ORGANIC CHEMISTRY

Daily Assignment
Home Work DPP

Reaction Mechanism (1)

1. Find the product and type of reaction

H OTs Bu4NCH3CO2
DMF

OCOCH3
H OCOCH3 H OCOCH3 H
(a) , SN2 reaction (b) S 1 reaction
+ , N

OCOCH3
(c) H S 2 reaction (d) None
, N
2. Find the incorrect statement?

Ph
O
CHEM ACADEMY
Br
N
H
O

Ph
(a) SN2 reaction take place there (b) Product of the reaction is N

(c) Rate of reaction is depend on the concentration of substrate

(d) Rate of reaction is independent of concentration of Nucleophile
3. Rate of S N 2 reaction is fastest in following substrate.

(a) Br (b) O2N Br (c) Br (d) CH3 – CH2 – Br

4. Find the major product?

O
PPh3
+
R OH HO Ph DEAD
O O
(a) (b) (c) (d) None of these
R O Ph R O Ph R OH

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5. Find the correct statement

O NaOH
+ A B
S R Br H2O

O S
(a) A is (b) A is
S R O R

O
(c) B is + (d) SN2 reaction take place there
O HS R
6. Find the incorrect statement.

OH
CO2Me K2CO3 KOH
+ Br A B
Acetone H2O
OH Br

OH
O CO2Me
(a) A is CO2Me (b) B is
O
Br O

(c) A is
CHEM ACADEMYOH

COOMe
(d) In both cases SN2 reaction take place
Br
7. Find the incorrect order of nucleophilicity.
(a) I > Br > Cl in H2O (b) Cl > Br > I in DMSO
(c) CH3O > PhO > CH3CO2 > NO3 (d) NH2 < OH < F
8. Find the incorrect statement
OH
Cl
O O A
Bu4N HSO 4
NaOH, H 2O, CH2Cl 2

O O
O O O O
(a) A is (b) A is

(c) It is a example of SN2 reaction (d) It is a example of SN2´ reaction

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9. Find the major products.

MeSO 2Cl R MeSO2Cl

R OH A OH B
(i) LiCl, DMF (ii) LiCl, DMF
base base

(a) A is R R
Cl ; B is OH

R
(b) A is ; B is R Cl
Cl

Cl
(c) A & B is (d) It is an example of SN2 reaction
R
10. Find the major product and type of

RCu, BF3
Cl A

R R
(a) , SN2 reaction (b) , SN2´ reaction

R R
(c) , SN2 reaction (d) , SN2´ reaction
CHEM ACADEMY
ANSWER KEY
1. c 2. d 3. b 4. a 5. b 6. a 7. d
8. b, c 9. a 10. d

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