Aldehydes and Ketones Homework

Home Worksheet-2
 Class-2-OCOC-II

Reactions of Aldehydes & Ketones

I. Typical (Direct) Nucleophilic Addition :

1. Of Hydride ion (H ) : LiAlH4 /ether or NaBH4 /H 2O
2. Of Alkynide ion (R-C C-Na)
+
3. Of H 2 O/H (Hydration)
4. (a) Of ROH/H (b) Of Glycols (c) Of 1,3 Diols
+

5. Of HCN/KOH
6. Of NaHSO3 (Bisulphate addition)
7. Of Grignard Reagent
8. Of Ylides (Wittig Reaction)
9. Of Ammonia & it’s derivatives
(a) of ammonia (b) of Amines (RNH2 & RNHR)
(c) of special derivatives (NH Y)
2 (d) Reductive amination
 Chemistry Aldehydes & Ketones Home Work Sheet-2
..
£ AIC/ 3
Cztlscoc ,
'

+ A B
60°C

03 1. NaBH4 Zn
E + F ☐ c
dust
1-1-40
# Zn
2 .

1
Br
=
KOH
2- + A
14

200°C 03
A B C + ☐
2h

3. A- B
CH3C=_ CH +
MeMgBr (g) +

B + Phcocl → C É ☐
H2O
 °
(CHZOH)z
4.
¥H A
Ht
B
Ht 11-20 0

ICOO Me

5-
#
Ph CHO
HAN
A + B
PCC
→
t, c
k◦µ
Cltzclz 11-20
R2 R2
C

6- Br 1- Phzp → > A

A 1- HCHO →
B c ¥> D

OH KOH
/
alk (0+3) 20
7. -
.

Hg A
Kmn 04 Ht
8 0Eᵗ
R' R2 R3
CHS CHZ -CH=CHz
§ § Cltz
§
-
- - -
-

Identify Reagents R, , Rz & R-3 .

9
#
.
It -1

'

HO OH
-1 0

HCN Ma HNOZ
10 . A B C
@µ Etolt

1. MeMgBr
D
2 .
11-30-1