27-12-2023 - SR - Super60 - Elite, Target & LIIT-BTs - Jee-Main-GTM-04 - Q.PAPER

You might also like

Download as pdf or txt
Download as pdf or txt
You are on page 1of 24

Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI


A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Sr.Super60_Elite, Target & LIIT‐BTs JEE-MAIN Date: 27-12-2023
Time: 03.00Pm to 06.00Pm GTM-04 Max. Marks: 300
IMPORTANT INSTRUCTION:
1. Immediately fill in the Admission number on this page of the Test Booklet with Blue/Black Ball Point Pen
only.
2. The candidates should not write their Admission Number anywhere (except in the specified space) on the
Test Booklet/ Answer Sheet.
3. The test is of 3 hours duration.
4. The Test Booklet consists of 90 questions. The maximum marks are 300.
5. There are three parts in the question paper 1,2,3 consisting of Physics, Chemistry and Mathematics having
30 questions in each subject and subject having two sections.
(I) Section –I contains 20 multiple choice questions with only one correct option.
Marking scheme: +4 for correct answer, 0 if not attempt and ‐1 in all other cases.
(II) Section‐II contains 10 Numerical Value Type questions. Attempt any 5 questions only, if more than 5
questions attempted, First 5 attempted questions will be considered.
∎ The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer
value (Example i,e. If answer is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and
less than 11 round off is 11).
To cancel any attempted question bubble on the question number box.
For example: To cancel attempted question 21. Bubble on 21 as shown below

.
Question Answered for Marking Question Cancelled for Marking
Marking scheme: +4 for correct answer, 0 if not attempt and ‐1 in all other cases.
SRI CHAITANYA IIT ACADEMY, INDIA 27‐12‐23_ Sr.Super60_Elite, Target & LIIT‐BTs _Jee‐Main_GTM‐04_Q.P
6. Use Blue / Black Point Pen only for writing particulars / marking responses on the Answer Sheet. Use of pencil is
strictly prohibited.
7. No candidate is allowed to carry any textual material, printed or written, bits of papers, mobile phone any electron
device etc, except the Identity Card inside the examination hall.
8. Rough work is to be done on the space provided for this purpose in the Test Booklet only.
9. On completion of the test, the candidate must hand over the Answer Sheet to the invigilator on duty in the Hall.
However, the candidate are allowed to take away this Test Booklet with them.
10. Do not fold of make any stray marks on the Answer Sheet

Name of the Candidate (in Capital): ________________________________________________

Admission Number:
Candidate’s Signature:________________ Invigilator’s Signature: ________________

27‐12‐23_Sr.Super60_Elite, Target & LIIT‐BTs _ Jee‐Main_GTM‐04_Test Syllabus


PHYSICS : TOTAL SYLLABUS
CHEMISTRY : TOTAL SYLLABUS
MATHEMATICS : TOTAL SYLLABUS

Sec: Sr.Super60_Elite, Target & LIIT‐BTs Page 2


SRI CHAITANYA IIT ACADEMY, INDIA 27‐12‐23_ Sr.Super60_Elite, Target & LIIT‐BTs _Jee‐Main_GTM‐04_Q.P
PHYSICS Max Marks: 100
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. The velocity – displacement graph describing the motion of a bicycle is shown in the


v ms 1 
50

10

O
200 400 x  m

The acceleration –displacement graph of the motion of a bicycle is best described by.

a ms 2  
a ms 2 

18 18

2 2
O O
1) 200 400 x  m  2) 200 400 x m


a ms 2 

a ms 2 

18 18

2 2
O O
200 400 x  m  200 400 x  m 
3) 4)
Sec: Sr.Super60_Elite, Target & LIIT‐BTs Page 3
SRI CHAITANYA IIT ACADEMY, INDIA 27‐12‐23_ Sr.Super60_Elite, Target & LIIT‐BTs _Jee‐Main_GTM‐04_Q.P
2. In order to determine the young’s Modulus of a wire of radius 0.2 cm (measured using a
scale of least count=0.001 cm) and length 1m (measured using a scale of least count=1mm),
a weight of mass 1kg(measured using a scale of least count =1 g)was hanged to get the
elongation of 0.5 cm(measured using scale of least count 0.001 cm).What will be the
fractional error in the value of Young ‘s Modulus determined by this experiment?
1) 0.9% 2) 0.14% 3)1.4% 4)9%
3. For changing the capacitance of a given parallel plate capacitor, a dielectric material of
dielectric constant K is used, which has the same area as the plates of the capacitor. The
3
thickness of the dielectric slab is d, where‘d’ is the separation between the plates of
4
parallel plate capacitor. The new capacitance  C ' in terms of original capacitance  C0  is

given by the following relation:


4 3 K 4K 4 K
1) C '  C0 2) C '  C0 3) C '  C0 4) C '  C0
3 K 4K K 3 3
4. An RC circuit as shown in the figure is driven by a AC source generating a square wave.
The output wave pattern monitored by CRO would look close to:

1) 2)

3) 4)
Sec: Sr.Super60_Elite, Target & LIIT‐BTs Page 4
SRI CHAITANYA IIT ACADEMY, INDIA 27‐12‐23_ Sr.Super60_Elite, Target & LIIT‐BTs _Jee‐Main_GTM‐04_Q.P
5. A block of 200 g mass moves with a uniform speed in a horizontal circular groove, with
vertical side walls of radius 20cm. If the block takes 40 s to complete one round, the normal
force by the side walls of the groove is:
1) 9.859  10 4 N 2) 6.28  103 N
3) 0.0314N 4) 9.859  10 2 N
6. The stopping potential in the context of photoelectric effect depends on the following
property of incident electromagnetic radiation:
1) Amplitude 2) Intensity 3) Frequency 4) Phase
7. A conducting wire of length ‘ l ’, area of cross-section A and electric resistivity  is
connected between the terminals of a battery. A potential difference V is developed its ends,
causing an electric current. If the length of the wire of the same material is doubled and the
area of cross-section is halved, the resultant current would be:
VA 1 VA 3 VA 1 l
1) 4 2) 3) 4)
l 4 l 4 l 4 VA

8. Four equal masses, m each are placed at the corners of a square of length ( l ) as shown in the
figure. The moment of inertia of the system about an axis passing through A and parallel to
DB would be:
D l C
m m

l
l

m m
A l B

1) 3ml 2 2) m l 2 3) 2ml 2 4) 3ml 2

Sec: Sr.Super60_Elite, Target & LIIT‐BTs Page 5


SRI CHAITANYA IIT ACADEMY, INDIA 27‐12‐23_ Sr.Super60_Elite, Target & LIIT‐BTs _Jee‐Main_GTM‐04_Q.P
9. The maximum and minimum distances of a comet from the Sun are 1.6  1012 m and
8.0  1010 m respectively. If the speed of the comet at the nearest point is 6  10 4 ms 1 , the
speed at the farthest point is :
1) 6.0  103 m / s 2) 1.5  103 m / s 3) 3.0  103 m / s 4) 4.5  103 m / s
10. In thermodynamics, heat and work are:
1) Path Functions 2) Extensive thermodynamics state variables
3) Point functions 4) Intensive thermodynamics state variables
11. The volume V of an enclosure contains a mixture of three gases, 16 g of oxygen, 28 g of
nitrogen and 44 g of carbon dioxide at absolute temperature T. Consider R as universal gas
constant. The pressure of the mixture of gases is:
4RT 88RT 3RT 5 RT
1) 2) 3) 4)
V V V 2 V
  
12. A charge Q is moved dl distance in the magnetic field B . Find the value of work done by B .
1) -1 2) 0 3) Infinite 4) 1
13. One main scale division of a vernier calipers is ‘a’ cm and nth division of the vernier scale
coincide with (n-1)th division of the main scale. The least count of the calipers in mm is:
10na  n 1 10a 10a
1) 2)  a 3) 4)
 n  1  10n   n  1 n

14. For an electromagnetic wave travelling in free space, the relation between average energy
densities due to electric (Ue) and magnetic (Um) fields is:
1)U e  U m 2)U e  U m 3)U e  U m 4)U e  U m
15. A block of mass m slides along a floor while a force of magnitude F is applied to it an angle
 as shown in figure. The coefficient of kinetic friction is  K . Then, the block’s acceleration
‘a’ is given by: (g is acceleration due to gravity)

Sec: Sr.Super60_Elite, Target & LIIT‐BTs Page 6


SRI CHAITANYA IIT ACADEMY, INDIA 27‐12‐23_ Sr.Super60_Elite, Target & LIIT‐BTs _Jee‐Main_GTM‐04_Q.P

F

F  F  F  F 
1) cos   K  g  sin   2)  cos   K  g  sin  
m  m  m  m 
F  F  F  F 
3) cos   K  g  sin   4) cos  K  g  sin  
m  m  m  m 
16. A conducting bar of length L is free to slide on two parallel conducting rails as shown in the
figure


R1  R2
B

Two resistors R1 and R2 are connected across the ends of the rails. There is a uniform

magnetic field B pointing into the page. An external agent pulls the bar to the left at a
constant speed .
The correct statement about the directions of induced currents I1 and I 2 flowing through R1
and R2 respectively is:
1) I1 is in clockwise direction and I 2 is in anticlockwise direction
2) I1 is in anticlockwise direction and I 2 is in clockwise direction
3) Both I1 and I 2 are in anticlockwise direction
4) Both I1 and I 2 are in clockwise direction

Sec: Sr.Super60_Elite, Target & LIIT‐BTs Page 7


SRI CHAITANYA IIT ACADEMY, INDIA 27‐12‐23_ Sr.Super60_Elite, Target & LIIT‐BTs _Jee‐Main_GTM‐04_Q.P
17. Time period of a simple pendulum is T inside a lift when the lift is stationary. If the lift
moves upwards with an acceleration g/2, the time period of pendulum will be:
3 T 2
1) T 2) 3) 3T 4) T
2 3 3
18. A plane electromagnetic wave of frequency 500 MHz is travelling in vacuum along y –

direction. At a particular point in space and time, B  8.0  108 zT
ˆ . The value of electric
field at this point is:
(Speed of light  3  108 ms 1 )
xˆ , yˆ , zˆ are unit vectors along x, y and z directions.
1) 24 xˆ V/m 2) 2.6 xˆ V/m 3) 2.6 yˆ V/m 4) 24 xˆ V/m
  
19. A body of mass 2kg moves under a force of (2 i + 3 j +5 k ) N. It starts from rest and was at
the origin initially. After 4s, its new coordinates are (8,b,20). The value of b is__________
(Round off to the Nearest Integer)
1) 12 2) 10 3) 9 4) 5
20. The pressure acting on a submarine is 3  105 Pa at a certain depth. If the depth is doubled,
the percentage increase in the pressure acting on the submarine would be:
(Assume that atmosphere pressure is 1  105 Pa; density of water is 103 kg m  3 ,
g = 10 ms 2 )
5 200 3 200
1) % 2) % 3) % 4) %
200 5 200 3
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If answer
is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
V
21. The resistance R  , where V  (50  2)V and I  (20  0.2) A . The percentage error in R is ‘x’
I
%.The value of ‘x’ to the nearest integer is……………...
Sec: Sr.Super60_Elite, Target & LIIT‐BTs Page 8
SRI CHAITANYA IIT ACADEMY, INDIA 27‐12‐23_ Sr.Super60_Elite, Target & LIIT‐BTs _Jee‐Main_GTM‐04_Q.P
22. Consider a frame that is made up of two thin mass less rods AB and AC as shown in the

figure. A Vertical force P of magnitude 100N is applied at point A of the frame.

700
A

B
700

1450

C

Suppose the force is P resolved parallel to the arms AB and AC of the frame.
The magnitude of the resolved component along the arm AC is xN.
The value of x, to the nearest integer, is……………….
[Given : sin(350 )  0.573 , cos(350 )  0.819
sin(1100 )  0.939 , cos(1100 )  0.342]

23. The first three spectral lines of H-atom in the Balmer series are given 1 , 2 , 3 considering
 1 
the Bohr atomic model, the wave lengths of first and third spectral lines   are related by a
 3 

factor of approximately ' x '101. .


The value of x, to the nearest integer, is………………...
24. Consider a 20 kg uniform circular disk of radius 0.2 m. It is pin supported at its center and is
at rest initially. The disk is acted upon by a constant force F=20 N through a mass less string
wrapped around its periphery as shown in the figure.

Sec: Sr.Super60_Elite, Target & LIIT‐BTs Page 9


SRI CHAITANYA IIT ACADEMY, INDIA 27‐12‐23_ Sr.Super60_Elite, Target & LIIT‐BTs _Jee‐Main_GTM‐04_Q.P

F= 20 N

Suppose the disk makes n number of revolutions to attain an angular speed of 50 rad s-1.
The value of n, to the nearest integer, is…………….
[Given : In one complete revolution, the disk rotates by 6.28 rad]
25. A fringe width of 6 mm was produced for two slits separated by 1 mm apart. The screen is
placed 10 m away. The wavelength of light used is ‘x’ nm.
The value of ‘x’ to the nearest integer is……………..

26. A force F  4iˆ  3 ˆj  4kˆ is applied on intersection point of x=2 plane and x-axis. The
magnitude of torque of this force about a point (2, 3, 4) is________ (Round off to the
Nearest Integer)
27. In the figure given, the electric current flowing through the 5 k resistor is ‘x’ mA.
3k
5k 3k

3k

21V ,1k

The value of x to the nearest integer is ……………..

Sec: Sr.Super60_Elite, Target & LIIT‐BTs Page 10


SRI CHAITANYA IIT ACADEMY, INDIA 27‐12‐23_ Sr.Super60_Elite, Target & LIIT‐BTs _Jee‐Main_GTM‐04_Q.P
28. The value of power dissipated across the zener diode Vz  15V  connected in the circuit as

shown in the figure is X 101 watt.

Rs  35

22V Vz =15V ~ RL  90

The value of X, to the nearest integer, is…………...


29. A sinusoidal voltage of peak value 250V is applied to a series LCR circuit, in which R  8 ,
L=24 mH and C= 60 F . The value of power dissipated at resonant condition is ‘x’ kW.
The value of x to the nearest integer is……………...
30. A ball of mass 10 kg moving with a velocity 10 3ms1 along X-axis, hits another ball of mass
20kg which is rest. After collision, the first ball comes to rest and the second one
disintegrates into two equal pieces. One of the pieces starts moving along Y-axis at a speed
of 10 m/s. The second piece starts moving at a speed of 20 m/s at an angle  (degree) with
respect to the X-axis.
The configuration of pieces after collision is shown in the figure.
The value of  to the nearest integer is………………………..
After ollision
Y

X-Axis

Sec: Sr.Super60_Elite, Target & LIIT‐BTs Page 11


SRI CHAITANYA IIT ACADEMY, INDIA 27‐12‐23_ Sr.Super60_Elite, Target & LIIT‐BTs _Jee‐Main_GTM‐04_Q.P
CHEMISTRY Max Marks: 100
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
31. Which of the following reaction does not involve Hoffmann bromamide degradation?
O
CH 2 - C -CH3 CH 2  NH 2
i)Br2 ,NaOH/H +

ii)NH3 /Δ
iii)LiAlH 4 /H 2 O
1)
O
NH 2
Cl

i)NH3 ,NaOH
ii)Br2 ,NaOH

2)
O
CH 2  NH 2
CH 2 -C-NH 2

Br2 , NaOH

3)
CN NH 2

KOH , H 2O
Br2 , NaOH
4)
32. The exact volume of 1 M NaOH solution required to neutralize 50 mL 1M H 3 PO3 solution and
100 ml 2M H 3 PO2 respectively are

1) 100 ml , 50 ml 2) 50 ml , 50 ml 3) 100 ml , 200 ml 4) 100 ml , 100 ml


33. Arrange the following metal complex/compounds in the increasing order of spin only
magnetic moment. Presume all the three, high spin system.
(Atomic numbers Ce=58, Gd=64 and Eu=63)
a)  NH 4 2 Ce  NO3 6  b) Gd  NO3 3 c) Eu  NO3 3
answer is
1)a<c<b 2)c<a<b 3)a<b<c 4)b<a<c
Sec: Sr.Super60_Elite, Target & LIIT‐BTs Page 12
SRI CHAITANYA IIT ACADEMY, INDIA 27‐12‐23_ Sr.Super60_Elite, Target & LIIT‐BTs _Jee‐Main_GTM‐04_Q.P
34. Given below are two statements: one is labeled as Assertion A and the other is labeled as
Reason R:
Assertion A: Size of Bk 3+ ion is less than Np3+ ion.
Reason R: the above is a consequence of the lanthanoid contraction.
In the light of the above statements, choose the correct answer from the option given below:
1) A is false but R is true
2) Both A and R are true but R is not the correct explanation of A
3) A is true but R is false
4) Both A and R are true and R is the correct explanation of A
35. Identify the elements X and Y using the ionization energy values given below:
Ionization energy (kJ/mol)
1st 2nd
X 495 4563
Y 731 1450
1)X=Na;Y=Mg 2)X=F;Y=Mg 3)X=Mg;Y=F 4)X=Mg;Y=Na
36. An unsaturated hydrocarbon X on ozonolysis gives A. compound A when warmed with
ammonical silver nitrate forms a bright silver mirror along the sides of the test tube. The
unsaturated hydrocarbon X is:
CH 3  C  C  CH 3
CH 3 CH 3
1) CH 3  C  C  CH 3 2)
CH 3

CH 3  C
3) 4) HC  C  CH 2  CH 3
37. Given below are two statements:
Statement I: The E  value for Ce4+ /Ce3+ is +1.74V .
Satement II: Ce is more stable in Ce 4  state than Ce3 state.
In the light of the above statement, choose the most appropriate answer from the option
given below:

Sec: Sr.Super60_Elite, Target & LIIT‐BTs Page 13


SRI CHAITANYA IIT ACADEMY, INDIA 27‐12‐23_ Sr.Super60_Elite, Target & LIIT‐BTs _Jee‐Main_GTM‐04_Q.P
1) Both statement I and statement II are correct
2) Both statement I and statement II are incorrect
3) Statement I is correct but statement II is incorrect
4) Statement I is incorrect but statement II is correct
38. Which among the following pairs of vitamins is stored in our body relatively for longer
duration?
1) Vitamin A and Vitamin D 2) Ascorbic acid and Vitamin D
3) Thiamine and Ascorbic acid 4) Thiamine and Vitamin A
39. Match List –I with List-II
List-I List-II
(a) Lassaigne’s test (i) Carbon
(b)Cu(II) oxide (ii) Sulphur
(c)Silver nitrate (iii) N,S,P and halogen
(d) The sodium fusion extract (iv) Halogen specifically
gives black precipitate with acetic
acid and lead acetate
The correct match is:
1) a  iii; b  i; c  iv, d  ii 2) a  i; b  iv; c  iii, d  ii
3) a  i; b  ii; c  iv, d  iii 4) a  iii; b  i; c  ii, d  iv
40.
H3C OH CH3 Cl

20%H3PO 4  CH3 3 CO K 


"A' "B"
358k (Major Product) (Major Product)
The products “A” and “B” formed in above reaction
CH 3 CH 2 CH 3 CH 3

A B A B
1) 2)
Sec: Sr.Super60_Elite, Target & LIIT‐BTs Page 14
SRI CHAITANYA IIT ACADEMY, INDIA 27‐12‐23_ Sr.Super60_Elite, Target & LIIT‐BTs _Jee‐Main_GTM‐04_Q.P

CH 2 CH 2 CH 2 CH 3

A B A B

3) 4)
41.
OH
NH2

NaNO 2 ,HCl "A"


"X"
273-278K

Major Product
In the above chemical reaction, intermediate “X” and reagent/condition “a” are:
N 2 Cl  NO2

X
; A  H 2O /  X
; A  H 2O / NaOH

1) 2)
NO2 N 2 Cl 

X
; A  H 2O /  X
; A  H 2O / NaOH

3) 4)
42. A group 15 element which is a metal and forms a hydride with strongest reducing power
among group 15 hydrides. The element is:
1) As 2) Sb 3) Bi 4) P

Sec: Sr.Super60_Elite, Target & LIIT‐BTs Page 15


SRI CHAITANYA IIT ACADEMY, INDIA 27‐12‐23_ Sr.Super60_Elite, Target & LIIT‐BTs _Jee‐Main_GTM‐04_Q.P
43. In chromatography technique the purification of compound is independent of:
1) Solubility of the compound 2) Length of the column or TLC plate
3) Mobility or flow of solvent system 4) Physical state of the pure compound
44. Given below are two statements: one is labeled as assertion A and the other is labelled as
Reason R:
Assertion A: the H  O  H bond angle in water molecule is 104.5
Reason R: the lone pair-lone pair repulsion of electrons is higher than the bond pair –bond
pair repulsion. In the light of the above statements, choose the correct answer from the
option given below:
1) A is true but R is false
2) Both A and R are true, and R is the correct explanation of A
3) A is false but R is true
4) Both A and R are true, but R is not the correct explanation of A
45. Assertion A: Enol form of acetone CH 3COCH 3  exists in <0.1% quantity. However, the

enol form of acetyl acetone CH 3COCH 2OCCH 3  exits in approximately 15 % quantity.
Reason R: Enol form of acetyl acetone is stabilized by intramolecular hydrogen bonding
Which is not possible in enol form of acetone?
Choose the correct statement:
1) A is false but R is true
2) Both A and R are true but R is not the correct explanation of A
3) A is true but R is false
4) Both A and R are true and R is the correct explanation of A
46. Which of the following is Lindlar catalyst?
1) Sodium and Liquid NH 3
2) Zinc chloride and HCl
3) Partially deactivated palladised charcoal
4) Cold dilute solution of KMnO4
Sec: Sr.Super60_Elite, Target & LIIT‐BTs Page 16
SRI CHAITANYA IIT ACADEMY, INDIA 27‐12‐23_ Sr.Super60_Elite, Target & LIIT‐BTs _Jee‐Main_GTM‐04_Q.P
47.
o

o
DIBAL-H,Toluene,-780C "P"
ii) H 3O
+
 Major product 

The product “P” in the above reaction is :


O

O  C H

CHO

1) 2)
OH

CHO COOH

3) 4)
48. Among the following, the aromatic compounds are:

CH2
A) B) C) D)
Choose the correct answer from the following option:
1) (B) and (C) only 2) (A) and (B) only
3) (A) (B) and (C) only 4) (B) (C) and (D) only
49. A central atom in a molecule has two lone pairs of electrons and form three single bonds.
The shape of this molecule is:
1) T-shaped 2) see-saw
3) trigonal pyramidal 4) planar triangular
50. Which of the following compound CANNOT act as a Lewis base?
1) SF4 2) PCl5 3) ClF3 4) NF3
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If answer
is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.

Sec: Sr.Super60_Elite, Target & LIIT‐BTs Page 17


SRI CHAITANYA IIT ACADEMY, INDIA 27‐12‐23_ Sr.Super60_Elite, Target & LIIT‐BTs _Jee‐Main_GTM‐04_Q.P
51. Then decomposition of formic acid on gold surface follows first order kinetics. If the rate
constant at 300 K is 1.0 103 S 1 and the activaton energy Ea  11.488 KJ mol 1 , the rate constant
at 200K is ……….. 105 s 1 . (Round off to the Nearest Integer). (Given: R  8.314 J mol 1K 1 )
52. 2MnO4 +bC2O42- +cH+  xMn 2+ +yCO2 +zH2O
If the above equation is balanced with integer coefficients, the value of c is…….
(Round off to the Nearest Integer).
53. AB2 is 10% dissociated in water to A 2+ and B the boiling point of a 10.0 molal aqueous
solution of AB2 is ………..  C . (Round off to the Nearest Integer).
[Given: Molal elevation constant of water K b  0.5 K kg mol 1 boiling point of pure water
=100  C
54. When light of wavelength 248nm falls on a metal of threshold energy 3.0 eV, the de-Broglie
wavelength of emitted electrons is …….. A . (Round off to the Nearest Integer).
[Use: 3  1.73, h  6.63  10 34 ] Js
31
[ me  9.110 kg; c  3.0 108 ms1;1eV  1.6 1019 J ]

55. For the reaction A( g )  B ( g ) at 495 K  r G  9.478kJ mol 1 .
If we start the reaction in a closed container at 495K with 22 mill moles of A, the
amount of B in the equilibrium mixture is……… mill moles (Round off to the Nearest
Integer)
[ R  8.31J mol 1 K 1 ; ln 10  2.303 ]
56. The equivalent of ethylene diamine required to replace the neutral ligands from the
coordination sphere of the trans-complex of CoCl3 4 NH 3 is ………( Round off to the nearest
Integer).
57. A 6.50 molal solution of KOH (aq). Has a density of 1.89g cm-3. The molarity of the solution
is….. mol dm-3. (Round off to the nearest Integer). [Atomic masses: K:39.0u; o:16.0u; H:1.0
u]
58. Two salts A2 X and MX have the same value of solubility product of 4.0 1012 . The ratio of
S  A2 X 
their molar solubilities i.e. =…(Round off to the nearest integer).
S ( MX )
59. Complete combustion of 750g of an organic compound provides 420 g of CO2 and 210 g of
H2O. Then percentage composition of carbon and hydrogen in organic compound is 15.3
and……. Respectively. (Round off to nearest Integer).
60.  6

0.01 moles of a weak acid HA Ka  2.0 10 is dissolved in 1.0 L of 0.1 M HCl solution.
The degree of dissociation of HA is ______  10 5 (Round off to the Nearest Integer).
[Neglect volume change on adding HA. Assume degree of dissociation <<1]
Sec: Sr.Super60_Elite, Target & LIIT‐BTs Page 18
SRI CHAITANYA IIT ACADEMY, INDIA 27‐12‐23_ Sr.Super60_Elite, Target & LIIT‐BTs _Jee‐Main_GTM‐04_Q.P
MATHEMATICS Max Marks: 100
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
61. Let [x] denote greatest integer less than or equal to x. If for n  N ,
 3n   3 n 1 
 2   2 
3n
1  x  x    a x
3 n
j
j
, then a 2j 4  a2 j 1 is equal to :
j 0 j 0 j 0

1) n 2) 2 3) 2n1 4) 1
  1
62. If for x   0,  ,log10 sin x  log10 cos x  1and log10  sin x  cos x    log10 n  1 , n  0 ,
 2 2
then the value of n is equal to:
1) 16 2) 9 3) 20 4) 12
k
 6 r

63. Let S k   tan 1  2 r 1 2 r 1  . Then lim Sk is equal to :
r 1 2 3  k 

 3 3
1) 2) tan 1   3) cot 1   4) tan 1  3 
2 2 2
64. Let the position vectors of two points P and Q be 3iˆ  ˆj  2 kˆ and iˆ  2 ˆj  4kˆ , respectively.
Let R and S be two points such that the direction ratios of lines PR and QS are (4, -1, 2) and
(-2, 1, -2), respectively. Let lines PR and QS intersect at T. If vector TA is perpendicular to
  
both PR and QS and the length of vector TA is 5 units, then the modulus of a position
vector of A is:
1) 171 2) 5 3) 482 4) 227
65. In a group of 100 persons 75 speak English and 40 speak Hindi. Each person speaks at
least one of the two languages. If the number of persons, who speak only English is α and
the number of persons who speak only Hindi is β , then the eccentricity of the
ellipse 25  β 2 x 2  α 2 y 2   α 2β 2 is
119 3 15 129 117
1) 2) 3) 4)
12 12 12 12
66. The least value of z where ‘z’ is complex number which satisfies the in-equality
  z  3 z  1 2 
exp  log e   log 5 7  9i , i  1, is equal to:

  z  1 

2

1) 5 2) 8 3) 2 4) 3
Sec: Sr.Super60_Elite, Target & LIIT‐BTs Page 19
SRI CHAITANYA IIT ACADEMY, INDIA 27‐12‐23_ Sr.Super60_Elite, Target & LIIT‐BTs _Jee‐Main_GTM‐04_Q.P
67. Given that the inverse trigonometric function take principal value only. Then the number

of real value of x which satisfy sin 1 


3x  1  4 x 
  sin    sin x is equal to:
1

 5   5 

1) 2 2) 3 3) 0 4) 1
       
68. Let a  iˆ  2 ˆj  3kˆ and b  2iˆ  3 ˆj  5kˆ . If r  a  b  r , r .( iˆ  2 ˆj  k )  3 and
    2
r .(2 i  5 j   k )  1,   R, Then the value of   r is equal to:

1) 11 2) 9 3) 15 4) 13

 
1 1 60
69. If n is the number of irrational terms in the expansion of 3  5 4 8
, then (n – 1) is

divisible by :
1) 26 2) 7 3) 8 4) 30
70. Let the functions f : R  R and g : R  R be defined as:

 x  2, x  0  x3 x 1
f  x   2 And g  x   
 x , x0 3x  2, x  1
Then, the number of points in R where (fog) (x) is NOT differentiable is equal to:
1) 0 2) 2 3) 1 4) 3
71. A pack of cards has one card missing. Two cards are drawn randomly and are found to be
spades. The probability that the missing card is not a spade, is :
3 52 22 39
1) 2) 3) 4)
4 867 425 50
 z  11 
72. Let a complex number z , z  1 , satisfy log    2 . Then, the largest value of z is
2  z  1
1
 2

 
equal to _________
1) 8 2) 7 3) 5 4) 6

Sec: Sr.Super60_Elite, Target & LIIT‐BTs Page 20


SRI CHAITANYA IIT ACADEMY, INDIA 27‐12‐23_ Sr.Super60_Elite, Target & LIIT‐BTs _Jee‐Main_GTM‐04_Q.P

 i i  8 x  8 
73. Let A    , i  1 . Then, the system of linear equations A 
 y  64  has:
 i i     
1) Infinitely many solutions 2) Exactly two solutions
3) No solution 4) A unique solution
74. Let a vector iˆ   ˆj be obtained by rotating the vector 3iˆ  ˆj by an angle 450 about the
origin in counterclockwise direction in the first quadrant. Then the area of triangle having
vertices  ,   ,  0,   and (0, 0) is equal to :

1 1
1) 2) 1 3) 2 2 4)
2 2

sin 2 x 1  cos 2 x cos 2 x


75. The maximum value of f  x   1  sin 2 x cos 2 x cos 2 x , x  R is :
sin 2 x cos 2 x sin 2 x
3
1) 5 2) 7 3) 4) 5
4
dy  
76. If y = y(x) is the solution of the differential equation, 2 y tan x  sin x, y    0 , then
dx 3
the maximum value of the function y(x) over R is equal to :
1 15 1
1) 8 2) 3)  4)
8 4 2
77. 
The number of elements in the set x  R :  x  3 x  4  6 is equal to: 
1) 3 2) 4 3) 1 4) 2
78. The range of a  R for which the function
 x  x
f  x    4a  3  x  loge 5  2  a  7  cot   sin 2   , x  2n , n  N has critical points, is:
2 2
 4 
1)  3,1 2) [1, ) 3) ( ,  1] 4)  ,2
 3 

Sec: Sr.Super60_Elite, Target & LIIT‐BTs Page 21


SRI CHAITANYA IIT ACADEMY, INDIA 27‐12‐23_ Sr.Super60_Elite, Target & LIIT‐BTs _Jee‐Main_GTM‐04_Q.P
dy
79. Let C1 be the curve obtained by the solution of differential equation 2 xy  y 2  x 2 , x  0.
dx
2 xy dy
Let the curve C2 be the solution of 2 2
 . If both the curves pass through (1, 1), then
x y dx
the area enclosed by the curves C1 and C2 is equal to :
 
1)  1 2)  1 3)  1 4)   1
4 2
80. Consider three observations a, b and c such that b = a + c. If the standard deviation of
a + 2, b + 2, c + 2 is d, then which of the following is true ?
2

1) b  3 a  c  d
2 2 2
 2) b 2  a 2  c 2  3d 2

3) b
2
 3 a 2
 c2   9d 2 2 2

4) b  3 a  c  9d
2 2

(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If answer
is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
81. Consider an arithmetic series and a geometric series having four initial terms from the set {
11, 8, 21, 16, 26, 32, 4}. If the last terms of these series are the maximum possible four digit
numbers, then the number of common terms in these two series is equal to _________
dy
82. Let the curve y = y(x) be the solution of the differential equation,  2  x  1 . If the
dx
4 8
numerical value of area bounded by the curve y = y(x) and x – axis is , then the value of
3
y (1) is equal to _______
83. Let f : R  R be a continuous function such that f  x   f  x  1  2 , for all x  R . If
8 3
I1   f  x  dx and I 2   f  x  dx , then the value of I 1  2 I 2 is equal to _______
0 1

 30 20 56  2 7 2 
  1  i 3
84. Let P   90 140 112  and A   1  1  where   , and I3 be the
  2
120 60 14   0    1

identity matrix of order 3. If the determinant of the matrix  P 1 AP  I 3  is  2 , then the
2

value of  is equal to ___________


Sec: Sr.Super60_Elite, Target & LIIT‐BTs Page 22
SRI CHAITANYA IIT ACADEMY, INDIA 27‐12‐23_ Sr.Super60_Elite, Target & LIIT‐BTs _Jee‐Main_GTM‐04_Q.P
85. The total number of 3  3 matrices A having entries from the set {0, 1, 2, 3} such that the
sum of all the diagonal entries of AAT is 9, is equal to _________
ae x  b cos x  ce x
86. If lim  2 , then a + b + c is equal to _____________
x0 x sin x
87. For real numbers  , ,  and  , if
 x2 1 
 x  1  tan  x 
2 1

 dx   log  tan 1  x  1     tan 1    x  1    tan 1  x  1   C


2  2
 2

 4 2 1  x  1 
2 e 
x 
  x  
x 

 x  3x  1 tan  x      
 

where C is an arbitrary constant, then the value of 10        is equal to _____

88. Let ABCD be a square of side of unit length. Let a circle C1 centered at A with unit radius is
drawn. Another circle C 2 which touches C1 and the lines AD and AB are tangent to it, is
also drawn. Let a tangent line from the point C to the circle C 2 meet the side AB at E. If the

length of EB is α+ 3β , where α,β are integers, then α+β is equal to _________

z+i
89. Let z and w be two complex numbers such that w=zz-2z+2, =1 and Re (w) has
z-3i
minimum value. Then, the minimum value of n  N for which wn is real, is equal to
_______
90. If the variance of the frequency distribution
xi 2 3 4 5 6 7 8
Frequency f i 3 6 16  9 5 6
is 3, then  is equal to ______.

Sec: Sr.Super60_Elite, Target & LIIT‐BTs Page 23


SRI CHAITANYA IIT ACADEMY, INDIA 27‐12‐23_ Sr.Super60_Elite, Target & LIIT‐BTs _Jee‐Main_GTM‐04_Q.P

Sec: Sr.Super60_Elite, Target & LIIT‐BTs Page 24

You might also like