Form No: SMSPL/QF/46

Rev- 00; Date:19.07.2021;

MEASUREMENT UNCERTAINTY RECORD

LAB CODE- 2021 314528 DATE OF COMMENCE : 1910.12.2023 DATE OF COMPLETED ; 23.12.12.2023
IRON ORE-LOI METHOD- IBM
Sources of Uncertainity: Type
1 Weighing Balance B
2 Muffle Furnace B
3 Purity of CRM B
4 Results Obtained A

Calculation of Uncertainity
Type A
6 sets of results
x1 7.98
x2 7.71
x3 7.80
x4 7.65
x5 8.02
x6 8.08
Mean 7.8733
SD 0.1775

Assumed as normal distribution, the standard Uncertainity for type A is given by:
UA 0.0724646
Standard Uncertainity UA 0.0725
± 0.9204 percent
Type B
Uncertainity due to balance (SMSPL/PDP/MIN/DAB/02) from calibration certificate ± 0.000248 gms
Assuming as normal distribution,
Standard Uncertainity at 95% confidence level ± 0.000124 percent
Uncertainity due to balance UB1 ± 0.000124 percent
Uncertainity due to CRM UB2 ± 0.000 percent
Uncertainity due to Muffle Furnace (SMSPL/PDP/MIN/02) from calibration certificate ± 1.8 º C
Assuming as normal distribution, the standard Uncertainity ± 0.9 at 95% C.L.
Temperature Uncertainity at 1000 º C UB3 ± 0.1000 percent

Combined Uncertainity K= 2 UC 0.9258 percent

Expanded Uncertainity U 1.8516 percent at 95% C.L.
± 0.1458 at 95% C.L.
Result 7.8733 ± 0.146 percent

Page 1 of 7
 Form No: SMSPL/QF/46
Rev- 00; Date:19.07.2021;
MEASUREMENT UNCERTAINTY RECORD

LAB CODE-2 202311793 COMENCE DATE-0903.10.2023 COMPLETE DATE-1003.10.2023

IRON ORE -TM METHOD-IS 1493 PART-1
Sources of Uncertainty : Type
1 Weighing Balance B
2 Hot Air Oven B
3 Results Obtained A

Calculation of Uncertainty
Type A
6 sets of results
1 10.35
2 10.40
3 10.00
4 10.50
5 9.95
6 10.10
Mean 10.22
SD 0.2295
Assumed as normal distribution, the standard Uncertainty for type A is given by:
UA 0.093689795
Standard Uncertainty UA 0.0937
± 0.9170 percent
Type B
Uncertainty due to balance(SMSPL/PDP/MIN/DAB/02 from calibration certificate ± 0.00940 gm
Assuming as normal distribution,
Standard Uncertainty at 95% confidence level K= ± 0.0047 percent
Uncertainty due to balance UB1 ± 0.004700 percent
Uncertainty due to Hot Air Oven (SMSPL/PDP/MIN/HAO/03) from calibration certificate ± 1.8000 º C
Assuming as normal distribution, the standard Uncertainty ± 0.9000 at 95% C.L.
Temperature Uncertainty at 110 º C UB3 ± 0.8182 percent

Combined Uncertainty K= 2 UC 1.2290 percent

Expanded Uncertainty at 95% C.L. U 2.4580 percent
± 0.2511 at 95% C.L.
Result 10.22 ± 0.251 percent

Page 2 of 7
 Form No: SMSPL/QF/46
Rev- 00; Date:19.07.2021;
MEASUREMENT UNCERTAINTY RECORD

LAB CODE- 2202314528 DATE OF COMMENCE : 05.

10.12.2023 DATE OF COMPLETED ; 23.12.12.2023
IRON ORE-Phosphorus METHOD- IS 1493 PART-1
Sources of Uncertainty: Type
1 Weighing Balance B
2 Purity of HCl B
3a Burette 50 ml B
3b Purity of CRM B
3c Pipette 20 ml B
4 Results Obtained A

Calculation of Uncertainty
Type A
Normality of
6 sets of results BR in ml
HCL
1 0.0550 5.50 0.10100
2 0.0570 5.30 0.10100
3 0.0490 5.90 0.10100
4 0.0570 5.30 0.10100
5 0.0490 5.90 0.10100
6 0.0470 6.05 0.10100
Mean 0.0523 5.66 0.1010
SD 0.0045 0.3323

Assumed as normal distribution, the standard Uncertainty for type A is given by:
UA 0.0018378731669454
Standard Uncertainty UA 0.0018
0.0000 ± 3.5119 percent
Type B
Uncertainty due to balance (SMSPL/PDP/MIN/DAB/02) from calibration certificate ± 0.000248 gms
Assuming as normal distribution,
Standard Uncertainty at 95% confidence level ± 0.000124 percent
Uncertainty due to balance UB1 ± 0.000124 percent
Uncertainty due to Purity of HCL UB2 ± 0.0010 percent
Uncertainty due to CRM UB3 ± 0.0000
Uncertainty due to burette () = ± 0.0001 at 95% C.L.
Assuming the normal distribution, the Standard Uncertainty ± 0.0000 percent
Uncertainty due to burette, ± 0.0005 percent
Where mean burette reading is 5.66 ml
Uncertainty due to pipette () = UB4 ± 0.0001 at 95% C.L.
Assuming the normal distribution, the Standard Uncertainty ± 0.0000
Uncertainty due to pipette, UB5 ± 0.0003 percent

Combined Uncertainty K= 2 UC 3.5119 percent

Expanded Uncertainty U 7.0237 percent at 95% C.L.
± 0.0037 at 95% C.L.
Result 0.0523 ± 0.004 Percent

Page 3 of 7
 Form No: SMSPL/QF/46
Rev- 00; Date:19.07.2021;
MEASUREMENT UNCERTAINTY RECORD

LAB CODE- 2CRM EURONOR-682-2 DATE OF COMMENCE : 1905.12.2023 DATE OF COMPLETED ; 2307.12.2023
Iron ore - Sulphur METHOD-IS 1493 PART-1
Sources of uncertainty: Type
1 Weighing Balance B
2 Muffle Furnace B
3 Purity of CRM B
4 Results Obtained A

Calculation of uncertainty
Type A
6 sets of results
1 0.019
2 0.014
3 0.012
4 0.017
5 0.018
6 0.012
Mean 0.015333333
SD 0.0031

Assumed as normal distribution, the standard uncertainty for type A is given by:
UA 0.001256096
Standard Uncertainty UA 0.0013
± 8.1919 percent
Type B
Uncertainty due to balance (SMSPL/PDP/MIN/DAB/02) from calibration certificate ± 0.000248 gm
Assuming as normal distribution,
Standard uncertainty at 95% confidence level ± 0.000124 gm
Uncertainty due to balance UB1 ± 0.000124 percent
Uncertainty due to CRM UB2 ± 0.0000 percent
Uncertainty due to Muffle Furnace (SMSPL/PDP/MIN/LAB/02) from calibration certificate ± 1.2300 º C
Assuming as normal distribution, the standard uncertainty ± 0.6150 at 95% C.L.
Temperature uncertainty at 900 º C UB3 ± 0.0683 percent

Combined uncertainty K= 2 UC 8.1922 percent

Expanded Uncertainty U 16.3844 percent at 95% C.L.
± 0.0025 at 95% C.L.
Result 0.0153 ± 0.003 percent

Page 4 of 7
 Form No: SMSPL/QF/46
Rev- 00; Date:19.07.2021;
MEASUREMENT UNCERTAINTY RECORD

LAB CODE- 2 202314528 DATE OF COMMENCE : 1910.12.2023 DATE OF COMPLETED ; 2312.12.2023

IRON ORE-ALUMINA METHOD-IS 1493 PART-1
Sources of uncertainty: Type
1 Weighing Balance B
2 Chemicals B
2a Purity of zinc B
2b Purity of CRM B
3 Burette 50 ml B
4 Results Obtained A

Calculation of uncertainty
Type A
6 sets of results BR in ml Molarity of zinc
1 6.43 31.40 0.010040
2 6.18 30.20 0.010040
3 6.48 31.70 0.010040
4 6.37 31.15 0.010040
5 6.22 30.45 0.010040
6 6.15 30.00 0.010040
Mean 6.305 30.82 0.010
SD 0.1395 0.6947 0.0000

Assumed as normal distribution, the standard uncertainty for type A is given by:
UA 0.0569649015
Standard Uncertainty UA 0.0570
± 0.9035 Percent
Type B
Uncertainty due to balance (SMPL/PDP/MIN/DAB/02) from calibration certificate ± 0.000248 gms
Assuming as normal distribution,
Standard uncertainty at 95% confidence level ± 0.000124 gm
uncertainty due to balance UB1 ± 0.000124 percent
Uncertainty due to Purity of EDTA UB2 ± 0.0001 percent
Uncertainty due to CRM UB3 ± 0.0070 percent
Uncertainty due to burette ± 0.0001 at 95% C.L.
Assuming as normal distribution, the standard uncertainty ± 0.0000 at 95% C.L.
Uncertainty due to burette, UB4 ± 0.0001 percent
Where the Mean Burette Reading 30.82

Combined Uncertainty K 2 UC 0.9035 percent at 95% C.L.

Expanded Uncertainty U 1.8070 percent at 95% C.L.
± 0.1139 at 95% C.L.
Result 6.305 ± 0.114 percent

Page 5 of 7
 Form No: SMSPL/QF/46
Rev- 00; Date:19.07.2021;
MEASUREMENT UNCERTAINTY RECORD

LAB CODE- 2 202314528 DATE OF COMMENCE : 19

10.12.2023 DATE OF COMPLETED ; 23.12.12.2023
IRON ORE-SiO2 METHOD-IS 1493 PART-1
Sources of Uncertainty : Type
1 Weighing Balance B
2 Muffle Furnace B
2b Purity of CRM B
3 Results Obtained A

Calculation of Uncertainty
Type A
6 sets of results
1 6.82
2 6.54
3 6.70
4 6.85
5 6.49
6 6.76
Mean 6.69
SD 0.1483
Assumed as normal distribution, the standard Uncertainty for type A is given by:
UA 0.06053465
Standard Uncertainty UA 0.0605
± 0.9044 percent
Type B
Uncertainty due to balance (SMSPL/PDP/MIN/DAB/02) from calibration certificate ± 0.000248 gm
Assuming as normal distribution,
Standard Uncertainty 0.000124 at 95% confidence level K= 0.000124
Uncertainty due to balance UB1 ± 0.000124 percent
Uncertainty due to CRM UB2 ± 0.1200 percent
Uncertainty due to Muffle Furnace (SMSPL/PDP/MIN/MF/01) from calibration certificate ± 1.7800 º C
Assuming as normal distribution, the standard Uncertainty ± 0.8900 at 95% C.L.
Temperature Uncertainty at 1050º C UB3 ± 0.0989 percent

Combined Uncertainty K= 2 UC 0.9177 percent

Expanded Uncertainty U 1.8353 percent at 95% C.L.
± 0.1228 at 95% C.L.
Result 6.69 ± 0.123 percent

Page 6 of 7
 Form No: SMSPL/QF/46
Rev- 00; Date:19.07.2021;
MEASUREMENT UNCERTAINTY RECORD

LAB CODE- 2202314528 DATE OF COMMENCE : 19.

10.12.2023 DATE OF COMPLETED ; 23.12.12.2023
Iron ore - Total Iron METHOD-IS 1493 PART-1
Sources of uncertainty: Type
1 Weighing Balance B
2 Chemicals B
2a Purity of K2Cr2O7 B
2b Purity of CRM B
3 Burette 50 ml B
4 Results Obtained A

Calculation of Uncertainty
Type A
6 sets of results BR N of K2Cr2O7
1 54.61 24.45 0.1
2 54.92 24.60 0.1
3 54.76 24.55 0.1
4 54.55 24.45 0.1
5 54.96 24.65 0.1
6 54.50 24.40 0.1
Mean 54.72 24.52 0.10000
SD 0.1942 0.0983 0.0000
Assumed as normal distribution, the standard uncertainty for type A is given by:
UA 0.079274487979706
Standard Uncertainty UA 0.0793
± 0.1449 percent
Type B
Uncertainty due to balance (SMSPL/PDP/MIN/DAB/02) from calibration certificate ± 0.000248 mg
Assuming as normal distribution,
Standard uncertainty at 95% confidence level 0.000124 percent
Uncertainty due to balance UB1 ± 0.000124 percent
Uncertainty due to Purity of K2Cr2O7 UB2 ± 0.0010 percent
Uncertainty due to CRM from Certificate UB3 (Euronorm-CRM No. 682-2) ± 0.0800 percent
Uncertainty due to burette ± ± 0.0001 at 95% C.L.
Temperature Uncertainty at 105 º C 0.0001
Assuming the normal distribution, the Standard Uncertainty ± 0.0000 percent
Uncertainty due to burette, UB4 ± 0.0001 percent
Where mean burette reading is 41.93 ml

Combined Uncertainty K= 2 UC 0.1655 percent

Expanded Uncertainty U 0.3310 percent
± 0.1811 percent
Result 54.72 ± 0.181 percent

Page 7 of 7