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T. Karthik - Prabha Karan C. - R. Rathinamoorthy - Nonwovens - Process, Structure, Properties and Applications-Woodhead Publishing India PVT. Limited (2016)
T. Karthik - Prabha Karan C. - R. Rathinamoorthy - Nonwovens - Process, Structure, Properties and Applications-Woodhead Publishing India PVT. Limited (2016)
T. Karthik
R. Rathinamoorthy
C. Praba Karan
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Preface ix
Foreword xiii
List of figures xv
List of tables xxi
1. Introduction to nonwovens 1
1.1 Definition of nonwoven 2
1.2 Classification of nonwovens 3
1.3 History of nonwovens 4
1.4 Market growth of nonwoven industry 6
1.5 Features of nonwoven fabrics 10
1.6 Raw materials for nonwovens 11
1.7 Product properties and applications of nonwovens 27
2. Web formation 34
2.1 Introduction 34
2.2 Staple fiber web formation system 35
2.3 Polymer lay process 75
2.4 Comparison of different web forming techniques 88
Index 315
Preface
The authors have put commendable effort in bring this book. This book
will be certainly useful to students, academicians, researchers and personnel
from industry.
Prof. R. S. Rengasamy
Department of Textile Technology
Indian Institute of Technology, Delhi
New Delhi-16
List of figures
Figure Description
No.
1.1 Structure of woven, knitted and nonwoven fabrics
1.2 Classification of Nonwovens based on production techniques
1.3 Classification of Nonwovens based on structure
1.4 Worldwide production of nonwovens by quantity
1.5 Worldwide productions of nonwovens by region
1.6 Nonwoven productions by web-forming processes
1.7 Nonwoven production by web-bonding processes
1.8 Worldwide Nonwoven Consumption in Leading Application
areas
1.9 World consumption of raw materials
1.10 Types of bi-component fibers
2.1 Classification of nonwoven based on web formation techniques
2.2 Dry-laid manufacturing process
2.3 Typical Blowroom line for processing of nonwoven
2.4 Schematic representation of a Bale breaker
2.5 Arrangement of beaters in Cleanomat
2.6 Multimixer blending machine
2.7 Tuft blender
2.8 Continuous dosing system
2.9 Storage trunk
2.10 Contifeed feeding system
2.11 Universal Roller Card
2.12 Action of Worker and stripper in card
2.13 Nonwoven Single Card
2.14 Tandem card
xvi Nonwoven: Process, structure, properties and applications
Figure Description
No.
2.15 Double doffer nonwoven card
2.16 Vibrating chute arrangment
2.17 Scan Feed Tuft Feeder
2.18 Micro-Weighing system
2.19 Scanning of feed weight
2.20 Parallel laying process
2.21 Camel back cross-laying process
2.22 Horizontal laying process
2.23 Diagramatic representation of Cross lapping angle
2.24 Struto perpendicular laying process
2.25 Principle of air-lay machine
2.26 Danweb air-laying process
2.27 Rando Opener
2.28 Random Card
2.29 Random Card K12
2.30 Random card K21
2.31 Wet-laid manufacturing process
2.32 Wet-laid nonwoven process
2.33 Pilot wet lay machine
2.34 Spunbonding process
2.35 Spunbonding process with a belt collector
2.36 Meltblown web formation process
2.37 Die design for meltblowing process
2.38 Web formation process
2.39 Schematic diagram of Meltblowing Process
3.1 Classification of bonding techniques used in nonwoven bonding
process
3.2 The basic principle of Needle punching process
3.3 Needle punching line
List of figures xvii
Figure Description
No.
3.4 Process flow in Needle punching
3.5 Needle Punching Technology
3.6 Needle punching needle barb structure
3.7 Structure of a felting needle
3.8 Structure of structuring needle
3.9 Conical needle
3.10 Stitch bonding process
3.11 The basic types of stitch structures
3.12 Stitch-bonding point and loop-formation cycle of Maliwatt
stitch-bonding machine
3.13 Steps in Stitch formation
3.14 Maliwatt stitch formation process and stitched nonwoven sample
3.15 Malivlies stitch formation process and the stitched fabric
3.16 Malimo stitch formation process
3.17 Malipol stitch formation
3.18 Voltex stitch formation process
3.19 Principle of hydro entanglement process
3.20 Working of hydro entanglement process
3.21 Hydroentangling Equipment and spunlace fabric
3.22 Chemical bonding of Nonwoven
3.23 Saturation bonding process
3.24 Foam bonding process
3.25 Spray bonding method for nonwovens
3.26 Print bonding technique for nonwoven
3.27 Powder adhesive sprinkling method
3.28 Types of calendar roller
3.29 Point bonding rollers
3.30 Embossing calendaring
3.31 Belt calendaring process
3.32 Through-air bonding with horizontal belt
3.33 Through-air bonding with rotary drum
xviii Nonwoven: Process, structure, properties and applications
Figure Description
No.
3.34 Ultrasonic bonding process
3.35 Infra-red bonding machine
4.1 Classification of Nonwoven finishing methods
4.2 Process of Nonwoven Compacting
4.3 Mechanism of Creping of nonwoven
4.4 Shearing process working mechanism
4.5 Raising rollers
4.6 Raising (napping) machine
4.7 Raising the face of the fabric
4.8 Line diagram of rotary-cylinder singeing machine
4.9 Principle of gas singeing
4.10 Line diagram of gas singeing machine
4.11 Rotogravure coating
4.12 Rotary screen coating
4.13 Spray coating
4.14 Wet or Cold laminating
4.15 Dry or Hot Laminating
5.1 Measurement of fiber orientation and orientation angle
5.2 Schematic diagram of GATS tester
5.3 Contact angle on different materials
5.4 Schematic diagram of contact angle
6.1 Nonwoven consumption of different product groups
6.2 Application of nonwovens in technical textiles
6.3 Market share of nonwovens in different application areas
6.4 Fashion apparel produced from nonwoven fabrics
6.5 Nonwoven frost covering fabric
6.6 Nonwoven mulching fabric
6.7 Nonwoven blanket fabric
6.8 Various functions of geotextile fabrics
List of figures xix
Figure Description
No.
6.9 Nonwoven in medical textiles
6.10 Application of nonwoven in a car
6.11 Global nonwoven filter market
7.1 Sandwich web-laying using multi card
7.2 Single stage multi-layered nonwoven using divider in card line
7.3 Multi-forming air-laid process
7.4 Three-layer headbox in wet-laid
7.5 Modified headbox system for improving the integrity of layered
nonwoven
7.6 Spunbond-spunbond-spunbond production process and fabric
7.7 SMS production process of Zimmer AG
7.8 SMS production process from same spinning line
7.9 SEM image of SMS nonwoven structure
7.10 CoForm® layered composite nonwoven process
7.11 Hydroknit® integrated spunbond-spunlace process
7.12 Evolon® spunlace process
7.13 SEM image of micro-fibers of splitted fibers
7.14 Laminated composite nonwoven structure from LDPE
7.15 Flame-lamination process
7.16 Hybrid nonwoven structure with scrim
7.17 VAPORWEB process
7.18 Principle of Electro Bubble Spinning
7.19 Production process of PVA nanofiber overlaid nonwoven
7.20 SEM micrograph of nanofiber overlaid nonwoven
7.21 Basic processes involved in production of nanofiber coated
textiles
7.22 SEM micrographs of nylon 6,6 electrospun fibers thermally
bonded onto viscose nonwoven
7.23 Particulates incorporated within the base substrate
xx Nonwoven: Process, structure, properties and applications
Figure Description
No.
7.24 SEM images of bonded particles between two nonwoven
structures
7.25 SEM photograph showing functional particles bonded to
bicomponent fibers
7.26 Decontamination three-layered wipe
7.27 SEM micrograph of three-layered composite nonwoven
7.28 Process sequence of production of pile-composite structure
7.29 Construction of composite nonwoven structure
7.30 3D Napco structure
7.31 3D Napco structure with PCM granules
8.1 Natural fiber classification
8.2 Oil sorption capacities of various natural fibers
List of table
Table No Description
1.1 Definitions of nonwovens
1.2 Worldwide Nonwovens Production by region
1.3 Worldwide Nonwovens Production in quantity
1.4 Properties of nonwoven fabrics
1.5 Fibers used in Nonwoven industry
1.6 Special types of binders and their application
1.7 Properties and application of nonwoven based on web formation
methods
1.8 Properties and application of nonwoven based on web bonding
methods
2.1 Wire point density for various parts of card (PPSI)
2.2 Card Width and Production rates
2.3 Relative merits of cross laying and parallel laying process
2.4 Merits and Limitations of Card Cross-lapping and Air laying
process
2.5 Relative merits of filament bonded and staple fiber bonded
Nonwovens
2.6 Comparison of Spunbond and meltblown fabrics
2.7 Comparison of Web Formation techniques
3.1 Different types of stitch bonding process
3.2 Application of thermobonded nonwovens
3.3 Comparison of different Web Bonding techniques
5.1 Standards for measurement of fiber properties
5.2 Various category of testing of various characteristics of
nonwoven products
5.3 ASTM Standards for testing of nonwoven
5.4 Standard conditions for measurement of nonwoven thickness
xxii Nonwoven: Process, structure, properties and applications
Table No Description
5.5 Common testing parameters and standards for nonwoven
application in different areas
6.1 Application fields of nonwoven fabrics
6.2 Application of different types of nonwoven fabrics
6.3 Application of nonwovens and fibers in different fields of
medical textiles
6.4 Application of nonwoven technology in automotive textiles
6.5 Comparison of Nonwoven technologies used in filtration
6.6 Application of different nonwoven products in home textiles
7.1 Composite nonwoven filters
8.1 Comparative properties of flax and other high modulus synthetic
fiber
8.2 Potential end uses of Jute based Nonwovens
8.3 Chemical composition of abaca fiber and natural fibers
8.4 Comparison of physical properties of natural fibers with sisal
fiber
1
Introduction to nonwovens
Figure 1.1 Structure of woven, knitted and nonwoven fabrics [Source: intech.com]
Contd...
Spun laid
nonwovens
1. Spunbond Mechanical Thermal bonding Chemical
2. Metblown Bonding 1. Calendering bonding
1. Needle punch 2. Through air 1. Impregnating
2. Spun laced bonding 2. Foam coating
3. Stitch bonded 3. Sonic bonding 3. Spraying
4. Print bonding
Fiber situated in the Fiber situated perpendicular Mechanically Chemically and thermally
fabric plane to the fabric plane bonded textiles bonded textiles
Table 1.2 Worldwide nonwovens production by region [Source: INDA Estimates &
Rory Holmes, INDA-CAB Conference 2012. www.inda.org]
12 300000
10 250000
8 200000
Tonnes (millions)
6 150200
m2 (millions)
4 100000
2 50000
0 0
2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015
8000
In '000 tonnes
7000
6000
5000
4000
3000
2000
1000
0
2001 2006 2011
4000
3500
3000
2500
In '000 tonnes
Dry-laid
2000
Wet-laid
1500 Polymer-to-web
1000
500
0
2001 2006 2011
1800
1600
1400
1200
In '000 tonnes
800 Spunlace
Thermal/Resin
600
400
200
0
2001 2006 2011
The drylaid process has continually progressed and has established itself
as the primary web forming technique. It is however very varied, especially
in terms of web bonding. In recent years, there has been a remarkable
increase of hydro-entangling, particularly related to the development of
wiping applications (Schoffmann and Schwend 1991; INDA 2007). Airlaid
fabrics using short fibers, which are the latest newcomer, are also making
quick progress. Although the wetlaid sectors have doubled their inputs in that
same time span, this appears to be insignificant when compared to the other
10 Nonwoven: Process, structure, properties and applications
Others
13%
Hygiene
26%
Construction
13%
Other
Medical
industrials
5%
4%
Wipes
Automotive
12%
6%
HF&B
Filtration 9%
7% Apparel
5%
From Figure 1.8, it is clear that the hygiene sector plays a vital role
in consumption of nonwovens. Nonwovens are widely employed in the
development of incontinence products and also in the baby care sector like
cover stocking, leg cuffs, tapes, acquisition/distribution layer, textile back
sheets, etc. Unfortunately, the oligopolistic market condition in the hygiene
sector has caused the nonwovens manufacturers to reap lower profits in this
sector (EDANA 2014). Another sector, which took off recently, is the wipes
sector, be it for personal, industrial or household applications. The geotextiles
and roofing applications have trebled in 15 years time.
1.6.1 Fibers
Nonwoven structures are fundamentally composed of fibers. Consequently,
the utility properties and performance of a nonwoven is dependent on the
fibers used to a significant extent. A fiber may be defined as any natural
or manmade substance, characterized by a high ratio of length to width,
12 Nonwoven: Process, structure, properties and applications
Figure 1.9 World consumption of raw materials [Source: ANFA, EDANA, INDA]
Wood pulp is the only natural fiber to be used in large quantities in the
nonwoven industry. Wood pulp is characterized by high water absorbency,
bulk and low cost which makes it preferable despite of being far shorter in
length than the traditional fibers. Cotton fibers facilitate easy fabrication into
nonwovens owing to their excellent inherent properties. The disposables
and sanitary products sector extensively makes use of viscose rayon fibers.
Rayon fibers can be effectively processed into webs and easily bonded into
nonwovens fabrics (Hansen 1993). The fibers like cotton, rayon and acetate,
being composed of cellulose, are moisture absorbent in nature. This moisture
absorbing tendency makes them act as carriers for microbes, thereby providing
them strength along with biodegradability.
Viscose rayon was a prominently used in the nonwovens manufacturing
until 1985. Over the years, the US and Western Europe have gradually cut down
the production of viscose rayon due to higher costs of the fiber. The reduction
in the costs of PP and PET in comparison with viscose rayon, (especially there
was big drop in 1989) and the inherent superior tensile properties of these
fibers forced the slow decline of shipment of viscose rayon fibers. Due to
the cleanliness and absorptive properties of viscose rayon fibers, nonwovens
manufactured from these are mainly utilized in medical/surgical/sanitary
sectors and in wet wipes (Lee and Cassill 2006). Likewise, the tampon and
incontinence products make use of cotton fibers. The utilization of cotton
fibers has stabilized at 40–45 million pounds.
Polypropylene (PP) is the most widely used man-made fiber. PP fibers
are well-known for their hydrophobicity, voluminous and thermoplastic
nature. PP is cheap and possesses good rheological characteristics to form
fine fibers. Polyethylene terephthalate (PET) is used in nonwovens requiring
tensile strength and mechanical properties to a greater extent. Nylon fibers are
utilized in nonwovens owing to their excellent resiliency properties (Albrecht
2003). Being more expensive than most of the other fibers, nylon is less used.
14 Nonwoven: Process, structure, properties and applications
The other “special fibers” listed in Table 1.1 have only a limited market share,
probably no more than 15 percent of the whole nonwovens market.
Bi-component fibers, fibers containing dissimilar polymers in the core
and sheath find extensive applications in thermally bonded nonwovens. The
segmented pie and islands in sea structures are recent developments in bi-
component fiber structures. The nature of the product being manufactured and
the fabrication process being used determines the properties required by the
constituent fibers. Considering that each manufacturing process produces a
range of fabrics with distinct properties, all the fibers cannot be used in equal
volumes in all nonwoven processes.
In spite of the availability of a large number of fibers, few fibers namely,
the polyolefins, polyester, and rayon dominate the commercially important
nonwoven fabrics. These three fibers constitute a major share of the nonwovens
market. The olefin-based fibers are gaining constantly importance, replacing
the natural fibers, viscose rayon and polyester in many applications. This shift
in fiber consumption can be regarded as the effect of increased use of olefin-
based nonwovens in absorbent products around the world.
The reasons for high consumption of PP in nonwoven sector are due to
the following properties:
• Low density enabling lightweight fabrics to be made
• Low glass transition and melting temperature, economical for thermal
bonding
• Inherent hydrophobicity
• Good bulk and cover
• Chemical stability
• Resistance to mildew, perspiration
• Stain and soil release
• Good mechanical strength and abrasion resistance
The two unconventional fibers emerging in nonwoven applications
namely, bicomponent fibers and nanofibers are discussed in detail below.
properties and can be designed to suit many new applications. The properties
of the individual components, the choice of combination of the different
polymers, additives and the shape of the bicomponent fiber are the major
factors influencing the resultant properties and possible applications of the
bicomponent fibers.
(a) Concentric sheath/core (b) Eccentric sheath/core (c) Side-by-side (d) Pie Wedge (e) Island/Sea
Figure 1.10 Types of bi-component fibers [Source: www.centexbel.be]
Properties of nanofibers
Nanofibers are characterized by special properties chiefly due to extremely
high surface to weight ratio compared to conventional nonwovens. Nanofiber
nonwovens are suitable for specific filtration applications due to its low
density, large surface area to mass, high pore volume, and tight pore size.
Application of nanofibers
Nanofiber webs have higher surface area compared to meltblown webs and
hence have substituted meltblown webs in critical filtration areas. Their highly
porous structure with high surface area makes them ideal for many filtration
applications. These nonwovens are most suitable for filtering submicron
particles from air or water. Some of the applications of nanofiber-based
nonwovens are aerosol filters, facemasks, and protective clothing (Li and Xia
2004). Recently, military fabrics make use of laminated layers of nanofibers
along with carbon fibers to enhance chemical and biological protection.
Nanofibers are also utilized in medical applications like drug and genes
delivery, artificial blood vessels, artificial organs, and medical facemasks. In
this field, carbon fiber hollow nano tubes which are finer than the blood vessels
are widely use. These carbon fiber hollow nano tubes have potential to carry
drugs into the blood cells thus enabling medicines to be directly transferred to
internal tissues (Baumgarten 1971). Companies like Johnson & Johnson and
Genzyme Corporation have developed anti-adhesion materials. Researchers
have developed nanofibers from compounds naturally present in blood for
applications in bandages and sutures which are capable of gradually dissolving
in blood. It has the advantages of reduced infection rates, minimized blood
loss and is capable of disintegrating without causing harm to the body
Layered composite structures are used to meet specific filtration
applications. These filters are composed with multiple meltblown layers
structured using fine to coarse filaments to constitute the bulk. These MB
layers are combined nanofiber webs. The MB layers incorporate fluid
resistance properties and the nanofiber layers provide smoothness for health,
wear and comfort (Doshi and Reneker 1995).
1.6.2 Binders
In fiber bonding, adhesives are usually polymeric in nature and for optimum
performance the adhesive-fiber combination should have most of these
characteristics:
• Polarity – The adhesive and fiber should be of similar polarity. Thus,
polar water soluble animal glue will stick to cellulose as both are
20 Nonwoven: Process, structure, properties and applications
the techniques alone (Young 1996). Also, most binder systems are compatible
with pigments and dyes and help in colouration of nonwoven fabrics.
Binders may be classified, by their physical state at the time of
application, into the two broad classifications of dry or wet binders. The
dry systems are made up of thermoplastic fibers or powders. Wet systems
include solutions, of both aqueous and solvent types, as well as polymer
dispersions and emulsions.
Table 1.6 Special types of binders and their application [Source: Mukherjee et al. 1992]
Contd...
Introduction to nonwovens 23
Contd...
S. no Type of binders Applications
10 Butyl-acrylate, styrene copolymer Self cross-linking resin for porous
separator material in batteries
11. Butyl acrylate copolymer Adhesive tape for water proof
fabrics
12. Copolymer of Bu-acrylate, acrylonitrile and Nonwoven material with improved
N-methylol acrylamide ironability
13. Emulsion polymer of acrylic unsaturated Aqueous dispersion type pressure
monomers (homo or copolymer; Tg = 2500K) sensitive adhesives for nonwoven
and aqueous dispersion of polymers prepared by
emulsion polymerization of ethylenic monomers
14. Acrylic acid ester copolymer; blended with 20% Interlining materials with good
SBR emulsion resilience, improved tensile strength
15. Butyl acrylate-vinyl acetate copolymer dispersion Air permeable nonwovens with
shape memory
16. Butyl acrylate, acrylonitrile, N-methylol acrylamide Nonwoven fabric for lining with
copolymer good laundering and dry cleaning
resistance
17. Latex containing acrylic acid-2-ethyl Polyolefin nonwovens with high wet
hexylacrylate-vinyl chloride-vinylidine chloride strength retention
copolymer
18. Carbonized sulfonated styrene-di-vinyl benzene Spun-bonded nonwoven protective
copolymer later o a suitable acrylate fabric having flame resistant and
flexibility
19. Acrylic polymer emulsion blend with ethylene vinyl Stretchable wrinkle fibrous sheet
acetate copolymer
20. Acrylic acid-acrylonitrile copolymer Hygroscopic products for sanitary
goods and sealing materials
21. Acrylic resin modified with chlorohexidine Antibacterial electric fiber webs
for filters and wipers are prepared
using the binder
22. Emulsion polymer of acrylic acid ester, M.F. resin, Laminated pattern paper for textile
organic amine printing
23. Acrylic polymer emulsion (Tg – 80–0°C) Two ply nonwoven fabric laminate
24. Cross-linkable polyacrylates impregnated with Non-blocking, non cross-linking
binder containing 10% silicone dispersion adhesively bonded fleeces
25. Vinyl chloride emulsion blended with small High loft polyester nonwovens.
amount of aminoplast Good flame resistance better
wash and dry-cleaning resistance,
resilience and compression
recovery
26. Ethylene-vinyl chloride copolymer Laminates of nonwoven fabric
with wood composite base for rear
package automobile interiors
27. Polyvinyl chloride emulsion Antistatic finish for textile and carpet
backings
28. Vinyl chloride-vinylidine chloride- copolymer or Chemical resistant fabrics for
Ethylene vinyl acetate copolymer protective garments
Contd...
24 Nonwoven: Process, structure, properties and applications
Contd...
Contd...
Contd...
1.6.3 Additives
Many materials apart from the constituent fibers are used in the manufacture,
bonding and finishing of nonwoven webs. Some additive materials form an
integral part of the nonwoven and added to the fiber or filament structure during
web laying. Examples of such additives are thermally active powders and
absorbents. But many of the additives are applied in one form or another to the
preformed web usually after bonding and are treated as an auxiliary process.
Table 1.7 Properties and application of nonwoven based on web formation methods
Contd...
Contd...
Introduction to nonwovens 29
Contd...
Table 1.8 Properties and application of nonwoven based on web bonding methods
Contd...
Chemical Bonding
Chemical - • Acrylics • Impregnation • Web saturated • Loss of • Roofing
latex •S
tyrene/ • Spray with binder porosity and polyester and
butadiene – maximum absorbency glass
• Foam
strength • Stiffness • Flooring
•E
thyl vinyl • Print bond
acetate • Useful for high • High drying • Batts
• Precipitation loft webs
•N
itriles energy • Highloft
(wetlaid only)
• Economical requirement nonwovens
•E
lastomers
Surface only • Good • Short fiber
•P
VC
effect housekeep- airlaid
• Much lower ing essential
• Battery
energy to avoid
separators
required contamina-
tion • Medical
• Penetrates
• Modern • Wall coverings
web without
blocking strength • Ceiling tiles
• Bonded area • Loose • Flooring
controlled by fibers in substrates
print pattern non-bonded • Wipes
areas
• Absorbency • Medical
maintained • Can be
difficult to • Gaskets
• Incorporation • Book covers
control
of colours and
other chemical • Loose • Ceramics
treatments surface fibers • Battery
• Deposits separators
binder in web
formation
stage
• Good strength
per unit of
binder
Chemical - •H
ydrated • Wet • High • Stiffness • High
inorganic aluminium deposition temperature • Low (but temperature
hydroxide binders adequate) insulation
•H
ydrated strength
silicic acid
Chemical - •U
ses the • High intensity • No added • Bonding only • Feminine
hydrogen ability of heated binder at densified hygiene
cellulose to calender points • Food contact
form hydrogen absorbents
bonds when
water is
present
Contd...
Introduction to nonwovens 31
Contd...
References
1. ASTM (1989). Annual Book of Standards. ASTM Standards.
2. Batra SK, Hersh SP, Barker RL, Buchanan DR, Gupta BS, George TW, Mohamed
MH (1989). A New System for Classifying Nonwovens. Eds Turbak AE, Vigo TL,
Nonwovens – An Advanced Tutorial. TAPPI Press.
32 Nonwoven: Process, structure, properties and applications
Abstract: This chapter discusses about the various methods of web formation
such as dry laid, wet laid and spun laid for nonwoven production. The details of
raw material requirements, working mechanism and characteristics of dry laid
and wet laid process have also been provided. The fibre preparation methods,
card and various kinds of web stacking process such as parallel lay, cross lay,
perpendicular lay and random lay have been discussed in detail. The raw material
requirements and product characteristics of polymer-laid processes such as spun-
bond and melt-blown are discussed in detail.
Key words: batt, dry lay, wet lay, air lay, spunbond, melt blown
2.1 Introduction
Nonwoven manufacturing is basically a continuous process in which the web
laying and web bonding are performed by two consecutive machines. A web is
nothing but a thin layer of fiber distribution. In the web laying process, several
webs are laid on top of each other to form a batt, which is taken directly to
bonding. Nonwoven can be classified based on web formation techniques as
shown in Figure 2.1.
1. Spunbond
1. Dry Laid 2. Meltblown
• Carding
• Aerodynamic (Air lay)
• Centrifugal dynamic
(Random carding)
2. Wet laid
Wet and dry laid technologies are the main methods of batt formation.
Alternative methods of batt formation like the spunbonding and meltblown
technologies were developed later. The contributions of each web laying
technology to the entire nonwovens market are: Wet laid nonwovens – 16.0%;
dry laid nonwovens – 44%; air-laid – 3%; spunbonding and meltblown about
– 37% (Russel 1997, Balasubramanian 2009). Versatility, process flexibility
and ability to produce wide range of products make the dry lay systems more
popular. The wet lay technology has been adapted from the paper-making
industry, which processes very short fibers into highly even web structures
with good flow through properties.
The polymer-based web forming system is based on the polymer
extrusion technology. This system is similar to the synthetic filament and
yarn manufacturing process. It has two major subdivisions: the spunbonding
process and the meltblown process. In the spunbond process, the polymer
chips are converted into a molten form and forced through the small holes
in the spinneret (Balasubramanian 2004). The web structure is formed
by collecting and condensing the extruded individual filaments from the
spinneret on a forming apron. The second system is the meltblown process.
The molten polymer being extruded at the spinneret is subjected to hot,
rapidly moving air at the extrusion point. This causes the extruded filament
to be blown into very fine fibers of variable length which are received on the
collecting surface.
opening and blending stages before carding and the card should be capable of
achieving higher level of opening.
Raw material
(Natural fibers, man-made fibers, inorganic fibers)
Preparation
(Opening to loose material, blending)
Web forming
1. Carding process (Parallel laid, cross laid)
2. Aerodynamic process (Random laid web)
The nonwoven lines can utilize either the short-staple revolving flat cards
or long-staple roller cards on a theoretical basis. The short-staple revolving
cards have certain advantages like higher production rates and higher opening
power (especially in terms of per unit of floor space occupied). The major
drawback pertaining to short-staple cards is their very narrow operating
widths. This drawback is overcome by the long-staple cards which are many
times wider, making them much more suitable for nonwoven manufacture.
Since many end applications require wider width nonwovens, the long staple
cards are highly preferred in most cases (Russel 1997). A typical nonwoven
Web formation 37
openers, the tearing machines or the small openers serve the purpose. Fibers
of staple length up to 100 mm can be sufficiently opened by the small openers.
For opening of polyester fibers, the single roll openers are more suitable.
Whereas cotton or viscose rayon fibers have more entangled tufts and require
multi-roller openers (Rupp 2012).
(1) Bale openers
The nonwoven industry incorporates a fiber preparation process which is very
similar to the process carried out in a conventional blowroom line. Figure 2.4
illustrates a bale opening machine. Several bales can be arranged on either
side of the wide bale opening machine according to the requirement. The
arranged bales may be composed of the same fiber or a combination of several
fibers to obtain the required blend. The bale opener opens the fibers from these
bales and mixes them to a certain extent (Rakshit et al. 1989).
bale opener are transported over the feed lattice (1) and then to the pressure
rolls (2). The two feed rolls (3) uniformly transport the fibers to the needle
roll or fully spiked roll (4). The fully spike roll then transfers the fibers to the
coarse or medium saw-tooth roll (5), which is followed by the fine saw-tooth
roll (6). The exhaust unit (7) transports the cleaned fibers to the next machine.
basic properties like length, fineness, strength, colour and maturity. Impurities
of various kinds are also present in the baled cotton. Every production line
aims to produce nonwovens with high levels of uniformity and maximum
efficiency (Balasubramanian 1991). To achieve this, homogeneous and
consistent blending must be ensured. The price of cotton fibers also influences
the composition of the raw materials. Every quality of nonwovens has a
corresponding market value. Whenever some lower quality fibers are used
for reducing the manufacturing costs and enable, these fibers require careful
handling and blending to avoid processing problems.
The quality of blending is a crucial parameter influencing the web
characteristics. The blended fibers should have consistent proportion in all
instances to minimise product variations as the properties of a nonwoven
fabric are fundamentally the function of the blend composition. Inefficient
blending leads to various in process as well as quality oriented problems. An
example of a type of blending machine, the multimixer from Trutzschler is
shown in Figure 2.6. The multimixer is designed with a series of individual
silos into which fiber is alternately fed.
The fibers enter through the connection for material feed (1) and fill
the trunks (2) by means of an external fan. The next machine in the line
is mechanically coupled with the conveyor belt of the feed lattice (10).
Depending on the material requirement by the subsequent machine, the fibers
are drawn out of the trunks by the delivery rolls (6) and the continuously
running opening rolls (7). These drawn out fibers are thrown onto the conveyor
belt (8). The feed lattice (10) and the pressure apron (9) receive the fibers
42 Nonwoven: Process, structure, properties and applications
from the conveyor belt. The feed lattice transfers the fibers to the subsequent
machine. For trouble-free running, any accumulations of impurities are
continuously extracted via the waste tray (11) and are fed into the pipeline for
dust exhaust (12). During running, a least one trunk remains unobstructed and
receives fibers from the previous machine. The trunks are filled in sequence
until the set pressure is reached. In the instance of all top light barriers (4)
being obstructed when the flaps (3) are switched to the next trunk, the material
feed will turned off. To sustain the corresponding pressure on the fibers in the
trunks, the material transport fan is always kept in operation. When the mixer
is full, the flaps of the trunks (3) continue switching in a one minute cycle to
avoid turbulence disturbing the material in one of the trunks. As soon as one
of the upper light barriers (4) becomes free again, new fibers will be fed into
that trunk.
(4) Tuft blender (Dosing system)
The tuft blending installations as in Figure 2.7 provide flexibility in the
manufacturing process – 2 to 6 different types of fibers can be blended to
cover a wide application range including even the addition of smallest portions
(e.g. 1% black fibers / 99% white fibers). The blends can be reproduced
with consistent high-end quality. The continuous dosing system for accurate
blending of fibers is shown in Figure 2.8. The most widely-used dosing
systems are:
1. Weighing pan system
2. Roller weighing system
3. Scanfeed system
• Fiber lubrication and spray systems: In most cases, the manmade fiber
manufacturers provide fibers applied with spin finish oil, and fiber
lubrication during processing is not required. However, to improve
blending some liquids can be added. As a general practise, lubricants are
added while processing natural fibers and anti-static agent are included
for synthetic fibers. In some cases, the water alone is added to facilitate
efficient processing. Spray systems accurately dose and apply the
required additives directly onto the fiber. Water can also be added using
an atomiser which sprays a fine mist prior to carding.
• Buffer zones: Buffer zones providing interim storage are essential to
ensure continuous material flow through the machine. These are usually in
the form of silos with delivery rolls at the base (Figure 2.9). Such storage
devices can be used within the blending machines and also between
blending and carding machines for supplying the materials continuously.
2.2.2.2 Card
The fibers after opening and cleaning are supplied to the carding machine.
The carding process aims at separation of small tufts into individual fibers and
parallelization of fibers and to produce uniform webs. The major functions of
the carding process are:
• Individualization of fiber tufts to almost single fiber
• Mixing of fibers to average out variations in fiber characteristics
• Forming a homogenous web of uniform weight per unit area
Roller and clearer type cards are widely used in the nonwoven industry.
The parallel laying process alone utilizes revolving flat cards. In contrast
to the revolving flat card, the roller card consists of a larger main cylinder,
ranging from 2.5 to over 5 meters in width. Spirals of sharp pointed and fine
gauge wire are used to cover the cylinder. A chute feeds the fibers from the
blending machine to the card. The primary function of the chute is to convert
the loose fiber into a compact mat of consistent density and to continuously
feed this mat to the card. The wire points on the main cylinder collect the
fibers from the feed rollers. Usually the main cylinder follows a breast roller.
The tandem type card with breaker and finisher cylinders can also be found
in the nonwoven industry. Figure 2.11 illustrates a roller top card. This card
is quite identical to the revolving flat card in its basic features with major
differences in the design of the main carding fields region.
Above the main cylinder are pairs of smaller wire covered rolls. The
largest of the pair is called the worker roll. The worker roll collects fiber from
the main cylinder. This process straightens the fiber and aligns it somewhat in
the machine direction. This action also creates some blending of the fibers
46 Nonwoven: Process, structure, properties and applications
which is a distinct advantage of the roller type card. The smaller roll behind
the worker roll is called the stripper roll. It is designed to take the fiber from
the worker roll and transfer it back onto the main cylinder where it is passed
forward to the next set of rolls. The action of worker and stripper against the
main cylinder is shown in Figure 2.12.
In front of the main cylinder, one or two additional wire covered rolls,
called doffer rolls, are positioned to remove a certain percentage of fiber
Web formation 47
from the main cylinder. The diameters of the doffer rolls are smaller than the
diameter of the main cylinder. As the fibers are deposited onto the doffer roll
from the main cylinder, a condensing action occurs. This condensing action
creates some fiber to fiber cohesion which is needed to hold the web structure
together as the web is transferred from the doffer roll. The use of more than
one doffer roll allows for faster removal of fiber from the main cylinder and,
therefore, more pounds per hour delivered.
The wire points on the worker roller oppose the wire points on the cylinder
to establish a point-to-point relationship. As the cylinder rotates, it conveys
the fibers towards the worker. When the fiber passes below the worker teeth,
some of the fibers are trapped on the worker teeth owing to the lower surface
speed of the worker. The fiber tufts which are partly trapped on the worker
and also trapped on the cylinder undergo a separation or carding action. The
fibers trapped by the worker are carried around as the roller rotates. The
stripper removes the fibers from the worker and re-presents them back onto
the cylinder. On the whole, the ‘working’ action occurs initially between the
worker and the cylinder followed by the stripping action takes place between
the stripper and the worker (Russel 1997). This series of actions represent
the fundamental operational function of a carding machine. Hence, the fibers
are progressively ‘worked’ and ‘stripped’ within a carding machine for
individualisation and parallelisation of fibers to produce a homogeneous web.
The striking difference between the nonwoven card and roller and clearer
card is the presence of a randomising roller between cylinder and doffer. The
preferential longitudinal orientation of fibers in the web is altered to a more
random orientation by the action of the randomising cylinder. Randomising
roller rotates is shown in Figure 2.13.
The randomising cylinder is made to rotate in a direction opposite to that
of the main cylinder. The wires on this roller are wound in inclined angle
48 Nonwoven: Process, structure, properties and applications
Batt uniformity
The critical parameter influencing the appearance, strength and all other
properties of nonwovens is the weight uniformity of batt produced. A
typical nonwoven is expected to have weight uniformity of ±2.5%. The batt
uniformity is directly controlled by the uniformity of the web from the card
50 Nonwoven: Process, structure, properties and applications
1 – Spring loaded sectional flap; 2 – Feed roller; 3 – Opeing roller; 4 – Feed trunk;
5 – Web thickness adjustment; 6 – Delivery roller; 7 – Spring loaded sectional measuring tray;
8 – Conveyor belt; 9 – Card feed roller; 10 – Licker-in
Figure 2.17 Scan Feed Tuft Feeder (Source: www.nptel.ac.in)
The tufts from opening roller section are drawn by a fan into an upper
trunk. The filling height is maintained constant by pneumatic pressure
controlled by combs covering air inlet. Feed roller at the lower end of trunk
feeds the material through a spring weighted feed plate to an opening roller.
Opened tufts are fed to lower trunk. The fibers are blown by air into lower
trunk and as air takes line of least resistance, uniformity across the width is
maintained. The fiber mass in lower trunk is pneumatically compressed and
the sheet is fed to a feed roller through a spring weighted segment. Material
thickness is automatically adjusted by the spring pressure on the segments
of feed plate. An optimal supplement is the web profile unit which improves
uniformity both in longitudinal and cross directions. Selective web profile
across the width can also be obtained with web profile unit (Rakshit et al.
1989).
Micro-weighing system
The micro weigh system, developed by Heigh chandwick and Temafa,
is designed to reduce variations in feed sheet to card (Figure 2.18). The
microprocessor controls the entire system comprising of a sensitive weigh
pan provided with pneumatically activated shutters solenoids, which inturn is
52 Nonwoven: Process, structure, properties and applications
mounted on transducers. The small tufts are capable of being dropped into the
pan with an accuracy level of ±2 g. The actual weight of the pan is constantly
compared with the required mass and when the required weight is attained,
the microprocessor opens the weigh pan to drop the material into the chute
feed. Hence this configuration reduces the batch to batch variation to as low
as ±1%.
Micro weighing
Soilnoid pans
Autoleveller
The following type of autolevelling (Figure 2.19) is commonly used in the
industry.
• The feed sheet to the card is passed over the balance and the thickness
is monitored by a sensitive load beam transducer. The force acting
on the beam generates a corresponding signal to control the speed of
feed rollers.
Web formation 53
In the NSC Nonwovens line, the batt fed to the card is continually
monitored by 4 weighing gauges and front roller speed is altered in
accordance to the measured weight. An alternative system measures the batt
density with reference to a constant thickness and changes feed roller speed.
Spinbau controls the feed roller speed based on the weight of the batt which is
measured by an electronic belt weigher (Balasubramanian 2009).
Web monitor
The web from the card is passed through the WIRA Web monitor, which
consists of a pair of rolers. The small top roller acts as the measuring roller
i.e., the thickness variation in the web is assessed by the vertical movement of
top roller coupled with a transducer. The deviation from the set value is used
to adjust the speed of feed roller.
Apart from these feeding systems, the basic method of improving the batt
uniformity is to produce finer finer card webs accompanied with proportional
increase in the number of doublings in crosslapper.
Card clothing
The nonwoven roller and clearer cards are generally installed with Garnett
type interlocking wire. In the case of wire damage, it is sufficient to rework
the damaged strips alone which lowers the maintainance costs. Hence these
interlocking wires are preferred in the industry. Finer fibers require the use of
finer type of wire clothing for cylinder and worker rolls. Wire point density
details are mentioned in Table 2.1. While processing coarser fibers, the wire
54 Nonwoven: Process, structure, properties and applications
height for cylinder, worker and doffer should be higher than that for finer
fibers. For easy transfer of fibers, doffer wire has greater front angle and
height than that of the cylinder and random roller wires (Crook 1993).
Table 2.1 Wire point density for various parts of card (PPSI) (Balasubramanian 2009)
Dust removal
The carding room can be made dust free by setting up securely sealed air
cleaning dust removal systems. The mordern cards do no not require frequent
cleaning as in the traditional cards.
Production rates
The production rates of different cards utilized in the nonwoven industry has
been analyzed in Table 2.2.
Contd...
Web formation 55
Contd...
is very low since there are very few fibers in this direction. The strength in
the machine direction is substantially greater than in the cross direction,
the strength ratio may be about 10:1. Such nonwovens find applications in
different end-uses such as tapes, interlinings, cable winding, filtration, etc.
laying speed to draw off speed. The cross-lay process performs the following
functions:
• To produce batts with higher weight per unit area than that of the card
web
• To produce batts with higher width than that of the card web
• To obtain preferentially orientation of fibers in the transverse direction
• To obtain batt with a layered structure
The cross-laying process can be done in two methods namely, camel back
laying and horizontal laying. Figure 2.21 illustratres the camel back laying
process. In camel back laying, the web coming out of the card is carried
upwards to a pivot point by means of a conveyor. The lower conveyor system
is designed to reciprocate from the pivot point in order to lay the web onto a
cross conveyor below this arrangement. The machine height and the machine
throughput are the important factors influencing the width of the batt.
layering speed in the middle region of the batt. The basic factors influencing
the laying speed are:
• web characteristic (fiber orientation)
• fiber type (synthetic fibers, viscose fibers, natural fibers)
• fiber dimensions (fineness and length)
• fiber elasticity (crimp)
• web mass
• spin finish and ambient conditions (temperature and relative humidity)
The important aspect in cross lapping is the lapping angle and number of
layers (Figure 2.23), which are given by the formula:
vmb
α = tan–1
vcl
vcl
N =
vmb
Where
Α – Lapping angle with respect to cross-machine direction
vcl – Linear speed of the cross-lapper (m/min)
vmb – Linear speed of the moving belt in the machine direction (m/min)
N – Number of layers
Web formation 61
CD
B
α
vcl
A vmb C MD
Table 2.3 Relative merits of cross laying and parallel laying process
1 – Carded web; 2 – Struto product; 3 – Forming comb; 4 – Pressure bar; 5 – Grid; 6 – Cover
plate; 7 – Conveyor belt
Figure 2.24 Struto perpendicular laying process
Web formation 63
The fiber webs are formed by drums in some air-lay systems. An example
for this system is the as Dan web system (Denmark). This system has been
illustrated in Figure 2.26. It consists of two perforated drums connected to
fixed pipes and rotating in opposte directions located transversely above
forming wire. A rotating brush roll is arranged transversely to the conveyor
belt inside the drums. It directs the fibers from the airstream and onto the
perforated drums (Adanur 1995). A vacuum located below the forming head
forms the web on the wire. This system can process fibers upto 15 mm in
length and reduces fiber accumulation inside the system. A highly uniform
distribution of fibers across the web can be achieved.
Machines used for air laying:
The two commonly used air-laying systems are
• Rando Opener
• Random Cards
Rando Opener
Rando Opener system was introduced by the Rando Machine Corporation.
A blowroom line opens the fibers. A hopper feeder and feed plate transports
the opened fibers to a saw tooth opening roller. The teeth of opening roller
carry the fibers almost individually. An air stream deposits the fibers on a
perforated lattice moving slowly for forming the batt (Figure 2.27). At the exit
of the opening roller, air is blown through a narrow duct by a powerful fan
arrangement. A suction system is provided underneath the perforated lattice.
This causes the fibers to randomly deposit on the lattice (Jakob 1989).
1 – Perforated lattice with suction; 2 – Opening roller; 3 – Feed roller; 4 – Blower fan
Figure 2.27 Rando Opener (Balasubramanian 2009)
66 Nonwoven: Process, structure, properties and applications
The batt produced by the rando opener is isotropic in nature. This random
orientation of fibers significantly improves the insulation properties and
bulkiness of the batt. These batts are widely used for wadding, high lofts
used in winter clothing. Additionally, sound insulation material, absorbent
pads, wipes and hygiene products are manufactured using this system. In the
Schirp system, a similar principle is employed. A perforated drum connected
to a special air system forms the batt by laying down the webs. The drum
is provided with a pin or saw tooth wire profile (Desai & Balasubramanian
1990). Batts ranging from 100 to 200 gsm can be produced using this system
with production rates up to 14 m/min.
Random Card
The random card was introduced by Fehrer. This card is based on aerodynamic
principles. In this card, small carding cylinders along with worker and stripper
rollers are arranged sequentially. The first card delivers some portion of the
fibers into a duct while the remaining fibers are transferred to the next card.
Individual ducts provided in each card carry the delivered fibers and deposit
on a common perforated surface and the fiber layers are taken forward by a
conveyor belt (Figure 2.28).
One over another deposition of fiber layers from the individual ducts on
the conveyor, results in excellent doubling and randomisation of fibers. This
significantly improves the batt uniformity. The working width of these cards
ranges from 1 m to 2.5 m. The technologically advanced batt forming line
from Fehrer utilizes a prior machine called pre web former V21/R decreases
the tuft size using opening roller arrangement to form batts with 300–500
gsm (Singh 2007). The output of the pre-web forming machine is fed to the
Random card K12 (Figure 2.29) comprising of a cylinder fitted with a pair
of workers and strippers. A transversal blower carries fibers delivered by the
card to a perforated conveyor lattice. Suction systems are provided in the
high loft device at the delivery section to increase the batt height and volume
(Chapman 2010). ‘High Loft’ material suitable for insulating applications can
be produced in this system. This “high loft” device is optional.
Web formation 67
(a)
1 – Deliver conveyor; 2 – K12 card; 3 – Pre-web former; 4 – Weighing belt; 5 – Worker and
stripper; 6 – Transversal blower; 7 – High loft device
(b)
Figure 2.29 Random Card K12 (www.nptel.ac.in)
deposit the fibers in four different positions of the conveyor belt and hence
thorough doubling is required in the collection zone to minimize the localised
variations. Unlike the K12, the K21 card has a closed web forming system
(Lin & Tsai 2001). Synthetic and viscose rayon fibes of fineness ranging from
1.7 to 3.3 dtex can be processed with a throughput rates of 300 kg/h.
Table 2.4 Merits and Limitations of Card Cross-lapping and Air laying process
Contd...
• The process is not very suitable for very fine, long or highly crimped
fibers.
• The air flotation tends to separate fibers of different deniers or
densities.
• In general, such plants are not very flexible to raw material changes.
• Pneumatic laying machines generate more noise.
• It is not possible to produce such nonwovens in large widths, at least
not as wide as crosslapped battings.
For the above-mentioned reasons, these machines are less popular as
compared to roller cards and are used mainly for processing high denier and
waste fibers or in those cases where random webs are required (Lin & Tsai
2001).
Applications of air-laid nonwoven products
Based on the choice of fibers and the bonding methods, air-laid nonwovens
are utilized in numerous applications. Some of the application are high-loft
products for the clothing and furniture industry, wadding, medical and hygiene
fabrics, geotextiles and roofing felts, filters, insulation and barrier materials,
wall and floor coverings, moulded products, wipes, preformed automotive
components, absorbent cores, acquisition and distribution layers, etc.
Raw material
(Short fibers, cellulose)
Preparation
(Blending, manufacturing of fiber-water suspension)
Web forming
(Spreading of suspension into a screen belt)
Figure 2.32 Wet-laid nonwoven process (Source: Glens Falls Interweb. Inc. New York)
2 l
nf = cv
3 d
Where
cv – Volume fraction (ratio of the volume occupied by fibers to the volume
of water)
l – Fiber length and
d – Fiber diameter
The velocity of water in relation to the velocity of wire determines the
structure of the web. When both the velocities are equal then the fiber lay-
down is found to be practically random. When the velocity of wire is higher
than the velocity of water then fibers are found to be preferentially orientated
in the machine direction, but when the velocity of wire is lower than the
velocity of water then fibers are found to be preferentially orientated in the
cross direction.
It is known that the fiber–water dispersion quality primarily dictates the
quality of the wet-laid nonwovens. The important fiber characteristics that
determine this dispersion are fiber length, fiber aspect ratio, and fiber bending
rigidity. The higher fiber length, fiber aspect ratio, and fiber bending rigidity
result in more fabric defects and vice-versa. The wet-laid process involves
suspension of fibers in water and nonwoven is made by draining the water
solution through a forming mesh. At this step, the preponderance of fibers is in
the form of clumps and which has to be split into individual fibers in a mixing
tank by means of shear applied on them by the flow field. To produce uniform
nonwoven structure, fibers must be well dispersed prior to be laid-down; or
else they remain as clumps and appear as defects (log defects) in the final
product. Logs are characterized by bundles of fibers with aligned cut ends that
are not dispersed, which happen mainly due to fiber supply problem or can be
the result of low under agitation of the initial dispersion. Rope formation is
another main concern particularly when fibers with varying degree of stiffness
are mixed. Ropes are characterized by assemblages of fibers, with unaligned
ends, that are clearly more agglomerated than in the general dispersion. They
are formed when fibers are encountered a vortex that facilitates in entangling
the fibers to form ropes. In this case, the more flexible fibers will twist and
wrap around the stiffer fibers.
Web formation 75
(a)
1 – Winder; 2 – Calendar; 3 – Guide roller; 4 – Edge guide; 5 – Forming belt; 6 – Extruder;
7 – Extruder drive; 8 – Compaction roller; 9 – Attenuation; 10 – Quench air; 11 – Spin pack;
12 – Pump; 13 – Filter; 14 – Polymer hopper
(b)
Figure 2.35 Spunbonding process with a belt collector (Source: www.reicofil.com)
For most of regular use products like cover stock for diapers and hygiene
materials, partial orientation is sufficient to provide the required strength.
Partial orientation also permits higher production rates. An air generation
unit is required to achieve partial orientation. The products like geotextiles,
carpet backing, roofing and industrial products require full orientation of the
polymer (Fourné 1992; Smorada 1992). For full orientation, the filaments are
drawn over heated godet rollers, with draw ratio of 1: 3 or 4 followed by
pneumatic acceleration. Following this, the uniformity and cover is improved
by passing the filaments through a pneumatic air gun where high velocity air
is forced through a constricted area of low pressure. Electrostatic charges are
applied to avoid filament entanglement during the drawing process. These
filaments are deposited on a moving conveyor belt in a random and uniform
manner. This batt is then bonded. In both the partial and full orientation, the
lay down can also be done in the cross direction depending on the end use.
The randomisation can be additionally enhanced by using suction systems
underneath the conveyor (Gilmor 1992).
The complex spunbonding process involves many operating variables such
as polymer throughput, polymer and die temperatures, quench environment,
bonding conditions and material variables as polymer type, molecular weight,
molecular weight distribution and many others. All these variables affect
the fiber diameter, fiber structure, web-lay down and physical and tensile
properties of the web (Brenk 2004; Lim 2010). The major performance
characteristics of spunbond fabrics such as strength, chemical and thermal
resistance are controlled by the characteristics of the polymer systems used.
The structure and properties of the final fabric are determined by the polymer
and the processing conditions (Rupp 2012).
• The Production rate of spunbonding machine per metre working
width in kg/hr
m × n × n × 60
PSP =
1000
m = throughput per nozzle (g/min)
n = number of nozzles per metre of spinning width (m–1)
• The mass per unit area of the web created on the perforated belt
PSP
mv =
VT
mv = Mass per unit area of the nonwoven (g/m2)
PSP = kg/h·m
VT = Speed of belt (m/min)
80 Nonwoven: Process, structure, properties and applications
Table 2.5 Relative merits of filament bonded and staple fiber bonded nonwovens
(a)
1 – Winder unit; 2 – Collector; 3 – Blower; 4 – Air compressor; 5 – Resin tank; 6 – Barow
tank; 7 – Resin bag; 8 – Vacuum pump; 9 – Extruder; 10 – Polymer filter; 11 – Gear pump;
12 – Static mixer; 13 – Meltblown die; 14 – Embossing unit
(b)
Figure 2.36 Meltblown web formation process (Source: www.kasen.co.jp)
3. Die assembly
• Feed distribution: It distributes the flow evenly to all the
spinnerets flow and ensures constant residence time across
the width of the die in all instances. The two types of feed
distributions are T-type (tapered and un tapered) and coat
hanger type (widely used due to better balancing of flow and
residence time)
• Die Nosepiece: The web uniformity depends upon the design
of the nosepiece. The spinneret used in spunbonding process
is replaced with the die nosepiece. This nosepiece is typically
a hollow and tapered piece of metal having linear arrangement
of several hundred orifices along its width. The polymer melt
is extruded through these holes and the emerging filaments are
quenched using hot air. The usual dimensions of the nosepiece
include a diameter of 0.4 mm and the number of orifices per
mm ranges from 1 to 4. Figure 2.37 shows the design of the
die.
improper airflow in the air stream. The vacuum under the collector should
be capable of withdrawing the entire air stream through the perforations and
randomly lock the fibers in place (Choi et al. 1988; Wehamann 1992). Usually,
as the distance between the die and the collecting screen decreases, the web
uniformity increases.
Product characteristics
The main characteristics and properties of melt-blown webs are as follows:
1. Random fiber orientation in the web.
2. Lower to moderate web strength, the strength is a result of the
mechanical entanglement and frictional forces.
3. Generally meltblown products have high opacity due to a high cover
factor.
4. Unique method to produce low GSM material.
5. Fiber diameter ranges from 0.5 to 30 m, but typically 2–7 m.
6. Basis weight ranges from 8 to 350 g/m2, but typically 20–200 g/m2.
7. Microfibers provide a high surface area for good insulation and
filtration characteristics.
8. Fibers have a smooth and soft surface texture and are circular in
cross-section.
9. Most melt-blown webs have a layered structure, the number of layers
increases with basis weight.
2.3.2.5 Applications of meltblown nonwoven
• Medical fabrics: Disposable gown, drape market, sterilization, wrap
segment, Sanitary products etc.
• Adsorbents: Sorbents to pick up oil from the surface of water, such as
encountered in an accidental oil etc.
• Filtration media: Filter media, cartridge filters, clean room filters and
others
• Apparel: Thermal insulation, disposable industrial apparel and
substrate for synthetic leather.
• Electronic specialties: Liner fabric in computer floppy disks, battery
separators and as insulation capacitors.
• Miscellaneous applications: Manufacture of tents, elastomeric
nonwoven fabrics etc.
2.3.2.6 Comparison of melt-blown and spunbond process
The spunbond and melt-blown processes are quite identical from machinery
and operator point of view. But the two major differences are:
Web formation 87
• The temperature and volume of the air used to attenuate the filaments
and
• The point of application of filament drawing or attenuation force.
Higher temperatures and higher volumes of air are used for attenuation
in meltblown process. The air temperature is close to the melting temperature
of the polymer. Conversely, the spunbond process generally uses a smaller
volume of air close at ambient temperature to for drawing the filaments
(McCulloch et al. 2003).
A melt-blown process uses large amounts of high-temperature air to
attenuate the filaments. The air temperature is typically as higher than the
temperature of the polymer. In contrast, the spunbond process generally uses
a smaller volume of air close to ambient temperature to apply the attenuation
force (Dhoke 2015).
In the melt-blown process, the attenuation force is applied at the tip of
the nosepiece for forming microfibers. This inhibits the polymer orientation
to build good physical properties. In the spunbond process, the polymer is
subjected to the drawing force after cooling. As a result the polymer is well
oriented but is not suitable to form microfibers. A critical comparison of
spunbond and meltblown process fabrics is given in Table 2.6.
Meltblown Spunbond
Developed 1950s
Opacity Opaque
Color Typically white, can be colored
Finishing Calendar, laminating, point bonding
Pleatable (Y/N) Yes, when heavy enough
Basis weight avg. 20–200 gsm 10–200 gsm
Basis weight range 8–350 gsm 5–800 gsm
Fiber diameter avg. 2–6 μm 15–35 μm
Fiber diameter range 0.5–15 μm 1–50 μm
Fiber length Discontinuous Continuous
Fiber orientation Random Random somewhat aligned
Fiber attenuation typical Strong air, at die exit Less air, away from die
polymers PP, PE, PBT, etc. PP, PET, PBT
Economics Less capital Faster, cheaper production
Binders Self-bonding, binders Chemical binders, needling
optional
2.4 Comparison of different web forming techniques (Table 2.7)
88
The comprehensive comparison of different web formation methods are given in Table 2.7.
Dry-laid Carded Opening, clean- Random with Most fiber types 125 ~ 600; New cards allow disposables Since carding
(Staple ing, removing some MD can be carded; Cards pro- the fiber arrays to for hygiene, begins with staple
Fiber) short fibers; direction- PP and PET duces be randomized; medicals, fibers,
Separation and ality: staple fibers high quality High-quality wipes, or durable one of the benefits
rearrangement most used; webs at products require a products for is the ability to
of fibers by Bicomponents relatively high constant apparel and blend
main cylinders, as binder fibers speeds climate during all shoe interlinings, different fiber
strippers, work- are common for production support types together to
ers, and doffers; thermally bond- stages; Webs for plastics, pack- produce
Converting the ed nonwovens; must be pre- ages, tea bags, a nonwoven.; In
individual fibers Recycled fibers bonded etc.; addition, depend-
into a uniform are also used or bonded just High-loft products ing
fibrous web if length is long after web forming for mattress, upon how many
enough; Very to transport them insulation, high cards
short fibers (pulp filter media, etc. are used, multiple
or fluff) cannot using layers can be
be processed by by new carding made to
carding equipment achieve different
performance
characteristics.
Carded + Somewhat Very low speed Web weight: Diverse applica- Randomize the
cross- random and and output, it at least 80 g/ tions is filters, ap- ODF; Create
lapping sometimes still existing m2 to 1,000 g/ parel, insulation, uniform
bimodal because: It m2 or more; carpets, etc. heavy weight
can be in Web width: webs for needle
continuous 2.5 m to 16 m, punching
process with usually, web or thru-air bonding
needle punch- of 2.5m to
ing, thermal, 6.0m
stitch bonding,
spunlacing
and chemical
bonding.
Contd...
Contd...
Process Name Technology Structure & Raw material Mixture Production Fabric weight Considerations Products & ap- Benefits/disad-
origin fiber orien- rate (m2/min)1 plications vantages
tation
Air-laid Opening, clean- Isotropic; short 3 – 4 mm Percentage of 75 ~ 250 Lightweight Maximum Composite are
ing, removing Random with (pulp) to long longest fiber and heavy and minimum easily achieved,
short fibers; some MD (flax fibers) must be kept to high loft fibrous web The basis weight
Fibers are direction- fibers; very low a minimum value nonwovens average weight, range flexibility
suspended in air ality: to very heavy because those are possible - characteristics of is high, as is the
within a forming dtex fibers; can gather into ~ from 100 g/ the raw material ability to produce
system then Woollen fibers big “lumps” that m2 to 8,000 g/ processed, special various densities
deposited them only for some can block some m2 made from properties of the being very low
as a batt/web special products; parts of the standard or nonwovens such and very high,
in a random Natural fibers; equipments in coarser fibers as high loft, absor- Stiffness and
orientation on a Man-made fibers motion such as bency, fiber web softness easily
moving forming especially PET, rollers, belts, etc; uniformity, delivery controllable over
screen or rotat- PP and PAN; For some fibers, speed range, a wide range,
ing perforated Recycled fibers; except those of output in kg per Diversity of raw
cylinder Superabsorbent pulp and fluff, hour, power con- materials, High
powders; the percentage sumption, machine capital costs. Can
Particles; of fibers less dimensions and use the intermedi-
than 5 – 10 mm production related ate process
must be kept to the floor space stacking
to a minimum unit the number
because they of operatives
can be removed involved, working
in air suction as width, noise level,
waste the environmental
task, equipment
price, etc.
Wet-laid Wet-laid Made by sus- Random with Long fibers; Synthetic Fibers 750 ~ 3000 Web structure Limited by cost Special papers Very capital
pending short some MD Any natural or Offer uniformity is closer, and availabil- (synthetic fiber intensive, Flexible
fibers in water direction- synthetic fibers, and consistency stiffer and ity; Important paper, dust filters, in weight, and
and processing ality: etc. (Wood pulp, of supply, More weaker than properties: Aspect filters for liquids, composition
them into a glass, polyester, difficulty in get- dry-laid webs, ratio (Length); etc.); Industrial but inflexible
fabric using a polyolefins, ting good disper- Fibers in the Tensile properties (waterproof in scheduling,
modified paper- Nylon, Metal) sion for crimped web can be (Shrinkage); sheeting roof, Energy intensive,
making process; fibers, 20 to 50% random or Flex resistance shingling, separa- High fiber qual-
Produce struc- more expensive, longitudi- (Density); Special tors, filters, etc.); ity requirements,
tures with textile Less compatible nally oriented, Fabric Features: Clothing (surgical, Draining large
fabric charac- with water Broad range Web structure is bed-linen, table volumes of water
Web formation
teristics (flex- of weights, closer, stiffer and cloths, etc.) from the web as it
ibility, strength) High produc- weaker than dry- is forming, Control
at speed tivity laid webs; of fiber orienta-
associated with tion during web
making paper formation
89
Contd...
Contd...
90
Process Name Technology Structure & Raw material Mixture Production Fabric weight Considerations Products & ap- Benefits/disad-
origin fiber orien- rate (m2/min)1 plications vantages
tation
Polymer- Spunbond Small volume of Web Polymers Multicomponent: 30 ~ 300 Open Versus Disposables: Various
laid air at ambient Formation: (Polypropylene, Non-splitting Closed System: Hygiene, Medical fiber shapes and
temp. to quench Air transport Polyethelene, ( Sheath/Core, Open (High fabrics, Wipes, sizes (Single layer,
& attenuate, of fiber to Polyester, Side-by-Side, Filament Speed, Filtration, Multiple layers),
Ambient air moving po- Polyamide); mixed filaments, Finer Fibers, Crop covers, Composite with
temperature, rous screen, New polymers etc), Splittables Flexible, Most Disposable other technologies
Drawing force Many propri- (Bio-Polymers, (Pie, Islands-in- Polymers, Shorter clothing, Fabric (example spun-
applied after etary devices Elastomers, Co- a-Sea, Tipped Height), Closed softener sheets, bond / meltblown
polymer cooled, are used Polymers, etc.) Trilobal, etc), (Better Bonding, Synthetic paper, / spunbond) ,
Allows polymer (Spreader Self Bulking ( Good Uniformity, Battery separa- Second step com-
orientation; plates, Side-by-Side) Well Defined tors; Durables: posites (example
Technologies: Coanda Process, Mostly Furniture, -film/spunbond
Creel Fed devices); PP, Not affected Bedding, laminate)
Laydown, Electrostatic by room air) Clothing interlin-
Typar, Original charging, ings, Shoes/
Reemay, Uniform air Leather goods,
Lurgi Process, veloc- Geotextiles,
Tyvek, Curtain ity through House wrap,
Spinning: collection Roofing, Carpet
Open vs. screen backing, Car
closed system, or belt is covers, Coating
Coathanger vs. critical to Substrates, Wall
multipump spin laying down coverings.
beams uniform web;
Multiple lay-
ers get tricky
(must lay
down without
disturbing
incoming
layer),
Compaction
of Web pro-
vides some
integrity,
Compaction
roll set and
Nonwoven: Process, structure, properties and applications
Heating
Contd...
Contd...
Process Name Technology Structure & Raw material Mixture Production Fabric weight Considerations Products & ap- Benefits/disad-
origin fiber orien- rate (m2/min)1 plications vantages
tation
Meltblown Extrude low Meltblown Produce fine fi- Combination of Typical PPMB “Shot” formation, Filtration,
viscosity process is ber (2-8 microns) PP meltblown fabric Fibers colliding Sorbents and
polymer melt a one-step for applications fibers with other together while still Wipes, Coform,
through fine process that where small materials greatly in melt state, Fiber Adhesive,
capillaries; High converts fiber, large fiber enhance the util- break occurs and Apparel, Acoustic
velocity hot air resin to fine surface area ity of meltblown the newly formed insulation, Battery
is blown to the diameter and pore size product fiber has an separator,
molten polymer fiber non- are required. undrawn fiber end
and attenuates woven web PP, PES (high (droplet), usually
the polymer or structure, temperature is caused by partially
melt; The Key at- required), and obstructed capil-
molten polymer tributes of PA. Majority of lary, lower than
is cooled by meltblown the meltblown normal output rate
the turbulent process: product uses PP (gram/hole/min)
ambient air to Produce fine because of ease for the process
form fine fiber; fiber (2-8 of processing, air, can be traced
The fiber is microns) for chemically to the same CD
deposited on a applications inert, safety, and location; Dirty die
collecting device where small attractiveness tip, fibers bending
to form useful fiber, large cost/benefit to one side
articles (web, fiber surface ratio;
tube, etc.) area and
pore size are
required
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3
Nonwoven bonding techniques
Abstract: This chapter deals with different types of bonding techniques used in
the nonwoven manufacturing. The first part of the chapter details the mechanical
bonding methods like needle punching, stitch bonding and hydro entanglement.
The second part discusses different chemical bonding method. In this process,
the methods like saturation, spray and etc were detailed. As a final, the thermal
bonding methods used in nonwoven manufacturing, like hot calendaring, belt
calendaring, ultrasonic bonding and etc., are detailed with clear illustration.
Key words: bonding, needle punching, hydro-entanglement, chemical bonding,
thermal bonding
3.1 Introduction
Nonwovens are characterized as fabrics formed by the assembly of fiber
structures and the adjustment, or bonding, of these filaments utilizing
mechanical, compound or warm routines. Nonwoven webs, whether made
from staple fiber by the dry process or from filaments, lack structural integrity.
The only exception is paper made from wood pulp, where hydrogen bonding
holds the fibers together. Consequently, the fibers have to be held together
either by entangling them or by incorporating a bonding agent such as a resin,
solvent, or a polymer melt. Besides the characteristics of the fiber (length,
fineness, crimp, fiber surface, cross-sectional shape, etc.), the method of web
making, the bonding type has a great influence on the mechanical (strength,
elongation, recovery from deformation, stiffness, tear, etc.) and the physical
properties (handle, drape, abrasion, softness, bulk, surface characteristics, etc.)
of the product. There have been a number of developments in the technology
of bonding. All these technologies, singly and in combination, have given
versatile tools in the hands of industry to tailor-make a product to meet the
end-use requirements.
The filaments in the fiber structure can be adjusted essentially in the
length bearing, basically in the width course or similarly in both directions.
The estimation of the procedure is that by utilizing the highlight of fiber
arrangement and shifting the type of bonding process, the product attributes
can be changed, consequently yielding a really engineered product. The
production of a nonwoven fabric includes a progression of individual steps.
The principal step is to focus the desirable product end use properties and
96 Nonwoven: Process, structure, properties and applications
choose the right fiber to match those necessities. The selected fiber must be
appropriately arranged for the kind of procedure to be utilized. The fiber is
then framed into a web structure with the right fiber arrangement, weight and
measurements. The following step is to choose the bonding system expected
to get the sorts of structure stabilization required for the end product. A
flat stiff structure requires a different bonding method than a lofty or soft
flexible product. Finishing of the product may be as simple as cutting the wide
delivered fabric into to narrower widths. It might likewise include applying
chemical or mechanical finishes, or it might be printing or colouring certain
sorts of these nonwoven fabrics.
Hydro
Print Through-air
entanglement
thermal bonding
(spunlace)
Foam
Ultrasonic
Powdered bonding
Radiant heat
bonding
high frequency sound waves to create molecular motion in the fibers. This
motion creates heat in the structure which reacts with the thermoplastic
polymer to create bonds between fibers. The powder bond process uses
thermoplastic polymer powders sprinkled into the fiber webs and heated to
form the bonds. Figure 3.1 explains the classification of different bonding
techniques used in the bonding of nonwoven web.
platform for the fibrous web to passes through the loom while, the stripper
plate strips the fibers from the needle so the material can advance through
the needle loom. The needle board carrying the needles is driven with some
simple harmonic motion so that the needles will move up and down through
the web. The fibrous webs are normally guided between two conveyor belts
or aprons to prevent fiber slippage in the sheath and core part of the web. The
distance between the stripper plate and base plate can be adjusted to control
the web compression during needling. Most of the needle loom comprises
two needle boards i.e. pre-needling and final needling for effective needling
operation and to reduce the thickness of the batt. After final needling, the
fabric is transported away from the needling zone by take-up rollers, the
movement of which may be intermittent or continuous.
On the off chance that adequate strands are suitably dislodged the web is
changed over into a fabric by the consolidating impact of these fibers plugs
or tufts. This activity happens in needle punching machines where a board
normally containing a few thousand spiked needles, in responded at pace of
around 2000 strokes every moment, contingent upon the machine width. This
activity normally occurs in vertical course and a few machines may have two
arrangements of needles, one working downwards and different upwards, so
that both sides of web are needled. Fabric properties are dependent on number
of factors, the two main ones being punch density and needle penetration. The
operation consists of pre-needler, drafter and a finish needle loom.
During needle punching, the webs are subject to stretching particularly in
the pre-needling machine. In the case of lightweight webs, the draft creates
thick and thin areas due to weight variations and the borders become heavier
because of width shrinkage. For producing lightweight felts, it is advisable to
work on larger widths and then slit the material after needling.
The needle punch webs offer a wide range of product characteristics such
as (Milin Patel & Bhrambhatt 2011),
1. Unique physical property, i.e. elongation in all (x, y, & z) directions
for moldable applications.
2. Ability to attach layers of different types of fiber webs to produce
nonwoven composite as well as reinforcement in composites.
3. High opacity per unit area.
4. High strength makes them overwhelming choice for geotextiles
fabrics.
stretch. During needling operation, the fabric tends to stretch and the amount
of this stretch increases with increase in penetration depth. Further, needle
penetration decides the number of fibers carried by the needle barbs during the
travel as well as the extent of fiber movement. The structural changes occur
during the needle punching process are given below.
• Fiber breakage could happen at higher depth of needle penetration as
the fabric is stretched.
• With increase in depth of penetration, the reorientation of fibers
and the more pressure exerted on fibers leads to decrease in fabric
thickness.
• At lower depth of needle penetration, the punched loops do not
protrude from the bottom surface of fabric.
• With increase in needle penetration, number of barbs penetrating
the web also increases which leads to better consolidation of fibers
resulted in higher density of fabric. The increase in fabric density
could exhibit the following characteristic on a fabric.
– The thermal resistance of fabric decreases due to increase in
fabric density.
– Air permeability decreases with the increase in needle
penetration due to increase in density.
• Owing to the reorientation of fibers into the vertical structure at higher
needle penetration, the initial modulus of fabric could increase.
• The bending length of fabric increases initially with increase in needle
penetration up to a certain level and then decreases.
• The compressibility of fabric decreases and recovery increases
with increase in depth of needle penetration owing to the higher
entanglement of fibers and web consolidation.
Effect of needling directions
• As the needles penetrate through a longer path and there is a possibility
of better entanglement of the fibers, oblique needling gives better
strengthening of the fibers in the web structure.
• Fabrics produced from double-sided oblique needling technique
gives higher tenacity.
• The fabric produced from the oblique needling method gives lower
extensibility, higher density and lower air permeability compared to
fabrics produced by single-sided perpendicular punching.
• Longitudinal extensibility and air permeability decrease and the
fabric density increases with an increased needle inclination.
106 Nonwoven: Process, structure, properties and applications
Parts of a needle
The different parts of barb needle and its structure are shown in Figure 3.6.
top and bottom. The primary function of this type of loom is to do interlocking
of fibers resulting in a flat, one dimension fabric. The structure of felting
needle is shown in Figure 3.7.
The types of products made with this process and needle loom are diverse
and multifaceted. They exist in variety of industrial products, geotextiles,
automotives, interlinings, home furnishings, etc.
Structuring needles
the board, keeping the new needles at the entry side. If a partial re-needling of
a board is made necessary because of an accident, it is advisable to replace the
broken needles with used ones to avoid needle marks. New generation needle
looms can be equipped with complete suction devices system, in order to
avoid dust accumulation and reduce to the minimum the times of maintenance
and needle board changing during working time.
For a given fiber blend, the type of felting needle has great influence on
the felt quality, needle wear and needle breakage. Presently, the felting needle
styles are in the range of 32–42 gauges, which are suitable for processing
fibers in the range 1–18 denier. Coarse needles like 20 and 25 gauges are
predominantly used to needle waste fibers. The use of finer needles indicates
that the industry is processing finer denier and virgin fibers for producing
higher quality felts.
Needle breakage in heavyweight felts is a problem. Certain types of fiber
finishes are used to reduce fiber–metal friction, to reduce static electricity and
increase wetting properties in case there is a post-chemical treatment. The
needle marks are often visible on the felt surface. Three types of patterns
may be seen: machine direction lines, horizontal lines and inclined lines.
The formation of horizontal lines is due to a high output speed as compared
to needle punching strokes. This pattern is seen especially in low weight
materials. This type of felt has poor bending characteristics. The presence of
longitudinal lines means intensive needling and that the material speed is too
slow compared to strokes. If the needle gauge, penetration, number and type
of needle punching machines are not suitable, such lines are highly marked.
Hence, during needle punching, the machine stroke should be adjusted to
have uniform surfaces. Machines with high density needle boards are helpful
in producing smooth surface felts.
that the whole area of a nonwoven filter can be used for filtration, whereas
in a woven fabric the yarns effectively stop the flow, leaving only the spaces
between the yarns for filtration. Generally important characteristics of needle
felts are the degree of felt compression, the strength-elongation ratio and
the permeability characteristics (Wilhelm Albrecht et al. 2003). For highly
entangled fiber felts for synthetic leather, the punching density may vary
between 500 and 1200 punches/cm2. Due to high needle punching intensity,
the production of synthetic leather needs 4–6 machines installed in tandem.
For filter felts, it may be up to 650 punches/cm2.
• Longer fiber lengths result in higher strength, higher felt density and
less air permeability.
• Finer fibers lead to smaller felt thickness and to lower air permeability.
The needling of finer fibers requires inevitably also the use of finer
needles to achieve sufficient strength characteristics
• Higher crimp results in a higher tear resistance and elongation and a
better dimensional stability of the needle felts.
• The characteristics and the structure of needle felts also depend on
the web structure and the area mass. Machine-oriented web results in
a high strength in the longitudinal direction and predominantly cross-
oriented webs result in a high strength in cross direction.
• The web area mass has a great influence on air permeability.
• The area ratio of the fiber plugs in the needle felt is in the range of
2–12%. The fiber length of the plug is 6–20% and the fibers are more
densely packed in the fiber plug than in the needle felt.
Figure 3.11 The basic types of stitch structures (Source: Albrecht et al. 2003)
Nonwoven bonding techniques 115
Table 3.1 Different types of stitch bonding process (Source: Mansfield 2002)
Maliwatt
The stitch formation process in Maliwatt machine and the resultant fabric
is shown in Figure 3.14. The horizontal compound needle and closing wire
framework, which works in conjunction with the knock-over sinker and the
supporting rail, enters through the substrate which is typically a cross-laid web.
The sheet of stitching yarn, which is embedded through the aides away from
any confining influence open hooks of the compound needles, frames stitches
that enter the web. The Maliwatt system consists of following components:
118 Nonwoven: Process, structure, properties and applications
• Stitch bonding unit with a control system for the working elements
• Web feeding system
• Yarn feeding and monitoring systems
• Winding and storage system for the stitch-bonded fabrics
• Cutting unit with a control system for the machine
Figure 3.14 Maliwatt stitch formation process and stitched nonwoven sample
The flat needle structure and the bonding arrangement of the yarn, which
works together with the instrument to evacuate officially shaped stitches so as
to make space for those to be framed, and the support guide, enter through the
substrate which is a web put across to the machine. The stitching yarn is strung
through the guides into the open needle hooks and forms the stitches, which
penetrate the web. Pillar and tricot stitches can be created by a cam shogging.
By modifying the needle framework and the bonding arrangement of the yarn,
it is conceivable to fuse in the meantime the fibers inside the stitches and keep
the withdrawal of the stitches from the limit of last shaped stitch. With tricot
weave, a yarn system parallel to warp can be arranged inside the web and later
on fused into the stitch bonded fabric. (Wilhelm Albrecht et al. 2003; Russell
2006)
Maliwatt – applications
• Soft furnishings, upholstery fabrics for mattresses and camping
chairs, blankets,
• Transportation cloth,
• Cleaning cloths, fabrics for hygiene and sanitary purposes,
• Secondary carpet backing,
• Lining fabrics, interlining for shoes and apparel,
Nonwoven bonding techniques 119
The laying-in sinker averts web movements amid the infiltration process.
When the needle framework moves back to the knocking over position, the
fibers which are in the front of the web hold tight the hooks of the needles, are
conveyed to within the hook of the end wire and drawn through the thickness
of the web. When these fibers are drawn through the stitches shaped by the
fibers on the former course, while they are as yet hanging at the needle hooks,
new stitches are framed through the current stitches, which are skipped by the
shut snares of the needles.
The Malivlies fabrics made completely out of fibers are mechanically
reclaimable. The principle sorts of fiber being used are polyester, polypropylene,
viscose and recovered fibers and the created fabrics have an area mass going
from 120 to 1200 g/m2. The primary applications are auto inside spreads,
felts for material blankets, sponges, cleaning fabrics, geotextiles and channel
materials, covering substrates and covers, items for therapeutic, hygienic and
clean utilize, rug sponsorships.
Malimo
Figure 3.16 shows the relative positions of a Malimo stitch-bonding unit. The
needle system (1) infiltrates the yarn layers (in weft and in warp), the webs,
the support fabrics, the films, the paper and whatever other layer of material,
which can be presented. The guide (3a–3b) spots the fabrics to be stitched in
the open hooks of the needle framework. The already shaped stitches let the
stitched material slide, while closing the stitches. The needles start to come
back to their knocking over position (4), the hooks of the needle system with
the new overlaid stitched yarns are presently shut by the end yarn so that the
old stitches can slide over the highest point of the needles. The old stitches
are secured over the highest point of the needles and new loops are attracted
through the stitches to finish the new course. Also, the guides shock to place
the stitching yarns in the right position for the resulting machine cycle, which
relates to another course.
Areas of appilcation
• Industrial textiles: Composites for high-tech areas (fiberglass, carbon,
Kevlar, HD-PE), sandwiche nonwovens, geotextiles, insulating
materials, laminating substrates, packing textiles
• Furnishing fabrics, home and household textiles: Furnishing fabrics,
upholstery fabrics, textile wall coverings, cleaning and polishing
cloths.
Based on the Malimo platform, different versions and auxiliary devices
have been developed. These developments enable:
• Non-continuous and continuous parallel weft insertion
• Multiaxial constructions
• Cross weft insertion
• Glass fabric manufacture
Malipol
Malipol stitch bonding systems have the following main elements:
• pile yarn
• ground fabric
• stitch bonding head
• fabric take-down and batching
The stitch formation process in Malipol machine is shown in Figure 3.17.
The compound needles penetrate the ground fabric and the stitching or pile
yarn is overlapped in the needle hook. The pile yarn is also laid on top of the
pile sinker at the same time so that a tricot movement is used to create the
pile and knit the yarn into the ground structure. The needles enter the fabric
122 Nonwoven: Process, structure, properties and applications
ground, and the stitching yarn is embedded into the needle hook. The loop yarn
is put over the knock over sinker in the meantime, so that a tricot racking, for
example 1-0/1-2, is utilized to make the pile and to stitch the yarn inside of
the essential structure. The machine is accessible in the gages 10,12 and 14
(number of needles/25 mm), with pile sinker tallness somewhere around 1 and
11 mm and stitch lengths somewhere around 1 and 3 mm, realistic through gear
controls. The machine rate ranges from 900 to 1300 stitches every moment.
1 – Compound needle bar 2 – Closing wire bar 3 – Guide bar for pile yarn
4 – Knock-over sinker bar 5 – Pile sinker bar 6 – Pile yarn
7 – Ground fabric
Figure 3.17 Malipol stitch formation (Source: Albrecht et al. 2003; Russell 2006)
The decision of the feeding system is depends upon the quality and
qualities of the item. Any substrate, which can be gone through by needles, can
be utilized as ground fabric, on condition that it stays undamaged. Concerning
weaves, sateens and twills are the most suitable, albeit likewise level, not
exceptionally conservative but rather wavy fabrics are good with this sort of
procedure. The options are the stitch bonded fabrics, latex, sews and movies.
Cotton or viscose fabrics ranging from 100 to 200 g/m2 are the most common
materials for blankets and waddings, whereas fabrics made of polyester and
polyamide continuous filament weighing between 50 and 200 g/m2 are to be
preferred for the production of plush and imitations fur.
Nonwoven bonding techniques 123
Application
• blankets
• cleaning textiles (wiping mop)
• pile fabric for velcro fastening stripes
• lining plush and soft-toy plush
• bathroom sets
• one-sided terry fabric
Voltex
Voltex fabrics are high-pile fabrics or plush fabrics based on two pre-formed
main elements: a ground fabric and a web. No preparation for stitching
yarns, as cone-winding or warping is required. The main elements of a voltex
machine are indicated in Figure 3.18. High pile or high plush fabrics based
on two principal reformed elements, a ground fabric and a web, which are
continuously introduced. No stitching yarn or yarn preparation, such as
winding or warping are required. The voltex stitch bonded fabrics are mainly
used in lining fabrics, imitation furs, soft-toy plush, shoe uppers and shoe
lining, floor coverings and upholstery fabrics.
The shaped web (for the most part air-laid or wet-laid, however in some
cases spun bond or melt-blown, and so on.) is initially compacted and pre
wetted to kill air pockets and after that water-needled. The water pressure
126 Nonwoven: Process, structure, properties and applications
for the most part increments from the first to the last injectors. Pressures as
high as 2200 psi are utilized to direct the water planes onto the web. This
pressure is adequate for most nonwoven fibers, albeit higher weights are
utilized as a part of specific applications. It has been contended that 10 lines
of injectors (five from every side of the fabric) ought to accomplish complete
fabric bonding. Injector opening diameters range from 100 to 120 micro meter
and the gaps are orchestrated in lines with 3–5 mm dividing, with one line
containing 30–80 openings per 25 mm (Allen 1997). The impinging of the
water streams on the web causes the snare of fibers. The jets debilitate a large
portion of the active vitality fundamentally in revamping fibers inside of the
web and, also, in bouncing back against the substrates, dispersing vitality
to the fibers. A vacuum inside of the move expels utilized water from the
product, counteracting flooding of the item and decrease in the viability of the
jets to move the fibers and bring about ensnarement.
The main entanglement move follows up on the first side various
times with a specific end goal to bestow to the web the fancied measure of
bonding and quality. The web then ignores a second entanglement come in
a converse bearing to treat and, in this way, solidify the opposite side of the
fabric. Hydroentanglement did at standard conditions oblige 800 pounds of
water every pound of item. Hence it is important to add to another filtration
framework ready to successfully supply clean water with this high throughput;
generally, water jets openings get to be clogged up. This framework comprises
of three stages: chemical mixing and flocculation, dissolved air flotation and
sand filtration. Spunlaced fabrics have led to a lot of speculation regarding
their manufacture because most of the manufacturing process details are
considered as proprietary (Elsharkawy, 2014).
Fiber
The choice of fiber will have a great effect on the productivity, amount of
entanglement, and final product characteristics. The fiber used in spunlaced
nonwoven should think about following fiber characteristics (Jürg Rupp,
2008 b).
• Modulus – In general, fibers with low bending modulus entangle
more easily than fibers with high bending modulus. Thus, cotton
and rayon entangle with much less energy input than polyester. The
temperature of the high pressure water is generally kept as high as
possible because warm water reduces bending modulus and increases
entanglement. Bending modulus also decreases as the filament size
(denier) is decreased.
• Fineness – For a given polymer type, larger diameter fibers are more
difficult to entangle than smaller diameter fibers because of their
greater bending rigidity.
• Cross section – Since the fiber cross-section affects bending modulus,
fibers of the same polymer type with a ribbon cross-section entangle
more easily than trilobal fibers. For a given polymer type and fiber
denier, a triangular shaped fiber will have 1.4 times the bending
stiffness of a round fiber. An extremely flat, oval or elliptical shaped
fiber could have only 0.1 times the bending stiffness of a round fiber.
• Length – The number of tie points or entangled areas is directly
proportional to the number of fiber ends present in the web; therefore,
short fibers will produce more tie points than long fibers. However,
fabric strength is also directly proportional to fiber length; and a
balance between fiber ends for more tie points and fiber length for
increased fabric strength is necessary. Wood pulp fibers are short
and create many tie points but are not long enough to provide fabric
strength.
• Crimp – Crimp is required in staple fiber processing systems and
contributes to fabric bulk. Too much crimp can result in lower fabric
strength and entanglement.
• Fiber wetability – Hydrophilic fibers entangle more easily than
hydrophobic fibers because of the higher drag forces.
Hydroentanglement could be carried out using dry-laid (carded or air-
laid) or wet-laid webs as a precursor. Most commonly, precursors are mixtures
of cellulose and man-made fibers (PET, nylon, acrylics, Kevlar (P84, (imide)
etc). In addition, Asahi Chemical Industry has used very fine fibers produced
from splittable composite fibers to produce hydroentangled substrates for
128 Nonwoven: Process, structure, properties and applications
synthetic suede leather products. As a rule, cellulosic fibers are favored for their
high quality, flexibility, plastic deformation resistance and water insolubility.
Cellulosic fibers are hydrophilic, chemically stable and generally dry. Another
favorable position is that cellulose has an inborn holding capacity created
by a high substance of hydroxyl gatherings, which draw in water atoms. As
the water dissipates from the fabric, the hydroxyl gathers on fiber surface
connection together by hydrogen bonds.
For the most part, low micronaire cotton is not prescribed for
hydroentangled nonwovens due to higher number of neps and little packages
of entrapped fibers, bringing about unattractive seeming fabric. Despite this,
fabrics made with lower micronaire fiber show higher quality, likely created
by a higher number of fine fibers and more prominent surface region. In
addition, greige cotton has been used in spunlacing technology. It has been
shown that the absorbency rate increases with increasing hydroentangling
energy. This is the result of oil and wax removal from the fiber surface. These
nonwovens can be subsequently bleached, which should raise the strength of
the fabric (Chellamani et al. 2013).
Web forming
Both dry and wet laid systems are employed to prepare precursor webs for
spunlace processes. When cards are used to prepare the web, the final product
has much higher machine direction strength than cross direction strength.
These non-isotropic products are acceptable for some of the spunlace market;
however, when balanced Machine Direction (MD) / Cross Direction (CD)
properties are required, they are not acceptable. The two major producers,
Chicopee and du Pont, have developed proprietary high speed air-lay systems
that produce isotropic webs. These products have MD/CD ratios of as
low as 1.2–1.5 as produced on the spunlace machine. More recently, wet-
laid processes have been used to prepare the webs. These systems have the
capability of producing very uniform webs with balanced MD/CD properties.
Water jets
The objective of the high pressure water system is to create fine, high velocity
columnar streams of water. Small holes are placed in a jet strip in one or
two rows with a density of 10–20 per cm. The holes range in diameter from
0.08 mm to 0.25 mm but usually are either 0.12–0.18 mm. The holes are
highly finished to smooth surfaces and produce columnar jet streams. Small
imperfections in a hole will cause the jet stream to break up and be less
efficient. The jets arc placed as close to the web as possible to assure that
the jet streams do not break up and dissipate their energy. The usual jet to
substrate or screen distance is 2 inches (50 mm) or less. Special care must be
Nonwoven bonding techniques 129
Needling substrate
Needling substrates play an important role in hydro entanglement process.
In addition to holding the web in place, substrates are designed to increase
needling efficiency and to create either non-patterned or patterned products.
Joining the belt, screen, or drum sleeve together in the right length is a
130 Nonwoven: Process, structure, properties and applications
• Antistat agents
• Bonding
• Stretching
drums or steam-heated cans.In print bonding, high viscose binders are applied
to limited, patterned areas (Russell 2006). A prewet/prebond step is required for
enough strength of webs, and typical steps in this bonding are in Figure 3.26.
Product characteristics
The fabric property is represented by the flexible nature of the fiber and the
resin. Thus the fabric modulus is of the request of the fiber modulus that is
greatly high. A high modulus in a spatially uniform material implies that it
will be solid, which clarifies why saturation bonded fabrics are hardened with
respect to ordinary materials. In the meantime elasticity is low, in light of the
fact that the bonds have a tendency to break before most strands break.
Print-bonded fabrics are much milder in feel furthermore considerably
more flexible to solid impact of the free fibers in the unbounded regions.
They are significantly weaker than saturation-bonded fabrics attributable to
the fiber slipping in unbounded ranges, but knowing the fiber length and the
fiber orientation it is possible to plan a print design which will minimize the
quality misfortune. Every spray application adjusts the thickness of the matt
somewhat, however it is still left generous lofty, the drying and curing stage
additionally causes some little dimensional changes. Finally the product is a
thick, open and grand fabric utilized generally as the filling as a part of knitted
fabrics, for duvets, for some upholstery furthermore for a few sorts of filter
media. (Dhanabalan 2013)
Applications
Nonwoven products in which binders are utilized:
• Wipes and towels
• Medical nonwovens
• Roofing products
• Apparel interlinings
• Filter media
• Coating substrates
• Automotive trim
• Carrier fabrics
• Bedding products (high loft)
• Furniture applications (high loft)
• Apparel
• Pillows (high loft)
as the bearer fiber and plasticized cellulose acetic acid derivation (polycaproic
acid – PCA) or polyvinyl chloride (PVC) as the binder fiber (Hoyle 1990). The
suitability of the thermal bonding procedure is established in the value point
of interest got by lower energy costs. In any case, the thermal bonding process
additionally addresses the requesting quality necessities of the commercial
center. The advancement of new raw materials, better web arrangement
innovations and higher production speeds have made thermal bonding
a reasonable process for the production of both durable and dispensable
nonwovens.
3.4.1 Binders
Many materials that can be used as a binder for thermally bonded nonwovens.
• Binding fibers
• Binding powder
• Binding web
• Type of web: In the same weight range, a staple fiber web will require
less pressure than filament because of its softness.
• Web weight: Heavier webs need higher pressures. A 75–150 gsm
spunbonded webs may require pressures in the range 80–110 N/mm2
while lower weights (15–70 gsm) need pressures in the range 50–80
N/mm2.
• Contact time: This is influenced by the machine speed. In case the
speed is increased, the contact time decreases. It means that the nip
pressure must be increased.
Temperature
When the web reaches the entrance cone created by the roll diameters, the air
at room temperature is dragged in which tends to cool the roll surfaces. But
the material is heated rapidly due to the following reasons:
• The movement of the rolls creates the formation of hot air rings
around their circumferences. This hot air is pulled in by the rolls and
the material gets preheated by convection.
• In the cone area, the fabric is also heated by radiation heat waves
emitted by the hot rolls.
• In the nip, the material is in direct contact with roll surfaces and is
heated by conduction.
• The heating and bonding of the inner layers is also due to the flowing
of the molten polymer from outside to inside caused by pressure.
The working temperature will depend upon the type of polymer, for
example:
• Polypropylene – 140–170°C
• Polyethylene – 85–115°C
• Homopolymer polyester – 230–260°C
• Bicomponent polyester – 120–200°C
• Nylon 6.6 – 220–260°C
• Nylon 6 – 170–225°C
The temperature has a direct influence on the fabric handle. Keeping other
parameters constant, with the increase of temperature, the fabric strength
increases up to a certain maximum value, after which strength declines.
Types of calendaring
There are three main types of hot calendaring (Russell 2006).
• Area bonding
• Point bonding
• Embossing
142 Nonwoven: Process, structure, properties and applications
There are two kinds of calender rollers namely embossed and flat
calender rollers as shown in Figure 3.28 where point, stick and grid bonding
are embossed one and area bonding is flat roller. It is generally known that
the point bonding results in softer fabric and the area bonding results in stiffer
fabric.
Area bonding
This procedure includes the utilization of a calender with a hot metal roll
contradicted by a fleece felt, cotton or special composition roll. Two, three or
four roll calenders can be utilized; contingent upon the heaviness of the web
to be bonded and the level of bonding heated roll on the top and base, with
the two compositions come in the center. The formless or co-polymeric binder
fibers utilized as a part of this procedure give holding at all cross-over points
between the carrier and binder fibers. The resultant item – normally utilized
as a part of electrical protection and covering substrates – is smooth, slim and
hardened. The material is constantly two sided; however, this impact is most
evident in material prepared through two and three move calenders.
The utilization of heat from the outside creates a material whose
inward range is less reinforced than its external surface. This turns out to
be more declared as the item weight increments past 35 g/m2 and can get
to be unfavorable unless restorative measures are taken. These incorporate
increasing heat, slowing speed, or increasing the binder/carrier fiber ratio. The
two-roll calender is utilized for low-to-medium weight items with light-to-
medium bonding. The three-roll calender is utilized for special bonding and
finish effects on a single surface. The four roll calender creates the amplest
weight range of materials on the grounds that it gives more adaptability in the
use of heat (Gao & Huang 2004).
Nonwoven bonding techniques 143
Point bonding
Point-bond hot calendering is the main method of thermally bonding in
disposables as diaper, sanitary products, and medical products. This method
involves the use of a two-roll nip consisting of a heated male patterned metal
roll and a smooth or patterned metal roll. The profile of point bonded calendar
rollers are shown in Figure 3.29.
For light and medium weight fabrics, 10–200 GSM, a 2-roll heat calendar
is used. Heavier weight nonwovens, therefore having high thickness, are
difficult to be bonded with a heat calendar because of de-lamination problem.
One roll is engraved while the other one has a smooth surface. The type of
engraving influences the properties and quality of the final product. Engraving
pattern is usually of geometrical type having square, rectangular, rhomboidal,
circle or oval section. The number of points determines the fabric softness
and the melting area influences the mechanical properties. The bond area is
generally designed in 5–25% range. For example, for a lightweight fabric
(15–35 GSM), a 20% contact area may be necessary whereas for heavier webs
(70–100 GSM), a 10% contact surface is sufficient. In a 2-roll heat calendar,
the two operating rolls are designed with an outside diameter which is
“almost” equal, and which grants a similar rotation speed. Roll diameters are
not identical in order to allow that the contact of the engraving point against
the smooth roll, at each rotation is joggled, granting a homogeneous wear of
the smooth roll, which does not become spotted.
In a typical production line, the web is fed by an apron leading to a
calender nip and the fiber temperature is raised to the point at which tackiness
and melting cause fiber segments caught between the tips of engraved points
and the smooth roll to adhere together. The heating time is typically of the
144 Nonwoven: Process, structure, properties and applications
calendering, time in the nip is 1–10 seconds. The pressure applied is around
1/10th of the weight connected in the hot calendering procedure (Russell
2006). The belt bonder comprises of a warmed roll and an elastic cover as
shown in Figure 3.31.
The nonwoven fabric is heat bonded by running it between the roll and
the cover
Pressure is applied by varying:
(a) The tension on the blanket against the heated roll
(b) The pressure on the exit guide roll inside the rubber blanket
Belt calendered products are much less dense and papery compared to
hot roll calendering. The belt bonder facilitates the use of binders with sharp
melting and flow properties. Such binders can present difficulties in a hot roll
calendering process.
more extensible than area bond hot-calendered material. Kim et al. (1997)
investigated experimentally the formation of bond and the bonding time for
different fiber diameters between two fibers laying orthogonal to each other.
Kim et al. (1999) in a follow up article investigated the bond formation and
development between two fibers by using a simple computational model and
predicted the characteristics shape.
Product characteristics
Products can be relatively soft and textile-like depending on blend composition
and bond area. The material production does not involve any chemical use
making it environment friendly and 100% recycling of fiber components can
be achieved. High bulk products can be bonded uniformly throughout the web
cross section.
Table 3.2 Application of thermo bonded nonwovens (Source: Goswami & Rajasekar 1992)
150
Table 3.3 Comparison of different Web Bonding techniques (Silva, www.acaemia.edu)
Thermal Calender Fibers are formed Heating via: Heat applied 12–20 g/m2 Coverstock for Wherein a thermoplastic
into a web; fibers Conduction, everywhere = (0.35–0.58 oz/ sanitary prod- element, in the form of a
are bonded by ap- Convection and area bonded; Heat sq yd) ucts, Interlings, film (continuous or fibril-
plication of heat; Radiation; applied in specific Geotextiles, Carpet lated), fiber or powder (but
locations = point backing, Insulations, not aqueous dispersion
fibers cool to ambi- Work bonded; Calendar Upholstery, Wiping of film forming, emulsion
ent; bonded web is (Mechanical bonding – between cloths, Tea bag, Food polymerized polymers), is
wound up (frictional), lands (Thin, coverings integrated into the web,
Electrical, squeezed) Wherein thermal energy
Chemical); (extrinsic or intrinsic) initi-
Through-Air Calendar bond- Heat applied 9–150 g/m2 ates bonding between
ing; Through air wherever fibers (0.27–4.4 oz/ fibers in the web, Wherein,
bonding; Infrared cross = High loft sq yd) in general, no fluids need
bonding (not squeezed) be evaporated (except
when using wet-laid webs).
Ultrasound Radiation – wher- Used primarily to
ever fibers cross pre-heat
under ultrasonic
horn
Mechanical Needle punch; Felting; The fibers are Technology in Can attach layers Smooth or Automotive, Factors influencing nee-
Needling; Needle forced to entangle which the fabric producing com- ribbed and Filtration, Furniture & dling: Fiber web (weight,
punching in the z direction is formed by posites, Achieve velours surfaces Bedding, Geotextiles, thickness, closeness,
and inter-lock with means of fiber extremely high den- by structure, flat Roofing, Aerospace, orientation and opening of
other neighboring entanglement sities, High strength or circular by Agriculture, Advanced fibers), Machine (construc-
fibers. There are 7 achieved by overwhelming surface form, 80 composites, tion, variable settings,
board arrange- the repeated choice geotextiles, g/m2 to 3,000 g/ Industrial, Insulators, punch depth, density, no.
ments, and the penetration of that plus superior m2, small pads Marine, Medical, of runs, barbs, frequency,
web can be single barbed needles filtration choice for to up to 16 m Paper, Protective plate design), Binding
or double sided through a pre- filtration media, geotextiles, clothing, Sports felts, Needle (type, shape and
punched. Needle formed dry fiber X/Y/Z direction small diameter Synthetic leather/ # of barbs, thickness,
barb spacing can web (carded and elongation unbeat- (25 mm) to pa- shoes, Wall cover- Neck/kick-up, wear),
influence needle crosslapped or able in moldable permakers felts. ings. Environment.
efficiency and fabric airlaid). applications.
surface
Contd....
Contd....
Process Name Technique Process Web support Fabric weights Applications & Considerations & benefits
system products
Fluid entanglement; The fibers twist Three main Forming wire 20 g/m2 to 600 Mostly used for fine It is the fastest growing
Spunlacing; Jet entan- around their neigh- factors: Water surface character- g/m2 fiber webs intended bonding technology
gling; Water entangling; bors and / or inter- pressure, Energy istics determine for the medical, Worldwide, The spunlacing
Hydroentangling; lock with them transfer and Web properties & personal care, baby process yields the most
Hydraulic needling support system; aesthetics of fabric, care and consumer textile like product of any
Energy transfer: Surface topography and hygiene markets. of the current processes;
determines of forming wire is Most wipes (dry & Spunlaced nonwovens,
hydroentangle- extremely important wet wipe) are made depending upon the fibers
ment efficiency and has direct by hydroentangling or processed, are strong, soft
Insufficient influence on final by Spun Melt and pliable and can be
energy transfer product appear- dense or open and are typi-
(low pressure) ance cally highly absorbent
rearranges but
not entangles
fibers, Excess
energy (high
pressure)
produces weak
areas & non-
uniformity
Chemical Common methods of Binder application Binders Strength – non- Wipes and towels, In the early history of
application include to nonwoven; contain polymer woven strength is Automotive trim, nonwovens almost all
saturation, foam, spray, Removal of produced by closely related to Medical nonwovens, nonwoven fabrics required
print and powder moisture or solvent; the reaction of binder strength; Carrier fabrics, a chemical binder. In very
bonding Formation of strong monomer in Adhesion to Fibers Roofing products, early stages of nonwoven
bond between the presence – adhesion strength Bedding products development natural
binder and nonwo- of initiators or of the binder to (high loft), Apparel resins and glues were
ven web catalyst. During fiber bond is im- interlinings, Furniture used as bonding agents.
moisture removal portant; Flexibility/ fabrics (High loft), However, because of the
film formation handle – some Filter media, Apparel, fabric properties chemically
takes place. fiber movement is Coating substrates, bonded fabrics were not
Chemical binder required; Elastic Pillows (high loft fully accepted.
most used today Recovery – good
is water-borne recovery under
latex, Applied in stain is needed to
Nonwoven bonding techniques
Contd....
152 Nonwoven: Process, structure, properties and applications
References
1. Albert G. Hoyle (1990). Thermal bonding of nonwoven fabrics, Tappi Journal, pp.
85–88.
2. Alfred Watzi (1994). Fusion bonding, thermal bonding and heat-setting of nonwovens-
theoretical fundamentals, practical experience, market trends”, Melliand, English, 12.
P.E 270.
3. Allen, Charles H. (1997). New Development for Spun-lacing Cotton, Paper presented at
Fiber Society Conference, University of Tennessee, and Knoxville 19th–21st Oct 1997.
4. Bhuvenesh C. Goswami, Rajasekar D (1992). Adhesive binders for nonwoven fabrics,
International conference on Nonwovens, Textile Institute, North India Section, Porritts
and Spencer, India.
5. Bonding, http://www.edana.org/discover-nonwovens/how-they’re-made/bonding,
Accessed on June 10th 2015.
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The Spunlace process and its application possibilities for hygiene textiles, J. Acad.
Indus. Res. Vol. 1(12).
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UploadFiles/BackCenter/20141109132921.pdf, Accessed on May 20th 2015.
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Hydroentangled Nonwoven, Fabrics, Tappi Journal, v.76, 135–141.
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progress, 7:2, 101–123
10. Dharmadhikary RK, Gilmore TF, Davisha & Batra SK (1995). Thermal bonding,
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academia.edu/440297/Comparison_of_web_formation_and_bonding_methods.
Accessed on May 12, 2015.
12. Eng Mohamed Elsharkawy (2014). Hydro-entanglement Bonding Process for
Production of Nonwoven Fabric, http://textilelearner.blogspot.com/2014/12/hydro-
entanglement-bonding-process-part-5.html, Accessed on June 10th 2015.
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10th 2015.
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fiber type and dimensions, J Text Inst, 59, 137.
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www.slideshare.net/himanshugupta3139/web-stitching-stitch-bonding-warp-
knitt?related=1 , Accessed on June 10th 2015.
Nonwoven bonding techniques 153
Abstract: This chapter discusses about the basic finishing of nonwoven fabrics
such as mechanical and chemical finishes and special finishes such as plasma
and micro-encapsulation. In mechanical finishing, the principle of perforation,
splitting and winding, shrinking, compacting, embossing, creping, calendaring,
shearing and raising has been discussed. In chemical finishing of nonwoven,
dyeing, printing aspects and value-added finishes such as antistatic, flame
resistant, water repellant and softeners were also discussed in detail.
Key words: Mechanical finishing, chemical finishing, calendaring, compacting,
creping, flame resistant, plasma, micro-encapsualtion
4.1 Introduction
The finishing of nonwovens is gaining importance among the manufacturers, as
it contributes to the specialized and aesthetical functionalities of the materials
to render them more suitable to the market requirements. Various types of
nonwovens are subjected to finishing treatments amid their processing cycle.
The wide range of finishing techniques, both chemical and mechanical, has
broadened the range of applications of nonwovens. The nonwoven finishing
techniques can be classified as shown in Figure 4.1.
Non woven finishing methods
4.2.3 Shrinking
The fibres have a tendency of reverting back to their original state in order to
release the stress built up during processing. This results in shrinkage of the
fabric. To avoid the subsequent shrinkage, the nonwoven can be subjected
to intentional shrinkage by immersing in cold water, steaming or providing
resin/chemical treatment (Kamath et al. 2004).
4.2.5 Compacting
Compacting of fabrics is a simple mechanical process in which the fabric is
subjected to compressive forces along the length. In general, the nonwoven
Finishing of nonwovens 159
fabric is fed into a converging passage, securely gripped and lead into the
treatment cavity, where the compaction takes place. Figure 4.2 shows the
nonwoven compacting process. For compacting a nonwoven fabrics, the
machinery setup includes a pair of juxtaposed rollers (2,3) and a superposed
roller (4) which are arranged in such a way to produce fibre compacting. The
central superposed roller (4) extends in preset space (9) between the juxtaposed
rollers (2,3) to achieve fibre compacting. Each of the rolls has perforations
(5) extending through the surface of a shell (6). The first conveyor (16,19)
feeds the nonwoven to the roller arrangement while the second conveyor belt
(17,20) draws the fibres away from the roller arrangement after compacting.
The conveyor belts (19,20) may also be perforated and surround the juxtaposed
rollers (2,3), respectively. The compacting process is assisted by means of
suction applied to the interior of the rollers, which draws the fibres through
the perforations (5) in the rollers (Lasenga 1989).
4.2.6 Embossing
The process of embossing produces a raised texture on the surface of the
nonwoven fabrics. Embossing is done by means of heated engraved rollers.
This process is suitable for all nonwovens except for woolen felts. Permanent
embossing can be achieved by combining the process with certain chemical
resins.
160 Nonwoven: Process, structure, properties and applications
4.2.7 Creping
The nonwoven web is attached to the surface of a roll or drum by means of
an adhesive and then the adhered nonwoven is mechanically detached from
the surface of the roll or drum. The absorbency (in case of hydrophilic fibres),
softness, and bulk of the nonwoven is improved as the fibre positions are
disturbed and are altered within the web during detachment process. Creping
can also be observed in the papermaking art.
Water-based adhesives, like latex adhesives, are widely used to attach
the nonwoven fibrous web to the creping roll or creping drum in the creping
process. To ensure proper adherence between the nonwoven web and the
creping roll or creping drum, the water must be removed from the adhesive
by drying. To achieve this, huge heated rolls or drums, like the Yankee Roll
(Figure 4.3), are used to dry the water-based adhesive. These drums are
expensive and consume a large amount of energy to efficiently dry the water-
based adhesive (Sayovitz 2004).
4.2.8 Calendaring
Calendaring is a non-durable mechanical finishing technique which can be
applied to nonwovens made of cellulose, protein and synthetic fibres. This
machine includes one or several pairs of rollers pressing against each other.
These rollers are provided with movable weight and identical nip speeds.
The fabric is subjected to a smoothing and a squeezing activity when passed
through these rollers. The surface of the rollers can either be hard or milder
depending on the material being processed. Stiff rollers are typically made of
steel or hardened cast iron with chrome-plated or nickel-plated or stainless
steel surfaces. The roller can be subjected to treatments that provide:
Finishing of nonwovens 161
4.2.10 Shearing
Shearing is a method of trimming or cutting adopted to expel the surface
fibres from the nonwoven fabric. Shearing is a distinct alternative to the
singeing process. The shearing process facilitates only a fractional surface
fibre removal. The fabric surface morphology is the main factor determining
the cutting stature. A shearing machine is demonstrated in Figure 4.4. The
shearing head consists of a winding spiral blade and a ledger plate. The spiral
blade is capable of revolving on its own axis and remains in contact with
the ledger plate. This arrangement replicates the trimming activity similar to
that of a scissors. When the nonwoven is passed through the shearing head,
the protruding surface fibres will come in contact with the ledger plate and
subsequently get cut by the sharpened steel (www.nptel.ac.in).
A cloth rest is provided such that the fabric forms an acute angle when it
is presented to the ledger plate. This sharp turn causes the pile to stand erect
Finishing of nonwovens 163
and can be more easily cut. The distance between the cloth rest and the ledger
blade can be adjusted according to the height of the pile.
4.2.11 Raising
Raising is a finishing process which, in contrast to the other finishing process,
raises the surface fibres in the nonwoven fabric. This is achieved by passing
the nonwoven through fast rotating rollers secured with metal points or teasel.
Raising is also known as the napping process. Excursion, wool, and fleece
broadcloth get their wool like appearance by this process. Additionally,
napping can be utilized for certain knit goods, covers, and different fabrics
with a raised surface. This operation is particularly well suited for wool and
cotton fabrics as a fluffy surface can be generated in these fabrics by rubbing
the material and pulling the fibre end to the surface. By providing a fluffy or
shaggy surface to the fabrics, the fabric appearance, fabric mass and fabric
handle (mild and more full hand value) can be varied. The warmth protection
of the material is enhanced due to the entrapment of air by the fuzzy surface of
the fabric and makes it suitable for wear in cold climatic conditions.
The metal needles or points secured to the raising roller surface rub the
nonwoven surface and pull out the fibres as illustrated in Figure 4.5. Typically,
the needles are 45° hooks projecting from the raising rollers. The needles
are fitted onto an elastic belt which is spiral wound on the raising rollers.
Moreover, the thickness and length of the needles can be changed according
to the nonwoven being processed (Mazharul Islam Kiron 2012). In general,
a couple of rollers are used. A roller with its hooks directed in the direction
of fabric feed (pile roller), is alternated with another roller with its hooks
mounted in the direction opposite to the fabric feed (counterpile roller).
pile rollers have independent drives and can rotate with different speeds and
direction to produce a variety of fascinating effects.
1: Roller; 2: Rollers equipped with hooks; 3: Fabric; 4: Nib cleaning brushes; 5: Fabric tension
adjustment
Figure 4.6 Raising (napping) machine (Source: Kiron 2012)
Figure 4.7 Raising the face of the fabric (Source: Kiron 2012)
The effectiveness of the raising process largely depends upon the fabric
strain (5) or the fabric velocity and the direction of roller rotation (2). By
varying these parameters, the extent of raising can be altered. Aggressive
raising activity subjects the fabric to extreme mechanical stress and can
potentially damage the fabrics. To avoid such fabrics damages, it is better to
Finishing of nonwovens 165
pass the wet fabric through the raising machine several times with mild raising
effects (dry when handling cotton fabrics). Wetting the material reduced the
friction between the fibres in case of synthetic fibres and enables easy pulling
out of fibres. Treating the fabric with softening-greasing agents also helps tit
prevent fabrics damage during raising (Figure 4.7).
4.2.12 Singeing
Singeing is the process of burning externally. The free fibres which are loosely
held on the surface are burnt-off in this process. Singeing is crucial finishing
treatment as it involves of burning of the fibres. Hazy print patterns, mottled
fabric surfaces, and pilling are some of the consequences of improper process
parameters in singeing. The main objectives of singeing are (Hussain 2012)
Singeing of a fabric produces a smooth and clean fabric surface.
• Singed fabrics show a lower soiling tendency compared to un-singed
fabrics.
• Singeing reduces the risk of pilling, especially with synthetics and
their blends.
• Printing of fine intricate patterns is possible in singed fabrics.
• The removal of randomly protruding fibres from the nonwoven
prevents the diffused reflection of light.
In this process, the fabric surface is initially brushed gently to raise the
undesirable and loose fibre ends. After this, the fabric can be singed by means
of heated copper plates or open gas flames. As the fabrics passes over the
heated plates or the flame, the fibre ends burn off. The fabric is moved quickly
such that the time of exposure is just sufficient to burn the protruding fibre
ends and not the entire fabric. A water bath or desizing bath is located at the
end of the singeing machine. This is essential to put off any singeing afterglow
or sparks that may degrade the fabric.
There are three main categories of singeing machines are listed below
(Hussain 2012):
1. Plate singeing machine
2. Rotary-cylinder singeing machine
3. Gas singeing machine
are usually heated to splendid redness and then the nonwoven is passed over
the plates. The contact time of the nonwoven with the plates is decided by
the speed of the fabric movement. Generally, the nonwovens are delivered at
a speed of 150–250 yards every second to the machine. The machine can be
designed to ensure that both the sides of the nonwoven come in contact with
the plates in a single passage of the nonwoven through the machine. To avoid
localized cooling of the plates due to constant material passage, an automatic
traversing mechanism is fitted to the machine. This mechanism constantly
changes the part of the plates which come in contact with the nonwoven,
thereby preventing localized cooling and wearing of the plates.
Figure 4.8 Line diagram of rotary-cylinder singeing machine (Source: Hussain 2012)
apart from strengthening the washing effect. Nonionic washing agents are
more productive at particular temperatures. The material must be subjected to
a certain amount of pressure in both the wet and dry washing procedures. The
applied pressure should not distort or expand the nonwoven.
4.3.2 Dyeing
Nonwovens can be dyed at different stages of nonwoven manufacturing as per
the end product requirement. They are explained in detail below (Aspland &
Jarvis 2007).
Dyeing of polymer – In the case of polymers like polyester, the colouring
agents can be added as a concentrate to the polymer melt just before the
filament extrusion. This method can be treated as a bulk colouration or melts
dyeing process. The concentrates added to the polymer melt are basically
pellets or beads with a high concentration of dyes or pigments. Polymer
dyeing offers several advantages compared to the other methods. This process
is much faster and does not require the newly formed fibre webs to undergo
a vigorous dyeing process which may distort the webs. Moreover, polymer
dyed fibres show superior colour fastness properties.
Staple and mass dyeing – Wet processing like dyeing and printing
is a time-consuming process with high energy and cost requirements. Wet
processing of nonwovens is frequently linked with the other wet processes
involved in the web bonding procedure. Alternatively, the fibres can be dyed
in the staple form.
Dyeing and bonding – The dyeing and bonding procedure is suitable
for chemically bonded webs. The colouring agents are added to the tank or
reservoir containing chemicals for web bonding. Finely dispersed pigments
are used as the colouring agent as the bonding agents perform bonding
action by coating the filaments of the web. The bonding agents show strong
adhesion to the fibres, thereby enhancing the rubbing fastness and colour
fastness properties of the pigments. Dyes with excellent fibre affinity can be
used instead of pigments in the bonding processes where the banding agent is
not uniformly dispersed over the web. This improves the dyeing uniformity
despite the uneven distribution of the bonding agent.
Subsequent dyeing – Dyeing and bonding process is not suitable when
various fibres are blended in the web. In such situations, the dyeing process
is performed later. The nonwoven fabric is considered as a woven or knitted
fabric and is dyed using the conventional techniques.
Cold pad batch dyeing – Cold pad batch dyeing was originally licensed by
Farbwerke Hoechst for the dyeing of polyamide-bonded webs. This method
Finishing of nonwovens 169
is used for dyeing spun bond or cross laid (card) nonwovens developed for
curtain and table linen applications. These nonwovens are bonded with the
help of acrylic acid esters and are coloured using coloured acid or metal
complex dyes. Acids can be added along with the dyes in order to form
hydrogen bonds between the acids and the cold wetting agents. This bonding
with the cold wetting agents facilitates migration of the dye molecules during
the batching period and helps in achieving better dyeing uniformity. Then, the
fabric is padded, batched and secured with polyethylene film. After 24 hours
time, the fabric is subjected to soaping and warm washing.
Continuous dyeing – Nonwoven fabrics with higher weight per unit area
can be dyed in a continuous dyeing range. The conventional pad-steam process
is preferred for continuous dyeing. Steaming is essential to properly fix the
dye molecules to the fibres. After padding and steaming, the nonwovens are
rinsed and washed (Kamath et al. 2004).
4.3.3 Printing
The printing systems and the colour range for printing nonwovens has
extensively developed due to the ever increasing utilization of nonwovens in
the home textiles sector. Similar to woven or knitted fabric printing, screen
printing and rotary screen-printing are widely used to print nonwovens. The
nonwoven fabric is placed on the printing backcloth and printed with suitable
dyestuffs depending on the nature of the fibre. It is then dried by steaming
and washed. Pigment printing is critical as pigment binders used also help
in bonding the fabric to a greater extent. The influence of pigment binders is
more significant in spunbonded fabrics.
• Printing of light nonwoven bonded fabrics: Almost the entire range
of light, nonwoven bonded fabrics can be printed using pigments.
Higher dye concentrations are required for printing light nonwoven
bonded fabrics.
• Printing of heavy nonwoven bonded fabrics: The composition and
viscosity of the printing paste used for printing of needled punched
fabrics is drastically different to the printing paste used for light
nonwoven fabrics. Additionally, heavy nonwovens must be printer at
slower speeds.
• Transfer printing: In transfer printing, dyes which are capable of
subliming are initially printed on a release paper and then transferred
from on to the nonwoven bonded fabric by means of heat and
pressure. Disperse dyes are widely used to print polyester fibres based
nonwovens in this method.
170 Nonwoven: Process, structure, properties and applications
4.3.4.3 Lubricants
Lubricants perform the task of reducing the fibre to fibre friction or in some
cases, the fibre to metal friction in nonwovens. The application of lubricant
Finishing of nonwovens 171
also makes the nonwoven feel softer. Lubrication is also essential in the the
stitching operation, as the rapid movement of the needles generate a lot of heat
while penetrating into the nonwoven fabric. If lubrication is not provided, the
overheated needles can damage the nonwoven fabric.
4.3.4.6 Softeners
The application of softeners provides a soft and delicate feel to the
nonwovens. Nonwovens which are in close contact with the skin like sanitary
Finishing of nonwovens 173
napkins, wipes, etc., require softening treatment. In general, the softeners are
hydrophilic in nature which in turn increases the wettability of the fabric.
4.3.4.7 Stiffeners
The stiffness or firmness of nonwovens can be improved by using stiffening
agents. The weight, compactness and volume of the nonwoven fabric are
increased by the addition of stiffeners and fillers. Consequently, the physical
properties like the tensile strength and abrasion resistance are enhanced.
When stiffeners are applied in the form of polymer dispersion by spraying
or padding, they cause bonding of adjacent fibres in the nonwoven fabric and
enhance the dimensional stability.
In the other method, wet on dry padding, the dry nonwoven is impregnated
with treatment liquor. During padding, the air in the nonwoven must be
eliminated and should be replaced with the treatment liquor. To achieve higher
pick-up levels, it is essential to de-aerate the nonwoven before impregnation.
Similar to calendaring, the squeeze rollers should exert uniform pressure
along the entire nip line. The treatment liquor is prepared depending upon the
required pick-up level.
4.3.5.2 Coating
In the coating process, the finishing agents are applied to the nonwoven in fluid
forms like solution or foam or dispersion. The coating process is followed by
the drying and curing process. There are different drying methods depending
upon the nature of the nonwoven and the water content to be removed. Coating
can be done as a single layer or as multiple layers. Consistent coating thickness
can be achieved with single layer coating. Multilayer coatings fill the holes
and gaps in the fabric surface providing a smooth and uniform surface to the
nonwoven. The major factor to be considered while coating nonwovens is the
rate of fabric let-off. If the rate of let-off is not set properly, it will result in
uncontrolled stretching of the fabrics.
The rotating roller (slop padding or kiss roll) is the most common
method of coating nonwovens. The slop padding roller is dipped halfway
in the coating solution and the nonwoven is passed over the roller making
contact with the other half of the roller. The pick-up level is determined by the
process parameters like slop padding roller speed, depth of roller penetration
in the coating solution and direction of roller rotation. The nonwoven can be
passed over the roller either in the direction of roller rotation or in a direction
opposite to the roller rotation. Penetration of coating solution is better when
the nonwoven is passed in the direction of the roller rotation, more noteworthy.
When the nonwoven is passed opposite to the direction of the padding roller,
the machine design is varied. The machine arrangement consists of a pair of
rollers, namely the application roller and the support roller. The nonwoven
is passed through the nip of the two rollers and the nip pressure determines
level of pick-up in the fabric. Attachments like scrubber, doctor blades, or
metering rods can be provided to remove the excess coating solution from
the nonwoven. The coating solution can be uniformly distributed through the
entire width of the fabric by means of special blades. The coating thickness
can be varied by altering the blade profile and the distance between the blade
and the nonwoven.
Besides roller coating, various other technologies like rotogravure
coating, rotary screen coating, extrusion coating and non contact coating are
Finishing of nonwovens 175
also available for coating nonwovens. Rotogravure rollers (Figure 4.11) are
used to impart patterned coating to the nonwovens. The rollers maintained
at higher temperatures to assist the bonding of thermoplastic components.
Rotary screen coating (Figure 4.12) is quite similar to the rotary screen printing
process. It is used to coat fusible nonwoven interlinings at higher production
rates. In this technique, the coating material can be in the form of a fluid
or powder. In case of powder coating, size and shape of the particles in the
powder should be compatible with the pores in the coating screen. Patterned
coating can also be achieved by using fine meshed screens. The extrusion
coating process involves lamination of the nonwoven by the extrusion of
thermoplastic polymers. This technique is used when the nonwoven must
be rendered impermeable. In non contact coating, the coating material is
sprayed on the nonwoven with the help of spray nozzles (Figure 4.13). This
method is of prime importance for coating nonwovens with poor dimensional
stability and a highly irregular surface. It also helps in achieving low add-on
percentages. (Lünenschloss & Albrecht 1985)
4.3.5.3 Laminating
Lamination is the process of securely attaching two or more pre-assembled
fabrics to produce a combined structure. If the components of the lamination
do not possess self-adhesion properties which are triggered by specific
conditions, a bonding agent must also be included in the lamination process.
(Bellini et al. 2001).
Wet laminating: A simple configuration for the wet lamination process is
illustrated in Figure 4.14. The adhesives used in the wet lamination process
are dissolved or dispersed in a suitable solvent. In wet lamination, the adhesive
is applied in the fluid form along the length of one of the component fabrics
which is to be joined. The second component fabric is then placed over it
with sufficient pressure to induce bonding between the layers. The amount of
pressure determines the extent of consolidation of the attached fabrics layers.
4.3.5.4 Flocking
Flocking is the process of creating three-dimensional piles on the surface of
the backing fabrics in a nonwoven. Synthetic fibres are more convenient for
flocking as they are manufactured in uniform pre-determined lengths. Natural
fibres should be ground into short fibres to make them suitable for flocking.
The base fabric is treated with an adhesive resin to secure the flock fibres
to its surface. The adhesive can be applied over the entire fabric in case of
aggregate flocking. Alternatively, the adhesive can be applied in specific
areas of the base fabric by means of printing to create flocked designs. The
mechanical flocking techniques include the shaking process and the sprinkling
process. These techniques create random piles on the fabric surface as they
cannot control the alignment of the fibres. The electrostatic flocking process
is preferred to create velvet finishes. In this process, the created electrostatic
field aligns the fibres vertically as they make contact with the backing fabric.
Flocked products find numerous applications like automotive interior panels,
shoes, apparels, filters, drapes and as patterned decoration effects (Tanchis
2008).
178 Nonwoven: Process, structure, properties and applications
4.3.6.2 Microencapsulation
Microencapsulation is a technique in which the droplets of active finishing
agent are surrounded by a thin coating to provide small capsules with
numerous functional properties. These microcapsules can be utilized to
impart various properties like antimicrobial property, flame retardancy, etc.,
to any kind of fibre. The resulting property can either be durable or temporary
depending on the method adopted. In comparison to conventional finishing
techniques, microencapsulation imparts specific properties to the nonwovens
with improved stability along with controlled release of the active compounds.
In this process, the microcapsules containing the active compounds
are incorporated into the nonwoven during the finishing treatment.
Microencapsulation is being increasingly used in nonwovens for cosmetic,
pharmaceutical and industrial applications. The active compound is released
in a controlled manner by several mechanisms. Usually, the capsule wall is
designed to break and release the active compounds. In another mechanism,
the capsule wall acts as a permeable medium allowing the diffusion of
Finishing of nonwovens 179
References
1. Russel SJ (2006). Handbook of Nonwovens. Woodhead Publishing Ltd. Cambridge.
2. Purdy AT (1983). Developments in Nonwoven Fabrics. Textile Progress, The Textile
Institute, Manchester, UK.
3. Wilhelm Albrecht, Hilmar Fuchs, Walter Kittelmann (2003). Nonwoven Fabrics: Raw
Materials, Manufacture, Applications, Characteristics and testing process. Wiley-
VCH Verlag GmbH & Co.
4. Joachim Lünenschloss, Wilhelm Albrecht (1985). Nonwoven bonded fabrics (Ellis
Horwood series in applied science and industrial technology). E. Horwood publisher,
1985. ISBN: 9780853126362.
5. Aspland JR, Jarvis CW (2007). The Coloration and Finishing of Nonwoven Fabrics.
Clemson University, Clemson, SC.
6. Kamath MG, Atul Dahiya, Raghavendra R. Hegde (2004). Finishing of Nonwoven
Bonded fabrics.
7. http://www.engr.utk.edu/mse/Textiles/Finishing%20of%20Nonwovens.htm
Accessed on May 20, 2015.
8. Finishing process of Nonwoven. http://www.nptel.ac.in/courses/116102014/11.
Accessed on May 20, 2015.
180 Nonwoven: Process, structure, properties and applications
5.1 Introduction
With present indecisive economic circumstances, industries need to be far
more competitive to make sure their products get into market first. This
indicates that a business has an advantage over its competitors by being the
initial occupant of a market sector and this phenomenon plays heavily in the
testing field. Industries should need to develop a balance between being first
to market and being the best in the market. Testing is not a process that can be
done in a hurry but it is vital for businesses to make sure their products meet
their customer’s expectations and yet the product needs to be ready in time to
ensure a competitive edge.
Testing is extremely important when developing a new product and
many problems can be easily unseen in the rush to get a product to market.
Unfortunately testing is quite often looked as an overhead as industries are
very keen to reach the end product and cannot see the tangible return-on-
investment testing can bring. Testing is the way of control or the process
to check or verify the nature, kind or character of fiber, yarn, fabric or any
material, hence to control the degree of excellence.
• Process development
• Product development & research
• Specification test
1. Fiber dimensions
• Fiber diameter and its variation
• Cross-sectional shape
• Crimp wave frequency and amplitude
• Length
• Density
2. Physical properties of fiber
• Young’s modulus, elasticity
• Tenacity
• Bending and torsion
• Rigidity
• Compression
• Friction coefficient
• Fibrillation propensity
• Surface chemistry and wetting angle
3. Structural parameters of a nonwoven
• Fiber alignment: fiber orientation distribution
• Porous structural parameters: fabric porosity, pore size, pore
size distribution, pore shape
Contd...
Contd...
188 Nonwoven: Process, structure, properties and applications
Contd...
S. Fiber Standards Principle of measurement Technology to be
no. parameter available more important
4 Testing of The fiber is clamped in a take-off
fiber crimp device with a fixed and a vertically
movable clamp under a pretensioning
force of 0.05 mN/tex. The clamping
length will depend on the nominal
length of the fibers. At least 100 fibers
are tested.
5 Determination DIN EN Direct measurement by Telescope- All technologies
of breaking ISO 5079: Goniometer
force and 1996-02
elongation at
break
of individual
fibers
6 Contact angle Direct measurement by Telescope- Filters and absorbent
of a fiber Goniometer materials
Contd...
Physical properties Chemical properties Aesthetic properties Commercial
properties
• Seam Strength • Oleophobic/philic • Surface Decoration • Shipping
• Flex Fatigue • Static Generation • Surface Texture • Exclusivity
• Shear Behavior • Electric Charge • Slick/Scroopy • Delivery Cycle
• Abrasion Resistance • Adhesion/Cohesion • Drape • Tariffs
• Compression Resist • Bioactivity • Warm/Cold • Liability
• Elasticity/Brittle • Liquid Repellency • Comfortable • Patent Protection
• Surface Friction • Dyeability • Clammy • Volume Breaks
• To self • Biodegradability • Stretchy • Licensing
• To other surface • Thermoplastic/Set • Bouncy/Dead • Royalties
• Moisture Vapor • Dye Stability • Fluffy/Hard • Trademarks
• Air Permeability • Melting Behavior • Bright/Dull • Merchandising
• Fluid Porosity • Wetting Behavior • Reversible • Hot/Old News
• Water Repellency • Absorbency • Textile/Papery • Converting
• Thickness • Cleanability • Feminine/Masculine • Safety
• Density/Bulk • Color • Cute • Efficacy
• Bending Resistance • Toxicity • Pretty • Regulatory Rules
• Surface Topography • Carcinogenicity • Sophisticated • Unique
• Thermal Conductivity • Printable • Trendy/Classic • Disposable/Durable
• Liquid Transport • Sterilizable • Quiet/Noisy • Environmental
• Pore Size • Fashionable • Impact
• Absorbency
• Fluid Uptake Rate
• Fluid Retention
• Sewability
• Wrinkle Resistance
• Weight/Mass
• Piling Resistance
• Cutting Behavior
7. Moisture management
Contd...
S. Test Standard Description
no.
IST ASTM
5 Bursting strength 30.1 D3786-87 Sample is clamped over a diaphragm that is
(psi or kPa) expanded by fluid pressure to the point of rupture.
It is the pressure difference between the pressure
to rupture and to inflate
6 Elmendorf Tear 100 D5734-95 Sample is fastened in the clamp, tear is started.
strength (gf) Pendulum is released and the sample is torn. The
force to tear is calculated.
7 Hydrostatic Head 80.6 Sample is subjected to standardised water
(mbar or Wc) pressure, increased until leakage appears.
Pressure at first sign of leakage is hydro head.
8 Air permeability 70.1 D737-96 Calculated from the rate of air flow passing
(cm3/s/cm2) perpendicularly through the known area of fabric
to obtain a prescribed pressure differential
ε (%) = (1 – f) × 100
Where ε is the fabric porosity (%), ρfabric is the volume fraction of solid
material (%), (kg/m3) is the fabric bulk density and ρfibre (kg/ m3) is the fiber
density.
A sample of known volume should be cut from the fiber assembly and
then the mass of dry sample should be noted. The sample is then immersed in
n-decane till saturation was achieved. After that, the mass of the wet sample
should be noted down. The difference in the mass of the wet and dry sample
gave the mass of n-decane absorbed. The quotient of this mass to the density
of n-decane resulted in the volume of n-decane absorbed. The quotient of the
volume of n-decane to the volume of the sample resulted in porosity of the
sample (Rengasamy et al. 2011; Dierickx 1999). Moreover, apart from direct
determination of porosity, for resin impregnated composite nonwovens, the
porosity can also be determined with density measurement on basis of the
Testing of nonwovens 199
Several testing methods are existing for the measurement of contact angles
for liquids against solid materials. Standard optical and Wilhelmy methods are
complicated or impossible to solve if a sample swells when exposed to the
liquid used for testing (Shang et al. 2008). Washburn theory specified that if
a porous solid material is brought into contact with a liquid in a manner that
the solid is not sunken in the liquid, however is slightly touching the surface
of the liquid, then the rise of liquid into the pores of the solid material due to
capillary action will be governed by the following equation:
m2 η
cos θ =
t ρ2 σc
For carrying out a Washburn experiment, a liquid of known density (ρ),
viscosity (η), and surface tension (σ) should be taken for the experiment. By
looking into the above equation, it is observed that the mass of liquid which
rises into the porous solid material could be monitored as a function of time.
Then two unknown parameters remaining are the contact angle of the liquid
on the solid material (θ) and the solid material constant (c). On the other
hand, if a Washburn experiment is carried out with a liquid which is having
a contact angle of θ = 0° (cos θ = 1) on the solid material, then the solid
Testing of nonwovens 203
material constant (c) is the only unknown parameter which can be determined.
N-hexane chemical is a better choice as the liquid for determining material
constants, due to its low surface tension (18.4 mN/m) at room temperature.
After the calculation of the solid material constant (c) of a particular solid
material, a second sample of the solid can be evaluated for wettability by
means of another kind of liquid. The solid material constant determined by the
N-hexane method is normally used in the Washburn equation, in combination
with m2/t data obtained during testing with the second liquid. This permits
determination of the contact angle between the second liquid and the solid. C is
related to tortuosity (r5) and square of number of pores (Rengasamy et al. 2011).
Washburn adsorption tests could be easily and automatically carried out
on a numerous porous materials using a Krüss Processor Tensiometer K100
in combination with Krüss LabDesk software in the Adsorption mode. This
solid material constant (c) contains information related to the pore structure,
pore size, and number of pores in the solid sample. This must remain constant
during an experiment for the resulting contact angle measurements to be
correct. For swelling solids the pore structure will change, creating a change
in the c-factor (Rengasamy et al. 2011).
Table 5.5 Common testing parameters and standards for nonwoven application in
different areas
Contd...
Contd...
Contd...
References
1. AATCC Technical manual (2013) Test methods for textiles. American Association of
Textile Chemists and Colorists (AATCC).
2. ASHRAE, ANSI/ASHRAE 52.1-1992, Gravimetric and Dust-Spot Procedures for
Testing Air-Cleaning Devices Used in General Ventilation for Removing Particulate
Matter, ASHRAE Standards, 1992.
3. ASTM (1989) Annual Book of Standards. ASTM Standards.
4. ASTM D1117-01 (1999) Standard Guide for Evaluating Nonwoven Fabrics. American
Society for Testing and Materials (ASTM).
5. ASTM D4751. Test Method for Determining Apparent Opening Size of a Geotextile.
6. ASTM D5729-97 Standard Test Method for Thickness of Nonwoven Fabrics.
7. ASTM D5736-95 Standard Test Method for Thickness of Highloft Nonwoven Fabrics.
8. ASTM D6767-02 Standard Test Method for Pore Size Characteristics of Geotextiles
by Capillary Flow Test.
9. ASTM F316-03, Standard Test Methods for Pore Size Characteristics of Membrane
Filters by Bubble Point and Mean Flow Pore Test.
10. ASTM F960-86 (2000). Standard Specification for Medical and Surgical Suction and
Drainage Systems.
11. ASTM Standards (1999). ASTM Standards for Textiles. American Society for Testing
and Materials (ASTM).
12. ASTM Test Methods for Geotextiles. http://www.usfabricsinc.com/specifications/
astm. Accessed on May 23, 2015.
13. Aydilek AH, Oguz SH, Edil TB (2002). Digital image analysis to determine pore
opening size distribution of nonwoven geotextiles. J. Comput. Civ. Eng., 16(4): 280–
290.
14. Bhatia SK, Smith JL (1996). Geotextile characterization and pore size distribution,
Part II: A review of test methods and results. Geosynthet. Int., 3(2): 155–180.
15. BS 6906-2:1989 Methods of test for geotextiles. Determination of the apparent pore
size distribution by dry sieving.
16. BSEN ISO 12956: 1999 Geotextiles and geotextile-related products. Determination
of the characteristic opening size.
17. Bugao Xu (1996). Measurement of Pore Characteristics in Nonwoven Fabrics Using
Image Analysis. Cloth Text Res J 14(1): 81–88.
18. CEN, EN779:2002 E, Particulate Air Filters for General Ventilation- Determination
o1 the Filtration Performance, European Standard, 2002.
19. Chatterjee K, Gupta BS (2002). Absorbent Technology. Elsevier Science B.V.
20. Chen HJ, Huang DK (1999). Online measurement of nonwoven weight evenness
using optical methods, ACT paper.
21. Chhabra R (2003). Nonwoven Uniformity – Measurements Using Image Analysis,
Intl. Nonwovens J. 12(1): 43–50.
Testing of nonwovens 209
22. Chuleigh PW (1983). Image formation by fibers and fiber assemblies. Text. Res. J.,
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23. Contact Angle Measurement System. https://nanolab.berkeley.edu/labmanual/
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24. Dierickx W (1999). Opening size determination of technical textiles used in
agricultural applications, Geotext. Geomembr., 17(4), pp. 231–245.
25. EDANA (2012). Standard test methods for nonwoven industry. EDANA.
26. Giovanni Tanchis (2008). The Nonwovens. ACIMIT, Italy.
27. Hassan M. Behery (1993). Characterization and Testing of Nonwovens with Emphasis
on Absorbency (Chapter 10) In Nonwovens--Theory, Process, Performance & Testing
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analysis techniques, Part III: Web Uniformity Analysis. Int. Nonwovens J 5(3): 28–
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on April 12, 2015.
30. Irwin Hutten (2007). Handbook of Nonwoven Filter Media. Elsevier Science &
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31. ISO 9073 Standards for Test methods for nonwovens (1989), ISO.
32. ISO 9092:1988; BS EN 29092:1992.
33. Jianying Shang, Markus Flury, James B. Harsh, Richard L. Zollars (2008). Comparison
of different methods to measure contact angles of soil colloids. J Colloid Inter Sci.
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34. Kallmes OJ (1969). Techniques for determining the fiber orientation distribution
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210 Nonwoven: Process, structure, properties and applications
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response to garments and its relationship to fabric properties. Text Res J 75: 531–541.
6
Applications of nonwovens
Abstract: This chapter provides the detailed information about the application
of nonwoven in different application fields. The application potential of nonwoven
in apparel sector and its advantages and challenges are discussed in detail. The
application of nonwoven in agriculture like mulching, weed and root control and
in geo textiles for separation, filtration, drainage and reinforcement applications
were also discussed. The applications of nonwoven in medical & hygiene sector,
automotives, wet and dry filtration areas, roofing and construction and in home
textiles are also discussed in detail.
Key words: Nonwoven, geotextiles, automotive, apparel, filtration, medical,
hygiene
6.1 Introduction
As per the research report in light of the worldwide business sector for
nonwoven materials and products, published by US-based Transparency
Market Research, the nonwoven business will develop at a CAGR of 6.7%
between 2013 and 2019. The nonwoven market, which earned incomes worth
US$28,783.8 million in 2012, will hoard incomes worth US$45,363.7 million
in 2019 (Zhang 2007; Zhang 2011). The report articulates that an expanded
worldwide interest for nonwoven materials and items from the medical and
health care industry is generally in charge of the unfaltering development of
the business sector sooner rather than later.
The nonwoven products are categorized into polypropylene, nylon,
polyester, bi-component fibers, nano-strands and cellulosic. Of these,
polypropylene nonwoven fabric held the biggest share of business sector income
and had total assets of US$16,438.7 million in 2012. A tremendous application
base of polypropylene nonwoven fabrics in the worldwide business sector will
keep on heightening its demand, prompting the segment’s development at a
CAGR of 6.7% somewhere around 2013 and 2019 to achieve a business worth
of US$25,808.2 million by 2019 (Zhang 2008). The nonwoven application is
further divided into disposable and durables. Of the key application of nonwoven
materials and products, durables gathered the biggest offer of income gained by
the business in 2012. This segment created income worth US$17,716.0 million
in 2012 and is relied upon to achieve US$28,335.6 million in 2019, enrolling a
CAGR of 7.0% between 2013 and 2019 (Ahmed & Zaman 2007).
212 Nonwoven: Process, structure, properties and applications
Applications of nonwovens
• Reinforcements • Floor-coverings, • Anti-slip matting,
and high quality protection and lifting and pulling
wallpapers composites
213
• Protective apparel, control,
• Bedding and • Cleaning and filtration
sheets and masks
214 Nonwoven: Process, structure, properties and applications
Road and Head liners, Carpets, wall Shoe, bags, Shoulder Polishing felts, abrasive
railway door trim, coverings, sport goods pads, felts, mineral fiber felts for
construction, parcel shelves, decor waddings, insulation
dams, roofing carpets, felts, wipe, mattresses
and drain felts, insulation felts, blankets
shore protection gas filters
Spunlace nonwovens
Surgical gowns Wound Baby wipes, Cleaning wipes, Industrial Headliners, Interlinings,
and drapes, dressings, facial clean protection fabric wipes, cleaning Coating
operational gauze, wet wipe, face for electronics, filtration, wipes substrates
cover sheets, tissue, cotton masks, home furnishing roofing, water for synthetic
bed sheets, products, pads disposable fabrics, table insulation, leather
towels pants cloths and protective
napkins, apparel, liquid
curtains absorbents
Stitch-bonded nonwovens
Interlining Some types Filling in quilted fabrics, for duvets, for some upholstery
fabric for of filter fabric,
textile clothing, in some cover
disposable/ stock and in
protective wiping cloths
clothing
Composites Interlinings, Food Cover stock for sanitary products, wiping cloths
and laminates Carpet coverings,
backings tea bags
Applications of nonwovens 215
Few of the nonwoven fabrics developed with various kinds of fibers are
mentioned below:
• Cotton-polyester blended nonwoven fabric
• Polyester nonwoven fabric
• Silk nonwoven fabric
• Wool nonwoven fabric
• Polyester durable nonwoven fabric
A 100% polyester nonwoven fabric can be manufactured from nonwoven
web subjected to hydro-entanglement process. The nonwoven web is then
gone through an image processing element which imparts a final design to the
web. The web is passed through a three water jet nozzle sections at a speed of
around 35 ypm (yards per minute) and at 150 bar entangling pressure. After
hydro-entangling or spun lacing process, the binder which contains elastomeric
mixture is applied while the web is passed through an application station.
The web is then passed through a sequence of drying organized one over
the other which are worked at around 310°C. Before utilization of nonwoven
fabric for garment manufacturing process, the fabric should be pre-treated
with a softening agent followed by jet dyeing and mechanical compaction
to a level of 7%. Mechanical finishing treatments like sanforizing, sueding,
napping, etc., can be carried out prior to or subsequent to printing and dyeing
(Kasemeyer 2007; Lamb & Costanza 1975).
6.3.2 Mulching
The nonwoven mulching fabric aids the farmers to save valuable fruits,
flowers and vegetables. Normally, spunbond nonwovens are best suited for
220 Nonwoven: Process, structure, properties and applications
this kind of applications. The nonwoven mulching fabric spread on the soil
is shown in Figure 6.6. Nonwovens made form polyester and polypropylene
with very low open area and reasonable strength are generally utilized.
The gap between the intersecting fibers of nonwoven fabrics are large
enough to permit air and water to enter the fabric and contact the crop;
Applications of nonwovens 221
however, sufficiently little to keep out insects. The shielding allows plants
and crops to grow without the need to utilize pesticides and herbicide.
Synthetic fibers are the preferred raw material for agricultural products.
Polyester and Polypropylene are two main fibers utilized in agrotech because of
the superior strength and flexibility. The utilization of spunbonded nonwovens
is growing in agrotech compared to woven fabrics. The bonding method
mostly used is needle-punching since needle punched nonwoven fabric is
flexible with adequate strength and higher elongation. They can be produced
with a superior control on the porosity and permeability of the fabric.
6.3.7 Containers
Nonwoven carriers for saplings and young roots are an important end use.
The controlled air and water permeability of spunbonded nonwovens and
laminated nonwovens (Meltblown, net el with spunbond) is an important
use for critical application. Nonwoven material also allows proper moisture
balance in the roots during storage.
moisture barrier for roads and railways off shore land reclamation, road side,
rail side, river and canal banks and reservoirs.
The three principle properties required for geotextiles products are its
mechanical characteristics, filtration capacity and resistance to chemicals.
The mechanical response of a geotextiles depends on the orientation and
uniformity of the fibers. Chemical resistance of fabric rely on the size of the
individual component fibers and their chemical composition. Generally, finer
fibers offer higher the surface area which is more susceptible to chemical
attack. But filtration capabilities of the material are better when fine fibers
with high surface area are used (Zornberg & Nathan 2012).
Table 6.3 Application of nonwovens and fibers in different fields of medical textiles
(Source: Chinta & Veena 2013)
Disposability is the primary reason for the hospitals and operating rooms
to desire nonwoven compared woven fabrics. Nonwoven used in gauze pad
must absorb exudates, protect from contamination, mitigate from trauma.
Normally, nonwovens used for medical textiles offer exclusive antimicrobial
activity (Kamran 2009; Chinta & Veena 2013). It provides improved protection
for the wearer and less possibility for cross contamination. Disposable mask is
expected to protect 98% of the bacteria from getting into the wearer, and it must
not lead to skin irritation; hence composite nonwoven structures such as SMS
are used. Surgical gown must protect from hazardous substances and should
provide water resistance with GSM less than 35 (Ahmed 2007). The composite
nonwovens are utilized in the application areas like gowns, laboratory coats,
coveralls and other type of protective clothing. They should shield blood or
infectious material from passing through under various ambient conditions. It
should have better tear resistance, burst strength, abrasion resistance, cracking
resistance, barrier properties and water vapor transmission (Ghosh 2000).
The raw materials used to manufacture medical nonwovens comprise
fiber, filament and antimicrobial finishes. Fibers used for medical nonwovens
should be non-toxic, non-allergic, non-carcinogenic and should be sterilized
without leading to any changes in the physical or chemical characteristics
(Yokura & Niwa 2000). By keeping the desired properties onto the product
in mind, combination of natural as well as synthetic fibers could be used.
228 Nonwoven: Process, structure, properties and applications
Natural fibers are used for its superior absorbency, for example wood pulp is
used in huge amounts because of its high absorbency and low cost (Russell
2007; Chapman 2006). Synthetic fibers are used due to its higher strength,
resistance to solvents and antimicrobial properties. Further, micro fibers are
used in medical nonwovens due to its better barrier properties, flexibility and
smooth surface. Cotton fiber is extensively used in medical nonwovens owing
to its high absorbent character.
The most prominent systems for manufacturing of medical nonwovens
are spunbonding, meltblown and their composites in specific end uses.
Spunbonding process is used when higher strength webs are desired.
Spunbonded fabrics are strong in machine direction as well as in cross
direction. These fabrics are soft, porous and dimensionally stable.
Spunbonding is commonly used for products such as face masks, head wears,
shoe covers, bed linens and disposable clothing etc. Dry-laid, wet-laid and
carding are utilized for production of different web properties depending on
web thickness necessary, speed of bonding technique to be used etc. (Russell
2007; Zhang 2006a & b).
It might be noticed that manufacturing methods are distinctive with
different products, for instance for therapeutic outfits, drapes spunlacing
process is primarily used to give absorbency and to show low linting behavior.
Generally speaking, in medical nonwovens, polyester for its strength and
thermal stability and polypropylenes for its hydrophobicity and cost is
exceedingly utilized (Cusick & Hopkins 1990). These fibers are bonded with
composite nonwoven process (SMS) since it gives better barrier properties in
protective mask and clothing.
about 10 μm and the GSM between 10 and 100 g/m2 based on the method of
manufacture, configuration of the web, the cross-sectional shape of the fiber.
• Cleansing pads: These are fiber sponges which are soaked with
water, alcohol or other active ingredients prior to use for a specific
endues application.
• Pain relief: These kinds of pads are normally saturated with alcohol
and benzocain and are useful for treating minor scrapes, burns, and
insect bites.
• Personal hygiene: These wipes are generally pre-moistened and
are available in individual pack or one larger container that can be
resealed.
• Pet care: Wet wipes are available for pet care like eye, ear, or dental
cleansing pads for dogs, cats, horses, and birds.
6.5.6.2 Household and home cleaning wipes
• Kitchen wipes
• Bathroom wipes
• Food service wipes
• Glass surface cleaning wipes
• Automotive care wipes
6.5.6.3 Industrial cleaning wipe
• Degreasing / machinery cleaning wipes
The three vital nonwoven technologies encouraging the growth of wipes
segment are airlaid, spunlace (hydro-entanglement) and SB-MB laminates.
Wipes are generally produced from spunlaced nonwoven fabrics from
polypropylene in blend with viscose/rayon in the GSM between 30 g/m2 and
70 g/m2 which may be saturated with an antiseptic finish (Zhang 2006a, b, c).
were given Figure 6.10 and the specific technology used for the production of
the same is given in Table 6.4.
(1) Door and side panelling; (2) Underbody covers; (3) Airbag covers; (4) Floor and footwell
covers; (5) Rear of seat; (6) Brake disks; (7) Textile wheel-arch liners; (8) Exhaust systems; (9)
Filters; (10) Engine insulation; (11) Turbocharger; (12) Battery; (13) Side and rear door panelling;
(14) Rear parcel shelf; (15) Stowage compartment cover 16 A- and C-columns; (17) Headliner;
(18) Sunshade; (19) Dashboard; (20) Bonnet covers; (21) Floor of boot, spare wheel cover
Figure 6.10 Application of nonwoven in a car (Source: https://www.groz-beckert.com)
6.6.2 Carpets
A huge quantity of nonwovens for automotive fabric involves usage of carpets.
As most carpets in automotives and light trucks in the NAFTA (North American
Free Trade Agreement) countries are of tufted pile fabrics, nonwovens play a
vital role as primary or secondary backing materials. Several newer needled
carpets include patterning and velour structures produced on the needle looms.
Presently, 47% of carpets uses nonwovens, with tufted carpets contributing to
49% and special combination products about 8% (Kemper & Hobi 2003).
6.6.4 Acoustics
One of the oldest application areas of nonwovens in automobiles is the sound
insulation. Impregnated jute materials have been used in earlier days in the
automobiles for damping of sound. The promising area for sound insulation
material in automotives is the hoodliner. In the past the hood liners are generally
made of a glass mat covered with plastic film but hoodliners in modern cars
are made of a blend of micro-denier and conventional fibers and moulded to
shape to match the engine and compartment to which it is fixed. It is predicted
that 40% of the sound/noise, for example, comes from the interaction of tires
on the road (Bõttcher 2002). Special nonwoven wheel well inserts have been
developed and engaged as standard equipment to minimize that noise.
6.6.5 Filtration
The oil and air filters in automobiles are well known but a key growth area
in automobiles is in the cabin filtration. Cabin filters which are typically the
electret, charged-ion type, will perform better in filtering out mildew, pollen,
and airborne particulates. Air and oil filters used earlier were treated paper;
however, now use of spunbond, dry-laid, spunlace nonwoven materials is
often used. The selection of materials and type of nonwoven depends on
the chemical nature of the fluid or material being filtered. Nonwovens are
also found application in battery separators for lower cost, better efficiency,
and longer battery life. The gaskets and seals which are vital for engine
performance also use nonwovens in many areas, as do brake and friction
components.
6.6.6 Safety
Safety is a mounting concern in automobiles. Numerous research works has
been carried out in flame retardant materials. Nonwovens could be easily and
economically treated to get the flame retardant property. A few high hazard
areas may need specialized products, such as aramids which are inherently
flame retardant. The majority of polyester and polypropylene can be treated
for FR (Flame retardant) and are efficient and effective in use. Airbags and
seat belts have been key growth areas.
surface (Tsai 1998). On one side of the filters, the particles can congest and
block the filters, leading to high fluid resistance across the filter, the point
when it needs a cleaning. This layer of substrate is normally called as a filter
cake. To avoid particles smaller than the pore size of filter from passing
through the surface filter, the surface of filter should be coated with a pre-coat
medium chosen to collect fine particles.
In case of depth filtration, a particle enters the filtration medium and
becomes ensnared within its structure (Freudenberg 2009; Tsai & Wadsworth
1994). This could take place even when the size of the particle is smaller
than the pore at that particular point. These kinds of filters are generally
more difficult to clean compared to surface filters, hence they are regularly
used in processes where the filter medium can be removed. These filters are
commonly utilized where there is a large difference in particle size.
• Basis weight
• Pore size/distribution
• Thickness
• Solid volume fraction (SVF)
• Porosity (P)
• Density
• Permeability
• Surface texture
• Moisture absorption capacity
• Flammability behaviour
• Strength and drape
• Electrostatic behaviour
• Chemical, thermal and biological stability of the materials
The following are the advantages of nonwoven fabrics over woven fabrics
in filtration:
• High permeability
• Higher filtration efficiency
• No yarn slippage
• Good gasketting characteristics
• Good cake discharge
areas are due to the fact that the nonwovens could be designed to have flame
retardant and anti-microbial properties (Assent et al. 2003; Chapman 2006).
Nonwovens are used in the production of mattresses as support and
insulation materials, as external coverings and as replacements for traditional
foams. Nonwovens are used as internal support and covering materials in
mattresses. Nonwoven utilized in this segment involves chemically bonded
polyester wadding, thermally bonded nonwovens and nonwovens laminated
with woven or knitted fabrics to give higher dimensional stability. Polyester
or polypropylene filament nonwovens are increasingly used to replace plain
weave cotton fabrics as mattress covers. Because of fire and health dangers
connected with polyurethane foam, nonwovens are increasingly being used as
a replacement material in the construction of mattresses. Nonwovens and fiber
fillings are frequently used within the production of pillows, quilts and duvets
(Chapman 2006; Stein & Slovacek 2003).
such as pile, tufting substrate (primary backing) and a secondary backing. The
primary backing is placed between the carpet pile and the secondary backing
and is normally manufactured using polypropylene and polyester in spunbond
processes.
and minimize the number of plastic bags being used. Examples of nonwoven
materials used in packaging materials are
• Beverage packing
• Breathable bags
• Canisters
• Confectionary packaging
• Envelopes/file folders
• Flow wraps
• Flower wrap
• Food pads
• Fruit liners
• Hazmat transport aids
• Individual packets
• Industrial bags
• Insulator materials
• Meat packaging trays
• Medical sterile packaging
• Separator sheets
• Tubs
• Vegetable packaging trays
References
1. Adanur S (1995). Wellington Sears Handbook of Industrial Textiles. Technomic
Publishing, Co. Inc., Lancaster.
2. Ahmed AI (2007). Nonwoven fabric finishing. Russell SJ (ed.) in Handbook of
Nonwovens. Woodhead Publishing Limited, Cambridge.
3. Ahmed N, Zaman N (2007). Pakistan lags behind in Technical Textiles. J Manage Soc
Sci 3(2): 120–127.
4. Assent HC, Hasse J, Stoll M, Brodtka M (2003). Nonwovens for Apparel. Albrecht
W, Fuchs H, Kittelmann W (eds) in Nonwoven Fabrics, Raw Materials, Manufacture,
Applications, Characteristics, Testing Processes. Pp. 523–544, Wiley-Vech,
Weinheim, Germany.
5. Aydilek AH, Oguz SH, Edil TB (2005). Constriction Size of Geotextile Filters, J
Geotech Geoenviron Eng 13(1): 28–38.
6. Backer Stanley, Petterson Dewitt R (1906). Some Principles of Nonwoven Fabrics.
Text Res J 30: 704–711.
7. Barrillon J (2005). Automotive filtration: A new horizon for nonwovens. Filtr Sepa 11:
28–30.
246 Nonwoven: Process, structure, properties and applications
48. Zhang D (2006c). The Future of Antimicrobial and Antibacterial Wipes. Pira
International Ltd, U.K.
49. Zhang D (2007). The Future of Global Markets for Nonwoven Wipes to 2011. Pira
International Ltd, U.K.
50. Zhang D (2008). The evolving roles of nonwovens in technical textiles. Nonwoven
Indus 98–113.
51. Zhang D (2011). The Future of Global Nonwoven Markets: strategic five-year
forecasts. Pira International Ltd, U.K.
7
Composite nonwovens
Abstract: The chapter deals with the composite nonwoven (CN) materials, their
significance, manufacturing technology, properties and application fields. The
types of composite nonwoven such as complex composite nonwovens, laminated
composite nonwovens, coated composite nonwovens, blended composite
nonwovens, technology-combined composite nonwovens have been discussed
in detail. Different technologies for manufacturing of composite nonwoven like
multi-forming, multi-beam, multi-bonding, particulate composite nonwoven and
hybrid method have also been discussed in this chapter. The application areas
of composite nonwoven in medical and hygiene sector, industrial filtration and
insulation have also been provided.
Key words: composite nonwoven, laminated composite, multi-form, multi-bond,
laminated composite, hybrid composite, particulate composite
7.1 Definition
The composite nonwovens are known as a macroscopic blend of two or
more dissimilar materials often with a recognizable interface between
them. A composite is considered as a multiphase material produced from a
combination of materials which differ in composition; stay bonded together,
and maintains their identities and properties. The composite nonwovens (CN)
are generally roll goods produced from two or more layers when the vital part
of a composite could be identified as a nonwoven.
CEN 29092 and ISO 9092 have defined the composite nonwoven (CN)
as ‘composite structures are considered nonwovens provided their mass
is constituted of at least 50% of nonwoven structures or if the nonwoven
component plays a prevalent role’. As per EDANA, composite nonwoven
term is used when the critical part of the composite is made of a nonwoven.
Hutten (2007) has defined composite nonwovens as ‘nonwoven products
that are produced by a combination of two or more different web formation
technologies in order to optimise the characteristics of the product’. Based on
this definition, it is presumed that the nonwovens produced from combination
of fibers of different sources but similar physical properties or produced from
combination of fibers of the same source but different physical properties can
be termed as composite nonwovens. The composite nonwovens (CN) can be
produced from (Das et al. 2012):
250 Nonwoven: Process, structure, properties and applications
Further, a divider can be utilized to separate the card line feeder into
sections which provides possibility of introducing two different colored fibers
to the card side by side. After the cross-laying process was completed, the
multi-layered nonwoven was needled and thermally bonded as shown in
Figure 7.2.
Figure 7.2 Single stage multi-layered nonwoven using divider in card line
(Source: http://www.emsgriltech.com/)
Figure 7.5 Modified headbox system for improving the integrity of layered nonwoven
(Kajander et al. 2012)
256 Nonwoven: Process, structure, properties and applications
fiber spinning lines, which are combined to produce multiple layers (Figure
7.7) that are finally bonded together to make a nonwoven composite structure.
On the other hand, multiple extruders could be used in the same fiber-spinning
machines (Figure 7.8). After combining the layers, bonding was carried out by
passing them through a set of heated rollers, in which one roller may be smooth
and the other having a plurality of raised points to make a patterning effect.
Figure 7.9 shows a Scanning Electron Microscope (SEM) image of a SMS
nonwoven structure.
Figure 7.9 SEM image of SMS nonwoven structure (Das and Pourdeyhimi 2014)
Several structural combinations like SM, SMS, SMMS and SSMMS are
achievable by just changing the position of spunbond and meltblown layers
and by altering the number of layers. These structures are generally self-
bonded composite media, but sometimes they may be thermally bonded also.
CoForm® process
it solidifies. As the synthetic fiber solidifies (cooled), the wood pulp fibers and
other external materials if any added, will adhere to the synthetic fiber structure
(Das and Pourdeyhimi 2014). After that, a preformed meltblown structure is
thermally laminated to one side of the CoForm® layer to produce an absorbent
composite structure (Figure 7.10). The application of CoForm® includes wipes,
feminine hygiene products, diapers and adult incontinence products.
Other processes
Apart from the above two methods, several techniques are available to produce
layered composite nonwovens. Few of them are listed below:
• A three-layer composite nonwoven, one from wood pulp (absorbent
layer), second layer from wet-laid process and third layer from
spunbond process can be combined and bonded by spunlace process
to produce absorbent nonwoven with more strength (Homonoff et al.
1992).
• Cotton-based layered composite nonwoven could be produced
by sandwiching the spunbond web in-between two carded cotton
nonwoven fabrics where the outer cotton layer provides functionality
while the core spunbond layer offers strength and stability of the
composite nonwoven (Chatterjee & Gupta 2002). On the other hand,
cotton carded web could be sandwiched between two spunbond
structures (Sun et al. 2000; Suskind et al. 1989).
• Some of the commonly used layered composite nonwovens are
spunbond–pulp–spunbond (SPS), carded–pulp–carded (CPC),
carded–pulp–spunbond (CPS) and carded–spunbond–carded (CSC).
The main application area of nano fiber layer composite structures are
• High performance filter media (air, liquid)
• Li-Ion battery separator with polymer/ceramic composite nanofiber
technology
• Tissue engineering
268 Nonwoven: Process, structure, properties and applications
fibers to the base nonwoven substrate by melting the adhesive powder. The
thermoplastic co-polyamide powder having a melting temperature of 80–
90°C was deposited onto the base nonwoven substrate in the form of dots by
means of screen printing at distances going from 5 to 20 mm and bonded to
the viscose nonwoven by means of infra red bonding method. Subsequently,
the electrospun nylon 6,6 nanofibers are deposited over the adhesive powder
and hot melt laminated at 110°C for 5 seconds to fuse the fibers to the base
nonwoven substrate by melting the adhesive powder. The SEM micrographs
of nylon 6,6 nanofibers thermally bonded onto the viscose nonwoven substrate
are shown in Figure 7.22.
Figure 7.22 SEM micrographs of nylon 6,6 electrospun fibers thermally bonded onto
viscose nonwoven (Faccini et al. 2012)
Figure 7.23 Particulates incorporated within the base substrate (Baer 2004)
Figure 7.24 SEM images of bonded particles between two nonwoven structures
(Baer 2004)
Numerous research works has been carried out by Nowicka (1993, 1994,
and 1995) in particulate composite nonwoven structures with powder-sorbent
particles such as active carbon, aluminium oxide, chitosan, etc. in meltblown
technology. These particulates are incorporated during meltblown process
using special dosing method. The particulates are bonded to the micro-fibers
on their way through probably due to the plasticity of micro-fibers which does
not require any binding agents. The micro-fibers (0.5–10 μm) from meltblown
process offer higher number of contact points with particulates leading to better
binding (Nowicka 2003). The composite nonwoven structure comprising of
elastomeric nanofibers along with one kind of active particle for the application
as protective garments has been reported by Kalayci et al. (2008).
The skin decontamination kit which serves the dual purpose of physical
and chemical decontamination of the toxic agent has been developed using
a particulate technology which comprises of six individual pockets of
carbonaceous reactive powder in a nonwoven matrix structure. The particulate
decontamination material in each pouch is a combination of adsorbent carbon,
polystyrene polymer and an ion-exchange resin (Lukey et al. 2004). James et
al. (2013) from 3M Innovative Properties Company has invented a nonwoven
abrasive wheel consists of one or more layers of a nonwoven fiber web and
a plurality of super abrasive particles which are bonded to the nonwoven
substrate by means of polyurethane binder. The developed nonwoven abrasive
wheel has a flexural modulus from 4.0 to 128.0 lb/inch of thickness per inch of
displacement.
7.5.1.1 Wipes
According to EDANA, the industrial wipes are defined as “disposable
nonwoven products used for a variety of applications in industry ranging
from heavy duty cleaning to fine polishing” for that the disposable wipes
are single use products or limited use products that become waste material
after use. The main advantages of using nonwoven structures in wipes are
disposability, engineered for specific applications and needs, flushability,
higher convenience, high quality level, lower risk, versatility, wide choice of
materials and manufacturing processes (Zamfir 2010).
The composite nonwoven wipes have higher abrasion resistance, high
wet and tear strength and increased barrier protection compared to single
layer conventional nonwoven structures. By using the composite nonwoven
structures, the strength and durability of lightweight products, softness,
absorption and strength and ability to form shapes by using an elastic film
as one of the layers can be achieved. By changing the nonwoven layers with
different fibers and properties, the strength, softness, opacity, texture and
stiffness of the composite nonwoven product could be altered without change
in the basis weight.
The industrial wipes are normally intended for liquid and oil absorption.
The liquid absorption is offered by natural fibers such as cotton, rayon and
wood pulp whereas oil absorption is provide by olefin fibers and polyester. One
example of composite structure in wipes is produced from CoForm® process
where 60–70% dry-laid wood pulp core is held by 30–40% polypropylene
meltblown structure (Anderson et al. 1978). The oil absorption wipes are
generally produced from 100% polypropylene microfibers and often to
enhance the durability of wipes micro-fiber layer form meltblown process
is combined with the spunbond coarser polypropylene layers (Adam 1997;
McCulloch & Brederode 1981) .
Composite nonwovens 273
inexpensive, readily available, and versatile enough to find utility with many
wound types. The composite nonwoven dressings provide higher absorbency,
conformability, softness and bulkiness and are relatively lint-free compared to
conventional gauze dressings (Dyer et al. 1992).
Conventional composite dressings consist of three main layers such
as non-adherent hydrating layer (hydrogels, alginates, hydro fibers), an
absorbent cushioning layer made of composite nonwoven and a polyurethane
membrane to impart strength. These layers in total make the dressing easy to
apply and remove and more durable than any of the components used alone
(Qin 2009). Most of the current wound dressings are laminated structures
comprise of four elements: a non-adherent wound-contact layer, a wicking/
transmission layer, a diffusion layer and a backing layer (bacterial barrier and
moisture-vapour/gas-permeable film. The composite nonwoven dressings
having super-absorbent powders, particles and fibers, along with hydrophilic
and hydrophobic fibers could resulted in efficient absorbent cores in wound
dressing (Pieniak 1985; Iskra 1986). To enhance the conformability and fit
of composite dressings, efforts were made to incorporate elastomeric films,
elastic meltblown aromatic polyether urethane nonwoven membranes and
elastomeric moulded copolymers into nonwoven fabrics used in wound
dressings (Taylor & Collier 1987; Morman & Wisneski 1987).
Face masks
Generally, the construction of face masks similar to surgical gowns has SMS
nonwoven structure. Two to three layers of polypropylene nonwovens are
sandwiched together to make facemasks along with a pleated face to enhance
the surface area. Numerous designs of respirator mask are developed using
advanced strategies for the multiple- use of masks. The four-ply nonwoven
needle-punched face mask having two outer layers consists of silver/copper
zeolite compounds incorporated onto the fibers and remaining two inner
filtration layers designed to protect from microbial or particulate penetration
has been developed by Carey International Ltd, Westerly, RI, USA.
Incontinence products
Composite nonwoven structures used in incontinence products are categorized
as:
• Baby care products: Baby nappies and baby wipes (dry or moisturized)
• Feminine hygiene products: Sanitary napkins, panty shields and
liners
• Adult incontinence: Adult nappies, nursing pads, disposable
underwear, bladder control pads
Contd...
Composite nonwovens 277
Contd...
fibers links are created by the needles from the cut fibbers which are already
present in the nonwoven structure. The machine adjustments permit accurate
control of structure thickness from 3 mm to 50 mm (Guigou-Carter et al.
2008).
Figure 7.31 3D Napco structure with PCM granules (Guigou-Carter et al. 2008)
Composite nonwovens 281
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8
Natural fiber nonwovens
Abstract: In this chapter, natural fibers like cotton, flax, jute, hemp, kenaf,
milkweed, pineapple, abaca fiber, sisal fiber wool and kapok fiber are reviewed
for their potential applications as nonwoven material. The chapter also reviews
and summaries the various researches initiated with natural fiber nonwovens in
different field of applications like sound absorption material, soil erosion control
material, medical and technical textile, filtration media, etc.
Key words: natural fiber, nonwoven, oil sorption, filter media, sound absorption,
soil erosion.
8.1 Introduction
Nonwovens showed up in the 1940s, and were later created with diverse
progress in different nations. Nonwovens innovation was further enhanced
and grew, especially concerning bonded nonwovens taking into account
important compound fibers and engineered bonding techniques encouraging
production of better and more helpful items for specialized use, apparel
and family utilization. Nonwovens have an extensive variety of utilizations
from furniture to the geo- and chemotextiles. Nonwoven fabric is a kind
of fabric which can be created by different procedures other than weaving
and knitting. Durable applications business is the biggest application region
for nonwoven materials and items followed by expendable applications
market. Durable applications incorporate home furniture, divider blankets,
covering substrates, clothing interlinings, material items and geo-materials.
Dispensable applications incorporate grown-up incontinence items, child
diapers, expendable wipes, feminine hygiene products, cloths, restorative
or surgical items, channels, filters, disposable garments and fabric softener
substrates. Additionally, durable applications business sector is the quickest
developing business for nonwoven materials and items. Automotive sector
is another growing potential for nonwovens. More than 40 noteworthy
applications have been distinguished and all the more new end uses are being
produced on a persistent premise. The rising worldwide interest for therapeutic
expendable supplies is required to be the significant driver for the developing
utilization of nonwoven materials and products. Nonwoven materials and
product business is relied upon to develop at a CAGR of 5.9% from 2013 to
2019 (www.Transparency market research.com).
286 Nonwoven: Process, structure, properties and applications
In the last decade, there has been a growing use of natural fibers such
as hemp, kenaf, pineapple, abaca, flax, coir, etc., in the form of nonwovens
or short fibers (Neira & Marinho 2009; Parikh et al. 2006; Reddy & Yang
2010). The potential of natural fiber nonwovens opens a wide variety of new
applications in the textile industry (Parikh, Chen & Sun 2006; Soukupova,
Boguslavsky & Anandjiwala 2007). Also, uses in other technical sectors, such
as automotive, are attractive. Natural fibers are found in nature or produced
naturally available material from plant and animal sources. The dominant
part if the natural fibers are plant based and fit in with the ligno cellulosic
classification. Cotton is common lingo cellulosic fiber that contains around
85% cellulose and 1% of lignin. Flax, kenaf, jute, hemp, coir and sisal
are different sorts of lingo cellulosic fibers that contains lower measure of
cellulosic and higher (5–20%) measure of lignin contrasted with cotton. By
and large, they are coarser and more grounded than cotton. Flax has properties
similar to cotton yet better quality and modulus (Rajesh et al. 2007).
Natural fibers
Organic Inorganic
Figure 8.2 Oil sorption capacities of various natural fibers (Source: Choi and Jerry 1993)
Other researchers result showed that the oil sorption capacities of natural
fibers are in the order of milkweed > kapok > cotton > wool > kenaf. With
the exception of kenaf, all natural sorbent materials sorbed more than 30 g oil
per g fiber in the simulated seawater bath. Milkweed showed the highest oil
sorption among the sorbents examined. Kenaf fiber sorbed only 5.6 g oil per
g fiber (Choi and Jerry 1993). Figure 8.2 represents the oil sorption capacities
of various natural fibers demonstrated by Choi and Jerry (1993).
Natural fiber nonwovens 289
Table 8.1 Comparative properties of flax and other high modulus synthetic fiber
(Source: Kers et al. 2009; Subhankar Maity et al. 2014)
demonstrate that mats produced using 100% flax and 75%/25% flax/cotton
mixes were like one another and fundamentally preferred at copper particle
retention over 100% cotton or 50%/50% flax/cotton mixed nonwoven mats
(Marshall et al. 2007).
The flax fiber materials (fabrics, nonwovens) were also used in medical
purpose like cancer and wound healing etc. (Janarthanan 2012). The medicinal
uses of flax promotes heart health, lowers cholesterol, protects against strokes,
lowers blood pressure, used for constipation, helps guard against breast
cancer, and other cancers (Sen et al. 2011). The flax filaments could act as
an antimicrobial material, which could be of interest not just in manufacture
of sterile and therapeutic articles, additionally of industrial materials.
Assembling of items for medicine, health, and cosmetology is turning into a
standout amongst the most developed segments in the structure of generation
of nonwovens, so that alteration of flax strands to make naturally dynamic
dressings is of undoubted scientific and practical interest. Researchers also
found that the spunlacing method helped the flax/PP nonwoven to grow the
end use for auto interiors with specific specialized benefits. The developed
nonwoven material were of improved tensile and flexural strengths, lesser
thick with controllable weight, higher noise absorption coefficient and
enhanced nonwoven flexibility along with fogging execution (Chen et al.
2008).
The flax nonwoven materials were discovered for their solid capacity to
absorb sound wave. In a study by Fages et al. (2013), flax fibers were mixed
manufactured with binder fibers and nonwoven structures were made by wet-
laid and subsequent thermal bonding. In general the acoustic assimilation
at low frequencies (underneath 300 Hz) is low for these nonwovens, with
retention coefficients in the 0.05–0.2 range. As in the case of flax: PVA
nonwovens, the absorption coefficient increments up to estimations of around
0.4–0.5 in the 300 Hz to 2 kHz frequencies reach, showing intriguing and
truly homogenous acoustic protection properties. For the spun laced flax/PP
nonwoven boards (after hot-squeezing), the sound absorption coefficient was
dependably beneath 0.3 inside of the entire testing scope of sound recurrence.
The sound protection test performed by the impedance tube instrument
uncovered that the spun laced flax/PP nonwoven boards behaved as a typical
isotropic slight board with the reverberation frequencies of 366 and 354 Hz
and the fortuitous event frequencies of 3576 and 3762 Hz relating to two
distinctive machine settings for the spunlacing procedure (Chen et al. 2010).
There likewise are other potential composite applications for flax in
sports equipment. As a support layer in tennis racquets, spunlaced flax is
lightweight and assimilates vibrations, and the surface designing potential
292 Nonwoven: Process, structure, properties and applications
Table 8.2 Potential end uses of jute-based nonwovens (Source: Maity et al. 2013)
at the posterior for support and coarse denier polypropylene/ acrylic fiber is
utilized on top for aesthetic appeal and smooth appearance, keeping thick
layer of jute fiber in the middle for strength (Sengupta et al. 1985).
The previous research studies had showed that the jute needle-
punched nonwovens were utilized in various applications like, as a part of
disintegration control in expressway dike and cut slops, stream bank security,
ground detachment capacities, filtration in street, fortification applications
in provisional unpaved streets, etc. (Pandey et al. 1989; Samajpati 1998). In
these applications, jute mainly preferred over the existing synthetic materials
due to their eco-friendly nature. Jute fiber has a splendid similarity with soil
and jute needle-punched nonwoven degrades in the soil within a couple of
months aiding in soil adjustment, cake development, and vegetation to soil to
develop plants (Majumdar 1999; 2001; Sengupta et al. 2008).
For the application of thermal insulation medium, the jute needle-
punched nonwovens are frequently preferred due to their thick and permeable
structure. The nonwoven contains uniformly scattered void or air, which is
in charge of thermal insulation. The added advantage of the jute fiber in the
use of thermal insulator other than structural aspect, the fiber itself a very
poor thermal conductive in nature. Based on the above-mentioned aspects,
the woollenised jute fibers were used in garments as a filler material against
cold weather as a warm garment (Debnath & Madhusoothanan 2011). Jute
needle-punched nonwoven may be a successful reinforcing agent for the
jute-based composites. By using jute needle-punched nonwoven fabric, the
products like tabletop, chair, washbasin, toolbox, signal casing, serving tray
rain pipe, corrugated sheet, fan blade, speaker box, and country boat have
been successfully developed. Also the jute-based needled fabric can be used
in decoration, furnishing, bags, soft luggage, apron, hat, gloves, file cover,
handicraft items (Sengupta et al. 2005).
Jute needle-punched nonwoven fabrics can be utilized as sound absorbent
medium effectively. The main benefits of using jute nonwoven material as
sound absorbent medium is their permeable surface and flexibility. These
properties act as reason for sound retentiveness inside the nonwoven. These
jute nonwovens can be utilized as wrapper of sound source or it can be utilized
as a part of the divider to lessen the resonations. Floor blankets utilizing natural
fibers (kenaf, jute, waste cotton, and flax) in mixes with polypropylene and
polyester were produced as checked needle-punched nonwoven for acoustic
retention in auto insides (Sengupta et al. 2008; Roy & Ray 2005; 2009). The
steady state growth of use of jute-nonwovens in the automotive sector is as
following (Ellison & McNaught 2000).
Natural fiber nonwovens 295
0.065 W/mK. A typical mineral wool has thermal conductivity in the extent
0.035–0.040 W/mK, wood 0.21 W/mK, air 0.026 W/mK. The authors had
mentioned that the developed hemp fiber hydroentangled nonwovens had a
phenomenal protection execution because of thermal insulation properties,
where thermal conductivity is from 0.031 to 0.040 W/mK (Carus et al. 2011).
The hemp fibers tows were traditionally used as insulation material between
timbers in earlier days. After 1990s, when hemp was rediscovered throughout
the world as an important raw material for bio-based products, their application
area becomes versatile (Kymäläinen 2004).
The bast fibers are commonly identified as better insulator material due to
their permeable structure, small diameter, and a low fiber bulk density. In case
of hemp fiber the bulk density is 1.48 g/cm3 and for glass fibers, it is 2.6 g/cm3.
This helps the hemp fiber a great deal of air entrapment between the fibers
and acts as an insulation material. Hemp nonwoven insulation can be utilized
as an option material for glass wool or mineral wool insulation materials,
and inward moistness regulation in structures. Furthermore, common fibers
are ignitable without buildups while glass fibers are most certainly not. In
result, incineration with energy recovery is a positive end-of-life alternative
as distinct option for reusing. Even after all these benefits, natural fibers
have also disadvantages, for instance, the increased moisture absorption,
flammability (Freivalde et al. 2011). Liga Freivalde et al. (2013) evaluated
the thermal properties of nonwoven samples of technical hemp fibers made
through the thermal bonding, needle punching and hydroentanglement. Their
results showed that hemp has the same or better thermal properties than
other commonly used thermal insulation materials, e.g. mineral wool. In the
comparative study results of different manufacturing technologies, the results
revealed that all the three hydro-entangled, thermal bonded and needle-
punched samples differ very less in their thermal conductivity.
In view of manufacturers point, the hemps fibers have high quality,
flexibility, ease of processing and recycling. But in the case of user point of
view, there are few drawbacks which still exist. These setbacks are arising due
to the purchasers’ newness to hemp fiber. Key inclinations of hemp fiber are its
high quality and low cost, and there are various organizations so far foreseeing
the usage of this fiber as it step by step propels into getting the chance to be
another option for manufacturers. Moreover, hemp fiber’s staple length and
quality can be modified by necessities of the purchaser. In spite of the way that
the business area is worth insightful, using better attributes of characteristic of
natural fibers results in lower value rejects, decreases downtime on the types
of equipments, minimizes loss of fiber amid preparation (Gbhat & Hrong
2005).
298 Nonwoven: Process, structure, properties and applications
1993). The inner part of the kenaf fiber, called as core is used as a panel in
manufacturing roof tiles, enlivening board substrates, floor tile substrates, and
certain auxiliary segments. Another direct application of kenaf fiber is waste
cleanup mats. Kenaf fibers treated with sodium hydroxide have been carded
and needle punched into 100% kenaf and kenaf/cotton mixed mats. These
mats are additionally biodegradable and have potential in the avoidance of
soil disintegration, the control of weeds, and cleanup of waste fluids (Tao &
Moreau, 1994). The various needle-punched nonwoven items like, lightweight
seeded grass mats, wild bloom mats, vegetable strips, erosion control mats,
oil retention tangles, cushions and pads, substrates for formed car parts, and
composites were developed from kenaf fibers or by using the cleaned of core
fibers as 100% or along with refined wood, synthetic and other natural fibers
as a blend (Fisher, 1994).
The study by de Guzman et al. (1982) was undertaken to explore a new
material for novel textile products from abaca, kenaf and pineapple fibers
using nonwoven techniques, specifically, needle-punching and adhesive-
bonding processes. One more advantageous aspect for nonwoven mats is that
they can be tailored by blending with another fiber to achieve the desired
mat properties. Tao et al. (1998) prepared nonwoven mats containing 100%
kenaf or kenaf/cotton blends. They have mentioned that adding cotton fibers
into kenaf mat increases mat strength and oil retention capacity, indicating
that the blended mats have 24 potential applications in the prevention of soil
erosion, weed control, and cleanup of waste liquids. Ramaswamy et al. (2003)
have attempted to develop nonwoven kenaf mats for high value and high-
volume end products like furniture, kitchen cabinets, fixtures, wall-coverings,
displays, and various other products. The researcher suggested that to make
kenaf mats as successful alternative materials for practical applications, the
processing has to be developed using conventional equipment in nonwoven
industries. Baldwin et al. (1999) demonstrated that nonwoven 100% kenaf
bast fiber mats could be used as a growth medium for the establishment of
some warm-season and cool-season grass species.
at this very moment fiber source (Adams et al. 1984; Heise & Vidaver 1989;
Witt & Knudsen 1993). There are two different kinds of fibers which can be
obtained from the common milkweed plant. The first one is the long, solid,
however fragile bast fiber and the next is the seed hair fibers known as floss.
It was found that, like elastic substance (in the latex), the nature of the bast
fibers fluctuated significantly with edaphic and climatic environment (the sort
of soil 16 the plant is developing in and the season, that is, dry or wet year).
Normal milkweed fiber (Asclepias syriaca) is a characteristic and
biodegradable different option for polypropylene fiber in oil sorbent
application. The microscopic evaluation revealed that, the lumina, or
inward structure of the seed fibers are hollow, which permits the oil to be
assimilated and held inside the individual fiber and also in the assembly.
Seed fibers are made out of 55% cellulose and 18% lignin. Since these mixes
are biodegradable, milkweed is an environmentally friendly distinct option
for polypropylene material in oil spill cleaning process (Das, Praba Karan,
& Rengasamy, 2011). Woven milkweed fibers have diverse properties than
individual fibers. Nonwovens assembly can frame chains or networks of
fibers that cooperate while keeping up attributes of individual fibers without
alter (Fotheringham, Mather, Wei, & Yang, 2003). Small size pores in the
nonwoven mess consider the retention and transportation of fluids and the
fibers hold the oil all the time. Since nonwovens of these milkweed fibers have
higher porosity than other fiber nonwovens, these nonwoven materials ought
to work the best at engrossing and holding oils.
Pretty nearly 300,000 tons of oil was spilled every year from a variety of
sources. From 1998 to 2007, more or less 2,800 tons of greasing up oil was
spilled every year in ports, adding to oil contamination (Fingas & Mervin,
2011). When oil has entered water, the properties of oil change, making
it harder to uproot. Thus it is imperative to prevent initial pollution of oil
from coming into contact with water and potentially emulsifying. Recently
cellulose-based materials like milkweed fibers have been examined for their
potential use in tidying up spilled oil on the grounds that they are effortlessly
biodegradable, yet other potential materials to replace the existing synthetic
materials like polypropylene and etc. (Hubbe, 2013). Milkweed and kapok
were natural fibers have been found to have comparative properties on oil
limits and recently used in oil spill cleanups.
In case of the oil sorption activities, even thought the polypropylene has
a high absorption capacity it possesses only minimum oil retention ability.
The research report mentions that during the first moment after oil retention,
a lot of oil is lost. From one minute to five minutes, the rate at which the oil
is discharged from the polypropylene is diminished rapidly. It is essential that
Natural fiber nonwovens 301
oil should be consumed, but it is also likewise critical that the oil is held for a
long time and not to discharge over into environment (Fotheringham, Mather,
Wei, & Yang, 2003). In the case of milkweed fibers, when milkweed fiber
retains oil, the condition of the oil changes from a fluid to a semi solid. This
makes the fiber to absorb more amount of oil than the expected quantity. The
researchers reported that at room temperature, milkweed has been indicated to
absorb approximately 40 g of oil for every 1 g of fibers (Chol & Cloud, 1992).
The thicker wax coat in the fiber inner structure aids the milkweed fibers to
absorb more oil than cotton and also provides improved oil retention. Further
it also evidenced that at a lower temperature, milkweed ingests more oil than
the elevated temperature. This phenomenon was explained by the researcher
as, the viscosity of the oil increases, the retention process becomes simpler.
However, the reduction in temperature affects the internal capillary action
of oil through the fiber pores and reduces the oil retention (Chol & Cloud,
1992). The researcher also evaluated the performance of the milkweed fiber,
after soaking it in water, the results demonstrated that the process reduced the
absorption capacities of the milkweed fiber. This cause was explained by the
authors as the hydrophobic nature is dominant in the stage, the capacity might
have reduced. Their study also confirmed that the deliberate uprooting process
in the milkweed fiber will allow the fiber to re-use and assimilate more oil
every time. In investigations of milkweed oil receptiveness, the capacity to
retain oil just somewhat diminished for rehashed uses, so the fibers could
possibly be reused for future utilization (Chol & Cloud, 1992).
Estabragh, one of the milkweed fibers, a natural silky indigenous, which is
generally extracted from a plant wildly grown in central plateau of the southern
regions of Iran (Bakhtiari et al. 2015). The lustrous acicular appearance and
physical properties of Estabragh fiber are very similar to other species which
totally belong to Aclepiadacae family. The Estabragh fibers possess very low-
density value of about 0.9 g/cm3 because of their hollow structural nature.
Nonwovens due to their technical and economical merits are used
extensively in numerous applications. These pliable fibrous structures can be
manufactured in various densities; thus in addition to their aesthetical aspects,
nonwovens also provide excellent sound insulation properties (Attenborough,
1971; Voronina, 1983, 1994). Hence, Sanaz Hassanzadeh et al. (2014)
evaluated the effect of needle-punching process parameters on the sound
absorption properties of Estabragh/polypropylene needle-punched nonwoven.
They have evaluated the predictor variables like fiber blend ratio, punch
density, and areal density. Their outcomes articulated that samples with higher
extent of Estabragh fibers can be viewed as more effective means for noise
absorption than the other proportion. This increased sound absorption capacity
302 Nonwoven: Process, structure, properties and applications
of the nonwoven fabric was due to the hollow structure of Estabragh fibers.
In general, the geometry of fibers and their arrangement within the structure
were the responsible for the acoustic performance of nonwoven structures.
Hence, the physical property of the constituent fibers of a nonwoven structure
was the main reason for the higher sound absorption nature of the assembly
(Tascan, 2005).
During the application of this natural fiber as a sound insulation material,
the researchers found two fundamental factors which influence the end use of
the nonwoven mat.
1. Higher the fiber entanglement achieved during needling operation
higher will be the sound retentiveness of the needled nonwoven
fabrics.
2. The increase in the areal density of the needle punching significantly
increases the energy loose in samples.
They researchers suggested that, due to their extraordinary characteristics
of the Estabragh fibers, these nonwovens can be used as a replacement of
conventional insulation materials in automotives and buildings. These
nonwoven materials were versatile; they can be used in different porosity
and mass rangers. Simple increment in the fiber per unit area will alter the
nonwoven mass and porosity. Hence, the fabric assimilates more solid. Also
it was found that the effect of punch density is insignificant as far as sound
absorption is concerned.
As connection to their previous study, researcher Sanaz Hassanzadeh et al.
(2014) further analyzed the four diverse controllable parameters incorporating
Estabragh fiber in the making of nonwoven fabric. They have analysed the
fiber ratio in blend, layer weight, punch density and the frequency of sound
were selected and the effects of each parameter on noise absorbency. They
have presumed that the proportion of entire distance across to fiber width
of Estabragh fibers is much higher than that of the hollow-polyester fibers.
For this situation, more the milkweed fiber in blend creates higher amount
of surface area of nonwoven subsequently than the normal nonwoven.
This creates more frictional losses of sound energy while it enters into the
nonwoven. Thus the tests would be resulted to the higher normal-incidence
sound Absorption Coefficient (NAC) values for the nonwoven with higher
Estabragh fiber content. The results additionally demonstrated that the layer
weight has critical impact on nonwovens acoustic execution. Expanding the
layer weight prompts builds the quantity of fibers inside of the structure which
thus brings about more sound energy losses.
Hasani et al. (2014) examined the effects of different thermal bonding
process variables such as Estabragh fiber ratio in blend, layer weight, needle-
Natural fiber nonwovens 303
The comparison of physical properties of natural fibers with sisal fibers were
listed in Table 8.4 (Vijayalakshmi et al. 2014). Latest studies had evidenced
that the sisal fibers has been utilized as a strengthening agent to replace
asbestos and fiberglass as well as an environment-friendly component in the
automobile industries (web.archive.org).
Table 8.4 Comparison of physical properties of natural fibers with sisal fiber
Physical properties Sisal Abaca Hemp Jute Linen Cotton
(leaf) (leaf) (bast) (bast) (bast) (seed)
brighter white colour. The cotton fibers might look a bit yellowish in colour
than kapok fiber. It is meaningful to mention that though both cotton and
kapok fibers appearance looks the same, the physical properties of both in
terms of length, diameter and moisture regain are different for each materials.
The careful microscopical examination of kapok fiber revealed that the kapok
fibers have a hollow tubular shape with a large lumen while cotton appears
like a kidney shape (Musa et al. 2011). In average the Kapok trees normally
reach 30–50 metres high Asian sub continent. Furthermore, the trunk can also
expand to 2.74 metres (9 feet) or 3.05 metres (10 feet) in diameter. The tree
is deciduous, which means it will shed all of its leaves during the dry time
(Mwaikambo, 2006).
The kapok fibers are traditionally used as a stuffing’s and fillings in
bedding, upholstery, life preservers and other water-safety equipment because
of its excellent buoyancy (Zhang et al., 2013), and for insulation against sound
and heat because of its air-filled lumen (Veerakumar and Selvakumar, 2012;
Xiang et al., 2013). The kapok fiber possesses an excellent heat retention
capacity. Hence, these fibers can be blended with other fibers to achieve
apparel fabrics with improved heat retention characteristics (Hong et al.,
2012). The other researchers studied the properties of kapok fiber nonwoven
developed by different manufacturing methods. Their experiment resulted the
findings like, for better performance, the nonwoven processing technology
should not be affect hollow of the kapok fiber. The nonwoven technology also
has an impact on products related performance like, products Gsm, different
thickness, permeability, heat retention, and compression elasticity were
different for various manufacturing methods (Li Suying et al. 2102).
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312 Nonwoven: Process, structure, properties and applications
A acicular 301
Aatcc 96, 136, 137, 153, 190, 204, aclepiadacae 301
207, 208, 312 acoustic 91, 187, 233, 257, 282, 291,
abaca 285, 286, 299, 304, 305, 306, 292, 294, 302, 310, 312, 313
309, 314 acrylamide 22, 23, 24, 25
abradant 194 acrylate-vinyl 23
abrasion 11, 12, 14, 84, 95, 104, 131, acute 162
162, 173, 189, 192, 194, 195, adaptable 133, 146, 220, 295
212, 225, 227, 232, 242, 260, add-on 132, 173, 175
268, 272, 274, 279
additives 1, 11, 15, 17, 27, 44, 132,
abrasive 25, 161, 162, 214, 269, 271, 172, 277
281, 282
adhesion 2, 3, 20, 26, 27, 84, 110,
absorbency 13, 30, 31, 89, 128, 131, 133, 151, 168, 182, 189, 263,
136, 160, 189, 200, 201, 205, 268, 274, 281
209, 228, 229, 275, 287, 302
adhesive 18, 19, 20, 22, 23, 24, 25,
absorbent 11, 13, 14, 22, 27, 28, 31, 26, 32, 91, 119, 133, 137, 152,
32, 66, 70, 146, 147, 151, 188, 160, 176, 177, 228, 243, 246,
201, 204, 208, 213, 226, 228, 251, 257, 262, 263, 268, 269,
229, 246, 260, 265, 269, 274, 270, 274, 279
275, 281, 282, 283, 287, 294,
310 adsorbent 271, 273, 274
absorption 10, 29, 132, 189, 196, adsorption 24, 198, 203, 274, 281,
199, 200, 201, 204, 205, 229, 288, 290, 298, 307
238, 252, 272, 273, 274, 285, adult 28, 230, 260, 276
287, 288, 289, 291, 292, 293, aerodynamic 34, 36, 43, 48, 66, 78,
297, 300, 301, 302, 314 94, 149, 246
abundantly 293, 307 aerosol 19, 207
acceptable 85, 128, 193, 206 agglomerate 4
accomplish 115, 126, 140 aggregate 37, 177, 224
acetate 13, 21, 22, 23, 24, 30, 94 agitation 17, 18, 74
316 Nonwoven: Process, structure, properties and applications
combifil 278 D
combs 51, 114 dams 214, 244
commodity 16, 292 danweb 64
compactness 103, 173 dash-boards 293
compartment 232, 233, 235 de-aerate 174
compressor 82, 83 de-lamination 99, 143, 242
concentric 15 deciduous 308
concrete 213, 221 decitex 261
cone-winding 123 decrystallization 178
constructions 121, 203, 237, 239, 274 deep-frozen 244
consume 160, 237 deformability 216
contifeed 44, 45 deionization 130
convection 141, 150 delamination 64, 255
copolymer 22, 23, 24, 25, 26 delta 54, 140
copper 165, 166, 276, 290, 291, 314 demineralized 307
cordage 295, 304, 305 dental 231
core-cladding 32 dermal 232
corona 278, 282 desizing 165
cosmetic 178, 230, 262 deteriorated 172
cosmetology 291 dewatering 125, 254
covelle 263 di-carboxylic 26
coverstock 25, 28, 29, 31, 150, 213, diapers 22, 58, 79, 80, 230, 251,
226, 257 260, 272, 285, 287, 304
creel 90 diaphragm 191, 194, 195, 206
crepe 246 diffusion 32, 178, 236, 275
cresol 26 dilo 29, 37, 92
cross-laid 4, 61, 97, 102, 117 dirt-holding 241
cross-lapper 60, 61, 99 dislodged 100, 108
crosslinking 157 disorienting 58
crude 304, 305 disperse 169
culvert 224 dispersion 23, 25, 71, 72, 73, 74,
curl 15, 17 89, 94, 150, 171, 172, 173, 174,
curtains 28, 214, 243 185, 281
cushions 299 disposables 3, 13, 88, 90, 143, 149
cyclodextrines 179 dissipate 128, 171
Index 319
non-hazardous 22 nottebohm 5
non-healing 232 novolak 25, 26
non-implantable 226 nozzle 18, 79, 217, 266
non-leachable 170 nozzles 79, 136, 175
non-splitting 90 nurseries 218, 220
non-stabilized 135 nylon 12, 13, 16, 18, 24, 26, 31, 75,
non-styled 113 80, 89, 113, 127, 141, 171, 211,
non-toxic 227 234, 261, 268, 269, 282
nonionic 168
nonlinear 101 O
nonstick 228
objective 128, 132, 193, 235, 240
nonwoven-layered 268
obliging 108
nonwovens 2, 3, 4, 5, 6, 7, 8, 10, 11,
12, 13, 14, 16, 19, 20, 22, 23, obtain 39, 59, 61, 108, 110, 191,
24, 25, 27, 30, 31, 32, 33, 35, 200, 309
36, 37, 39, 41, 49, 53, 58, 62, occur 105, 158, 281
68, 70, 74, 76, 80, 81, 85, 88, odor 188, 213, 232
89, 92, 93, 94, 95, 98, 111, 121, oekotech 213
126, 128, 130, 133, 134, 135,
off-seasonal 221
136, 137, 138, 139, 143, 148,
149, 151, 152, 153, 154, 155, offshore 213
156, 157, 158, 159, 160, 161, oil-repellent 172
166, 168, 169, 170, 171, 172, oil-spill 309
173, 174, 175, 177, 178, 179, olefin 223, 272
181, 182, 183, 184, 185, 189,
190, 191, 192, 193, 194, 198, oleophobic 189
208, 209, 210, 211, 212, 214, oligopolistic 10
215, 216, 217, 218, 219, 220, on-line 85
221, 222, 224, 225, 226, 227, onstream 92, 94
228, 229, 230, 231, 232, 234,
opacity 29, 81, 86, 87, 100, 272
235, 240, 242, 243, 244, 245,
246, 247, 248, 249, 250, 251, opaque 87, 106, 188, 197
257, 260, 262, 263, 264, 266, optical 193, 197, 199, 200, 202, 208
268, 269, 270, 272, 276, 278, optimizing 218
281, 283, 284, 285, 286, 287, orchestrated 110, 126
289, 290, 291, 292, 293, 294,
organic 23, 130, 286, 303, 304, 310
295, 296, 297, 298, 300, 301,
302, 303, 304, 305, 307, 309, organobromine 172
310, 311, 312, 313 organochlorine 172
norrköping 6 organohalogens 289
Index 327
orientation 26, 47, 48, 57, 59, 60, 61, particulate 24, 130, 208, 213, 239,
62, 66, 69, 78, 79, 81, 86, 87, 240, 249, 250, 269, 270, 271,
88, 89, 90, 91, 102, 108, 109, 276
138, 150, 181, 186, 196, 197, patented 222, 259, 260, 261
198, 199, 209, 210, 224
pathogens 275
orifices 78, 83
pathology 310
orthogonal 147 pavements 221
oscillating 187 pellets 77, 81, 168
osmosis 218, 237, 277, 278 pendulum 191
oven 31, 137, 139, 263 penetrate 105, 118, 121
overfeed 158 penetration 28, 100, 102, 103, 104,
overlapped 121 105, 110, 111, 116, 150, 174,
oxidation 178 183, 203, 204, 218, 222, 225,
oxygen 134, 289 275, 276, 279
penetrometers 207
perfojet 30
P perforation 156, 157, 224, 244
pacific 7 performance 2, 11, 12, 19, 20, 26,
packaging 24, 31, 188, 213, 244, 32, 33, 55, 79, 88, 92, 93, 192,
245, 247, 257, 262, 263, 293 195, 203, 208, 209, 216, 225,
packtech 213 229, 232, 234, 235, 237, 242,
250, 263, 266, 267, 275, 278,
padded 169, 173 282, 287, 290, 292, 295, 301,
pads 66, 150, 213, 214, 230, 231, 302, 305, 308, 309, 314
242, 245, 262, 276, 299 permeability 25, 92, 104, 105, 112,
panasonic 298 187, 189, 191, 195, 198, 199,
pant 230 204, 205, 207, 221, 222, 223,
panty 29, 230, 276 225, 231, 236, 238, 244, 289,
papermaking 2, 93, 160, 295 290, 308
papers 3, 89, 154, 262, 284, 304, 309 permittivity 207
para-aramid 252 perpendicular 4, 34, 57, 59, 62, 105,
129, 183, 200, 207
paraffin 22, 187
perpetually 286
parallelisation 47
pertaining 36
parcel 213, 214, 233, 295
pervasive 290, 296
partial-wrap 17
pesticides 215, 218, 219, 221, 296
particle 137, 207, 236, 237, 241,
252, 265, 269, 270, 271, 278, petroleum 307
283, 290, 291, 298 pharmaceutical 178, 237, 239
328 Nonwoven: Process, structure, properties and applications
stiffeners 156, 173, 293 surgical 13, 28, 70, 80, 89, 93, 131,
stitch-bonded 2, 3, 115, 116, 118, 204, 208, 214, 215, 226, 227,
154, 157, 214 229, 272, 275, 276, 277, 283,
stitchbonding 29 285
surround 159
stocking 10
sustainability 287
strategic 248, 287
sutures 19
strength-elongation 112
swabs 213
stretchable 11, 23
swatch 191
stretched 61, 105, 187
sweating 200
strike 204, 218
swelling 203
stripped 47
synthetic 2, 5, 12, 20, 22, 24, 25,
strips 53, 56, 100, 129, 299 35, 37, 38, 39, 44, 60, 61, 68,
strung 118 69, 72, 75, 86, 89, 90, 112, 128,
studies 183, 193, 294, 296, 306, 313 133, 147, 150, 160, 165, 171,
stylish 293 172, 177, 203, 204, 214, 221,
224, 227, 228, 229, 239, 247,
styrene 22, 23, 24, 25, 26, 30, 72, 252, 260, 262, 264, 277, 289,
132 290, 294, 296, 298, 299, 300,
subgrade 224 307
subject 69, 99, 100, 139, 295 syriaca 300
subliming 169
submicron 19
T
suction 63, 65, 66, 67, 72, 79, 89,
111, 125, 145, 159, 208 tablecloth 257
sued 156, 161 tabletop 294
sueder 161, 162 tackiness 143
sueding 161, 217 tactile 256
suitability 139, 185, 189 taguchi 303, 313
sulfate 26 tailor-make 95
sulfide 16 tailored 299
sulfonated 23 take-off 46, 49, 68, 188
sunlight 219 take-up 81, 100, 114, 200
superabsorbent 12, 89, 226 taken 34, 56, 58, 66, 106, 117, 129,
superhydrophobicity 314 135, 142, 190, 195, 202, 204,
superimposing 281 207
surfacing 28, 213 takes-in 59
surgeons 275 tampons 230
Index 335
V
U
vacuum 65, 72, 82, 84, 85, 86, 126,
ultra-fine 278 129, 135, 241, 277
ultra-hydrophobic 202 value-added 156
Index 337