Sr no Description of process

1 Recovery of ( Methanol + Thinoyl chloride ) is to be done in 08 KL GLR

2 Hot water of 80 degree celsius will be used in reactor jkt .
3 For vapor condensation , utility of +05 celsius will be in primary graphite condensor
4 Rxn mass is only 3441 Kg , Therefor for peak load calculation , volume occupancy factor is 0.5
5 During recovery mean reactor temperature is 40 celsius
Assumptions
1 Latent heat of pure methanol is used in rxn
Point to be checked
1 90 % recovery of rxn mass is to be done which may result in minimum temperature sensing & minimum stirring problem
Conclusion
1 Maximum boil up rate will be 249 Kg/hr
2 For thermic fluid , 01 KL reactor is not suitable
Recommendation
1 For thermic fluid , shell & tube heat exchanger of Heat transfer area 20 m2 should be used
2 For reduction in CAPEX , Plate heat exchanger can be used inplace of shell & tube heat exchanger.(Sizing should be done by vendor)
3 Pumping flow rate required 36 m3/hr
Justification
1 Pumping flow rate is high because of low specific heat capacity & density of methanol as compared to water

Recovery reactor 08 KL GLR

Sr no Description Units Remarks Note
1 Name of solvent Methanol
2 Latent heat of solvent 1175 KJ/kg
3 Maximum heat input 81 KW =(Overall HTC * HTA*Average approach*Volume factor) At 0.5 volume occupancy factor
4 Maximum boilup rate 249 Kg/hr =(Maximum heat input*3600/Latent heat of solvent) At 0.5 volume occupancy factor

Utility design for reactor condensor utility

Sr no Description Units Remarks Note
1 Inlet temperature 11 celsius T1
2 Outlet temperature 5 celsius T2
3 Inlet temperature of brine -15 celsius T3
4 Outlet temperture of brine -10 celsius T4
5 DELTA T1 21 celsius (T4-T1)
6 DELTA T2 20 celsius (T3-T2)
7 (DELTA T1)/DELTA T2) 1.05 celsius =(T4-T1)/(T3-T2)
8 LMTD 20.5 celsius =(DELTA T1-DELTAT2)/((LNDELTAT1/DELTAT2))
9 Overall HTC 250.0 W/M2k For Shell & tube heat exchanger
10 Heat load 97.6 KW =Maximum heat input *1.2 20 % safety factor is consider
11 Heat transfer area required 19.0 m2 =Heat load /(Overall HTC * LMTD)
Utility flow rate calculation
1 Specific heat capacity of methanol 2.5 KJ/KgK Cp
2 Temperature change across condensor 5 celsius ∆T
3 Density of methanol 792 Kg/m3 Density
4 Flow rate required 35.5 m3/hr =Heat load*3600/(Cp*Density*∆T)

Reactor condensor sizing for phase change only

Sr no Description Units Remarks
1 Vapour Inlet temperature 40 celsius T5
2 Vapour Outlet temperature 40 celsius T6
3 Inlet temperature of utility 5 celsius T7
4 Outlet temperture of utility 11 celsius T8
5 DELTA T3 29 celsius (T8-T5)
6 DELTA T4 35 celsius (T7-T6)
7 (DELTA T3)/DELTA T4) 0.83 celsius =(T8-T5)/(T7-T6)
8 LMTD 31.91 celsius =(DELTA T3-DELTAT4)/((LN(DELTAT3/DELTAT4))
9 Overall HTC 250 W/M2k For Graphite condensor
10 Heat load (At volume occupancy factor 0.5) 81 KW
11 Heat transfer area required(At volume occupancu factor 0.5) 10.20 m2 =Heat load /(Overall HTC * LMTD)
12 Heat transfer area required(At volume occupancu factor 1) 20.39 m2 =Heat load /(Overall HTC * LMTD)

Shell Side Primary condensor Secondary condensor

Sr No MOC ID of equipment Capacity Volume Factor Heat transfer area Steam HWT CW CHW BRINE CW CHW CHW BRINE Boilup rate at different volume occupancy
1 GLR R-01 08 KL 0.5 20 104580 81340 58100 40670 26145 104580 81340 20916 16268 249
2 GLR R-01 08 KL 0.4 20 83664 65072 46480 32536 20916 83664 65072 16733 13014 199
3 GLR R-01 08 KL 0.3 20 62748 48804 34860 24402 15687 62748 48804 12550 9761 150
4 GLR R-01 08 KL 0.2 20 32536 100
5 GLR R-01 08 KL 0.1 20 16268 50
Total Load (W) 250992 195216 139440 97608 62748 250992 50198 50198 39043
Peak load 81340 0 81340 #REF!
Peak load with respective units 0 81 0 0 0 0 23 0 #REF!
Kg/hr KW TR TR TR TR TR TR TR