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    Chemistry full portion test

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    Chemistry paper 2023-24

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    Chemistry full portion test

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    163 views6 pages

    Chemistry Paper 2023-24

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    spotify.test.premium2
    Chemistry full portion test

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    © All Rights Reserved
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    BUA oS ®@ CHENNAI SAHODAYA SCHOOLS COMPLEX (General Instructions) ~ ‘Please check that this question paper contains 8 printed pages. “© Please check that this question paper contains 33 questions. + Please write down the serial number ofthe question before attempting it Reading time of 15 minutes i given to read the question paper alone. COMMON EXAMINATION Class-12 (CHEMISTRY-043) SET-1 Time allowed: 3 hours Maximum Marks: 70 Read the following instructions carefully. (4) There are 33 questions inthis question paper with internal choice. (8) SECTION A consists of 16 multiple choice questions carrying I mark eack. (0) SECTION B consists of S short answer questions carrying 2 marks each. (d) SECTION C consists of 7 short answer questions carrying 3 marks each. (©) SECTION D consists of ? case - based questions carrying 4 marks each. SECTION E consists of 3 long answer questions carrying S marks each. (@) All questions are compulsory. (i) Use of tog tables and calculators is not allowed. SECTION A The following questions are multiple -choice questions with one correct answer. Each question carries 1 mark. There is no internal choice in this section. 1. Whats tue about the eel constant ofa conductivity cell? 4) Itchanges with change of electrolyte. by) Itchanges with change of concentration of electrolyte. ¢) It changes with temperature of electrolyte. Af it remains constant for a given cell. 2. Oxidation of toluene to benzaldehyde using chromyl chloride is called (2) Wurtz reaction (b)Fttig reaction @Etard's reaction (®Rosenmund’s reaction. 3. ‘The base which is present in DNA but not in RNA, is (@) Cytosine. ——_(b) Guanine, (Adenine. Otryenine 4, Which of the following orga ‘compounds answers both fodoform test as well as Fein’ test? ‘Ethanal (©) propanone (© Ethanol (@ methanot 5.” Which of the following alkyl halides will undergo'SN' reaction most readily? ~~ rae @ (CHy)C-F (&) (CHy)sC—C ©CHyC—Br WEuy,cH1 & CHENNAI SAHODAYA SCHOOLS COMPLEX 6. KMnO, acts as an oxidising agent in alkaline medium. When alkaline KMnO is treated with KI, iodide ion is oxidised to he _ - Oh wo 6105" ! @ 100. 7. Fora first order reaction, the time taken to reduce the initial concentration by a factor of % is 20 ‘minutes. Thus the time taken to reduce to 1/16 is @) 20 min (&) 10 min (©) 80min 65.40 min e number of structural isomers possible from the molecular formula Cy nitrogen gas on reaction with Nitrous aci i @s 2 ©3 4 9. Mark the correct order of decreasing ci which liberates 3 strength of the following compounds. (Phenol (i). m-Nitrophenol (ji). Methoxyphenol (iv). 2,4 — Dinitrophenol (v). 24,6 Trinitrophenol Mo rtvpdir(rtiiy ©) (iv) >GPG PGi) Gi >> >™) 10, The rate constant is numerically same for thre reactions of fist, second and tied onder respectively. Which one of the following is true for the rates of these reactions with concentration ‘greater than 1 M? fee quai @renen Gwen — ¥Wacncn —(@)thereis no definite relationship 11 The major product obtained on interaction of phenol with sodium hydroxide and carbon dioxide is (a) Salicyladehyde @f Salicylic acid (¢) Phthalic acid’ (d) Benzoic acid 12. Cerium (Z=58) is a Lanthanoid element, Which of the following statements about Cerium is incorrect? @) The common oxidation state of Cerium is +3 and +4, (&) The oxidation state of +3 is more stable than +4, {97 The +4 oxidation state of cerium is not known in solutions. (@) Cerium (1V) acts as a good oxidising agent. (Q. No. 13-16): Each of the following questions consists of two statements, one is Assertion and the other is Reason. Choose the correct option. (@) Both Assertion and Reason are true and Reason isthe correct explanation of Assertion, (b) Both Assertion and Reason are true but Reason isnot the correct explanation of Assertion, (©) Assertion is true but Reason is flse, (@ Assertion is false but Reason is true 13, Assertion(A) — Albumin is a globular protein, & _ Reason(R) ~ Polypeptide chain coils around to give a spherical shape 14, Assertion(A) — Molar conductivity of a weak electrolyte at infinite dilution cannot be determined ‘experimentally. O — Reason(R) — Kohlrausch’s law helps to find molar conductivity of a weak electrolyte at infinite ditutior a 15. Ascrtion(A) -Neopentyl alcohol on treatment wth Lucas reagent gives tubidity ater five rmintes. eae roan ean area en ZA CHENNAI SAHODAYA SCHOOLS COMPLEX Baths ASR freon” (0) Assertion(A) - Benzaldchyde isles eacive than ethanal towards nucleophi Reason(R) = All the-carbon atoms are sp? hybridised. SECTION B This section contains 5 questions with internal choice in one question. The following questions are very short answer type and carry 2 marks each. 17. A reaction is of second order with respect to a reactant, How will the rate ofthe reaction be affected ifthe concentration ofthis reactant is (7) doubled (i) reduced to half. Two liquids A and B on mixing form an ideal solution. At 30°C, the vapour pressure ofthe solution Containing 3 moles of A and 1 mole of Bis $50 mm Hg, But when 4 moles of X and 1 mole of Y ‘are mixed, vapour pressure of the solution thus formed is 560 mm Hg. What would be the vapour pressure of pure liquids A and B? 18, 19, a) What happens when chloroform is exposed to air and light. Give equation. b) What are Freons? Give an example. 20, Give reasons to suppor the answer: (@) Formic acid does not undergo HVZ reaction. (b) 3-Hydroxy pentan-2-one shows positive result to NaOH and iodine. (oR) Write about the following reactions with suitable equations (@) Stephen's reduction * (@)HVZ reaction y 21. Differentiate the following: — a) Globular proteins and Fibrous proteins — Fs b) RNA and DNA. SECTION C This section contains 7 questions with internal choice in one question. The following questions are short answer type and carry 3 marks each. 22. (i) Name the type of isomerism shown by the complex [Ag(NUs j_}[Fg(CN):] and waite the formula ofthe isomer. 1) On the bess of erystal field theory, write the delectronic configuration for dion if °. (Atomic number of Ni = 28) 23, Calculate E%ay and AG? for the following reaction at 25°C: ‘A+B (0.001 M) > A® (0.0001 M) +B Given Bzeu = 2.6805V, 1 F =96500 C mol 24. Give reasons for the following: is (@ Phenol is more acidic than methanol. ) The C-O-H bond angle in alcohols i slightly les than the tetrahedral angle (109°28"). Gii) (CHs)sC-O-CHy on reaction with HI gives (CH3))C-I and CHs-OH as the main produets and ‘not (CH3))C-OH and CHis-1. 3 a CHENNAI SAHODAYA SCHOOLS COMPLEX 25. Give simple chemical tests to distinguish between the following () Berzoic acid and Phenat (i Propanal and Propanone 3 (i) Benzldehyde and actehyde 26. The rate constant of rst order reaction increases rom 4% 10? Js to 24 107s when the ‘empertue changes from 300K to 350 K, Calculate the nergy of ectivaton (1og2= 0301, 1og3 = 0.4771, log4=0.6021, og 6 = 0.7782) 77. How can he fllowing conversion be cated out: (Aniline bromobenzene ‘of ompounds: i) Chlorobenzene to 4-chloroacetophenone Chloroethane to butane (oR) ‘Write the chemical equations as to what happens when: (0 Chlorobenzene is treated with Cl; (FeCl, Gi) Ethyl chloride is tested with AgNO, ( is weated with alcoholic KOH? 28. A first order reaction has arate constant of 0.0051 mi 2-bromopent {fwe begin with 0.10M concentration of ‘he reactant, what concentration of reactant will remain in solution after 3 hours? (ntilog of 03986 = 2.503) SECTION D ‘The following questions are case-based questions. Each question has an internal choice and carries 4 (14142) marks each Read the passage carefully and answer the questions that follow. zs 2, Wemerin 1858, propounded hs teary ofcortinaton compounds, He ebservedpropentes ae

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