x61 in (1 + x2 + x4)30 = 0
@JEEAdvanced_2024
16. Ans. (C)

(I) ab2c3, a2b3c4, a3b4c5 are in A.P.
divided by ab2c3 ⇒ 1, abc, a2b2c2 are in A.P.
⇒ 2abc = 1 + a2b2c2
⇒ (abc – 1)2 = 0 ⇒ abc = 1
a +b+c
≥ ( abc )
1/3
AM > GM ⇒
3
⇒a+b+c>3
1
(II) Equation of BD ⇒ y – 6 = − ( x − 5)
m AE
put mAE = 2 ⇒ 2y + x = 17
 π   3π   5π 
(III) 64sin   sin   sin   = 8
 14   14   14 
(IV) tanAtanB = 2 and tanA + tanB + tanC=6
In ∆ABC ⇒
tanA+tanB+tanC = tanAtanBtanC
6 = 2tanC
⇒ tanC = 3
tan2 C 9
=
sin2 C =
1 + tan C 10
2
now tanA tanB = 2

tanA + tanB = 3
if tanA = 1 then tanB = 2
1 4
⇒ =
sin2 A =,sin2 B
2 5
if tanB = 1 then tanA = 2
4 1
⇒=
sin2 A =,sin2 B
5 2
4 1 9 22
⇒ sin2 A + sin2 B + sin2 C = + + =
5 2 10 10

@JEEAdvanced_2024
17. Ans. (A)
L1
(1, –3)
(2, –6)
L2
−4 −(3 + 4λ ) 4
(I) m = ⇒ =
−
3 1 + 3λ 3
⇒ λ = ∞ ⇒ L2 itself
5 −5
⇒ y-int. = – ⇒ 3⋅ =
5
3 3
(II) Maximum distance is between
⇒ Distance between
(1, –3) & (2, –6) ⇒ 10
⇒ Square of max. distance is 10.
(III) Locus of foot of ⊥ from (0, 0) is
(x – 0)(x – 1) + (y – 0)(y + 3) = 0
x2 + y2 – x + 3y = 0 ⇒ a + b = 2
(IV) Image of (0, 0) w.r.t. L2
x − 0 y − 0 −2(5)
= =
4 3 25
 8 6
(x,y) ≡  − , −  ⇒ α2 + β2 = 4
 5 5
18. Ans. (A)

y
Equation of S3 is
(x – 0) (x – 1) + (y – 0)2 + λy = 0 S3
i.e., x2 + y2 – x + λy = 0
C1
(0,0) C2
x
1 λ 2
i.e., + −0 =1⇒ λ = ± 3 S1
(1,0)
4 4 S2
∴ As circle S3 lie above x-axis
⇒ λ=− 3
⇒ S3 ≡ x2 + y 2 − x − 3y =0

@JEEAdvanced_2024
1 3 
∴ centre of S3 ≡  ,
 2 2 
 
slope of line joining C1 & C2 = 3
⇒ Slope of common tangent is 3.
i.e., 3x − y + k =
0 , is required
common tangent and touches circle S1
k
⇒ =⇒
1 k=±2
3+1
∴k=2
⇒ Required common tangent is
3x–y+2=0
⇒ a= 3,b = −1
∴ a2 = b = 3 – (–1) = 4

Major Test - 1 (Paper 2)

Uploaded by

Document Information

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

Major Test - 1 (Paper 2)

Uploaded by

Copyright:

Available Formats

@JEEAdvanced_2024

(Academic Session: 2022 - 2023)

JEE (MAIN + ADVANCED)

PATTERN : ADVANCED COURSE : NURTURE

READ THE INSTRUCTIONS CAREFULLY

Your Hard Work Leads to Strong Foundation

 Digital www.allendigital.in [1]

[2] www.allendigital.in  Digital

Negative Marks : –2 For incorrect answer

(A) A will break before B if rA < 2rB

 Digital www.allendigital.in [3]

(C) the speed of the particle = 2.8 3 m/s

when the rod makes angle θ = 60° with the vertical.

[4] www.allendigital.in  Digital

SECTION–III : (Maximum Marks : 12)

 Digital www.allendigital.in [5]

[6] www.allendigital.in  Digital

18. Column-I Column-II

 Digital www.allendigital.in [7]

2. In how many of the following cases, the negative charge is delocalised?

3. Total number of geometrical isomers in the given compound are

[8] www.allendigital.in  Digital

6. The reaction of nitrogen with hydrogen to make ammonia has ∆H = – 92 kJ.

9. Which compound(s) is/are soluble in aqueous NaOH :

 Digital www.allendigital.in [9]

(A) (B) (C) (D)

10. Diborane undergoes unsymmetrical cleavage reactions with :

11. Which of the statement(s) are correct ?

13. Which of the following are correctly matched?

SECTION–III : (Maximum Marks : 12)

[ 10 ] www.allendigital.in  Digital

(5) Functional group isomer

 Digital www.allendigital.in [ 11 ]

(Q) Kp (2) pNH3 + pCO2

(R) Total pressure at equilibrium (3) (p

(S) KC (4) Zero

[ 12 ] www.allendigital.in  Digital

 Digital www.allendigital.in [ 13 ]

6. If B is reflection of A(1, 5) about line 3x + 4y = 0 and C is reflection of B about line 4x – 3y = 0,

[ 14 ] www.allendigital.in  Digital

9. If a, b, c > 0, such that a2 + b2 + c2 = 27, then-

10. If α and β are the roots of the equation x2 – 6x – 4 = 0, then

(A) real number

11. If circle S : x2 + y2 + 2gx + 2ƒy + c = 0 is orthogonal to x2 + y2 + 4x + 2y + 3 = 0 and passes

13. Consider three distinct lines

tan θ tan2θ tan22 θ tan2n θ

SECTION–III : (Maximum Marks : 12)

(A) (I)→(Q); (II)→(R); (III)→(S); (IV)→(P)

(A) (I)→(P); (II)→(Q); (III)→(S); (IV)→(R)

 Digital www.allendigital.in [ 17 ]

Consider family of straight lines.

(I) thrice of absolute value of y-intercept of line (P) 2

(II) Square of maximum distance of point (2, –6) (Q) 4

(III) If locus of foot of perpendicular drawn from (R) 5

(IV) If (α, β) be the image of (0 ,0) with respect to L2, (S) 10

then (α2 + β2) is

(A) (I)→(R); (II)→(S); (III)→(P); (IV)→(Q)

(B) (I)→(R); (II)→(S); (III)→(T); (IV)→(Q)

[ 18 ] www.allendigital.in  Digital

(I) The ordinate of centre of circle S3 is (P) 1

(A) (I)→(Q); (II)→(R); (III)→(S); (IV)→(P)

 Digital www.allendigital.in [ 19 ]

Q = ∫ 2( 0.2 + 0.16T + 0.024T 2 ) dT

[ 20 ] www.allendigital.in  Digital