CREANE MEMORIAL HIGH SCHOOL, GAYA

Annual 2022-23
CLASS: Xl
Subject: P.M.: 70
CHEMISTRY TIME: 3 hours

General Instructions:
1. There are 35 questions in this
question paper.
2. All questions are compulsory
3. SECTION A- Q.No 1 to 18 carrying
I mark each.
4. SECTIONB- Q. No. 19 to 25
carrying 2 marks each.
5. SECTIONC-Q. No. 26 to 30 carrying
3 marks each.
6. SECTIOND- Q.No.31 to 32 carrying
4 marks each.
7. SECTIONE- Q. No.33 to 35 carrying
5 marks each.

SECTIONA
The following questions are
Multiple Choice Questions with one correct answer. Each question carries 1
mark. There is no internal
choice in this section.
I. how many significant figures
are present in 5005 ?

2. what will be the molarity of a solution

which contains 5.85 g of NaCl per 500 mL ?
a) 4 mol.c l b) 20 mol.L I c) 0.2 mol.L l d) 2 mol.L I
3. What will be the electronic configuration
of 0 2- ?
a) Is i 2s2 2p 2 b) 1s2 2s2 2p6 c) 1s2 2s2 2p 4 d) 1s 2 2s 2 2p 5
4. How many 4d electrons can have spin quantum
number—h ?

5. Li has the diagonal relationship with

a) Si c) Na d) Mg
6. Sodium belongs to
a) Halogens b) Alkaline Earth Metal c) Alkali Metal d) Noble Metal
7. The species which has the bond angle 1200
a) CH4 b) BCG c) H20 d) NH3
8. The shape of PC15molecule is
a) Trigonal bipyramidal b) Tetrahedral c) Trigonal Planar d) Square Planar
9. For the process to occur under adiabatic condition, the correct condition is

10. The enthalpies of all elements in their standard states are:

a) Unity b) Less than zeo c) zero d) Very large
11. Ka for CH3COOH is 1.8 X 108 and Kbfor NH40H is 1.8 X 10-5. The pH of ammonium acetate will be
a) 7.005 b) 7.0 c) 4.75 d) between 6 and 7
12. What will be the relation between KPand Kcfor the following chemical equation:
2soz(g) + 02(g) 2s03(g)
a) KP = Kc(RT) b) KP = Kc(RT) 1
13. In which of the following metal displacement reaction will not take place ?
a) Mg + Cu 2+-> b) Pb + Ag++ c) zn + cu 2+» d) Cu + Mg2++
14. The oxidation number of sulphur in H2S04is

In the following questions a statement assertion followed by a statement of reason is given.

Choose the correct answer out of the following choices.
a). Both Assertion(A) and Reason(R) are true and Reason(R) is the correct explanation Of
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 b). Both AssertiontA) and Reasoh(R)
thüéuüt héason(R) is not the correct explanation of
Gertion(A).
c). Assertion(A) is true but Reason(R) is false
d). Assertion(A) is false and Reason(R) is true.
15. Assertion(A) : Neopentone has lower boiling
point than n-Pentane and isopentane.
Reason(R) : Boiling point increases with increase in branching.
16. Assertion(A) : Boiling point of hydrocarbons
increases with increase in carbon chain.
Reason(R) : Surface orea increases, Van der waal's forces increases with increase in carbon
chain.
17. Assertion(A) : Boiling point of ethanol is higher.
Reason(R) : Inter molecular hydrogen bonding is present between ethanol molecules.
18. Assertion(A) : Propan-l-ol and Propan-2-ol ore position
isomers.
Reason(R) : Position isomers differ in the positions offunctional group or a substituent.

SECTION B
This section contains 7 questions with internal choice in two questions. The following questios
are very short answer type and carry 2 marks each.
19. Balance the following equation in basic medium by Ion Electron Method.
Fe2+(aq) + Cr2072-(aq) Fe3+(aq) + Cr 3+(aq)
20. In three moles of ethane(C6H6)Calculate:
i) Number of moles of carbon atoms.
ii) Number of moles of hydrogen atoms.
OR,
i) Define Molarity.
ii) Calculate the molarity of NaOH in the solution prepared by dissolving its 4 g in enough water
to form 250 mL of the solution.
21. Using s,p,d notations, describe the orbital with the following quantum numbers.

OR,
Show that the circumference of the Bohr Orbit for the hydrogen atom is an integral multiple of
the de Broglie wave length associated with the electron revolving around the orbit.
22. Explain any two
i) Electron Gain Enthalpy
ii) Ionisation Energy
iii) Electronegativity
iv) Ionic Radius
23. Answer the following:
i) Draw the resonance structure of C032
ii) Define hydrogen bond. Is it weaker or stronger than Van der waars forces ?
24. Answer the following:
i) Write the expression for equilibrium constant Kcfor the following reaction.
2cu0(s) +, 4N02(g) + 02(g)
ii) The PK. of acetic acid and pKbof ammonium hydroxide are 4.76 and 4.75 respectively.
Calculate the pH of ammonium acetate solution.
25. Draw the structure of any two of the following:
i) 0-Ethylanisole
ii) p-Nitroaniline
iii) 3,4-Dimethylphenol
iv) 2,2,4,4-Tetramethylpentane
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 SECTION C
This section contains 5 questions with internal choice in one question •Thefollowing questions
are short answer type and carry 3 marks each.
26. Answer the following:
i) Why are axial bonds longer as compared to equatorial bonds in PCIs molecule ?
ii) Explain Extensive and Intensive Properties.
iii) Explain Spontaneous process.
27. Explainany three:
i) Redox couple ii) Standard Electrode Potential iii) Torsional strain
iv) Electrophile v) Nucleophile vi) Decarboxylation
28. How would you bring out the following conversion ?
i) Propene into methanal and ethanal.
ii) Ethyne into benzene
iii) Chloroethane int ethene.
29. Answer the following:
i) Define Standard Enthapy of Vaporisation
ii) Derive the relation ,
AH +
30. Answer the following:
species ?
i) How many neutrons and protons are their in the following
s u
26Fe € and 38Sr
ii) Write the electronic configuration of Cr. (Given Z =24)
iii) Which atoms are indicated by the following configurations ?
a) [Nel 3s23p3 b) [Arl 4s23dI

Derive the relation ,

KP = Kc.(RTpn
SECTION D
has an intemal choice and
Thefollowing questions are case-based-questions. Each question
answer the questions that
carries 4 (1+1+2)marks each. Read the passage carefully and the
follows:-
31. Read the passage carefully.
the shapes of molecules. It involves
The concept of hybridization has been introduced to explain
atom but in different sub-
the intermixing of two or more atomic orbitals belonging to same
orbitois called hybrid
shells so as to intermix and redistribute energies to form equivalent
hybridization may
orbitals. Depending upon the number and nature of the orbitals involved , the
(trigonal bipyromidcl),
be divided into sp (linear), spa (trigonal), sp3(tetrahedral), sp3d
3 3 that the orbitals of
sp 3d(octahedra/) and sp d (pentagonal bipyramidal) types. it may be noted
isolated atoms never hybridise and they do so at the time of bond formation.
Answer the following.
i) What type of hybridisation is present in P atom of PCIs molecule ?
ji) What will be the bond angle around the atom which uses sp2 hybridisation ?
the shape and bond
iii) Describe the hybridisation of C atom in CH4 molecule and also mention
angle in CH4 molecule.
32. Read the passage carefully.
Presence of double bond in an alkene is tested by reacting with either bromine water or with
dilute solution of Bayer's reagent. Theposition ofdouble bond is located with the help of
ozonolysis. It is done by joining together the products of ozonolysis which are carbonyl
compounds at their carbonyl carbon atoms by double bond.
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 Answer the following.
i) What happens when propene is
treated with bromine water ? Write the chemical equation.
ii) Give the chemical equation for ozonolysis of
ethene.
iii) Describe a Chemical test to detect an unsaturated
hydrocarbon.
SECTION E
Thefollowing questions are long answer type and carry 5 marks. One question
has an
intemalchoice.
33. Answer the following:
i) What happens when ethanol is heated with Conc.H2S04? Write the chemical equation.
ii) Draw the structure of cis-But-2-ene and
trans-But-2-ene.
iii) Identify Product
Peroxide
CH3-CH + H-Br Product

iv) The compound sodium benzoate on decarboxylationgives a compound X. Compound X is

heated with the mixture of Conc.HN03 and Conc.H2S04gives another compound Y and water.
Identify X and Y.
v) Give the chemical equation for the following reaction.
Ethyne is warmed with water at 333K in presence of HgC12and dilute H2S04.
OR,
i) Draw all the resonating structures of phenol.
ii) Draw eclipsed and staggered Newman projections of ethane.
iii) Explain ß-Elimination reaction.
iv) Draw the bond line structure of 1,3,5,7-octatetraene.
v) Calculate 0-bonds and It-bonds in 1,3,5,7-octatetraene.
34. Answer the following:
i) State Hess's Law. Give its mathematical form.
ii) When AG is positive, the process is always non-spontaneous. Explain.
iii) 2 litres of an ideal gas at a pressure of 10 atm expands isothermally into a vacuum until its total
volume is 10 litres. How much heat is absorbed and how much work is done in the expansion ?
iv) Express the change in internal energy of a system when no heat is absorbed by the system from
the surroundings, but work (W) is done on the system. What type of wall does the system have ?
v) Express the change in internal energy of a system when no work is done on the system , but q
amount of heat is taken out from the system and given to the surroundings. What type of wall
does the system have ?
35. Answer the following:
i) Calculate the mass percentage of benzene (C6H6) if 22g of benzene is dissolved in 122 g of
carbon tetrachloride (CC14).
ii) Calculate the amount of water (g) produced by the combustion of 16 g of methane ?
iii) Why do elements in the same group have similar physical and chemical properties ?
iv) The solubility product constant (Ksp)of barium sulphate (BaS04) in water is 1.1 X 10-10at 298K.
Calculate the molar solubility of barium sulphate.
v) Classify the following species into Lewis acid and Lewis base.

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