Board Pattern Test-02 Arjuna JEE (2023)
CHEMISTRY
SECTION - A
Passage Type Questions (1–2) (2 × 4 = 8)
Passage I
1. Read the passage given below and answer the
following questions:
After the Bohr model of atom was put forward
postulating that electrons are revolving around the
nucleus in circular orbits, the next studies were
focussed on finding the energies of the electrons
revolving in different orbits, the radii of the
different orbits and the velocities with which the
electrons were revolving in different orbits. Bohr
himself had given a formula for calculation of
energies of different orbits (called stationary states
or shells). This formula is known as Bohr's formula.
Subsequently, formulae were derived for
calculation of radii of different orbits and the
velocities with which the electrons were revolving
in these orbits. As total energy is the sum of
potential energy and kinetic energy and knowing
that potential energy of an electron in the nth shell
is — Ze2/r, expression for kinetic energy can be Objective Type Questions (3–16)
found out. 3.
Answer the following questions
(i) Why is electronic energy taken as negative?
(1)
(ii) Calculate the radius of third orbit of He+ ion.
(1) 4.
(iii) The velocity of electron in the first orbit of
hydrogen atom is 2.18 × 106 ms–1. Then
calculate the velocity of electron in third
orbit of He+ ion. (1)
(iv) In the Bohr's orbit calculate the ratio of
kinetic energy to the total energy of the 5.
electron. (1)
Passage II
2. Read the passage given below and answer the
following questions:
There are two different approaches that have 6.
been put forward to explain the shapes of
molecules. These are Valence Shell Electron
Pair Repulsion (VSEPR) theory and
Hybridisation. VSEPR theory is based on the
repulsions among the electron pairs (bond pairs 7.
and lone pairs) present around the central atom
so that they take up the directions where there
are no further repulsions between them.
Hybridisation is based on mixing of atomic
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orbitals of an atom (empty, half-filled or fully-
filled) of comparable energy forming new
equivalent orbitals of same shape and energy,
called hybrid orbitals. These hybrid orbitals then
overlap with the orbitals of other atoms.
Overlapping may take place between two half-
filled orbitals or one empty and one fully filled
orbital. The direction of overlap gives the
direction of bonds formed and hence the shape
of the molecule or ion.
Observe the table carefully and answer the
questions given below.
(i) On the basis of VSEPR theory, explain
the shape of hydronium (H3O+) ion. (1)
(ii) On the basis of hybridisation, explain the
shape of PC15. Why does it easily
dissociate into PC13? (1)
(iii) H2O involves sp3 hybridisation. Then
why bond angle H–O–H is not equal to
109° 28'? Further, why bond angle in H2S
(H-S-H) is less than that in H2O ? (2)
(14 × 1 = 14)
Law of multiple proportions is illustrated by one
of the following pairs
(1) H2S and SO2 (2) NH3 and NO2
(3) Na2S and Na2O (4) N2O and NO
A nitric acid solution has a density of 1.41 g mL–
1
and mass percent of nitric acid in it being 69%.
The molarity of the solution will be
(1) 12.8 (2) 13.2
(3) 14.4 (4) 15.4
One mole of carbon atoms weigh 12 g. The
number of atoms in it is equal to
(1) 12 × 1023 (2) 6.022 × 1022
(3) 12 × 10 22
(4) 6.022 × 1023
The number of planar and spherical nodes is 4f-
orbital are respectively.
(1) 4 and 3 (2) 0 and 3
(3) 2 and 1 (4) 3 and 0
An element with mass number 81 has 31.7%
more neutrons than protons. The atomic number
of the element is
(1) 35 (2) 37
 (3) 38 (4) 39 (2) cyclic process: q = – w
(3) isochoric process: U = q
8. Identify the element for which electronic
configuration of +3 oxidation state is 3d5 (4) adiabatic process: U = –w
(1) Cr (2) Mn 16. When 1 mol of a gas is heated at constant volume
(3) Co (4) Fe temperature is raised from 298 to 308 K. Heat
supplied to the gas is 500 J. Then which
statement is correct?
9. The atomic number of the element unnilennium
is (1) q = w = 500 J, U = 0
(1) 109 (2) 119 (2) q = U = 500 J, w = 0
(3) 102 (4) 108 (3) q = 500 J, U = w = 0
(4) U = 0, q = w = – 500 J
10. In general the property (magnitudes only) that
shows an opposite trend in comparison to other
properties across a period is SECTION - B
Very Short Answer Questions (17–25) (9 × 2 = 18)
(1) Electron gain enthalpy
17. Calculate the number of atoms in each of the
(2) Electronegativity following
(3) Ionization enthalpy
(i) 52 moles of He (1)
(4) Atomic radius
(ii) 52 u of He. (1)
11. The shape of ClF3 molecule is
(1) Triangular (2) Pyramidal 18. State and explain the following
(3) T-shape (4) Linear (i) Aufbau’s principle (1)
(ii) Pauli’s exclusion principle. (1)
12. Among CH4, CO2, H2O and SO2, the bond angle
is the highest in 19. Calculate the uncertainty in the velocity of a
(1) CH4 (2) CO2 wagon of mass 3000 kg whose position is known
(3) H2O (4) SO2 to an accuracy of ± 10 pm
(Planck’s constant = 6.63 × 10–34J s).
13. I, II and III are three isotherms at T1, T2 and T3
20. Account for the following:
respectively as shown below. Temperature will
be in the order (i) Noble gases have positive electron gain
enthalpy.
(ii) Cation is smaller in size than its parent atom.

21. Write down the electronic configuration of O2+

ion on the basis of M.O.T. Also assign its bond
order and magnetism.

22. Define hybridization. What is the shape of XeF4?

(1) T1 = T2 = T3
(2) T1 < T2 < T3 23. Define Boyle’s law. How is it represented
(3) T1 > T2 > T3 mathematically?
(4) T1 > T2 = T3
24. What are the extensive and intensive properties?
14. Volume of the air that will be expelled from a
vessel of 300 cm3 when it is heated from 27°C to 25. Calculate w, q and U when 0.75 mol of an ideal
37°C at the same pressure will be gas expands isothermally and reversibly at 27°C
(1) 310 cm3 (2) 290 cm3 from a volume of 15 L to 25 L.
(3) 10 cm3 (4) 37 cm3
SECTION - C
15. Which one of the following equation does not Short Answer Questions (26–30) (5 × 3 = 15)
correctly represent the first law of
26. A compound containing carbon, hydrogen and
thermodynamics for the given process?
oxygen gave the following analytical data:
(1) isothermal process : q = –w
C = 40.0% and H = 6.67%
[2]
 Calculate the molecular formula of the
compound if its molecular mass is 180. 32. (i) To which block (s, p, d or f) and period does
the element with atomic number 50 belong?
27. What transition in the hydrogen spectrum would (ii) Explain the following (2)
have the same wavelength as the Balmer
(a) Ionization enthalpy of Mg is more than
transition from n = 4 to n = 2 of He+ spectrum?
that of Na and Al.
(b) Ionization enthalpy of nitrogen is more
28. Define the term ionization enthalpy. How does it
than that of oxygen.
vary along a period and along a group?
(c) Halogens have very high negative
electron gain enthalpies. Explain. (3)
29. Account for the following:
(i) Water is a liquid while H2S is a gas. 33. (i) Why vegetables are cooked with difficulty
at a hill station?
(ii) NH3 has higher boiling point than PH3.
(1)
(ii) Boiling point of HF is lower than that of
water. (ii) List the important postulates of kinetic
theory of gases.
30. (i) What is kinetic gas equation? (1) (2)
(ii) A sealed tube which can withstand a (iii) What will be the pressure exerted by a
pressure of 3 atmosphere is mixture of 3.2 g of methane and 4.4 g of
filled with air at 27°C and 760 carbon dioxide contained in a 9 dm3 flask at
mm pressure. Find the temperature above 27°C? (2)
which it will burst. (2)

SECTION - D
Long Answer Questions (31–33) (3 × 5 = 15)
31. (i) Define the following terms: (2)
(a) Molality
(b) Limiting reactant.
(ii) 3.0 g of H2 react with 29.0 g of O2 to form
H2O (3)
(a) Which is the limiting reactant?
(b) Calculate the maximum amount of H2O
that can be formed.
(c) Calculate the amount of the reactant left
unreacted.

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