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8.ARQ - Chemical Kinetics
8.ARQ - Chemical Kinetics
Assertion
Assertion-Reason type questions
A Assertion and reason both are true, reason is correct explanation of assertion.
B Assertion and reason both are true but reason is not the correct explanation of assertion.
C Assertion is true, reason is false.
D Assertion is false, reason is true statement
1 Assertion:: Order of the reaction can be zero or fractional.
Reason: We cannot determine order from balanced chemical equation.
2 Assertion: Presence of catalyst does not make a non spontaneous reaction proceed at a faster
rate.
Reason: Catalyst provides an alternate pathway involving lower activation energy for the
forward reaction only
3 Assertion: At high pressure the following reaction is zero order.
Reason : At high pressure, the surface of catalyst is completely saturated with ammonia, so
further change in pressure does not affect rate
4 Assertion: Order of the reaction can be zero or fractional.
Reason: We cannot determine order from a balanced chemical equation..
5 Assertion : The enthalpy of reaction remains constant in the presence of a catalyst.
Reason : A catalyst participating in the reaction, forms a different activated complex and
lowers down the activation energy but the difference in energy of reactant and product
remains the same.
6 Assertion: Order of reaction can be zero or fractional.
Reason : We cannot determine order from balanced chemical equation.
7 Assertion : Rate constants determined from Arrhenius equ
equation
ation are fairly accurate for
simple as well as complex molecules.
Reason: Reactant molecules undergo chemical change irrespective of their orientation
during collision.
Q.No. Answer
1 B
2 C
3 A
4 B
5 D
6 A
7 C
8 C
9 B
10 D
11 B
12 A
13 A
14 C
15 B
16 D
17 B
18 C
19 C
20 B
21 C
22 B
23 A
24 C