PINNAACLE CLASSES
31. A reversible reaction is one which
(a) Proceeds in one direction
(b) Proceeds in both directions
(c) Proceeds spontaneously 37. When rate of forward reaction becomes equal to
(d) All the statements are wrong
32. Which of the following is a characteristic of a
reversible reaction
(a) Number of moles of reactants and products 38. In chemical reaction A ⇌ B , the system will be
are equal
(b) It can be influenced by a catalyst
(c) It can never proceed to completion
(d) None of the above
33. Which of the following reactions is reversible
(a)
H 2 + I 2 ⃗ 2 HI
(b) H 2 SO 4 +Ba (OH )2 ⃗ BaSO 4 +2 H 2 O
(c)
NaCl+ AgNO 3 ⃗ NaNO 3 + AgCl
(d) Fe+ S ⃗ FeS
34. All reactions which have chemical disintegration
(a) Is reversible
(b) Is reversible and endothermic
(c) Is exothermic
(d) Is reversible or irreversible and endothermic
or exothermic
35. In any chemical reaction, equilibrium is supposed
to be establish when
(a) Mutual opposite reactions undergo
(b) Concentration of reactants and resulting
products are equal
(c) Velocity of mutual reactions become equal
(d) The temperature of mutual opposite reactions
become equal
36. Which of the following conditions represents an
equilibrium
(a) Freezing of ice in a open vessel, temperature
of ice is constant
(b) Few drops of water is present along with air in
a balloon, temperature of balloon is constant
(c) Water is boiling in an open vessel over stove,
temperature of water is constant
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(d) All the statements (a), (b) and (c) are correct
for the equilibrium
backward reaction, this state is termed as
(a) Chemical equilibrium (b) Reversible state
(c) Equilibrium (d) All of these
known in equilibrium when
(a) A completely changes to B
(b) 50% of A changes to B
(c) The rate of change of A to B and B to A on
both the sides are same
(d) Only 10% of A changes to B
39. A chemical reaction is at equilibrium when
(a) Reactants are completely transformed into
products
(b) The rates of forward and backward reactions
are equal
(c) Formation of products is minimised
(d) Equal amounts of reactants and products are
present
N 2 + 3 H 2 2 NH 3
40. In the chemical reaction ⇌ at
equilibrium point, state whether
N H
(a) Equal volumes of 2 and 2 are reacting
N H
(b) Equal masses of 2 and 2 are reacting
(c) The reaction has stopped
(d) The same amount of ammonia is formed as is
N H
decomposed into 2 and 2
41. For the reaction PCl 3 ( g )+Cl 2 (g ) ⇌ PCl 5 ( g ) the
position of equilibrium can be shifted to the right by
(a) Increasing the temperature
(b) Doubling the volume
Cl
(c) Addition of 2 at constant volume
PCl 3
(d) Addition of equimolar quantities of and
PCl 5
42. According to law of mass action rate of a chemical
reaction is proportional to
(a) Concentration of reactants
 PINNAACLE CLASSES

(b) Molar concentration of reactants [ A ]3 [ B ]2 [C]

3 2
(c) Concentration of products (c) [ C ] (d) [ A ] [ B ]
(d) Molar concentration of products
50. In the reversible reaction A+ B ⇌ C+ D , the
43. In a reaction the rate of reaction is proportional to concentration of each C and D at equilibrium was
its active mass, this statement is known as K
0.8 mole/litre, then the equilibrium constant c will
(a) Law of mass action be
(b) Le-chatelier principle (a) 6.4 (b) 0.64
(c) Faraday law of electrolysis (c) 1.6 (d) 16.0
(d) Law of constant proportion
51. On a given condition, the equilibrium concentration
44. The active mass of 64 gm of HI in a two litre flask HI , H 2 I
of and 2 are 0.80, 0.10 and 0.10 mole/litre.
would be H +I
(a) 2 (b) 1 The equilibrium constant for the reaction 2 2 ⇌
2 HI will be
(c) 5 (d) 0.25
(a) 64 (b) 12
(c) 8 (d) 0.8
45. Under a given set of experimental conditions, with
increase in the concentration of the reactants, the
rate of a chemical reaction 52. In which of the following, the reaction proceeds
(a) Decreases towards completion
3 −2
(b) Increases (a) K=10 (b) K=10
(c) Remains unaltered (c) K=10 (d) K=1
(d) First decreases and then increases
53. Pure ammonia is placed in a vessel at temperature
46. The law of mass action was enunciated by where its dissociation constant (α ) is appreciable.
(a) Guldberg and Waage (b) Bodenstein At equilibrium
K
(c) Birthelot (d) Graham (a) p does not change significantly with
pressure
47. Theory of ‘active mass’ indicates that the rate of (b) α does not change with pressure
chemical reaction is directly proportional to the NH 3
(c) Concentration of does not change with
(a) Equilibrium constant
pressure
(b) Properties of reactants
H N
(c) Volume of apparatus (d) Concentration of 2 is less than that of 2
(d) Concentration of reactants
54. For the system A( g )+2 B( g ) ⇌C (g ) , the equilibrium
48. In the thermal decomposition of potassium chlorate concentrations are (A) 0.06 mole/litre (B) 0.12
2 K ClO3 ⃗ 2 KCl+3 O2 K
given as , law of mass action mole/litre (C) 0.216 mole/litre. The eq for the
(a) Cannot be applied reaction is
(a) 250 (b) 416
(b) Can be applied −3
(c) Can be applied at low temperature (c) 4×10 (d) 125
(d) Can be applied at high temp. and pressure
55. For the reaction A+2 B ⇌ C , the expression for
equilibrium constant is
49. For the system 3 A +2 B ⇌ C , the expression for
equilibrium constant is [ A ][ B ]2 [ A ][ B ]
[ 3 A ][2 B ] [C ] (a) [ C ] (b) [C ]
(a) C (b) [ 3 A ][2 B ]

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 PINNAACLE CLASSES
[C] [C ]
(c) [ A ][ B ]2 (d) 2[ B ][ A ]

56. For which of the following reactions does the

equilibrium constant depend on the units of
concentration
1 1
NO( g ) N 2( g )+ O2( g )
(a) ⇌2 2

Zn( s )+Cu(2aq+ )
Cu +Zn(2aq+ )
(b) ⇌ ( s)
C 2 H 5 OH ( l)+CH 3 COOH ( l) CH 3 COOC 2 H 5(l )+H 2 O(l )
(c) ⇌
(Reaction carried in an inert solvent)
COCl 2 ( g) CO +Cl
(d) ⇌ (g) 2 (g)

57. Unit of equilibrium constant for the reversible

H +I
reaction 2 2 ⇌ 2 HI is
−1 −2
(a) mol litre (b) mol litre
−1
(c) mol litre (d) None of these

N O NO 2
58. The decomposition of 2 4 to is carried out at
280 K in chloroform. When equilibrium has been
N O −3
established, 0.2 mol of 2 4 and 2×10 mol of
NO 2
are present in 2 litre solution. The equilibrium
N O 2 NO 2
constant for reaction 2 4 ⇌ is
−2 −3
(a) 1×10 (b) 2×10
−5 −5
(c) 1×10 (d) 2×10

59. In a reaction A+ B ⇌ C+ D , the concentrations of

A, B, C and D (in moles/litre) are 0.5, 0.8, 0.4 and
1.0 respectively. The equilibrium constant is
(a) 0.1 (b) 1.0
(c) 10 (d) ∞

60. In a chemical equilibrium A+ B ⇌ C+ D , when one

mole each of the two reactants are mixed, 0.6 mole
each of the products are formed. The equilibrium
constant calculated is
(a) 1 (b) 0.36
(c) 2.25 (d) 4/9

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