TM TM

JEEJEE
(Main
(Main ++ Advanced) 2020
Advanced) 2020
ENTHUSIAST & LEADER COURSE
Path to success KOTA (RAJASTHAN ) ENTHUSIAST & LEADER
Path to success KOTA (RAJASTHAN) COURSE

GRP RACE # 06 ORGANIC CHEMISTRY

M.M. : 41 TIME : 30 Min.

1. Column - I Column - II [8, 0]

(A) & (P) Identical

Me
Me Me
Br H
(B) & Br H (Q) Geometrical isomers
H Cl H Cl
Me

Me CH2OH

(C) H OH & H Me (R) Diastereoisomers

CH2OH OH

Me Me
H OH H OH
(D) & (S) Enantiomers
H OH HO H
Et Et
F F

2. Statement-1 :
F F
(I) (II)

(I) and (II) are optically active molecules. [3, –1]

Statement-2 : Molecules containing plane of symmetry or centre of symmetry or both cannot be
optically active.
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1
(C) Statement-1 is false, statement-2 is true
(D) Statement-1 is true, statement-2 is false
3. Which of the following can not show optical isomerism– [3, –1]
Me
Me Br
H H Cl O
(A) Cl (B) (C) Me (D)
Me H Cl O
H
Me C=C
Me Me Et

4. Compound which never exist in diastereomeric pair [3, –1]

Me Me
H3C CH3 H 3C CH3
H Cl H OH C=C=C=C C=C=C
(A) (B) (C) (D)
Cl H H OH H H H H
Me Me

ORGANIC /R # 06 E-1 /3
 TM
JEE (Main + Advanced) 2020
Path to success KOTA (RAJASTHAN )
ENTHUSIAST & LEADER COURSE

5. Give the correct order of initials T or F for following statements. Use T if statement is true and
F if it is false. [3, –1]
I. Me–CH=C=C=CH–Br is optically active.
II. All optically active compound are chiral.
III. All chiral pyramidal molecules are optically inactive.
IV. CH3–CH2–CH2–COOH and CH3–CH–CH3 are positional isomers.
COOH
(A) FTFF (B) FTFT (C) TFTF (D) FTTF
6. Which of the following molecule(s)/orientation(s) are identical to the [X] [4, –1]
CH3
H Br
[X] =
H Cl
C2H5
CH3 Cl
Cl Br Cl Br H CH3
Cl
(A) (B) (C) (D) Et
Me Et Et CH 3 H Br
Br
Et
7. Which mixture of structure in each container would rotate plane polarised light : [4, –1]
[Assuming each component does not react with each other]
H H
C C H
CO2H H H3 C C C
CH3 H H H CO2H
C C C H OH (I)
H
H3C H H OH CO2H
(A) (I) (B) CO2H H OH
C) OH OH H (D) H CH2CO2H
CH3 H (I) C C
(I) OH H
C C C H H OH H C=C
C C H 3 C CH3
C2H5 CH3 CO2H (II) H3C CH3
(II) (II)
(II)

Paragraph for Q.No. 08 to 09

Among the following structures ?

O O
COOH
H OH H Cl
(I) (II) NH2 (III) (IV)
N N HO H Cl H
R R COOH
NH2
Cl
Cl
COOH
F Cl
H OH
(V) (VI) (VII) C=C=C=C (VIII) H OH
I Br
COOH
Cl Cl
8. Optically active compound is : [3, –1]
(A) III (B) IV (C) V (D) VII
9. Which of the following will not show optical isomerism - [3, –1]
(A) I (B) II (C) V (D) VIII

ORGANIC /R # 06 E-2 /3
 TM
JEE (Main + Advanced) 2020
Path to success KOTA (RAJASTHAN )
ENTHUSIAST & LEADER COURSE

10. Find relationship between following pairs. [6, 0]

Me H
F Cl
H OH Me OH
Cl Br F Br
(a) H OH & HO H (b) &
H OH H Me Cl Br Br I
Me OH I Cl
SH SH OH

(c) CH3CH2CH2–CHO & CH3CHCH3 (d) &

OH
CHO
Br H OH
Br Br
Br
(e) & (f) D OH & D
H
T T

FILL THE ANSWER HERE

1. 2. 3. 4.

5. 6. 7. 8.

9.

10(a). (b) (c) (d)

(e) (f)
ORGANIC /R # 06 E-3 /3