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Transition Metal Isocyanide Complexes
Transition Metal Isocyanide Complexes
isocyanide
complexes
structure of Os3(CO)9(CNCH2)3CMe.[2]
The first metal carbene complex, Chugaev's red salt, was not
recognized as such until decades after its preparation.[10]
Fe(CNR)5 + H+ → [HFeL5]+
Fe(CO)5 + H+ → no reaction
Some electron-rich isocyanide complexes
protonate at N to give aminocarbyne
complexes:[12]
LnM-CNR + H+ → [LnM≡CN(H)R]+