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Richardson 1988
Richardson 1988
49
illustrate the development of discussions and The program OCCURVE, for obtaining an ing more than 40 years after the initial experi-
the relevance of mathematical models. operating characteristic, adopts the very te- ments. The field is so vast that it is a major
This study can be recommended both as a dious approach of calculating binomial coef- task to write a book which, starting from the
text book for advanced students of welding ficients using Pascal’s triangle. The sum of a elementary theory of NMR spectroscopy, is
engineering and as a valuable source of binomial series is much more easily obtained by able ‘to provide sufficiently detailed informa-
reference for anyone working in the field of using the recursion formula. tion to familiarize the reader with not only the
welding research and development. The use of matrix algebra for the programs theoretical foundation but the numerous ap-
Ian’ M. Richardson for linear calibration would be much more plication of this technique’. Unfortu-
efficient than the author’s elementary treat- nately this book is not really successful in its
ment and would enable more information to be aims. One major problem is that the standard
Three Degrees Above Zero. Bell
easily obtained. of proof reading is very poor throughout the
Laboratories in the Information Age. By
In writing the programs for cusum techni- book. In addition it is confused and confusing
Jeremy Bernstein. Pp. 247. Cambridge
ques, the author may have reinvented the about several topics. For instance, the discus-
University Press. 1987. f 17.50.
wheel, as flow charts and documentation sion of spin lattice relaxation states that
Bell Research Laboratories has played a already exist in BS5703: Data Analysis and eqn.l.15 becomes eqn.l.16 when tempera-
spectacular role in the history of science and Quality Control Using Cusum Techniques. ture is explicitly considered. Temperature
technology as well as that of industrial re- To the best of the writer’s knowledge Dr does not appear in either equation and is not
search. Jeremy Bernstein’s book reaffirms Hartley’s programs are new, the exceptions explicitly required to describe the approach to
this with a refreshing look at the contribu- being those for fitting straight lines and cusum thermal equilibrium. The discussion on polar-
tions to the Laboratories’ success made by a techniques. The others, in spite of their de- ization transfer is unclear. How does ‘the
number of the organisation’s most famous ficiencies in technique, fulfil adequately the application of two simultaneous 180” pulses’
employees. The account was compiled from task they are supposed to do, and will be of use transfer polarization? The more complex
hours of conversation with Bell’s numerous in organisations with small computing facilities pulse sequences, e.g. INEPT, are discussed
Nobel and other prize winners combined with and someone with an enthusiasm for com- before the simpler inversion recovery etc.
the author’s own observation of the Labor- puting. pulse sequences. In summary, although the
atories at work. D. J. Lancaster range of topics is reasonable for a first intro-
It is not a scholarly study; it is, as Bernstein duction to NMR for chemists, rather better,
is keen to emphasise, a scientifically-literate cheaper books exist.
journalist’s attempt to recount the essence of Fifty Years of Neutron Diffraction. The
R. Dupree
the success of Bell Labs as perceived by those Advent of Neutron Scattering. Edited by
most closely involved. The reasons suggested G. E. Bacon. Pp. 280. Adam Hiiger, Bristol
and the int. Union ofCrystallography. Aquatic Surface Chemistry. Chemical
by all had an uncanny similarity: interdiscipli-
1987. f30.00. Processes at the Particle-Water Interface.
narity, ease of communication, and the free-
Edited by Werner Stumm. Pp. 520. Wiley,
dom of individuals to pursue ‘pure’ scientific This book completes a trilogy, sponsored by
Chichester. 1987. f64.15.
inquiry with only very long-term possibilities the IUC, describing the histories of the X-ray,
of affecting the telecommunications industry. electron, and neutron diffraction techniques. This symposium in print is a synthesis of
Indeed the sub-plot of this book was soon It covers the period from 1936, from the first current knowledge on chemical processes
evident: what would the impact be on this suggestion that thermal neutrons might be occurring at the soil-water interface. Each
unique combination of academic freedom and diffracted by crystalline materials up to the author presents the principles underlying a
massive financial input, of the divestiture of present day. Its editor, G. E. Bacon, has particular process and then explores the re-
the parent company, AT&T, of its status as a clearly had a formidable task in compiling this sults and implications of recent research,
regulated monopoly? This happened in Janu- history of the technique within the limit of 280 emphasizing quantitative, mechanistic ex-
ary 1984; perhaps a postscript is now needed pages. His selection of topics includes the planation and intellectual stimulation rather
assessing the actual effect of divestiture. evolution of neutron sources from radium- than extensive documentation. Links be-
M. Williams beryllium to the present dedicated high-flux tween theory, controlled laboratory inves-
research reactors and accelerator-based tigations, and environmental behaviour are
pulsed sources. It also follows the develop- constantly stressed, as are current areas of
Computerized Quality Control Programs ignorance.
ment of neutron instruments from the early
for the Analytical Laboratory. By T. F. Part 1 (The solid-solution interface, 6 chap-
primitive devices to the modern machines
Hartley. Pp. 165. Ellis Horwood, ters) deals with adsorption mechanisms, elec-
capable of dealing with microgram samples
Chichester. 1986. f 18.50. trical double layers, charged polyelectrolyte
and real-time experiments. The geographical
Computerized Quality Control is a textbook spread of the technique, which has led to a gels, and the surface chemistry of oxides and
of eleven computer programs in BASIC with world-wide neutron scattering community, is soils. Part 2 (Formation and dissolution of
detailed commentary by the author. The also described. A balance is maintained solid phases, 5 chapters) discusses the control
programs were written for use by analytical throughout between scientific aspects of the exerted by the kinetics of surface reactions
chemists, but there will be no difficulty in technique and personal reminiscences, which and describes how these reactions can be
using them in other branches of technology often illustrate the excitement of working in simulated by Monte-Carlo methods. Part 3
and industry. neutron scattering, both in the pioneering (Regulating the composition of natural wa-
The program listings are in very clear type. days and today. The book will obviously be ters, 7 chapters) examines the fate of metal
However, when program listings have to go popular with neutron scientists but deserves a ions in lakes; metal complexation; particle-
through the intermediate process of being much wider readership as a fascinating particle interactions; the role of colloids in
typeset one has to be more than ordinarily account of this ‘peaceful use of atomic partitioning solutes in natural waters and of
careful that no errors are inadvertently over- energy’. particles in regulating the composition of
looked. The fact that SPLINE: line 752 and N. Cowlam seawater; and the abiotic transformation of
VMASK: line 3310 contain errors means that organic chemicals.
there may be others. The text is nicely printed, but lacks a
In several places the author used express- Nuclear Magnetic Resonance. General standard format for the references and the
ions of the type EX2 - (Ex)‘/n to obtain the Concepts and Applications. By William W. many graphs. There is a good index and
sum of squares instead of the more fun- Paudier. Pp. 291. Wiley, Chichester. 1987. extensive cross-references between chapters.
damental E(x-x)‘. The latter avoids the well f32.10. The book is essential reading for all working
known problem which occurs when Ex’ and The techniques and applications of Nuclear in aquatic surface chemistry.
(Ex)‘/n are very nearly equal. Magnetic Resonance are still rapidly develop- D. A. Rose
50